• Title/Summary/Keyword: Adhesion and Removal

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Applicability Assessment of Carbon Nanotube to Slow Sand Filtration for Bacteria Removal (박테리아 제거를 위한 완속 모래여과에서 탄소나노튜브의 적용성 검토)

  • An, Hee-Kyung;Park, Seong-Jik
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.12
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    • pp.873-878
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    • 2014
  • The applicability of carbon nanotube (CNT) to slow sand filtration for the removal of bacteria was studied using scanning electron microscope and column experiments. The morphology of CNT were investigated using scanning electron microscope and the CNT looked like a skein serving bacteria favorable site for adhesion. Column experiments were performed over a range of CNT filter depth, pH, and ionic strength. Bacteria removal efficiency was found to increase from 44.15% to 99.95% as the CNT filter depth increased from 1 cm to 5 cm, and 3 cm of CNT filter depth was required for significant removal of bacteria. pH increase from 5.5 to 8.5 decreased the bacteria removal efficiency, due to the electrostatic repulsion between bacteria and CNT at higher pH. Bacteria removal efficiency decreased from 97.25% to 70.90% as the ionic strength increased from 0 mM to 50 mM. This study demonstrated that the CNT can be applied to slow sand filtration for treating microbially contaminated water.

Increased Cell Surface Hydrophobicity of A Lipopolysaccharide-defective Mutant of Bradyrhizobium japonicum

  • JAE-SEONG S0;PAE, KYEONC-HOON
    • Journal of Microbiology and Biotechnology
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    • v.5 no.4
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    • pp.241-243
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    • 1995
  • A lipopolysaccharide (LPS) defective mutant of Bradyrhizobium japonicum was characterized in terms of its cell surface hydrophobicity (CSH). By monitoring the kinetics of adhesion to hexadecane the LPS mutant was found to be far more hydrophobic than the wild type strain; the removal coefficients were 4.65 $min^{-1}$ for the mutant, as compared with only 2.40 $min^{-1}$ for the wild type. The possible role of cell surface hydrophobicity of B. japonicum in nodulation process is discussed.

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Development of a New Process for PVA Degradation in Desize Wastewater by lmmobilized Symbiotic Bacteria (고정화 공생 Bacteria를 이용한 호발폐수 중 PVA분해 신공정 개발)

  • 김정목;조무환조윤래정선용
    • KSBB Journal
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    • v.6 no.4
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    • pp.395-402
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    • 1991
  • A new process was developed to degrade PVA(polyvinyl alcohol) in desize wastewater. Two symbiotic bacteria of Pseudomonas strain G5Y and PW were immobilized on the media by adsorption. A natural zeolite was chosen as the best media considering cell adhesion capacity, sedimentation rate, and material cost. PVA and COD removal efficiencies of this system for synthetic wastewater were 84% and 85% at the retention time of 6 hr, when the volumetric loading rate was PVA 8g/L·day and COD 8g/L·day, and cell density was 19,775 mg/L. In case of desire wastewater, they were 78% and 72% at the retention time of 6 hr, respectively, when the volumetric loading rate was PVA 8g/L·day and COD 13.2g/L·day, and cell density was 32,899mg/L. In case of desize wastewater, PVA and COD removal efficiencies were lower than synthetic wastewater, but cell density of the desize wastewater was lower than that of the synthetic wastewater, because there were insufficiency of necessary nutrition and variety of desize materials in the desize wastewater. A pilot test was successfully performed showing 88% and 82%, PVA and COD removal efficiencies at the retention time of 24 hr, when volumetric loading rate were 4.7 PVA g/L·day and COD 6.9g/L·day, and cell density was 12,,324 mg/L.

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Nitrogen and Phosphorous Removal from Wastewater by SBBR(Sequencing Batch Biofilm Reactor) System (연속회분식 생물막 반응기를 이용한 폐수중의 질소.인 제거)

  • 김조웅;이정복;최대건;임윤택;김두현;황재웅;이용희;반용병
    • KSBB Journal
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    • v.13 no.6
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    • pp.638-643
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    • 1998
  • An investigation was made to develop new biofilm medium which could be applied to the Sequencing Batch Biofilm Reactor(SBBR) system for enhanced nutrient removal. 21 kinds of polyurethane media were tested fro adhesion ability for nitrifying bacteria. Nitrification rates were also tested by introducing synthetic wastewater containing ammonium-nitrogen to reactors with biofilm media. It was found that Z96-06 medium had higher selective adhension ability for nitrifying bacteria than the other biofilm media. The nitrification rate was 2.21 mg {{{{ { NH}`_{4 } ^{ +} }}}}-N /L$.$h$.$g MLSS when we operated the SBBR system containing Z96-06. Nitrification rate of the SBBR system increased approximately by 30% compared with that of the Sequencing Batch Reactor(SBR) system which did not contain biological carrier.

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Fundamental Structure in Simultaneous Removal for Phytoplankton and Nutrient Salt in Lakes

  • SEKI, Tatsuhiro;ISHII, Yuuichi;ISHII, Toshio;TAKI, Kazuo
    • Environmental Engineering Research
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    • v.14 no.4
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    • pp.220-225
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    • 2009
  • The water quality in eutrophic lakes is affected by serious problems, such as abnormal increasing of Cyanobacteria. The purpose of this study was to investigate the possibility of a modified flotation system using a hybrid technique formed by chemical compounds and an electrostatic bridge. Therefore, experiments using the hybrid technique were performed to measure the zeta potential value on the phytoplankton surface and the removal efficiencies of phytoplankton, ammonia nitrogen, nitrate nitrogen and phosphoric acid. The results were as follows: Firstly, the zeta potential of M.aeruginosa was observed to approach charge neutralization due to adhesion of magnesium hydroxide precipitate on the phytoplankton surface in the pH range 10.5 to 11. Secondly, the concentration of chlorophyll-a decreased from about 150 to 20${\mu}g$g/L, with a maximum removal efficiency of 84% due to coagulation with pH values higher than 10. Thirdly, the N$H_4$-N concentration was observed to decrease from 0.62 to 0.54mg-N/L (13%), and the P$O_4$-P concentration, which is a limiting factor to the formation of algae blooms, decreased from 0.27 to 0.02mg-P/L (92%). These findings suggest that the modified flotation system can be applied for the purification of the raw water of numerous lakes containing high phytoplankton populations and elevated pH.

Interfacial Electrical Studies on Adhesion of Hematite Particle to Polyester Fabric and its Removal from the Fabric(Part I) -The interaction energy between particle and fabric- (Polyester직물에의 Hematite입자의 부착과 제거에 관한 계면전기적 고찰(제1보) -기질과 입자간의 상호작용에너지-)

  • Kang, In-Sook;Kim, Sung-Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.3
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    • pp.380-390
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    • 1993
  • Effect of interfacial electrical conditions on adhesion of ${\alpha}-Fe_2O_3$ particles to PET fabric and the removal of ${\alpha}-Fe_2O_3$ particles from PET fabric, were investigated as functions of pH, electrolyte and ionic strength. The ${\zeta}$ potential of PET fiber and ${\alpha}-Fe_2O_3$ particles in the electrolyte solution were measured by streaming potential and microelectrophoresis methods respectively. The potential energy of interaction between ${\alpha}-Fe_2O_3$ particles and PET fabric were calculated by using the heterocoagulation theory for a sphere-plate model. The negative ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle and PET fiber increased with pH, and then decreased certain pH and isoelectric points of ${\alpha}-Fe_2O_3$ particles and PET fiber were pH 6.5 and pH 3.5, respectively. The negative ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle and PET fiber affected by electrolytes, were relatively high with polyanion electrolytes in solutions and were low with neutral salts. However, at surfactant solution, ${\zeta}$ potential was levelled off. The influence of the ionic strength on the ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle was small but the negative ${\zeta}$ potential of PET fiber increased with the ionic strength. In the presence of anionic surfactant, the ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle and PET fiber increased regardless of solution conditions. The interaction energy between ${\alpha}-Fe_2O_3$ particle and PET fabric increased with pH. The interaction energy was relatively high with polyanion electrolytes in solution, and the influence of ionic strength on the interaction energy was small, and the effective thickness of electrical double layer increased with decreasing the ionic strength.

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Improvement of Polishing Characteristics Using with and without Oxidant ($H_2O_2$) of Ti/FiN Layers (산화제($H_2O_2$)의 첨가 유무에 따른 Ti/TiN막의 CMP 연마 특성)

  • Lee, Kyoung-Jin;Seo, Yong-Jin;Park, Chang-Jun;Kim, Gi-Uk;Park, Sung-Woo;Kim, Sang-Yong;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.88-91
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    • 2003
  • Tungsten is widely used as a plug for the multi-level interconnection structures. However, due to the poor adhesive properties of tungsten (W) on $SiO_2$ layer, the Ti/TiN barrier layer is usually deposited onto $SiO_2$ for increasing adhesion ability with W film. Generally, for the W-CMP (chemical mechanical polishing) process, the passivation layer on the tungsten surface during CMP plays an important role. In this paper, the effect of oxidants controlling the polishing selectivity of W/Ti/TiN layer were investigated. The alumina ($Al_2O_3$) abrasive containing slurry with $H_2O_2$ as the oxidizer, was studied. As our preliminary experimental results, very low removal rates were observed for the case of no-oxidant slurry. This low removal rate is only due to the mechanical abrasive force. However, for Ti and TiN with $H_2O_2$ oxidizer, different removal rate was observed. The removal mechanism of Ti during CMP is mainly due to mechanical abrasive, whereas for TiN, it is due to the formation of metastable soluble peroxide complex.

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Role of oxidant on polishing selectivity in the chemical mechanical planarization of W/Ti/TiN layers (W/Ti/TiN막의 연마 선택비 개선을 위한 산화제의 역할)

  • Lee, Kyoung-Jin;Seo, Yong-Jin;Park, Chang-Jun;Kim, Gi-Uk;Kim, Sang-Yong;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.33-36
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    • 2003
  • Tungsten is widely used as a plug for the multi-level interconnection structures. However, due to the poor adhesive properties of tungsten (W) on $SiO_2$ layer, the Ti/TiN barrier layer is usually deposited onto $SiO_2$ for increasing adhesion ability with W film. Generally, for the W-CMP (chemical mechanical polishing) process, the passivation layer on the tungsten surface during CMP plays an important role. In this paper, the effect of oxidants controlling the polishing selectivity of W/Ti/TiN layer were investigated. The alumina $(Al_2O_3)$ abrasive containing slurry with 5 % $H_2O_2$ as the oxidizer, was studied. As our preliminary experimental results, very low removal rates were observed for the case of no-oxidant slurry. This low removal rate is only due to the mechanical abrasive force. However, for Ti and TiN with 5 % $H_2O_2$ oxidizer, different removal rate was observed. The removal mechanism of Ti during CMP is mainly due to mechanical abrasive, whereas for TiN, it is due to the formation of metastable soluble peroxide complex.

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Half-degumming Behaviors of Raw Silk Yarns Degummed with Soap and Alkalis (비누와 알칼리에 의한 실크 생사의 반숙정련 거동)

  • Park, Geon-Yong
    • Textile Coloration and Finishing
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    • v.22 no.4
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    • pp.349-355
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    • 2010
  • To investigate the half-degumming of raw silk, the degumming was carried out with soap or sodium carbonate or sodium bicarbonate and some mixed agents at $80^{\circ}C$ for 15 and 30 minutes. With soap of 20~25%o.w.f. degumming losses were about 7~12%. Degumming losses with sodium carbonate of 2~5%o.w.f. were about 6~15%. And about 6~12% wright losses were observed in the degumming with sodium bicarbonate of 20~30%o.w.f. In the degumming with the mixed degumming agents of soap and sodium carbonate, degumming losses were 9~15% with 5%o.w.f. soap and 2~5%o.w.f. sodium carbonate. Sodium carbonate was more effective on the removal of sericin from raw silk than soap. During drying generally half degummed silk yarns stuck together to result in harsh and hard lumps by the adhesion and solidification of the residue sericin of partially degummed silk. Sodium hydrosulfite in degumming agent effectively protected the adhesion of half degummed silk yarns.

Effects of Alkali Treated Nano-kenaf Fiber in Polypropylene Composite upon Mechanical Property Changes (알카리로 처리된 나노케냐프 섬유가 PP 복합소재 내에서 기계적 물성 변화에 미치는 영향)

  • Oh, Jeong Seok;Lee, Seong-Hoon;Kim, Kwang-Jea
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.99-106
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    • 2015
  • The surface of nano-kenaf containing cellulose fibers was treated with alkali (NaOH) and their effects on the physical properties of the polypropylene (PP) composite were investigated. The treatment of alkali on the fibers increased the melt flow index (M.I.), elongation%, and impact strength, while it decreased the tensile strength, flexural modulus and heat deflection temperature (HDT) of the compound compared to the untreated one. It seemed the alkali treatment on the nano-kenaf fiber changed the character of the fiber due to removal of impurities and chemicals on the surface and resulted in decreased interfacial adhesion between the nano-fiber surface and the PP matrix and changed the character of the PP.