• Journal of the Korean Ceramic Society
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• v.27 no.2
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• pp.211-218
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• 1990

CA2-based clinker with highly activated surface and hydraulic properties was synthesized at a comparatively lowr temperature than that of conventional synthesis by "hydration-burning method". This consists of calcining the mixture of CaCO3 and Al2O3 to obtain a primary clinker, hydrating the primary clinker and reburning the hydrates to obtain final clinker. Burning of primary clinker above 1200℃ was necessary to eliminate free CaO in it and to obtain it's solid hydrate. However, rising the burning temperature above 1300℃ is ineffective due to the decrease in hydraulic properties of the primary clinker with the temperature. Hydration of primary clinker at the elevated temperature(>35℃) was required to obtain the hydrate with more porous structure and final clinker with more active surface. CA2 was formed and increased with temperature at above 1150℃, finally became a primary phase of the final clinker. However, burning at the temperature above 1300℃ resulted in reverse effect on the hydraulic properties of the final clinker due to rapid decrease in it's surface area with the temperature.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.49 no.8
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• pp.487-494
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• 2000

This paper describes the design, fabrication and experiments of surface-micromachined aluminum micromirror array with hidden pin-joints. Instead of the conventional elastic spring components as connection between mirror plate and supporting structure, we used pin-joint composed of pin and staples to support the mirror plate. The placement of pin-joint under the mirror plate makes large active surface area possible. These flexureless micromirrors are driven by electrostatic force. As the mirror plate has discrete deflection angles, the device can be ap;lied to adaptive optics and digitally-operating optical applications. Four-level metal structural layers and semi-cured photoresist sacrificial layers were used in the fabrication process and sacrificial layers were removed by oxygen plasma ashing. Static characteristics of fabricated samples were measured and compared with modeling results.

• Macromolecular Research
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• v.16 no.7
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• pp.651-658
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• 2008

Poly(butylene succiate) (PBS), poly(butylene succinate-co-L-lactate) (PBSL), and poly(butylene succinate-co-6-hydroxycaproate) (PBSCL) polymers were degraded by lipase $PS^{(R)}$, and the enzymatic degradation mechanism of PBS was analyzed in detail. The enzymatic degradation of PBS gave 4-hydroxybutyl succinate (4HBS) as the main product. An exo-type hydrolysis mechanism was proposed based on this observation. The terminal chain of PBS had conformational similarity to ordinary tri- and diglycerides and could be incorporated as a substrate in the active site of this lipase. The surface adsorption of the lipase was much larger on PBS and its copolymer films than on the other polyester films because the lipase adhered quite strongly to the polymer terminal through a specific adsorption mechanism. Kinetic analysis showed that the total number of surface adsorption points per unit area of PBSL and PBSCL copolymers was larger than that of the PBS homopolymer.

• Korean Journal of Crystallography
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• v.16 no.2
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• pp.61-65
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• 2005

Despite a short history, the research on porous coordination polymers is gaining importance in inorganic chemistry thanks to facile synthesis, unambiguous characterization by X-ray diffraction and potentials as high-surface-area materials. Recently, gas sorption properties of various porous materials are under active investigations in order to know whether it is possible to store industrially important gases through physisorption, and porous coordination polymers are one of the most promising candidates for such a purpose. This article reviews two recent papers reporting a series of isomorphous frameworks based on Zn(II), dicarboxylate and diamine ligands and their gas sorption properties.

• Microbiology and Biotechnology Letters
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• v.7 no.3
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• pp.165-173
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• 1979

Recovery component for cell division in UV-irradiated E. coli B was detected with use of the cell extract of E. coli B/r which is a resistant mutant of E. coli B against UV-irradiation. The active substance was non-dialyzable and increased the activity by adding B-NAD remarkably. One more factor for increasing or promoting the restoration recognized was magnesium. Magnesium was effective to stabilze the substance in procedure of isolation. Two active substances were obtained from sucrose gradient centrifugation. One of them was recovred from the botton area and the other from top area just below below surface. the former was not stabilized by magnesium, while the latter stabilized the activity by it remarkably. The former which did not require magnesium was insensitive to protease and the latter which required magnesium was sensitive to it. Both were insensitive to RNase and DNase. Recovery ratio was doubled by using nitrogen gas than aeration in purification process. DNA-ligase less mutant was revealed same activity on it's recovery ratio with the parent strain of E. coli K-12. The active substance stimulating the filament cell may exist as a complex which is inactivated easily in the dissociated state ana requrie B-NAD or magnesium.

• Corrosion Science and Technology
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• v.20 no.5
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• pp.249-255
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• 2021

In this work, we proposed a facile method to fabricate the three-dimensional porous copper current collector (3D Cu CC) for a Si-dominant anode in a Li-ion battery (LiB). The 3D Cu CC was prepared by combining chemical etching and thermal reduction from a planar copper foil. It had a porous layer employing micro-sized Cu balls with a large surface area. In particular, it had strengthened attachment of Si-dominant active material on the CC compared to a planar 2D copper foil. Moreover, the increased contact area between a Si-dominant active material and the 3D Cu could minimize contact loss of active materials from a CC. As a result of a battery test, Si-dominant active materials on 3D Cu showed higher cyclic performance and rate-capability than those on a conventional planar copper foil. Specifically, the Si electrode employing 3D Cu exhibited an areal capacity of 0.9 mAh cm^-2 at the 300^th cycles (@ 1.0 mA cm^-2), which was 5.6 times higher than that on the 2D copper foil (0.16 mAh cm^-2).

• Ocean and Polar Research
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• v.25 no.2
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• pp.133-145
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• 2003

Deep-sea surface sediments were collected using a multiple corer at 20 stations of Clarion-Clipperton fracture zone in the northeast equatorial Pacific to understand latitudinal and longitudinal variations of geotechnical properties. There was a distinct latitudinal variation of geotechnical properties in the study area. The northern sediments showed finer grain size, lower water content and porosity, higher bulk density and specific grain density, lower liquid limits and plastic limits than their southern counterparts. The northern sediments are classified into inorganic clays of low plasticity (fat clays) on plasticity charts and normal to active clay on activity chart, whereas, the southern sediments are classified into fine-grained, highly-plastic, inorganic and biogenic silt or organic clays on plasticity chart and normal to very active clay on activity chart. When shear strength are considered, the northern sediments were found to be in unconsolidated states, while the southern ones to be normal to over-consolidated states. These latitudinal variations in sediment characteristics are likely caused by differences in productivity of surface water that controls sediment compositions, sedimentation rates, and grain solubility.

• Proceedings of the KIEE Conference
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• 2005.10b
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• pp.273-275
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• 2005

Active thermography is being used since several years for remote non-destructive testing. It provides thermal images for remote detection and imaging of damages. Also, it is based on propagation and reflection of thermal waves which are launched from the surface into the inspected component by absorption of modulated radiation. For energy deposition, it use external heat sources (e.g., halogen lamp or convective heating) or internal heat generation (e.g., microwaves, eddy current, or elastic wave). Among the external heat sources, the ultrasound is generally used for energy deposition because of defect selective heating up. The heat source generating a thermal wave is provided by the defect itself due to the attenuation of amplitude modulated ultrasound. A defect causes locally enhanced losses and consequently selective heating up. Therefore amplitude modulation of the injected ultrasonic wave turns a defect into a thermal wave transmitter whose signal is detected at the surface by thermal infrared camera. This way ultrasound thermography(UT) allows for selective defect detection which enhances the probability of defect detection in the presence of complicated intact structures. In this paper the applicability of UT for fast defect detection is described. Examples are presented showing the detection of defects in PCB material. Measurements were performed on various kinds of typical defects in PCB materials (both Cu metal and non-metal epoxy). The obtained thermal image reveals area of defect in row of thick epoxy material and PCB.

• Korean Journal of Materials Research
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• v.32 no.10
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• pp.408-413
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• 2022

The oxygen evolution reaction (OER) is very sluggish compared to the hydrogen evolution reaction (HER). Considering this difference is essential when designing and developing a cost-effective and facile synthesis method for a catalyst that can effectively perform OER activity. The material should possess a high surface area and more active sites. Considering these points, in this work we successfully synthesized sheets of cobalt phosphate hydrate (CP) and sulphurated cobalt phosphate hydrate (CPS) material, using simple successive ionic layered adsorption and reaction (SILAR) methods followed by sulfurization. The CP and CPS electrodes exhibited overpotentials of 279 mV with a Tafel slope of 212 mV dec^-1 and 381 mV with a Tafel slope of 212 mV dec^-1, respectively. The superior performance after sulfurization is attributed to the intrinsic activity of the deposited well-aligned nanosheet structures, which provided a substantial number of electrochemically active surface sites, speeded electron transfer, and at the same time improved the diffusion of the electrolyte.

• Carbon letters
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• v.9 no.1
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• pp.8-16
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• 2008

Oxidized activated carbons were prepared by reacting steam-activated carbon developed from pecan shells with nitric acid of varying strength (15, 30, 45 and 60%). The textural properties and the chemistry of the surface of the non-oxidized and of the oxidized carbons were determined from nitrogen adsorption and base neutralization capacities. The uptake of Pb(II) and Cd(II) from aqueous solution by these carbons was determined by kinetic and equilibrium experiments as well as by the column method. Treatment with nitric acid brought about drastic decrease in surface area and remarkable increase in the pore size of the carbon with these changes depending on the strength of nitric acid. Nitric acid increased the surface acidity by developing new surface oxygen functional groups of acidic nature. $HNO_3$-oxidized carbons exhibited high adsorption capacities for Pb(II) and Cd(II). The adsorption of these ions increased with the decrease of the surface pH of the carbon and with the increase of the solution pH from 2.5 to 6 and 7. The amount adsorbed from lead and cadmium was also related to the amount of surface acidity, the pH of the point of zero charge and on some metal ion parameters. Cadmium and lead uptake by the investigated carbons followed pseudo-second order model and the equilibrium sorption data fitted Langmuir adsorption model.