• Title/Summary/Keyword: Active IR

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Characterization of Convective Weather Systems in the Middle Himalaya during 1999 and 2000 Summer Monsoons (1999년과 2000년 여름몬순기간 동안 히말라야 지역에 발생한 대류계의 특성에 관한 연구)

  • Kim, Gwang-Seob;Noh, Joon-Woo
    • Journal of Korea Water Resources Association
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    • v.36 no.3 s.134
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    • pp.495-505
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    • 2003
  • Convective weather systems such as organized mesoscale convective systems (Mesoscale Convective Complex, MCC and Convective Cloud Clusters, CCC) and much weaker Disorganized Short-lived Convection (DSC) in the region of India and Nepal were analyzed using the Meteosat-5 IR imagery. The diurnal march and propagation of patterns of convective activity in the Himalayas and Northern Indian subcontinent were examined. Results indicate that infrared satellite images of Northern India and along the southern flank of the Himalayas reveal a strong presence of convective weather systems during the 1999 and 2000 monsoons, especially in the afternoon and during the night. The typical MCCs have life-times of about 11 hours, and areal extent about $300,000km^2$. Although the core of MCC activity remains generally away from the Middle Himalayan range, the occurrence of heavy precipitation events in this region can be directly linked to MCCs that venture into the Lesser Himalayan region and remain within the region bounded by $25^{\circ}-30^{\circ}N$. One principal feature in the spatial organization of convection is the dichotomy between the Tibetan Plateau and the Northern Indian Plains: CCCs and DSCs begin in the Tibetan Plateau in the mid-afternoon into the evening; while they are most active in the mid-night and early morning in the Gangetic Plains and along the southern facing flanks of the Himalayas. Furthermore, these data are consistent with the daily cycle of rainfall documented for a network of 20 hydrometeorological stations in Central Nepal, which show strong nocturnal peaks of intense rainfall consistent with the close presence of Convective Weather Systems (CWSs) in the Gangetic Plains (Barros et al. 2000).

The Physicochemical and Optical Characteristics of FeaSibCcHd Films (FeaSibCcHd 박막의 물리·화학 및 광학적 특성)

  • Kim, Kyung-soo;Jean, Bup-Ju;Jung, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.105-111
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    • 1999
  • When the preparation method of iron silicide films possess the annealing process, the interfacial state of the films is not fine. The good quality films were obtained as the plasma was used without annealing processing. Since the injected precursors were various active species in the plasma state, the organic compound was contained in the prepared films. We confirmed the formation of Fe-Si bonds as well as the organic compound by Fe and Si vibration mode in Raman scattering spectrum at $250cm^{-1}$ and Ft-IR. Because of epitaxy growth being progressed by the high energy of plasma at the low temperature of substrate, iron silicide was epitaxially grown to ${\beta}$-phase that had lattice structure such as [220]/[202] and [115]. Band gap of the prepared films had value of 1.182~1.174 eV and optical gap energy was shown value of 3.4~3.7 eV. The Urbach tail and the sub-band-gap absorptions were appeared by organic compound in films. We knew that the prepared films by plasma were obtained a good quality films because of being grown single crystal.

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Eye Region Detection Method in Rotated Face using Global Orientation Information (전역적인 에지 오리엔테이션 정보를 이용한 기울어진 얼굴 영상에서의 눈 영역 추출)

  • Jang, Chang-Hyuk;Park, An-Jin;Kurata Takeshi;Jain Anil K.;Park, Se-Hyun;Kim, Eun-Yi;Yang, Jong-Yeol;Jung, Kee-Chul
    • Journal of Korea Society of Industrial Information Systems
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    • v.11 no.4
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    • pp.82-92
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    • 2006
  • In the field of image recognition, research on face recognition has recently attracted a lot of attention. The most important step in face recognition is automatic eye detection researched as a prerequisite stage. Existing eye detection methods for focusing on the frontal face can be mainly classified into two categories: active infrared(IR)-based approaches and image-based approaches. This paper proposes an eye region detection method in non-frontal faces. The proposed method is based on the edge--based method that shows the fastest computation time. To extract eye region in non-frontal faces, the method uses edge orientationhistogram of the global region of faces. The problem caused by some noise and unfavorable ambient light is solved by using proportion of width and height for local information and relationship between components for global information in approximately extracted region. In experimental results, the proposed method improved precision rates, as solving 3 problems caused by edge information and achieves a detection accuracy of 83.5% and a computational time of 0.5sec per face image using 300 face images provided by The Weizmann Institute of Science.

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Synthesis and Electrochemical Characterization of Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine Composite as Polymer Cathode Material (Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine 복합체 고분자 양극재료의 합성과 전기화학적 특성)

  • Oh, Ji-Woo;Ryu, Kwang-Sun
    • Journal of the Korean Electrochemical Society
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    • v.15 no.4
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    • pp.222-229
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    • 2012
  • We studied the electrochemical phenomena and increase of capacity according to the polymer composite electrode of two different polymeric materials with different the voltage range and capacity. Polyaniline (PANI) with relatively high voltage and small capacity and poly [1,2] bis-thio[1,8]-naphthylidine (PTND) with slightly low voltage and large capacity were used as polymer composite electrode materials. After PTND was synthesized, PANI was synthesized on the surface of PTND. The synthesis and the fine structure were analyzed by FT-IR, XPS, FE-SEM, and FE-TEM. Charge/discharge capacity and cyclic voltammetry measurements were carried out for the electrochemical performance as a polymer cathode active material for lithium secondary batteries. The discharge capacities of PANI/PTND after 1,5, and 10 cycles at 1.3~4.0 V voltage range and room temperature 167 mAh/g, 90 mAh/g, and 81 mAh/g. When we compared with PANI (80, 67, and 62 mAh/g), the discharge capacity after 10 cycles was improved about 30%. After 50 cycles, the discharge capacity of PANI/PTND was 67 mAh/g.

Decolorization and Degradation Products of Melanoidin by Active Oxygens II. Decolorizatlon and Degradation Products of Melanoidin on Ozonolysis (활성산소종에 의한 Melanoidin의 탈색 및 분해생성물 II. Ozone에 의한 Melanoidin의 탈색 및 분해생성물)

  • KIM Seon-Bong;PARK Yeung-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.1
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    • pp.36-44
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    • 1986
  • Nondialyzable melanoidins prepared from a glucose-glycine system were investigated as to their decolorization and degradation products on of one treatment. Melanoidins were decolorized to degree of $84\%\;and\;97%$ after ozonolysis at $-1^{\circ}C$ for 10 min and 90 min, respectively, and the mean molecular weight of melanoidins decreased from 7,000 to 3,000 after ozonolysis for 40 min. IR measurement showed that the absorption at $1,290\;cm^{-1}$ disappeared and that at $1,720\;cm^{-1}$ newly appeared on ozonolysis, and the absorption at $1,620\;cm^{-1}$ disappeared on acid hydrolysis after ozonolysis. Furthermore, the major degradation products in the ether-soluble fractions obtained from ozone-treated melanoidins were identified as butanedioic acid, glycolic acid, 2-hydroxybutanoic acid and so on. In the aqueous fraction, one or the major products was glycine, which was produced to the level of $1.05\%$ on ozonolysis which increased to $5.75\%$ per melanoidin on acid hydrolysis after ozonolysis. From these findings and the IR results, it is postulated that glycine was considerably incorporated into melanoidin molecules as the amide form.

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Synthesis of Aminated Poly(ether sulfone) as Anion Exchanger and its NO Gas Adsorption (Aminated Poly(ether sulfone)의 합성과 NO 가스의 흡착특성)

  • Son, W.K.;Park, S.G.
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.857-862
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    • 1999
  • Aminated poly(ether sulfone)(APES) was prepared by amination of nitrated poly(ether sulfone)(NPES) after poly(ether sulfone)(PES) was nitrated with mixed acid of nitric acid and sulfuric acid(sulfuric acid is a catalyst). As a results of the FT-IR spectrum analysis, the nitration of PES was confirmed by the bands of asymmetric stretching and symmetric stretching of $NO_2$ group at 1537 and $1351cm^{-1}$, respectively. Also when the NPES was aminated, it was disappeared to absorbance peaks of $NO_2$ group. And It was confirmed by the bands of asymmetric stretching and symmetric stretching of $NH_2$ group at 3470 and $3374cm^{-1}$, respectively. The optimum condition of the nitration on PES(5 g; 21.55 mmol.) was 12 hr of reaction time, $120^{\circ}C$ of reaction temperature, nitric acid of 28.00 mmol. and sulfuric acid of 52.00 mmol. As a result of the elemental analysis of APES, reapeating unit per amine groups were induced to 0.89. The adsorption rate of NO gas was lower than that of silica gel and active carbon. But the adsorption capacity of NO gas was higher than that of these. When the APES was absorbed to NO gas, the chemical adsorption rate was lower than the physical adsorption rate. But the chemical adsorption capacity of it was higher than physical adsorption capacity.

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Purification and Characterization of Anticarcinogenic Compound from Corni fructus (산수유에 함유된 항암물질의 정제 및 특성)

  • Kim, Byeong-Hyeon;Park, Kyung-Wuk;Kim, Jae-Yong;Jeong, Ill-Yun;Yang, Gi-Ho;Cho, Young-Sook;Yee, Sung-Tae;Seo, Kwon-Il
    • Korean Journal of Food Science and Technology
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    • v.36 no.6
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    • pp.1001-1007
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    • 2004
  • Chloroform layer from methanol extract of Corni fructus (Cornaceae) showed strong antiproliferation effect on human cancer cell lines by SRB assay. Anticarcinogenic-active compound was isolated and purified by silica gel column and thin layer chromatograpies, and identified as ursolic acid ($3{\beta}$-hydroxyrus-12-ene-28-oic acid, MW:456) by mass and IR spectrophotometries, and $^1H-and\;^{13}C-NMRs$. The compound inhibited proliferation of A549 (human lung cancer cell line) and MCF-7 (human breast cancer cell line) cells in dose-dependant manner when treated for 48 hr. Inhibition rates of both cells were over 40% and 90% compared with control cells at the $30\;{\mu}g/mL\;and\;100\;{\mu}g/mL$, respectively. Morphology of cells treated with the compound for 15 hr at $10\;{\mu}g/mL$ was distorted with shrinked cell mass, and cell number was lower than that of control cells. Cell cycle analysis showed sub-G1 phase arrest in both cell lines following 15 hr exposure to the compound; % of cell phase increased to 11.7 and 11.2% compared to the control of 4.0% and 2.1% in A549 and MCP-7 cells, respectively.

Development of Biologically Active Compounds from Edible Plant Sources XVI. -Isolation of Sterols from the Aerial Parts of Sajabalssuk (Artemisia herba)- (식용식물자원으로부터 활성물질의 탐색 XVI. -사자발쑥(Artemisia herba)의 전초로부터 sterol 화합물의 분리-)

  • Bang, Myun-Ho;Chung, Hae-Gon;Song, Myoung-Chong;Yoo, Jong-Su;Chung, Sun-A;Lee, Dae-Young;Kim, Se-Young;Jeong, Tae-Sook;Lee, Kyung-Tae;Choi, Myung-Sook;Baek, Nam-In
    • Applied Biological Chemistry
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    • v.49 no.2
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    • pp.140-144
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    • 2006
  • Sajabalssuk (Artemisia herba) was extracted with 80% aqueous MeOH, and the concentrated extract was partitioned with EtOAc, n-BuOH and $H_2O$, successively. From the EtOAc and n-BuOH fractions, four sterols were isolated through the repeated silica gel and ODS column chromatographies. From the results of physico-chemical data including NMR, MS and IR, the chemical structures of the sterols were determined as ${\beta}-sitosterol$ (1), ergosterol peroxide (2), stigmasterol (3) and daucosterol (4). They were the first to be isolated from Sajabalssuk (Artemisia herba).

A Development and Validation of Cosmetic Container Based on L-Ascorbic Acid Oxidation Property (L-Ascorbic Acid의 산화특성에 따른 화장품 용기 개발 및 유효성 분석)

  • Yoon, Sungwook
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.2
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    • pp.149-158
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    • 2013
  • L-ascorbic acid, the representative antioxidants, has a great effect on skin whitening, collagen synthesis, and anti-aging, but has low oxidative stability during storage. Therefore, in this study, thermal and oxidation properties of L-ascorbic acid under various storage conditions (powder, aqueous phase, changes of temperature, UV-irradiation, and inflow of external air etc.) were investigated. And the storage stability of ingredient was validated in the double-spaced pouch by analysing oxidation properties under each storage conditions (powder phase and blended with essence). In oder to analyze the thermal properties, TGA, DSC, and FT-IR analysis were carried out and UV-visible spectrophotometer & redox titration were used in parallel for oxidation property analyses. From the result of experiment, L-ascorbic acid was oxidized fast when it contained lots of metallic ion, hydroxy ion in aqueous solution under high temperature, UV-irradiation & inflow external air, whereas it was not oxidized for a long time when it was stored as pure powder although it has same condition as heating up, UV-irradiation & inflow external air. Based on this result, retention period of cosmetics which is using L-ascorbic acid, less stable material in oxidation can be innovatively increased when using double-spaced pouch that is designed and produced for separating storage of active ingredients.

Isolation and Purification of an Antitumor Metabolite from Alternaria brassicicola SW-3, the Cause of Brassica Black Leaf Spot Disease. (Phytopathogenic fungus Alternaria brassicicola SW-3가 생산하는 항암활성 물질의 분리 정제)

  • 나여정;이방숙;남궁성건;정동선
    • Microbiology and Biotechnology Letters
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    • v.30 no.1
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    • pp.51-56
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    • 2002
  • An antitumor substance was purified from the culture filtrate of phytopathogenic fungus Alternaria brassicicola SW-3 isolated from soil of a chinese cabbage patch, and its characteristics were investigated. Antitumor activity of A. brassicicola SW-3 was measured by MTT assay. The cytotoxic activity against human cancer cell line was detected in the culture filtrate of A. brassicicola SW-3, but no activity found in mycelium. Antitumor substance was isolated from the culture broth by ethyl acetate extraction and purified by silica gel column chromatography. Structure of the purified compound was analyzed by the instrumental analysis such as $^1$H-NMR, $^{13}$ C-NMR and IR spectroscopy. The purified fungal metabolite of an A. brassicicola SW-3, consists of 11 carbon chain with two hydroxyl groups and two epoxides which is identical to depudecin. The $IC_{50}$/ values of the active compound identified as depudecin were $69\mu$g/mL and $57\mu$g/mL against mouse melanoma B16BL6 cell line, and human hepatoma SK-HEP1 cell line, respectively.