• Title/Summary/Keyword: Activated material

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Pretreatment of Waste-activated Sludge for Enhancement of Methane Production (메탄발효 효율향상을 위한 하.폐수 슬러지의 전처리 기술)

  • NamKung, Kyu-Cheol;Jeon, Che-Ok
    • Microbiology and Biotechnology Letters
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    • v.38 no.4
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    • pp.362-372
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    • 2010
  • Although different disposal routes of waste-activated sludge are possible, anaerobic digestion plays an important role for its abilities to further transform organic matter into methane. The potential of using methane as energy source has long been widely recognised and the present paper extensively reviews the principles of anaerobic digestion, the process parameters and hydrolysis. Hydrolysis is recognised as rate-limiting step in the complex digestion process. To accelerate the digestion and enhance the production of biogas, various pre-treatments can be used to improve the rate-limiting hydrolysis. These treatments include mechanical, thermal, chemical and biological interventions to the feedstock. All pre-treatments result in a lysis or disintegration of sludge cells, thus releasing and solubilizing intracellular material into the water phase and transforming refractory organic material into biodegradable species. The reader will finally be guided to extensive discussion for anaerobic digestion processes.

The Influence of the Mg-doped p-GaN Layer Activated in the O2 Ambient on the Current-Voltage Characteristics of the GaN-Based Green LEDs (O2 분위기에서 p-GaN 층의 Mg 활성화가 GaN계 녹색 발광소자에 미치는 전류-전압특성)

  • 윤창주;배성준
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.441-448
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    • 2002
  • The electrical properties of the GaN-based green light emitting diodes(LEDs) with the Mg-doped p-GaN layer activated in $N_2$ or $O_2$ ambient have been compared. For the $N_2$ -ambient activation the current-voltage behavior of LEDs has been found to be improved when the Mg dopants activation was performed in the higher temperature. However, for the $O_2$-ambient activation the current-voltage characteristic has been observed to be enhanced when the Mg dopants activation was carried out in the lower temperature. The minimum forward voltage at 20mA was obtained to be 4.8 V for LEDs with the p-GaN layer activated at $900^{\circ}C$ in the $N_2$ ambient and 4.5V for LEDs with the p-GaN layer treated at $700^{\circ}C$ in the $O_2$ambient, repectively. The forward voltage reduction of the LEDs treated in the $O_2$-ambient may be related to the oxygen co-doping of the p-GaN layer during the activation process. The $O_2$ -ambient activation process is useful for the enhancement of the LED performance as well as the fabrication process since this process can activate the Mg dopants in the low temperature.

Fabrication and Mechanical Properties of WC-Mo2C-Co Hard Materials by the Pulsed Current Activated Sintering Method (펄스 전류 활성 소결법을 이용한 WC-Mo2C-Co 소결체 제조 및 기계적 특성 평가)

  • Youn, Hee-Jun;Bang, Han-Sur;Bang, Hee-Seon;Oh, Ik-Hyun;Park, Hyun-Kuk
    • Korean Journal of Metals and Materials
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    • v.50 no.12
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    • pp.921-929
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    • 2012
  • The pulsed current activated sintering method (PCAS) is a new rapid sintering method that was developed recently for fabricating ceramics and composites. This method combines a high temperature for a short time with pressure application. In this work, PCAS was used to fabricate $WC-5wt%Mo_2C-5wt%$ Co hard material using WC, $Mo_2C$, and Co. The $WC-Mo_2C-Co$ was almost completely dense with a relative density of up to 100% after the simultaneous application of a pressure of 60 MPa and electric current for 11 min without grain growth. The average grain size of WC that was produced through PCAS was about $0.5-0.6{\mu}m$. The vickers hardness and fracture toughness of the $WC-5wt%Mo_2C-5wt%$Co hard materials were about $2453.5kg/mm^2$ and $7.9MPa{\cdot}m^{1/2}$, respectively, for 60 MPa at $11200^{\circ}C$.

An Experimental Study on Microleakage in Light-activated Temporary Filling Materials (광중합형 임시충전재의 미세누출에 관한 실험연구)

  • Hwang, Su-Hyun;Yu, Ji-Su;Kim, Sun-Ju
    • Journal of dental hygiene science
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    • v.11 no.4
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    • pp.333-337
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    • 2011
  • The purpose of this experiment was to examine possibility of microleakage by water, temperature change, and bite force inside the mouth during the period of using light-activated temporary filling materials. 2 kinds of light-activated temporary filling materials were used in order to measure weight and compressive strength and to evaluate microleakage between filling material and cavity wall according to frequency of thermal circulation. First, Light-activated temporary filling material was increased the weight, which was measured according to the period of using. As for the result of comparing between products, the weight of Quicks was indicated to be higher. Second, Compressive strength of Spacer had significant difference depending on period of using. However, significant difference wasn't shown in the compressive strength of Quicks. In Spacer that showed significant difference, the compressive strength increased greatly in the difference of 3 days. Third. As for micro-leakage according to frequency of thermal circulation, the microleakage was indicated to be the highest in the group that carried out 7,000 times. The group with operation of 1,000 times and the group with operation of 3,000 times were indicated the statistically lower micro-leakage than the group with operation of 7,000 times. This study brought about a rise in micro-leakage depending on the passage in the period of using. However, it is obvious fact that micro-leakage increases according to the passage of time after restoration.

Fabrication and analysis of electrochemical performance for energy storage device composed of metal-organic framework(MOF)/porous activated carbon composite material (금속유기골격체(Metal-organic Framework) 소재가 첨가된 다공성 활성탄소 복합재료 전극 기반의 에너지 저장 매체 제조 및 전기화학적 특성 분석)

  • Lee, Kyu Seok;Jeong, Hyeon Taek
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.2
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    • pp.260-267
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    • 2020
  • In this study, supercapacitor based on the all solid state electrolyte with PVA(polyvinyl alcohol), ionic liquid as a BMIMBF4(1-buthyl-3-methylimidazolium tetrafluoroborate) and activated carbon/Ni-MOF composite was fabricated and characterized its electrochemical properties with function of MOF. In order to analysis and comparison that electrochemical performances [including cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge test] of prepared supercapacitor based on activated carbon/Ni-MOF composite and all solid state electrolyte. As a result, specific capacitance of the supercapacitor without Ni-MOF was 380 F/g which value decreased to 340 F/g after adding Ni-MOF to activated carbon as a electrode material. This result exhibited that decreased electrochemical property of the supercapacitor effected on physical hinderance in the electrode. In further, it needs to optimization of the Ni-MOF amount (wt%) in the electrode composite to maximize its electrochemical performances.

A Study on the Activated Carbon Injection and Filtration Process for Removal of Chlorinated Organic Compound in the Incinerator Flue Gas (활성탄의 분무 여과에 의한 소각로 배가스 중의 유기 염소계 화합물의 제거 공정 연구)

  • Choo, Changupp;Whang, Jaedong;Lee, Joyoung;Cho, Chulhoon;Shin, Byungchul
    • Clean Technology
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    • v.6 no.2
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    • pp.113-119
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    • 2000
  • Due to the toxicity of dioxin in the incinerator flue gas, it becomes a severe social problem. Activated carbon adsorption process is one of the methods for removing dioxin in the flue gas and was investigated its performance for removing hazardous organic compounds. Since dioxin is very hazardous material, 1,2-dichlorobenzene(o-DCB), one of the precursor material of dioxin, was used as adsorbate. The effects of air flow rate, pressure drop in the bag filter, operation temperature of bag filter, and kinds of adsorbents on the removal of o-DCB were measured and analysed. Experimental results showed that the operating temperature was recommended within the range of $140{\sim}170^{\circ}C$ considering the operating condition of incinerator. Also it was necessary to maintain the pressure drop of bag filter $120mmH_2O$ for enhancing the adsorption at the surface layer of activated carbon formed on the bag filter. The use of mixture of same amount of activated carbon and diatomite showed more than 90% removal of o-DCB and also reduced the consumption of activated carbon.

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Effect of highly activated calcium on the growth of mushrooms (고활성칼슘의 버섯 생육에 대한 효과)

  • Chang, Hyun-You;Goo, Ja-Joon
    • Journal of Mushroom
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    • v.3 no.1
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    • pp.35-39
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    • 2005
  • Highly Activated Calcium(below HAC) is the oxidized calcium made by dissolving shell materials with high voltage about 15,000V and high temperature ($1,500{\sim}5,000^{\circ}C$). This HAC is a material with a very high degree of purity without toxicant. This HAC decreases chemical reaction so the degree of being active and dissolving living material is outstanding. The effects of HAC on the propagation of mushrooms are following. In the case of the Pleurotus ostreatus, when controlling media moisture by mixing with the HAC, mycelium cultivating days were shortened by 2days. The day required for primordial formation after inoculation(DPI) were one day faster. The number of stem was 15 and individual weight was 248g/850cc, a 6.5% increase. In the case of Pleurotus eryngii, when controlling media moisture by mixing with the highly activated calcium, mycelium cultivating days were shortened by 3days. DPI were l day faster. The day required for colonization after inoculation was shortened by 6days and individual weight was 108.8g/850cc, a 9.7% increase. In the case of Flammulina velutipes, the highly activated calcium was the best for scraping up mycelium. Mycelium incubating days were shortened by 2days. DPI were shortened by 3days. The day required for colonization after inoculation was 1day faster and the period of cultivation was shortened by 3days. Individual weight was 165g/850cc, a 6.7% increase. In the case of Lentinula edodes, when mixing media with the highly cultivated calcium, cultivating days were shortened by 3 days. The days for becoming brown in color were 2 days faster and the days of the first harvest were shortened by 4 days. The weight of mushrooms was 169g/2kg, a 9.7% increase.

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Characteristics of Bacterial Community for Biological Activated Carbon(BAC) by Culturable and Unculturable Methods. (배양적 및 비배양적 방법에 의한 생물활성탄 부착세균 군집 특성)

  • Park, Hong-Ki;Jung, Eun-Young;Jung, Mi-Eun;Jung, Jong-Moon;Ji, Ki-Won;Yu, Pyung-Jong
    • Journal of Life Science
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    • v.17 no.9 s.89
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    • pp.1284-1289
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    • 2007
  • The Biological Activated Carbon (BAC) process in the water treatments represents a kind of biofiltration process which capabilities of bacteria to remove organic matters are maximized. It enables to eliminate organic matters and effectively reduce microbial regrowth potentials. As attached bacteria employ natural organic matter as a substrate, they are significantly dependent on indigenous microorganisms. In this study, characteristics of bacterial community by culturable and unculturable Methods have been conducted in a pilot plant using SAC in water treatment process at the downstream of the Nakdong River. Based on the results, HPC and bacterial- production for coal-based activated carbon material were $1.20{\sim}56.2{\times}l0^7$ cfu/g and $1.2{\sim}3.7\;mgC/m^{3}h$, respectively, in the SAC process. The highest level of attached bacteria biomass and organic carbon removal efficiency was found in the coal-based activated carbon. The genera Pseudomonas, Flavobacterium, Alcaligenes, Acilzetobacter, and Spingomonas were identified for each activated carbon material. Pseudomonas vesicularis was the dominant species in the coconut- and coal-based materials, where as Pseudomonas cepacia was the dominant species in the wood-based material. The Scanning Electron Microscope (SEM) observation of the activated carbon surface also found the widespread distribution of rod form and coccus. The community of attached bacteria was investigated by performing Fluorescent in situ hybridization (FISH) analysis. a group was dominant in coal, wood and coccunt-based materials, ${\alpha},\;{\beta}\;and\;{\gamma}$ group ranged from 27.0 ${\sim}$ 43.0%, 7.1 ${\sim}$ 22.0%, 11.3 ${\sim}$ 28.6%, respectively. These results suggest that a group bacterial community appears to be regulated removal efficiency of organic material in water treatment process.

Quality Improvement of Crude Glycerol from Biodiesel Production Using Activated Carbon Derived from Krabok (Irvingia malayana) Seed Shells

  • Wuttichai Roschat;Sarunya Donrussamee;Phatcharanan Smanmit;Samlit Jikjak;Tappagorn Leelatam;Sunti Phewphong;Krittiyanee Namwongsa;Preecha Moonsin;Vinich Promarak
    • Korean Journal of Materials Research
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    • v.34 no.1
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    • pp.1-11
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    • 2024
  • This research investigated the preparation of activated carbon derived from Krabok (Irvingia malayana) seed shells to improve the quality of crude glycerol obtained during biodiesel production. The activated carbon was prepared using a dry chemical activation method with NaOH, utilizing an innovative biomass incinerator. The results revealed that the resulting KC/AC-two-step exhibited favorable physicochemical adsorption properties, with a high surface area of 758.72 m2/g and an iodine number of 611.10 mg/g. These values meet the criteria of the industrial product standard for activated carbon No. TIS 900-2004, as specified by the Ministry of Industry in Thailand. Additionally, the adsorption efficiency for methylene blue reached an impressive 99.35 %. This developed activated carbon was then used to improve the quality of crude glycerol obtained from biodiesel production. The experimental results showed that the KC/AC-two-step increased the purity of crude glycerol to 73.61 %. In comparison, commercially available activated carbon (C/AC) resulted in a higher crude glycerol purity of 81.19 %, as analyzed by the GC technique. Additionally, the metal content (Zn, Cu, Fe, Pb, Cd, and Na) in purified glycerol using KC/AC-two-step was below the standards for heavy metals permitted in food and cosmeceuticals by the Food and Drug Administration of Thailand and the European Committee for Food Contact Materials and Articles. As a result, it can be inferred that Krabok seed shells have favorable properties for producing activated carbon suitable as an adsorbent to enhance crude glycerol purity. Furthermore, the improved crude glycerol from this research has potential for various industrial applications.

Protein Analysis Using a Combination of an Online Monolithic Trypsin Immobilized Enzyme Reactor and Collisionally-Activated Dissociation/Electron Transfer Dissociation Dual Tandem Mass Spectrometry

  • Hwang, Hyo-Jin;Cho, Kun;Kim, Jin-Young;Kim, Young-Hwan;Oh, Han-Bin
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3233-3240
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    • 2012
  • We demonstrated the combined applications of online protein digestion using trypsin immobilized enzyme reactor (IMER) and dual tandem mass spectrometry with collisionally activated dissociation (CAD) and electron transfer dissociation (ETD) for tryptic peptides eluted through the trypsin-IMER. For the trypsin-IMER, the organic and inorganic hybrid monolithic material was used. By employing the trypsin-IMER, the long digestion time could be saved with little or no sacrifice of the digestion efficiency, which was demonstrated for standard protein samples. For three model proteins (cytochrome c, carbonic anhydrase, and bovine serum albumin), the tryptic peptides digested by the IMER were analyzed using LC-MS/MS with the dual application of CAD and ETD. As previously shown by others, the dual application of CAD and ETD increased the sequence coverage in comparison with CAD application only. In particular, ETD was very useful for the analysis of highly-protontated peptide cations, e.g., ${\geq}3+$. The combination approach provided the advantages of both trypsin-IMER and CAD/ETD dual tandem mass spectrometry applications, which are rapid digestion (i.e., 10 min), good digestion efficiency, online coupling of trypsin-IMER and liquid chromatography, and high sequence coverage.