• Bulletin of the Korean Chemical Society
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• 제17권9호
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• pp.849-853
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• 1996

Hetero Dieis-Alder reactions containing phosphorus atom at various positions of diene and dienophile as well as standard Dieis-Alder reaction between ethylene and cis-l,3-butadiene have been studied using ab initio method. Activation energy showed a good linear relationship with the FMO energy gap between diene and dienophile, which can be normally used to explain Dieis-Alder reactivity. Since π-bond cleavage and σ-bonds formation occur concertedly at the TS, geometrical distortion of diene and dienophile from the reactant to the transition state is the source of barrier. Based on the linear correlations between activation barrier and deformation energy, and between deformation energy and π-bond order change, it was concluded that the activation barrier arises mainly from the breakage of π-bonds in diene and dienophile. Stabilization due to favorable orbital interaction is relatively small. The geometrical distortions raise MO levels of the TS, which is the origin of the activation energy. The lower barrier for the reactions of phosphorus containing dienophile (reactions C, D, and E) can be explained by the electronegativity effect of the phosphorus atom.

• 대한환경공학회지
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• 제22권6호
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• pp.1037-1044
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• 2000

본 연구에서는 국내에서 쉽게 구할 수 있으며 탄화시 높은 강도를 가질 수 있는 참나무를 이용하여 생물 활성탄 공정(BAC)에 적합한 활성탄, 즉 흡착뿐만 아니라 미생물의 안식처로서의 역할을 할 수 있는 거대 세공이 많이 발달된 활성탄을 제조하는데 그 주안점을 두었다. 활성탄의 제조는 인산 침적에 의한 화학적 활성화법을 이용하여 제조하였고 제조된 활성탄의 요오드 흡착력(mg/g), 메틸렌 블루 탈색력(mg/g), B.E.T Method에 의한 비표면적($m^2/g$), 세공 크기 분포(Pore size distribution)를 분석하여 현재 생물 활성탄 공정에 많이 사용되고 있는 P사의 'picabiol' 활성탄과 비교하였다. 본 연구에서 사용된 화학적 활성화법의 주인자는 인산의 침적농도, 활성화 용도, 그리고 활성화 시간이다. 이중 활성화 시간은 예비 실험으로 3시간으로 고정시켰다. 최적 활성화 온도와 인산 첨적 농도를 찾기 위하여 활성화 온도는 $600^{\circ}C$에서 $800^{\circ}C$ 로 변화시켰으며 인산 침적 농도는 35wt%에서 50wt%로 변화시켰다. 이렇게 제조된 활성탄 중 $800^{\circ}C$에서 활성화시켰을 때 모든 인산 침적 농도에서 요오드 흡착력(1000~1100 mg/g)과 메틸렌 블루 탈색력(200~400 mg/g)으로서 가장 높은 효율의 활성탄을 얻을 수 있었으며 picabiol과 비교하여 보았을 때 비슷하거나 더 높은 효율의 활성탄을 제조할 수 있었다.

• 한국재료학회지
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• 제22권6호
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• pp.321-327
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• 2012

The production of functional activated carbon materials starting from inexpensive natural precursors using environmentally friendly and economically effective processes has attracted much attention in the areas of material science and technology. In particular, the use of plant biomass to produce functional carbonaceous materials has attracted a great deal of attention in various aspects. In this study the preparation of activated carbon has been attempted from rice husks via a chemical activation-assisted microwave system. The rice husks were milled via attrition milling with aluminum balls, and then carbonized under purified $N_2$. The operational parameters including the activation agents, chemical impregnation weight ratio of the calcined rice husk to KOH (1:1, 1:2 and 1:4), microwave power heating within irradiation time (3-5 min), and the second activation process on the adsorption capability were investigated. Experimental results were investigated using XRD, FT-IR, and SEM. It was found that the BET surface area of activated carbons irrespective of the activation agent resulted in surface area. The activated carbons prepared by microwave heating with an activation process have higher surface area and larger average pore size than those prepared by activation without microwave heating when the ratio with KOH solution was the same. The activation time using microwave heating and the chemical impregnation ratio with KOH solution were varied to determine the optimal method for obtaining high surface area activated carbon (1505 $m^2$/g).

• 영어어문교육
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• 제3호
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• pp.95-122
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• 1997

The purpose of this research was to investigate the effects of content and formal schema on reading comprehension. Five hundred fiftynine subjects from high school were assigned to one of the following levels and treatment conditions : (1) Higher level & Schema Activation, (2) Higher level & Non-schema Activation, (3) Lower level & Schema Activation, and (4) Lower level & Non-schema Activation. To evaluate the effects of schema activation. two experiments were conducted : one was related to the content schema and the other to the formal schema. To evaluate the effects of content schema, three different types of tests were conducted : (1) cloze test, (2) guessing the meanings of nonsense words, and (3) immediate recall test. To evaluate the effects of formal schema instruction, four kinds of tests were conducted : (1) sorting the sentences according to the importance, (2) identifying the signal words, (3) immediate recall test, and (4) identifying the specific information. For content schema condition, results indicated that the subjects given the titles or pictures before reading in "Content Schema Activation" treatment had better grades than those of the other treatment in all types of tests. regardless of their levels. Schema activation helped the subjects to increase the cognitive predictability of missing words and to participate in the tasks more actively with risk-taking. And it was also shown that good readers tend to process the words meaningfully, while poor readers tend to process the words phonetically or morphologically. Formal schema activation through teaching the text organization also had a significant influence on three types of tests: sorting the sentences according to the importance, identifying the signal words, and immediate recall test, but not on identifying the specific information. The implications from this study can be briefly noted as follows : (l) In teaching reading, the student's background knowledge should be activated as a pre-reading activity. (2) In reading, it is more important to emphasize the student's schema than the features of the text. (3) Various educational interventions should be introduced, especially for the lower level students. (4) Teaching text structures can be a powerful method for the top-down processing strategy.

• Archives of Pharmacal Research
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• 제24권4호
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• pp.307-311
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• 2001

The activation of NF-$\kappa$B induced by kojic Acid, an inhibitor of tyrosinase for biosynthesis of melanin in melanocytes, was investigated in human transfectant HaCaT and SCC-13 cells. These two keratinocyte cell lines transfected with pNF-$\kappa$B-SEAP-NPT plasmid were used to determine the activation of NF-$\kappa$B. Transfectant cells release the secretory alkaline phosphatase (SEAP) as a transcription reporter in response to the NF-$\kappa$B activity and contain the neomycin phosphotransferase (NPT) gene for the dominant selective marker of geneticin resistance. NF-$\kappa$B activation was measured in the SEAP reporter gene assay using a fluorescence detection method. Kojic Acid showed the inhibition of cellular NF-$\kappa$B activity in both human keratinocyte transfectants. It could also downregulate the ultraviolet ray (UVR)-induced activation of NF-$\kappa$B expression in transfectant HaCaT cells. Moreover, the inhibitory activity of kojic Acid in transfectant HaCaT cells was found to be more potent than known antioxidants, e.g., vitamin C and N~acetyl-L-cysteine. These results indicate that kojic Acid is a potential inhibitor of NF-$\kappa$B activation in human keratinocytes, and suggest the hypothesis that NF-$\kappa$B activation may be involved in kojic Acid induced anti-melanogenic effect.

• 대한통합의학회지
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• 제6권4호
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• pp.91-100
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• 2018

Purpose : The study investigated the effects of Pilates exercise on strengthening trunk muscles of females who perform such exercise for the purpose of comparing activation of trunk muscles that contact while performing Pilates motions between females with or without at least 8 weeks of Pilates experience. Methods : The study investigated 10 females with at least 8 weeks of Pilates experience in the past 6 months (experienced group) and 10 healthy females without Pilates experience (non-experienced group). The study used basic Pilates postures involving hip abduction, lift, and leg swing motions as the measurement postures in comparing the activation of muscles used for stabilization, such as the rectus abdominis, external oblique abdominal, and transverse abdominis & internal oblique abdominal muscles. Surface electromyography was used for measuring muscle activation, and the measurements targeted activation of the rectus abdominis, external oblique abdominal, transversus abdominis, and internal oblique abdominal muscles. Results : The study results showed that, as compared to the non-experienced group, the experienced group had significantly higher muscle activation in the transverse abdominis and internal oblique abdominal muscles during hip abduction (p<.05) and significantly higher muscle activation in the rectus abdominis, external oblique abdominal, and transverse abdominis & internal oblique abdominal muscles during lift and leg swing motions (p<.05). Conclusion : Pilates exercise performed over a long period can be recommended as an effective exercise method that can increase the activation of trunk muscle, and especially, repeated performance of highly difficult motions can increase muscle activation even more, which can help promote spinal stabilization, prevent pain, and improve performance of activities of daily living.

• 한국운동역학회지
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• 제31권2호
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• pp.140-147
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• 2021

Objective: The purpose of this study is to identify the mechanism of changes in maximum voluntary torque with the magnitude and duration of pre-activation torque during voluntary isometric knee extension. Method: 11 male subjects (age: 25.91±2.43 yrs., height: 173.12±3.51 cm, weight: 76.45±7.74 kg) participated in this study. The subjects were required to produce maximal voluntary isometric torque with a particular pre-activation torque condition. The properties of pre-activation torque consisted of the combinations of 1) three levels of magnitude, e.g., 32 Nm, 64 Nm, 96 Nm, and 2) two levels of duration, e.g., 1 sec, and 3 sec; thus, a total of six conditions were given to the subjects. The force and EMG data were measured using the force transducers and wireless EMG sensor, respectively. Results: The results showed that the maximum voluntary torque increased the most with relatively large and fast (96 Nm, 1 sec) pre-activation condition. Similarly, with relatively large and fast (96 Nm, 1 sec) preactivation, it was found that the integrated EMG (iEMG) of the agonist muscles increased, while no significant changes in the co-contraction of the antagonist muscles for the knee extension. Also, the effect of pre-activation conditions on the rate of torque development was not statistically significant. Conclusion: The current findings suggest that relatively larger in magnitude and shorter in duration as the properties of pre-activation lead to a larger magnitude of maximal voluntary torque, possibly due to the increased activity of the agonist muscles during knee extension.

• 정보보호학회논문지
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• 제33권5호
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• pp.761-773
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• 2023

본 논문에서는 딥러닝 분야에서 사용되는 신경망 모델, 그중에서도 다중 계층 퍼셉트론 모델에 사용되는 지수함수 기반의 활성화 함수를 근사 함수로 대체하고, 근사 함수에 마스킹을 적용함으로써 신경망 모델의 추론 과정의 전력 분석 저항성을 높이는 방법을 제안한다. 이미 학습된 값을 사용하여 연산하는 인공 신경망의 추론 과정은 그 특성상 가중치나 편향 등의 내부 정보가 부채널 공격에 노출될 위험성이 있다. 다만 신경망 모델의 활성화 함수 계층에서는 매우 다양한 함수를 사용하고, 특히 지수함수 기반의 활성화 함수에는 마스킹 기법 등 통상적인 부채널 대응기법을 적용하기가 어렵다. 따라서 본 연구에서는 지수함수 기반의 활성화 함수를 단순한 형태로 근사하여도 모델의 치명적인 성능 저하가 일어나지 않음을 보이고, 근사 함수에 마스킹을 적용함으로써 전력 분석으로부터 안전한 순방향 신경망 모델을 제안하고자 한다.

• 한국항공우주학회지
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• 제31권4호
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• pp.26-34
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• 2003

본 논문에서는 이동최소자승 근사법 등의 무요소 근사법을 이용하여 유한요소모델 절점의 연결성과 무관하게 유한요소 절점을 자유로이 활성화시킬 수 있는 절점활성화 기법을 제안하고, 제안된 방법의 타당성을 고찰하기 위해 일관성 조건, 수치해의 유계성 등에 대한 이론적 고찰을 수행한다. 제안된 절점활성화 기법을 이용하면 많은 수의 유한요소 절점 중 관심이 있는 일부 절점만을 선택, 활성화시켜 이들만을 미지수로 이용하여 문제를 해석할 수 있기 때문에 설계 및 재해석을 효율적으로 수행할 수 있다.

• 대한물리치료과학회지
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• 제20권1호
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• pp.37-42
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• 2013

Background : The purpose of this study is to find out the impact of kinesio-taping method for female university students, who are vulnerable to constipation, on the activation of intestine. Methods : This study has been conducted for a total of three weeks including the pre-inspection, and it explained the purpose of the study upon selecting the adequate subjects who met the criteria for constipation among the female students. And It chose the nine students, who agreed to the experiment, as the subjects. It verified the frequency and time of excretion before experiment and the constipation ejaculation measure, and compared pre-arbitration with post-arbitration as for the time and frequency of excrement, the point of constipation ejaculation measure, etc. after two weeks since the application of tape. Result : The frequency of excrement after arbitration increased compared with pre-arbitration as result of the application of kinesio-taping method, and the time, which was taken for excrement, decreased. It was also shown that the point decreased in the point comparison for constipation ejaculation measure; thus, it obtained the result that showed the improvement of the level of constipation and all were statistically significant(p<.05). Conclusion : It is believed that kinesio-taping method has a positive impact on the activation of intestine of female university students.