• Title/Summary/Keyword: Adhesion Properties

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Evaluation of physical properties of Zn-Al metal coating according to arc metal spray surface treatment method (아크 금속 용사 표면 처리 방법에 따른 Zn-Al 금속 용사 피막의 물리적 특성 평가)

  • Jang, Jong-Min;Kim, Yeung-Kwan;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.89-90
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    • 2022
  • Arc metal spraying is a widely used method for improving the performance of construction structures such as corrosion resistance and electromagnetic wave shielding. However, when arc metal spraying is applied to a concrete structure, adhesion performance may deteriorate. Therefore, the effect of each surface treatment method on the physical properties between the arc metal spray coating and concrete was reviewed by evaluating the deposition efficiency and adhesion performance according to the arc metal spray surface treatment method (surface reinforcing agent, roughening agent, and sealing agent). As a result, it is suggested as an optimal surface treatment condition to induce non-interface failure by using a roughening agent and to improve the properties of concrete and metal coatings by applying a surface reinforcing agent and sealing agent.

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Study on the Thermal Properties and Adhesion Strength of Amorphous Polyalphaolefins/Petroleum Resin Blonds as a Hot Melt Adhesive (핫 멜트 접착제로 사용되는 비 결정성 올레핀 수지/석유수지 블렌드의 열적 성질 및 접착성에 관한 연구)

  • 홍인오;김환기;강호종
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.513-519
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    • 2000
  • The effect of petroleum resin as a tackifier for polyalphaolefin (APAO) hot melt adhesive on thermal properties, crystallinity and adhesion strength was investigated. The presence of petroleum resin resulted in the melting temperature decrease in APAO/petroleum blend, especially, in APAO with low ethylene content/C$_{5}$ petroleum blend. It was also found that petroleum resin caused the decrease of crystallinity regardless of ethylene content in APAO. The maximum adhesion strength was found to be at 50/50 (APAO/petroleum) composition. $C_{5}$ resin was more effective to increase adhesion strength than $C_{9}$ for APAO with high ethylene content. In addition, it was found that the adhesion strength was improved with the decrease of crystallinity in APAO/petroleum resin hot melts.

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Effect of 1,6-Hexamethylenediamine Content on the Properties/Adhesive Strength of EVA/Itaconated EPDM Blend Foams (I) (헥사메텔렌 디아민이 EVA/Itaconated EPDM 블렌드 발포체의 물성 및 접착강도에 미치는 영향 (I))

  • Jung, Hyun-Ji;Lee, Young-Hee;Kim, Jung-Soo;Lee, Dong-Jin;Kim, Sung Yeol
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.107-116
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    • 2018
  • Simplification of the manufacturing process in shoe making is essential to improve productivity and reduce production costs. To improve the adhesion of EVA foam used as a midsole, EVA/itaconated EPDM(EPDM-g-IA)(80/20wt%) blend was prepared using Torque Rheometer-Plasti-Corder, and 1,6-hexamethylenediamine/crosslinking agent/foaming agent/additive were mixed, followed by amidation reaction and foaming to prepare EVA/EPDM-g-IA foam for shoe midsole. In this study, we investigate the effect of the content of 1,6-hexamethylenediamine(0, 0.5, 1.0, 2.0, 3.0) on the mechanical properties, water-contact angle and adhesion of EVA/itaconated EPDM foam. As the content of 1,6-hexamethylenediamine increased, mechanical properties such as tensile strength, tear strength, tensile elastic modulus, hardness, and water-contact angle were lowered, but elongation at break and compression set(%) were increased. Both normal type and non-UV type adhesive strength increased with increasing diamine content. In particular, it was found that the adhesion strength of the non-UV type adhesion increased sharply with increasing diamine content. As a result, an adherend rupture occurs in a foam sample having a content of 1,6-hexamethylenediamine of 3phr. From this, it can be seen that the EVA/itaconated EPDM foam for shoe midsoles, which can be used for non-UV adhesion without primer and UV treatments, have been developed.

Adhesion of Bifidobacteria to Caco-2 Cells and in Relation to Cell Surface Hydrophobicity (비피도박테리아의 Caco-2 세포에 대한 부착성과 세포 표면 소수성)

  • Lim, Kwang-Sei;Huh, Chul-Sung
    • Food Science of Animal Resources
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    • v.26 no.4
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    • pp.497-502
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    • 2006
  • The adhesion of 16 bifidobacterial strains, including 10 isolates from Korea infants, to Caco-2 cells and their cell surface hydrophobicity were tested. The results of adhesion and cell surface hydrophobicity of for various bifidobacterial strains were obtained and correlations between adhesion and hydrophobicity were strain-dependent properties. Any correlations between species of tested strains were not observed. Among the tested strains, Bifidobacterim longum D6, B. longum H4, B. thermophilum ATCC 25525, B. suis ATCC 27533, and B. animalis subsp. lactis BB12 had higher adherent properties and B. bifidum B3, B. longum D6, B. longum stronger hydrophobicity, respectively. Due to the strain-dependant correlation between adhesion to Caco-2 cells and cell surface hydrophobicity of bifidobacteria, these results provide a possible method for preliminary selection of bifidobacteria potentially adherent to Caco-2 cells by means of cell surface hydrophobic properties.

The morphology and mechanical properties of the blends of syndiotactic polystyrene and polystyrene-block-poly(ethylene-co-butylene)-block-polystyrene copolymers

  • O, Hyun-Tack;Kim, Hwang-Ryong;Kim, Jin-Kon;Park, Joon-Young
    • Korea-Australia Rheology Journal
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    • v.13 no.2
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    • pp.83-87
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    • 2001
  • The morphology and mechanical properties of the blends of a syndiotactic polystyrene (SPS) and poly-styrene-block-poly(ethylene-co-butylene)-block-polystyrene copolymers (SEBS) with various polystyrene block contents are studied. Mechanical properties, especially elongation at break and impact strength (IS), of the blend depend upon the morphology and interfacial adhesion, which in rum are affected by the viscosity ratio of constituent components and the styrene block content in SEBS. The IS of a blend was affected by the combined effect of rubber content and the interfacial adhesion. A maximum IS was found for a blend with the weight fraction of the PS block in an SEBS of 0.18. The IS of blends with smaller weight fractions of the PS block exhibited lower due to poor interfacial adhesion between SPS/SEBS in spite of a larger amount of rubber block. On the other hand, the IS of blends with larger weight fraction of the PS block becomes smaller due to lower amounts of rubber block in spite of better interfacial adhesion.

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Effect of Ni Bond Coat on Adhesive Properties of Fe Coating Thermal Sprayed on Al Substrate (Ni 본드코팅이 Al 기지에 고온 용사 코팅된 Fe 코팅층의 접합특성에 미치는 영향)

  • Kwon, Eui-Pyo;Kim, Dae-Young;Lee, Jong-Kweon
    • Korean Journal of Materials Research
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    • v.26 no.10
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    • pp.542-548
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    • 2016
  • The influence of NiCrAlY bond coating on the adhesion properties of an Fe thermal coating sprayed on an Al substrate was investigated. By applying a bond coat, an adhesion strength of 21MPa was obtained, which was higher than the 15.5MPa strength of the coating without the bond coat. Formation of cracks at the interface of the bond coat and the Al substrate was suppressed by applying the bond coat. Microstructural analysis of the coating interface using EBSD and TEM indicated that the dominant bonding mechanism was mechanical interlocking. Mechanical interlocking without crack defects in the coating interface may improve the adhesion strength of the coating. In conclusion, the use of an NiCrAlY bond coat is an effective method of improving the adhesion properties of thermal sprayed Fe coatings on Al substrates.

Dielectric properties of Pt/PVDF/Pt modified by low energy ion beam irradiation

  • Sung Han;Yoon, Ki-Hyun;Jung, Hyung-Jin;Koh, Seok-Keun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.110-110
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    • 1999
  • Polyvinylidenefluoride (PVDF) is most used in piezoelectric polymer industry. Electrode effect on the electrical properties of PVDF has been investigated. al has been used due to fair adhesion for PVDF. Work function of metal plays an important role on the electrical properties of ferroelectrics for top and /or bottom electrode. However, Al has much lower work function than Pt or Au and so leakage current of Al/PVDF/Al may be large. Pt or Au has not been used for electrode of PVDF system due to poor adhesion. PVDF irradiated by Ar+ ion beam with O2 environment takes good adhesion to inert metal. Contact angle of PVDF to triple distilled water was reduced from 75$^{\circ}$ to 31$^{\circ}$ at 1$\times$1015 Ar+/cm2. Working pressure was 2.3$\times$10-4 Torr and base pressure was 5$\times$10-6 Torr. Pt was deposited by ion beam sputtering and thickness of pt film was about 1000$\AA$. in previous study, enhancing adhesion of Pt on PVDF was shown. in this study, effect of electrode on PVDF will be represented.

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Surface Modification of Polyester by UV-irradiation with Oxidizing Agent, and Its Adhesion Property (자외선/산화제 처리에 의한 폴리에스테르의 표면개질 및 접착성)

  • 최창남;김종배;김상률
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.50-56
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    • 1999
  • The adhesive properties of polyester cord in rubber matrix were investigated according to the surface modification. The polyester cord was oxidized in sodium hypochlorite solution, and graft-polymerized with acrylic acid under the irradiation with ultraviolet light, and then coated with resorcinol-formaldehyde latex (RFL). The modified surface was checked with scanning electron microscope. The adhesive properties were measured by the full-Out method, and evaluated with regard to the energy of adhesion and the maximum load. The polyester was not oxidized in sodium hypochlorite solution, so the surface was not able to etch to produce the coarse topology. As the concentration of acrylic acid and the reaction time were increased, the graft yields were also increased. It was considered that the acrylic acid would swell the polyester and diffuse easily to the inner side of substrate. The adhesive properties of polyeser to rubber matrix were affected by the surface condition. Namely, the maximum load was almost same, but the energy of adhesion was rather higher In the polyester grafted with acrylic acid than in control one. We concluded that the flexible aliphatic chains of polyacrylic acid situated in the interface of cord and rubber matrix were distributed well the stress and strain all over the filler resulting the high energy of adhesion.

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Studies on Mechanical Properties of Thermoplastic Vulcanizate Containing Acid Group (Acid Group이 도입된 TPV (Thermoplastic Vulcanizate)계 열가소성 탄성체의 기계적 물성에 관한 연구)

  • Kim, Dong Ho;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.16 no.2
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    • pp.63-68
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    • 2015
  • We synthesized thermoplastic polyurethane elastomer containing carboxylic acid group and TPV (thermoplastic vulcanizate). We measured the mechanical, grip, debris, contact angle and adhesion properties according to introducing acid group in elastomer structure. Mechanical and wet slip properties were improved because of the hydrogen bonding by introduction of acid group. Also adhesion strength was increased as increasing of surface polarity by carboxylic acid group. The debris property of TPV made from TPU containing carboxylic acid group was improved.

Investigation on Mechanical Property and Adhesion of Oxide Films Formed on Ni and Ni-Co Alloy in Room and High Temperature Environments

  • Oka, Yoshinori I.;Watanabe, Hisanobu
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.145-151
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    • 2008
  • Material degradation such as high temperature oxidation of metallic material is a severe problem in energy generation systems or manufacturing industries. The metallic materials are oxidized to form oxide films in high temperature environments. The oxide films act as diffusion barriers of oxygen and metal ions and thereafter decrease oxidation rates of metals. The metal oxidation is, however, accelerated by mechanical fracture and spalling of the oxide films caused by thermal stresses by repetition of temperature change, vibration and by the impact of solid particles. It is therefore very important to investigate mechanical properties and adhesion of oxide films in high temperature environments, as well as the properties in a room temperature environment. The oxidation tests were conducted for Ni and Ni-Co alloy under high temperature corrosive environments. The hardness distributions against the indentation depth from the top surface were examined at room temperature. Dynamic indentation tests were performed on Ni oxide films formed on Ni surfaces at room and high temperature to observe fractures or cracks generated around impact craters. As a result, it was found that the mechanical property as hardness of the oxide films were different between Ni and Ni-Co alloy, and between room and high temperatures, and that the adhesion of Ni oxide films was relatively stronger than that of Co oxide films.