• Title/Summary/Keyword: Activation method

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Kinetics of Thermal Degradation of Waste styrene compound and Paper Sludge Blend (폐 스티렌계수지와 제지슬럿지 Blend의 열분해에 관한 연구)

  • Seul, Soo-Duk;Kim, Nam-Seok;Wang, Seok-Ju;Na, Sang-Do
    • Elastomers and Composites
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    • v.30 no.2
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    • pp.105-111
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    • 1995
  • The thermal decomposition of the paper sludge with poly (acrylonitrile-butadiene-styrene) was using a thermal analysis techniques in the stream of nitrogen gas of 30ml/min at various heating rates from 4 to $20^{\circ}C/min$. The mathmatical, derivative and integral method were used to obtain values of activation energy of decomposition reaction. 1. The values of activation energy evaluated by derivative and Intergral method were consistent with each other very well. 2. The maximum value of heat of decomposition evaluated by DSC method was 10.120cal/g at weight ratio of paper sludge/ABS=20/80. 3. The thermogravimetric trace curve agreed with the theoretical equation.

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Kinetics of Pyrolysis Degradation of on ${\alpha}-Cellulose$. - Effect of Acid Catalysts NaCl- (${\alpha}$-셀룰로오즈의 열분해에 관한 연구(I) - 산촉매 NaCl의 영향 -)

  • Na, S.D.;Hwang, J.H.;Choi, J.S.;Seul, S.D.;Sohn, J.E.
    • Elastomers and Composites
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    • v.31 no.2
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    • pp.122-129
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    • 1996
  • The Thermal decomposition of the ${\alpha}-Cellulose$ and NaCl was studied using a thermal analysis technique in the steam of nitrogen gas with 30ml/min at various heating ranges from 4 to $20^{\circ}C/min$. The Derivative and Integral method used to be obtained values of activation energy of decomposition reaction. 1. The values of activation energy evaluated by Derivative and Intergral method were consistent with each other very well. 2. The maximum value of heat of decomposition evalated by DSC method was ${\alpha}-Cellulose/NaCl= 90/10$. 3. The thermogravimetric trace curve agreed with the theoretical equation.

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Estimation of the Setting Time of the Super Retarding Concrete Combining Mineral Admixtures (혼화재를 조합 사용한 초지연 콘크리트의 응결시간 추정)

  • Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.3
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    • pp.111-117
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    • 2008
  • This study provides the setting time prediction method of super retarding concrete incorporating mineral admixtures at the same time including fly ash(FA), blast furnace slag(BS) based on maturity method. The setting time was retarded, as super retarding agent contents increase and curing temperature decreases. In addition, apparent activation energy by Arrhenius function was ranged from $24{\sim}35KJ/mol$ with slightly difference along with mixture proportion. This value is smaller than existing value $30{\sim}50KJ/mol$. It is Indicated that equivalent age using setting time can be a proper method to predict setting time and it also exhibited comparable relativity between prediction value and measurement value. Therefore, this study provided setting time prediction value with super retarding agent contents and mineral admixture combination. Setting time prediction equation provided herein is possibly valid for estimating precise setting time of the super retarding concrete at the job site.

Influence of Activation Temperature on Surface and Adsorption Properties of PAN-based Activated Carbon Fibers/Phenolic Resin Matrix Composites (활성화 온도에 의한 PAN계 활성탄소섬유/페놀수지 복합재료의 표면 및 흡착특성)

  • 박수진;김기동;이재락
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.97-104
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    • 2000
  • PAN-based activated carbon fibers/phenolic resin matrix composites (ACFCs) were manufactured via molding process with oxidized carbon fabrics (plain-type) and phenolic resin (resole-type) compounded by 70 : 30 wt%. The green body (as molded) was submitted to carbonization (at 100$0^{\circ}C$) in an inert environment and activation (at 700, 800, 900 and 100$0^{\circ}C$) in a $CO_2$ environment. In this work, the influence of activation temperatures was investigated in surface properties, such as pH, acid- and base-values by titration method, and in adsorption properties, i.e., specific surface area and pore structures by BET-method of the composites. Also, the pressure drops of the specimens were calibrated by ASTM. As a result, the activation temperature influenced the surface property of ACFCs. When the activation temperature was higher than 90$0^{\circ}C$, the surface was gradually developed in basic nature. And, the evolutions of specific surface area, total pore volume and pore size distribution of ACFCs could be easily confirmed the dependence on the activation temperature. Among them, well-developed pore structure from adsorption characteristics was changed of the ACFCs activated at 90$0^{\circ}C$. Also, the pressure drop was slightly decreased with increasing the temperature due to increasing the burn-off with heat treatment temperature of ACFCs.

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Asymmetric Cyanosilylation of Aldehydes by Chiral Ti-TADDOL Complex

  • Kim, Sung-Soo;Kwak, Ju-Myung;Rajagopal, Gurusamy
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1638-1640
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    • 2006
  • A variety of chiral cyanohydrins were readily prepared from aldehydes with TMSCN under the influence of chiral titanium complex formed in situ from $Ti(O^iPr)_4$/TADDOL(I) in the presence of $Ph_3PO$ as additive. The double activation method produces trimethylsilylethers in excellent yield (95%) with moderate enantiomeric excess.

Enhanced SARM for Similar Components Retrieval (유사부품 검색을 위한 개선된 SARM)

  • 한정수;김귀정
    • Proceedings of the Korea Contents Association Conference
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    • 2003.11a
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    • pp.128-131
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    • 2003
  • This paper enhanced similar components retrieval algorithm-spreading activation method. The solution is that retrieval speed is overcome and more efficiently components are retrieved. Also we implemented interface for component information and query, and constructed component retrieval system.

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Activation Strategy of Railroad Engineering through Abroad Case (해외 사례를 통한 철도공학의 활성화 방안)

  • Lee Tai Sik;Lee Dong Wook;Koo Ja Kyung;Park Eun Soo
    • Proceedings of the KSR Conference
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    • 2005.05a
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    • pp.1010-1016
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    • 2005
  • Purpose of this research is considering activation way of stagnant railroad education. This research investigated domestic railroad education present condition and foreign countries' developed railroad college's education example by method of study. This research is going to produce railroad specialist who can achieve active and leading role base growth of railroad education and railroad industry development through link with resemblant railroad learning.

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BSCCO Superconducting Powder by SHS

  • Soh, Dea-Wha;Cho, Yong-Joon;Korobova, N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.99-102
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    • 2002
  • The BSCCO superconductor materials of using Self-propagating High-temperature Synthesis (SHS) were studied. Mechano-chemical activation - as a pre-treatment of the reactants mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product. In this paper as an effort for fabricating the SHSed BSCCO superconductor powder SHS method was considered to application in the synthesis of superconducting materials.

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Characterization of Korean Clays and Pottery by Neutron Activation Analysis(II). Characterization of Korean Potsherds

  • Lee, Chul;Kwun, Oh-Cheun;Kim, Seung-Won;Lee, Ihn-Chong;Kim, Nak-Bae
    • Bulletin of the Korean Chemical Society
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    • v.7 no.5
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    • pp.347-353
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    • 1986
  • Fisher's discriminant method has been applied to the problem of the classification of Korean potsherds, using their elemental composition as analyzed by neutron activation analysis. A combination of analytical data by means of statistical linear discriminant analysis has resulted in removal of redundant variables, optimal linear combination of meaningful variables and formulation of classification rules.