• Title/Summary/Keyword: Active Oxygen

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Mechanisms of $Cl_2$ Molecules Dissociation in a Gas Discharge Plasma in Mixtures with Ar, $O_2.N_2$

  • Efremov, A.M.;Kwon, Kwang-Ho
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.1 no.4
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    • pp.197-201
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    • 2001
  • The influence of argon, oxygen, and nitrogen admixtures on the dissociation of $Cl_2$ molecules in a glow discharge low-temperature plasma under the constant pressure conditions was investigated. For $Cl_2/Ar$ and $Cl_2/O_2$mixtures, the concentration of chlorine atoms was observed to be a practically constant at argon or oxygen concentrations up to 50%. This invariability is a most pro bably explained by relative increase in rate of $Cl_2$ direct electron impact dissociation due to the changes in electrophysical parameters of plasma such as EEDF, electron drift rate and mean energy. For all the considered mixtures, the contribution of stepwise dissociation involving active species from gas additives (metastable atoms and molecules, vibrationally excited molecules) was found to be negligible.

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Effect of Active Species Generated from Flexible Plasma Patch on Polysaccharide Surface (플렉서블 플라즈마 패치에서 발생되는 활성종이 다당류 표면에 미치는 영향)

  • Lee, Yu Ri;Lee, Seunghun;Kim, Do-Geun
    • Journal of the Korean institute of surface engineering
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    • v.51 no.2
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    • pp.133-137
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    • 2018
  • Plasma devices such as jets, pencils, and torches have been developed as new tools that help penetration of target agents and applied to plasma medicine. However, these devices cannot be used in a large area. Therefore, we introduced a flexible plasma device, which can be treated of large area and designed as bendable plasma. In additional, in vitro model based on agarose gel was prepared that can be show effectiveness in the depth of penetration. Plasma treatment conditions such as power, time and distance can be optimized on the agarose gel wound model. The chemical structure of changed polysaccharides was predicted due to reactive excited atoms and molecules, UV photons, charged particles and reactive oxygen and nitrogen species (RONS).

Photocatalytic Epoxidation of Olefins Using Molecular O2 by TiO2 Incorporated in Hydrophobic Y Zeolite

  • Kuwahara, Yasutaka;Magatani, Yasuhiro;Yamashita, Hiromi
    • Rapid Communication in Photoscience
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    • v.4 no.1
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    • pp.19-21
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    • 2015
  • Zeolite is an ideal host material for encapsulating nano-size metal catalyst species because of its defined microporous structure, prominent adsorption/condensation properties, high surface area, chemical/thermal stability, and transparency to light. In this study, $TiO_2$ photocatalyst was incorporated in highly hydrophobic Y zeolite and its photocatalytic activity was examined in the photocatalytic oxidation of olefins under UV-light irradiation using molecular oxygen as an oxygen source. $TiO_2$ nanoparticles incorporated in hydrophobic Y zeolite exhibited a markedly enhanced photocatalytic activity compared with bare $TiO_2$ owing to its excellent affinity toward organic moieties, which facilitates the mass transfer of organic substrates and allows them to efficiently access to the neighboring active $TiO_2$ surface.

Active role of oxygen on penicillin sensitivity and fromation of membrane protein in escherichia coli K12 (Escherichia coli K12의 막단백질 형성과 페니실린 민감성에 대한 산소의 능동적 역할)

  • 박현근;한홍의
    • Korean Journal of Microbiology
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    • v.24 no.3
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    • pp.263-269
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    • 1986
  • Membrane proteins of facultatively anaerobic Escherichia coli K12 which was logarithmically grown in aerobiosis and anaerobiosis were compared on 5 to 10% liner gradient gel electrophoresis (Na Dod $SO_4 -PAGE$). Membrane proteins were formed as different patterns between aerobiosis and anaerobiosis. Among them, 91Kdal protein (pbp1a) was not synthesized in aerobiosis and 60Kdal protein (fts cluster), in anaerobiosis. Thereby cells cultured aerobically were differenciated as diversiform cell shape, comparing cells cultured anaerobically and the latter were resistant to penicillin G. Thus it is believed that in facultative anaerobes atmospheric oxygen regulated the synthesis of membrane proteins and even the expression of equivalent genes, and moreover alleviated the resistance to an antibiotic penicillin.

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Oxidative Stress and Antioxidant Defences in the Tasar Silkworm Antheraea mylitta D: Challenged with Nosema Species

  • Jena, Karmabeer;Pandey, Jay Prakash;Sinha, Ajit Kumar
    • International Journal of Industrial Entomology and Biomaterials
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    • v.28 no.2
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    • pp.85-91
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    • 2014
  • This study was designed to find out the effect of Nosema spore on oxidative damages and antioxidant defence in the midgut of tasar silkworm Antheraea mylitta. Higher level of lipid peroxidation (LPX) and total hydroperoxides indicate the resultant oxidative stress in the Nosema exposed specimen. Increased superoxide dismutase (SOD) suggests activation of physiological mechanism to scavenge the superoxide radical produced during Nosema infection. Higher activities of catalase and glutathione-S-tranferase on $18^{th}$ d indicate adaptive behaviour of the tissue against oxyradicals. The results suggest that Nosema infection is involved in altering the active oxygen metabolism by modulating LPX and reactive oxygen species (ROS), which is indicative of pebrine disease disorder.

Flame Retardancy and Mechanical Property of Recycled Polyolefinic Plastic Composites with Hybrid fillers (폴리올레핀계 폐플라스틱/복합filler 성형체의 난연성 및 기계적 물성 연구)

  • 강영구;송종혁
    • Journal of the Korean Society of Safety
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    • v.18 no.2
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    • pp.56-63
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    • 2003
  • Flame retardancy and mechanical properties of recycled polyolefinic plastics/inorganic filler composite systems were investigated by using several inorganic flame retardants such as magnesium hydroxide and slag powder generated electro arc furnace Compatibilizer user each maleic anhydride functionalized polyethylene (PE-g-MAH) and polypropylene(PP-g-MAH) or used mixture of these. The effect of polymeric compatibilizers on the properties of composites was studied by tensile and impact test, differential scanning calorimetry, in the changed fracture mechanism. The improved adhesion was particularly reflected in the mechanical properties. The flame retardancy of composites was examined by measuring limiting oxygen index(LOI, ASTM D2863), smoke density(ASTM D2843) and vertical burning test(UL94). Regarding the flame retardant effect, the EAF slag powder is behaving as synergists as they are only active in the presence of magnesium hydroxide.

Effect of Aeration on Denitrification by Ochrobactrum authropi SY509

  • Song, Seung-Hoon;Yeom, Sung-Ho;Park, Suk-Soon;Yoo, Young-Je
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.6
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    • pp.352-356
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    • 2002
  • Aeration was found to affect the biological denitrification by Ochrobactrum authropi SY509. Although cell growth was vigorous under 1 vvm of aeration and an agitation speed of 400 rpm in a 3-L jar fermentor, almost no nitrate was removed. Yet under low agitation speeds (100, 200, and 300 rpm), denitrification occurred when the dissolved oxygen was exhausted shortly af-ter the inoculation of the microorganism. Ochrobactrum authropi SY509 was found to express highly active denitrifying enzymes under anaerobic conditions. The microorganism also synthesized denitrifying enzymes under aerobic conditions (1 vvm and 400 rpm), yet their activity was only 60% of the maximum level under anaerobic conditions and the nitrate removal efficiency was merely 15%. However, although the activities of the denitrifying enzymes were inhibited in the presence of oxygen, they were fully recovered when the conditions were switched to anaerobic conditions.

High Temperature Oxidation of Ti-15Mo-5Zr-3Al Alloy (Ti-15Mo-5Zr-3Al 합금의 고온산화)

  • 우지호;김종성;백종현;이동복
    • Journal of the Korean institute of surface engineering
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    • v.31 no.5
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    • pp.278-285
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    • 1998
  • Alloys of Ti-15Mo-5Zr-3Al(wt%) were oxidized in air between 700 and $900^{\circ}C$. It was found that the oxidation resistance is much better than that of either commercially available pure Ti-6Al-4V(wt%) alloys. The oxide scales were primarily composed of thick Ti-ox-ides which were formed by the inward diffusion of oxygen from the atmosphere. At higher temperatures a thin $\alpha$-$Al_2O_3$ layer was formed on Ti-oxides owing to the outward diffusion of Al from the base alloys. Molybdenum, the noblest metal among the alloy components, was predominantly present behind the oxide-substrate interface. Zirconium, an oxygen active metal, was present at both the oxide layer and the substrate.

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Kinetics and Mechanism of the Oxidation of Carbon Monoxide on H$_2$-Reduced NiO-Doped $\alpha$-Fe$_2O_3$

  • Kim, Don;Kim, Keu-Hong;Choi, Jae-Shi
    • Bulletin of the Korean Chemical Society
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    • v.9 no.2
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    • pp.81-84
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    • 1988
  • The CO oxidation was performed on $H_2$-reduced NiO-${\alpha}-Fe_2O_3$ in the temperature range 150-$250^{\circ}C$. The kinetic study and the conductivity measurements indicate the oxidation reaction follows Langmuir-Rideal type process that is uncommon in heterogeneous catalyst$^1$. No active site is found on the catalyst surface for CO adsorption, but an oxygen vacancy adsorbs an oxygen, and this step is rate initiation. The partial orders are half for $O_2$ and first for CO, respectively. Apparent activation energy for over-all reaction is 9.05 kcal/mol.

Free Radical Scavenging Compounds of Polygoni Multiflori Ramulus

  • Li-Xun;Kim, Mi-Hee;Ko, Eun-Kyung;Jun, Jung-Yang;Oh, Myung-Hun;Shin, Hwa-Woo;Kim, Youn-Chul
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.381.2-381.2
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    • 2002
  • There is now increasing evidence that free radicals and active oxygen species are involved in a variety of pathological events. often associated with ageing. Free radical-mediated cell damage and free radical attack on polyunsaturated fatty acids result in the formation of lipid radicals. These lipid radicals react readily with molecular oxygen to produce peroxy radicals responsible for initiating lipid peroxidation. The peroxidation of cellular membrane lipid can lead to cell necrosis and considered to be implicated in a number of pathophysiological conditions as well as in the toxicity of many xenobiotics. (omitted)

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