• Title/Summary/Keyword: Activation Properties

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The Properties of carbonized and activated RDF (탄화 및 활성화된 RDF의 특성 연구)

  • Choi, Yeong-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.87-90
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    • 2006
  • The experimental study has been done for two kinds of pelletized RDFs to Investigate the carbonization effect to the chlorine concentrations, the heating value and the yield of Produced char in variable conditions of the carbonizing temperature and reaction time. One(RDF-1) is made of 100% wasted plastics and the other(RDF-2) is made of 60% wasted paper with 40% wasted plastics. The screw type carbonizer heated Indirectly by oil burner was used for the experiment and RDF feeding rate was 3kg/hr. The carbonizing temperature was 300, 350 400 and $45^{\circ}C$ and the reaction tine was 5, 10 and 15 minutes respectively. As the increase of carbonizing reaction time and temperature, the chlorine reduction rate was increased and oppositely the yield of char was decreased At the temperature of $400^{\circ}C$ and reaction time of 10 minutes the chlorine reduction rate was 60% and the char yield rate was 80% for the RDF-1 and those of RDF-2 were 80% and 75%, respectively. Additional activation experiment to the char produced from RDF-2 was done in the activation reactor by hot steam supply. As the increase of activation time the iodine number was increased. At the activation time of 20 minutes the iodine number was 552mg/g and the yield of activated carbon was 16%.

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Preparation and Characterization of KOH-Activated Carbons Developed from Petroleum Coke

  • Sayed Ahmed, S.A.;Abo El-Enin, Reham M.M.;El-Nabarawy, Th.
    • Carbon letters
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    • v.10 no.4
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    • pp.293-299
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    • 2009
  • Potassium hydroxide activated carbons were prepared from Egyptian petroleum cokes with different KOH/coke ratios and at different activation temperatures and times. The textural properties were determined by adsorption of nitrogen at $-196^{\circ}C$. The adsorption of iodine and methylene blue was also investigated at $30^{\circ}C$. The surface area and the non-micropore volume increased whereas the micropore volume decreased with the increase of the ratio KOH/coke. Also the surface area and porosity increased with the rise of activation temperature from 500 to $800^{\circ}C$. Textural parameter considerably increased with the increase of activation time from 1 to 3 h. Further increasing of activation time from 3 to 4 h was associated with a less pronounced increase in textural parameters. The adsorption of iodine shows the same trend of surface area and porosity change exhibited by nitrogen adsorption, with KOH/coke ratio and temperature of activation. Adsorption of methylene blue follows pseudo-first-order kinetics and its equilibrium adsorption follows Langmuir and D-R models.

Preparation and Characterization of OXI-PAN Based Carbon Fibers Activated by Hydroxides (수산화물에 의해 활성화된 OXI-PAN계 섬유의 제조 및 특성)

  • Moon, Sook-Young;Han, Dong-Yun;Lee, Byung-Ha;Lim, Yun-Soo
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.469-474
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    • 2005
  • Activated Carbon Fibers (ACFs) are widely used as adsorbents in technologies related to pollution abatement due to their highly porous structure and large adsorption capacity. The porous structure and surface area of ACFs depends strongly on both the activation processes arid the nature .of the precursors. The chemical activation with hydroxides has recently been, of great interest as it permits the preparation of activated carbon fibers with highly developed porosity. In this work, OXI-PAN fiber used as precursor for the preparation of activated carbon fibers by chemical activation with KOH and NaOH. The affects of several activation conditions on the surface properties, pore size distribution and adsorption capacity of Ag ion and Iodine ion on ACFs studied.

A Simulation of the Myocardium Activation Process using the Discrete Event Cell Space Model (DEVCS 모델을 사용한 심근 활성화과정의 시뮬레이션)

  • Kim Gwang-Nyeon;Jung Dong-Keun;Kim Gi-Ryon;Choi Byeong-Cheol;Lee Jung-Tae;Jeon Gye-Rok
    • Journal of the Korea Society for Simulation
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    • v.13 no.4
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    • pp.1-16
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    • 2004
  • The modelling and simulation of the activation process for the heart system is meaningful to understand special excitatory and conductive system in the heart and to study cardiac functions because the heart activation conducts through this system. This thesis proposes two dimensional cellular automaton(CA) model for the activation process of the myocardium and conducted simulation by means of discrete time and discrete event algorithm. In the model, cells are classified into anatomically similar characteristic parts of the heart and each of cells has a set of cells with preassigned properties. Each cell in this model has state variables to represent the state of the cell and has some state transition rules to change values of state variables executed by state transition function. The state transition rule is simple as follows. First, the myocardium cell at rest stay in passive state. Second, if any one of neighborhood cell in the myocardium cell is active state then the state is change from passive to active state. Third, if cell's state is an active then automatically go to the refractory state after activation phase. Four, if cell's state is refractory then automatically go to the passive state after refractory phase. These state transition is processed repeatedly in all cells through the termination of simulation.

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Heat Inactivation of Proteolytic Enzymes in Papaya Latex (Papaya Latex에 있는 단백질분해효소(蛋白質分解酪素)들의 열불활성(熱不活性)에 관하여)

  • Noh, Bong-Soo;Park, Kwan-Hwa
    • Korean Journal of Food Science and Technology
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    • v.12 no.3
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    • pp.209-215
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    • 1980
  • Proteases from papaya latex were partially purified by ammonium sulfate precipitation and separated into two fractions (Fraction I and II ) by carboxymethyl cellelose column chromatography. Each fraction, mixture of the two fractions, and crude extract of the papaya latex at pH 7.0 were inactivated at the range of $60{\sim}90^{\circ}C$ and thermal properties of the enzymes were investigated. In the thermal inactivation of fraction I, the enthalpy of activation was 89.5 kJ/mol; the entropy of activation, -44.0 J/mol K; the free energy of activation, 104.6 kJ/mol; z-value, $25^{\circ}C$. For fraction II, the enthalpy of activation was 96.5 kJ,/mol; the entropy of activation, -22.0 J/mol K; the free energy of activation, 104.0 kJ/mol; z-value, $23^{\circ}C$. For the mixture of fraction I and II, the enthalpy of activation was 90.9 kJ/mol; the entropy of activation, -38.8 J/mol·K; the free energy of activation, 104.2 kJ/mol; z-value, $24.6^{\circ}C$. For crude extract, the enthalpy of activation was 113.8 kJ/mol; the entropy of activation, 22.0 J/mol·K; the free energy of activation, 106.2 kJ/mol; z-value, $23.2^{\circ}C$. It was indicated that the fraction I was more heat-stable than the fraction II and this suggested that the thermal stability of the proteases in papaya latex is probably due to the fraction I.

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Electrical Transport Properties of Gd0.33Sr0.67FeO3 Ceramics (Gd0.33Sr0.67FeO3 세라믹스의 전기전도 특성)

  • Jung, Woo-Hwan
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.131-135
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    • 2006
  • In this study, the dielectric, magnetic and transport properties of $Gd_{0.33}Sr_{0.67}FeO_3$ have been analyzed. The dielectric loss anomaly was found to be around 170 K. The activation energy corresponding to relaxation process of this dielectric anomaly was 0.17 eV. From the temperature dependence of the characteristic frequency, we concluded that the elementary process of the dielectric relaxation peak observed is correlated with polaron hopping between $Fe^{3+}\;and\;Fe^{4+}$ ions. The electrical resistivity displayed thermally activated temperature dependence above 200 K with an activation energy of 0.16 eV. In addition, the temperature dependence of thermoelectric power and resistivity suggests that the charge carrier responsible for conduction is strongly localized.

Electrical Properties of Ultrafine $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ Powders Prepared by Glycine Nitrate Process for the High Efficient Solid Oxide Fuel Cell Applications

  • Lee, Kang-Ryeol;Park, Sung
    • The Korean Journal of Ceramics
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    • v.7 no.1
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    • pp.6-10
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    • 2001
  • Ultrafine $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ solid solution powders synthesized by the glycine-nitrate process, with specific surface areas of $19-23\;\textrm{m}^2$/g were sintered at $1500^{\circ}C$ for various sintering times and then their electrical characteristics were investigated using AC impedance and four-point probe measurements. The electrical resistivity of the sintered $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ bodies showed the minimum value at the sintering time of 10 hrs. The minimum total resistivity of the $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ bodies sintered at $1500^{\circ}C$ for 10 hrs seems to result from the lowest activation energy for the electrical resistivity by the combination between the activation energies for the resistivities at the grain interior and grain boundary.

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Thermal and Electrical Properties of Conductive Polymer and PMMA, Eccogel Blend (도전성 고분자와 PMMA 및 Eccogel Blend의 열적 성질 및 전기적 특성에 관한 연구)

  • Park, Seong-Ja;Kim, Byung-Chul;Kim, Dong-Keun;Seul, Soo-Duk
    • Elastomers and Composites
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    • v.24 no.3
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    • pp.185-192
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    • 1989
  • The thermal degradation of the homopolymer poly(methyl methacrylate)(PMMA)/tetra cyano quino dimethane(TCNQ) blend and Eccogel/TCNQ blend were carried out using the thermogravimetric method in the stream of nitrogen gas with 60ml/min at various heating rate from 1 to $20^{\circ}C/min$. Friedman and Ozawa mathermatical methods were used to obtain the value of activation energy. Produced electrical properties and activation energy by electric conductivity method that used LCR meter.

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GLOBAL ROBUST STABILITY OF TIME-DELAY SYSTEMS WITH DISCONTINUOUS ACTIVATION FUNCTIONS UNDER POLYTOPIC PARAMETER UNCERTAINTIES

  • Wang, Zengyun;Huang, Lihong;Zuo, Yi;Zhang, Lingling
    • Bulletin of the Korean Mathematical Society
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    • v.47 no.1
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    • pp.89-102
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    • 2010
  • This paper concerns the problem of global robust stability of a time-delay discontinuous system with a positive-defined connection matrix under polytopic-type uncertainty. In order to give the stability condition, we firstly address the existence of solution and equilibrium point based on the properties of M-matrix, Lyapunov-like approach and the theories of differential equations with discontinuous right-hand side as introduced by Filippov. Second, we give the delay-independent and delay-dependent stability condition in terms of linear matrix inequalities (LMIs), and based on Lyapunov function and the properties of the convex sets. One numerical example demonstrate the validity of the proposed criteria.

Thermal Properties of Interpenetrating Polymer Network Epoxy-silicone Compound

  • Cho, Young-Shin;Shim, Mi-Ja;Klm, Sang-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.475-478
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    • 1999
  • The thermal properties of epoxy resin/siloxane for the electrical insulation were investigated by using dynamic DSC run method. As the heating rate increased, the peak temperature on dynamic DSC curve increased. From the linear relation on the Kissinger plot the curing reaction activation energy and pre-exponential factor could be obtained. The curing activation energy from the straight line of the Kissinger plot was 46.72 kJ/mol.

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