• Transactions of the Korean hydrogen and new energy society
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• v.12 no.1
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• pp.65-73
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• 2001

Carbon nanotubes were prepared by catalytic decomposition of $CH_4$ using Ni-MgO catalyst at various temperatures. $H_2$ effect on crystallinity and morphology during the synthesis of carbon nanotubes was investigated. The crystallinity and morphology were characterized by SEM, TEM, XRD, TGA, and Raman spectroscopy. In addition, the hydrogen adsorption properties were evaluated by PCT measurement in a hydrogen pressure range between 1 and 120 bar. The optimal synthesis temperature of carbon nanotubes was elevated in the presence of $H_2$, although significant difference of carbon nanotube morphology was not found. It is believed that hydrogen served as self-cleaner mops the amorphous carbon on the catalyst surface. It is proved that the carbon nanotubes have multi-walled structure, short length with a outer diameter of 20 ~40nm and open tips after elimination of the catalyst. The amount of hydrogen adsorbed in carbon nanotubes is increased as the pressure of hydrogen is increased and reaches 1.3 wt % under the hydrogen pressure of 120 bar at room temperature.

• Journal of the Korean Chemical Society
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• v.20 no.6
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• pp.453-459
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• 1976

Rate constants for the reaction of methyl chloroformate with substituted anilines, and for the halogen exchanges in phenyl chloroformate have been determined in acetone. Although the rate data can be interpreted equally well with the addition-elimination mechanism($S_AN$) involving an intermediate, results of MO and isotope effect studies strongly favor the synchronous ($S_N2$) mechanism for the reactions studied. It was concluded that for the fast reacting nucleophiles the transition state is of "late" type while for the slow reacting nucleophiles it is of "early" type.

• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.845-851
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• 2002

The synthesis of the intramolecular donor - stabilized silyl and germyl complexes of the type ($Cab^c.p) MMe_2X$ (2a:M=Si, X=Cl;2b;M= Ge, X=Cl;2e;M=Si,X=H) was achieved by the reaction of $LiCab^c,p$ (1) with $Me_2SiClX$ and $Me_2GeCl_2$ respectively. The intramolecular M←P interacion in 2a-2c is provided by $^1H$, $13^C.$, $31^P$ and $29^Si$ NMR spectroscopy. The salt elimination reactions of dichlorotetramethyldisilane and -digermane with 1 afforded the $bis(\sigma-carboranylphosphino)disilane$ and disgermane [$(Cab^C.P)MMe_2]_2(4a;M$ = Si;4b: M=Ge). The oxidative addition reaction of 4a-4b with $pd_2(dba)_3CHCl_3afforded$ the bis(silyl)-and bis(germyl)-palladium complexes. The chloro-bridged dipalladium complexes were obtained by the reaction of 2a-2b with $pd_2(dba)_3CHCl_3$ The crystal structures of 5a and 7b were determined by X-ray structural studies.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.7
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• pp.713-720
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• 2006

To analyze atmospheric fate of PCBs in the Kanto region, Japan, an one-compartment box model was used and the relationship between behavior of each PCB homologue and air temperature was simulated. In addition, the emission rates and the deposition fluxes in the overall Kanto region were estimated by the model. The total emission rate and deposition flux was 3,320 kg/yr and 1,480 kg/yr, respectively. The contribution of advection was ranged from 22 to 38% among elimination processes(advection, dry & wet deposition and degradation) of PCBs from atmosphere. The rates of degradation(OH radical process) for PCBs in the Kanto region would be negligible. This study showed that one-compartment box model can be available to understand the overall atmospheric behavior of PCBs.

• Archives of Pharmacal Research
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• v.23 no.4
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• pp.374-380
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• 2000

Propentofylline (PPF, 3-methyl-1-(5-oxohexyl)-7-propylxanthine) has been reported to be a compound for treatment of both vascular dementia and dementia of the Alzheimer type. The short half-life (about 15 min) of PPF at the terminal elimination phase and poor bioavailability after oral administration of PPF to rabbits (Kim et al., 1992) suggest in part that this drug takes the extensive first-pass metabolism in the liver. In addition, the metabolic pathway for PPF remains unclear. The objective of this experiment is to identify urinary metabolites of PPF in rats. For the identification of the metabolites, rat urine was collected after oral administration of 100${m}g/kg$ PPF. PPF metabolite, 3-methyl-1-(5-hydroxyhexyl)-7-propylxanthine, was synthesized and confirmed by gas chromatography/mass spectroscopy (GC/MS) and $^1H$ nuclear magnetic resonance spectroscopy. The urinary metabolites of PPF were extracted with diethyl ether and identified by electron impact and chemical ionization GC/MS. One urinary metabolite was confirmed to be 3-methyl-1-(5-hydroxyhexyl)-7-propylxanthine by synthesized authentic compound. Several metabolites of monohydroxy- and dihydroxy-PPF were identified based on mass fragmentation of both intact and trimethylsilylated derivatives of PPF metabolites and the novel structure of these metabolites is suggested based on mass spectra.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2017.05a
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• pp.346-349
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• 2017

Digital image processing is widely used in a variety of areas, and noise elimination is used as the preprocessing in all the image processing processes. Degradation is occurred in the image data due to multiple reasons. Degradation is to add the noise in the image signal, and salt and pepper noise is the representative one to cause degradation. Therefore, image restoration algorithm was proposed to process with histogram weight filter and median filter by the noise density of local mask to restore the damaged image in the salt and pepper noise environment, in this article. In addition, it was compared with the existing methods using peak signal to noise ratio(PSNR) as the objective determination factor of improvement effect.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.835-839
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• 2010

The rate constants of solvolyses of 2,2,2-trichloro-1,1-dimethylethyl chloroformate ($\underline{I}$) in 33 solvents can be well correlated using the extended Grunwald-Winstein equation, with incorporation of the $N_T$ solvent nucleophilicity scale and the $Y_{Cl}$ solvent ionizing scale, with sensitivities towards changes in the scale having values of $1.42\;{\pm}\;0.09$ for l and $0.39\;{\pm}\;0.05$ for m, respectively. The activation enthalpies are ${\Delta}H^{\neq}\;=\;12.3$ to $14.5\;kcal{\cdot}mol^{-1}$ and the activation entropies are -28.2 to $-35.5\;cal{\cdot}mol^{-1}{\cdot}K^{-1}$, consistent with the proposed bimolecular reaction mechanism. The kinetic solvent isotope effect of 2.14 in MeOH/MeOD is in accord with a bimolecular mechanism, probably assisted by general-base catalysis.

• Journal of Institute of Control, Robotics and Systems
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• v.12 no.12
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• pp.1241-1248
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• 2006

In high reliability systems for industrial network such as railway signal system, fieldbus protocols have been known to satisfy the real-time and fault tolerant requirements. But, the application of fieldbus has been limited due to the high cost of hardware and software, and the difficulty in interfacing with multi-vendor products. Therefore, as an alternative to fieldbus, the computer network technology, especially Ethernet(IEEE 802.3), is being adapted to the industrial network. In this paper, we propose a switched Ethernet based railway signal system because of its very promising prospect for industrial application due to the elimination of uncertainties in the network operation. In addition, we propose the redundancy architecture for the reliability of network components. More specifically, this paper presents an analytical performance evaluation of switched Ethernet for railway signal system, and shows experimental evaluation of redundancy architecture.

• Journal of the Korea Safety Management & Science
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• v.13 no.3
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• pp.45-53
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• 2011

The research proposes seven elimination rules of redundant gates and blocks in Fault Tree Analysis (FTA) and Reliability Block Diagram (RBD). The computational complexity of cut sets and path sets is NP-hard. In order to reduce the complexity of Minimal Cut Set (MCS) and Minimal Path Set (MPS), the paper classifies generation algorithms. Moreover, the study develops six implementation steps which reflect structural importance (SI) and reliability importance (RI) from Reliability Centered Maintenance (RCM) that a priority of using the functional logic among components is to reduce (improve) the system unavailability (or availability). The proposed steps include efficient generation of state structure function by Rare Event Enumeration (REA). Effective use of importance measures, such as SI and ill measures, is presented based on the number and the size of MCS and MPS which is generated from the reference[5] of this paper. In addition, numerical examples are presented for practitioners to obtain the comprehensive understanding of six steps that is proposed in this research.

• Journal of the Korean Chemical Society
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• v.37 no.6
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• pp.618-625
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• 1993

Rate constants of hydrolysis of N-(benzoyl)-C-(N-methylanilino)imidoylchlorides were determined by UV spectrophotometry in 50% (v/v) aqueous methanol at 25$^{\circ}C$. On the basis of rate equation, substituent effect, solvent effect, salt effect, thermodynamic parameters and hydrolysis product analysis, it may be concluded that the hydrolysis of N-(benzoyl)-C-(N-methylanilino)imidoylchlorides proceed through $S_N$1 mechanism via azocarbonium ion intermediate in the range of from pH 3.0 to pH 10.0, while above pH 10.0 and below pH 3.0 the hydrolysis proceeds through nucleophilic addition-elimination (A$d_{N-E}$) mechanism.