• Title/Summary/Keyword: Adhesive Properties

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A Study on the Development of a Dry PFB Method with High Fire Resistance (건식화 P0SCO E&C Fire Board (PFB)공법 개발에 관한 연구)

  • Kim, Woo-Jae
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.953-956
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    • 2008
  • The present study was to develop a dry PFB method similar to the existing gypsum board construction method in order to apply the existing wet PFB method that uses fire.resistant adhesive. It was found that the existing wet method can produce concrete compressive strength of 80MPa and fire resistance of 3 hours with 30mm PF boards. The goal of development in this study was fire resistance of 3 hours through dry construction of 15mm fire.resistant boards.According to the results of fire resistance test, when the dry PF method was applied, the temperature of the main reinforcing bar was 116$^{\circ}$C in 15mm, 103.8$^{\circ}$C in 20mm, and 94$^{\circ}$C in 25mm, and these results satisfied the current standards for fire resistance control presented by the Ministry of Land, Transport and Maritime Affairs. When a 3.hour fire resistance test was performed and the external properties of the specimen were examined, the outermost gypsum board hardly remained and internal PF board maintained its form without thermal strain.

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Fabrication and Evaluation of Composite Panel with Hat-shaped Stiffeners (모자(Hat)형 보강재를 가진 복합재 패널의 제작과 평가)

  • Kim, Geon-Hui;Lim, Do-Wan;Choi, Jin-Ho;Kweon, Jin-Hwe;Lee, Tae-Joo;Song, Min-Hwan;Shin, Sang-Joon
    • Composites Research
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    • v.23 no.2
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    • pp.31-39
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    • 2010
  • In this paper, composite panels with hat-shaped stiffeners were made using the co-curing, co-bonding and secondary bonding methods. Co-curing is a manufacturing method in which the hat part and the plate are cured simultaneously in a manner that is more cost effective than other methods. Co-bonding is a method in which the stacked prepregs are cured with other cured parts, and secondary bonding is a method in which cured parts are bonded together using an adhesive. A rubber mold was manufactured for co-curing of composite panel with hat-shaped stiffeners, and finite element analyses were done to evaluate the expanding pressure of the rubber mold consistent with the curing temperature. The manufactured panels were also evaluated using a 3-D measurement tester and an ultrasonic tester. Pull-off tests were performed to evaluate their mechanical properties.

The Mixture Ratio Effect of Epoxy Resin, Curing Agent and Accelerator on the Fatigue Behavior of FRMLs (프리프레그 제작용 에폭시 수지.경화제.경화촉진제 혼합비 변화에 따른 FRMLs의 피로거동 특성)

  • Song, Sam-Hong;Kim, Cheol-Ung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.4
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    • pp.592-601
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    • 2001
  • Fiber reinforced metal laminates(FRMLs) are new types of hybrid materials. FRMLs consists of high strength metal(Al 5052-H34) and laminated fiber with structural adhesive bond. The mixture ratio effect of epoxy resin$.$curing agent$.$accelerator on the fatigue behavior of FRMLs was investigated in this study. The epoxy, diglycidylether of bisphenol A(DGEBA), was cured by methylene dianiline(MDA) with or without an accelerator(K-54). Eight different kinds of resin mixture ratios were selected for the test ; five kinds of FRMLs(1) and three others of FRMLs(2). The relationship between da/dN and ΔK with variation of resin mixture ratio was studied. FRMLs(1) and FRMLs(2) indicated approximately 2 times and 2.2 times more improved maximum bending strengths in comparison with those of Al 5052-H34. The resin mixture ratio <1:1> in case of FRMLs(1) indicated the maximum fatigue life, while the resin mixture ratio <1:1:0.2> in case of FRMLs(2) indicated the maximum fatigue life. As results, FRMLs(2) turned out to have more effective characteristics on the fatigue properties and the bending strength than those of FRMLs(1).

Effect of Mixing Ratio of Amphoteric and Anionic Latices on Print Quality of Coated Papers (라텍스의 혼합비율이 도공지 품질에 미치는 영향)

  • 강태근;박규재;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.72-79
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    • 1999
  • The binder plays important roles in determining the quality of pigment coating. In addition to its primary role of binding the pigment to the base paper, the binder performs several other important functions. The binder, also referred to as the adhesive, is the dominant in the aqueous phase of the formulation. Thus it plays a major role in determining viscosity, rheology, water release, and setting time for the coating. Latices based on styrene-butadiene dominate the market for synthetic paper coating binders. Consumption is high and is expected to increase further due to the present tendeyncy toward high-solids coating. The purpose of this study is understanding the impact of various parameters of latex(i.e. Tg, Particle size) affecting prontabilities and optical properties of the coated papers, as well as providing basic information on the use of amphoteric latex for improving print qualities of coated papers. Recently, amphoteric latices, Which are cationic at low pH's but turn anionic at high pH's have attracted interests of paper scientists and engineers. Therefore we investigated the effect of the Tg(glass transition temperature) and particle size of amphoteric latex on the coating qualities. We also studied the effect of mixing ratios (Amphoteric / Anionic)of latex on the coating qualities. Our results showed that Tg and particle size of amphoteric latex have to be controlled for optimizing coated paper qualities. The formulation consisting of 10 parts of amphoteric latex and 5 parts of anionic latex gave best results in ink receptivity, smoothness, air permeability, opacity and sheet gloss. If the results hold for the industrial paper coatings, the amount of expensive amphoteric latex can be reduced while achieving best available printing quality.

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EFFECT OF ROASTED BARLEY TEA ON THE ADHESIVE PROPERTIES ON SALIVA-COATED HYDROXYAPATITE BEADS OF CARIOGENIC MUTANS STREPTOCOCCI (보리차(Hordeum vulgare var, hexastichon)가 수산화인회석에 대한 우식유발성 세균의 부착에 미치는 영향)

  • Kim, Young-Jae;Kim, Chong-Chul;Kim, Kack-Kyun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.29 no.4
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    • pp.618-624
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    • 2002
  • Effect of the roasted barley tea in commercial markets on the adherence to the saliva-coated hydroxyapatite(HA) beads and the cell surface hydrophobicity of Streptococcus mutans and Streptococcus sobrinus as cariogenic microorganism was examined in vitro. Adherence activity and hydrophobicity in bacteria tested in all the barley tea samples decreased and the values were different according to the type of tea and the type of treatment. The inhibition of bacterial adsorption to HA beads suggest that barley tea active molecules as catechins and melanoidins may adsorb to a host surface, preventing the tooth receptor from interacting with any bacterial adhesions. The obtained results showed that the barley tea may inhibit bacterial adherence, the first step of the pathogenesis of dental caries in which these microorganism are involved.

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A Study on Fabrication Conditions of Al-SiCp Composites by Squeeze Casting (Squeeze Casting에 의한 Al-SiCp 복합재료의 제조 조건에 관한 연구)

  • Kim, Sug-Won;Woo, Kee-Do;Han, Sang-Won
    • Journal of Korea Foundry Society
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    • v.14 no.5
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    • pp.471-479
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    • 1994
  • Al-2%Si-2%Mg alloy containing SiC particle in 20, $70{\mu}m$ were prepared by mean of squeeze casting with various pressure 50, 100, 150 and 220MPa respectively. The specimens were made by casting into $50{\Phi}{\times}100{\ell}$ mold under various squeeze conditions(pressures, pressurizing temperature, particle sizes). Mechanical properties(hardness, tensile strength, elongation and wear characteristics) were evaluated at room temperature with those various fabrication factors. It became feasible to make favorable Al-SiCp composite free from casting defects by the injection of Ar gas during melting and 100MPa pressure squeeze casting. However, pressure of 50MPa was not sufficient to avoid completely porosity formation as a result of precessing and shrinkage during solidification. As the particle size is smaller and the squeeze pressure is higher, the hardness and tensile strength at room temperature are higher. Cell size became smaller gradually with increase of squeeze pressure. With increase of squeeze pressure(MPa), wear behaviors of those composites were changed from adhesive into abrasive wear, and the tendency of above behavior became outstanding with increasing sliding speed. The chemical reaction(4Al+3SiC${\rightarrow}$$Al_4C_3+3Si$) is more accelerated at interface between SiCp and matrix with increase of squeeze pressure. Therefore $Al_4C_3$ intercompound and Si peak intensity is increased at interface.

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Improvement of Polishing Characteristics Using with and without Oxidant ($H_2O_2$) of Ti/FiN Layers (산화제($H_2O_2$)의 첨가 유무에 따른 Ti/TiN막의 CMP 연마 특성)

  • Lee, Kyoung-Jin;Seo, Yong-Jin;Park, Chang-Jun;Kim, Gi-Uk;Park, Sung-Woo;Kim, Sang-Yong;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.88-91
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    • 2003
  • Tungsten is widely used as a plug for the multi-level interconnection structures. However, due to the poor adhesive properties of tungsten (W) on $SiO_2$ layer, the Ti/TiN barrier layer is usually deposited onto $SiO_2$ for increasing adhesion ability with W film. Generally, for the W-CMP (chemical mechanical polishing) process, the passivation layer on the tungsten surface during CMP plays an important role. In this paper, the effect of oxidants controlling the polishing selectivity of W/Ti/TiN layer were investigated. The alumina ($Al_2O_3$) abrasive containing slurry with $H_2O_2$ as the oxidizer, was studied. As our preliminary experimental results, very low removal rates were observed for the case of no-oxidant slurry. This low removal rate is only due to the mechanical abrasive force. However, for Ti and TiN with $H_2O_2$ oxidizer, different removal rate was observed. The removal mechanism of Ti during CMP is mainly due to mechanical abrasive, whereas for TiN, it is due to the formation of metastable soluble peroxide complex.

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Electrochemical Characteristics of MnO2 Electrodes as a function of Manufacturing Process (제조공정에 따른 MnO2산화물 전극의 전기화학적 특성)

  • 김현식;이해연;허정섭;이동윤
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.486-491
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    • 2004
  • Dimensionally stable anode(DSA) can be used for the hydro-metallurgy of non-ferrous metals like as Zn, and the electrolysis of sea water. MnO$_2$ electrode satisfies the requirements of DSA, and has a good cycle life and a low overpotential for oxygen evolution. MnO$_2$ electrodes based on Ti matrix were prepared by using thermal decomposition method and also MnO$_2$ was coated on Ti and Pb matrix with DMF and PVDF compositions. The MnO$_2$ electrodes prepared by thermal decomposition method had very weak adhesive strength onto Ti matrix and MnO$_2$ layer was removed out so that electrochemical properties for MnO$_2$ were not investigated. The viscosity of solvent used as a binder of MnO$_2$ Powder increased with the increasing PVDF contents. The thickness of the MnO$_2$ layer on Pb matrix in DSA, which was prepared with 5 times dipping at the solution mixed with PVDF : DMF = 1 : 9, was 150${\mu}{\textrm}{m}$. When the ratio of PVDF to MnO$_2$ was lower than 1 : 6, the Pb electrode didn't show any reaction irrespective of the concentrations of DMF. However, When the ratio of PVDF to MnO$_2$ was higher than 1: 6, the Pb electrode showed constant current reactions and homogeneous cyclic voltammetry even though at a high cycle. The reason for the high current and homogeneous cyclic voltammetry is the good catalytic reactions of MnO$_2$ powder in electrode.

The Effect of Graphite and MoS2 on Endurance and Cutting Performance of Diamond Micro Blades (다이아몬드 마이크로블레이드의 내구성과 절삭성능에 미치는 흑연과 MoS2의 첨가효과)

  • Moon, Jong-Chul;Kim, Song-Hee
    • Journal of the Korean institute of surface engineering
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    • v.41 no.6
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    • pp.335-340
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    • 2008
  • Cutting performance and wear behavior were studied with the diamond micro-blade of Cu/Sn bond materials containing various amount of lubricant materials such as graphite and $MoS_2$. Measurement of instantaneous electric power consumption for cutting glass workpiece at the constant velocity was conducted and proposed as a method to assess cutting efficiency. The energy consumption of micro-blade for glass cutting decreased with the content of graphite and $MoS_2$ while wear amount of blade in volume increased with the amount of lubricant addition during the dicing test. It is because that hardness, flexural strength, and fracture toughness ($K_{IC}$) reduced with the amount of lubricant addition. Blades with $MoS_2$ additive showed higher mechanical properties than those with graphite additives when the same amount of the lubricant additive in wt.% was added. Due to the lower density of graphite than $MoS_2$, higher volume fraction of graphite could result in stronger effect on lowering electric power consumption by reducing the friction between blade and work piece however increasing wear rate due to the reduction in strength and fracture toughness. Adhesive wearing mode of micro blade could be remarkably improved by the addition of graphite as well as $MoS_2$.

Evaluation of Properties of Polymer-Modified Mortar with CSA (CSA를 혼입한 폴리머 시멘트 모르타르의 성능평가)

  • Joo, Myung-Ki;Lho, Byeong-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.1
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    • pp.35-44
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    • 2015
  • Two main parameters were examined such as CSA content and polymer-binder ratio to find effects on the strength, water absorption, chloride ion penetration depth, carbonation depth, length change and chemical resistance of polymer-modified mortar with CSA and EVA polymer powder (EVAPP). As results, compressive, flexural, tensile, adhesive strengths, and length change of the polymer-modified mortar with CSA and EVAPP increases with increasing CSA content and polymer-binder ratio, although the water absorption, chloride ion penetration depth, and carbonation depth decrease with increasing polymer-binder ratio and CSA content, and also the chemical resistance decreases. Such strength and durability development is attributed to the high tensile strength of EVA polymer and the improved bond between cement hydrates and aggregates because of the addition of EVAPP and CSA.