• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.781-786
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• 2001

The Salt attack is one of the primary factors that cause the deterioration of durability in steel reinforced concrete structure. And to depreciate the deterioration from the Salt attack in concrete structure, pozzolanic materials are used widely in recent years. In this study, experiments about the resistance of chloride infiltration of concrete according to the replacement rations of Activated Hwangtoh and various pozzolanic materials(silica fume, fly ash, blast furnace slag and non Activated/Activated Hwangtoh) are performed and the results of this study were shown as follows; 1) As the replacement ratios of Activated Hwangtoh were getting higher, the strength of concrete was increased and in case of various pozzolanic materials, strength of Activated Hwangtoh in specimen was better than that of fly ash, blast furnace slag and non Activated Hwangtoh. 2) As the replacement ratios of Activated Hwangtoh were getting higher, the resistance of chloride infiltration of concrete was increased and in case of various pozzolanic materials, silica fume is better than any other pozzolanic materials and Activated Hwangtoh was better than that of fly ash, blast furnace slag and non Activated Hwangtoh.

• Journal of the Korea Concrete Institute
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• v.22 no.5
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• pp.685-694
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• 2010

As a eco-friendly material, Hwangtoh (red clay) has been studied for complete or partial replacement of portland cement. Most of existing studies focused on the material properties of the Hwangtoh concrete including the compressive strength, drying shringkage, and creep. In the present study, the shear strength of the beams made with the Hwangtoh concrete was tested. Further, bond strength of tension re-bars embedded in the Hwangtoh concrete was tested. One of the concrete tested consisted of activated Hwangtoh replacing 20% of the cement. The other consisted 100% activated. Hwangtoh replacing all the cement. The beam specimens were tested under two point static loading. The test result showed that the shear strength of activated Hwangtoh concrete beams replacing 20% and 100% of cement was equivalent to that of the ordinary portland cement concrete beam. However, the bond strength of activated Hwangtoh concrete replacing 100% of the cement was less than that of the ordinary portland cement concrete.

• Journal of the Korea Concrete Institute
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• v.22 no.4
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• pp.567-574
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• 2010

As a eco-friendly material, Hwangtoh(red clay) has been studied for a partial or complete replacement of portland cement. Most of existing studies focused on the mechanical properties of the Hwangtoh concrete including the compressive strength, drying shrinkage, creep. In the present study, the flexural capacity of the beams made with the Hwangtoh concrete was tested. One of the concrete tested consisted of activated Hwangtoh replacing 20% of the cement. The other consisted 100% activated Hwangtoh replacing all the cement. The simple beams were tested under two point static loading. The flexural strength, cracking moment, deflection, and ductility were compared with those of the beams made with ordinary portland cement concrete.

• Journal of the Korea Concrete Institute
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• v.13 no.2
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• pp.123-129
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• 2001

Pozzolan is to improve the strength and the durability of concrete as a result of the pozzolanic reaction, Broadly speaking, pozzolanic materials can be artificial materials, such as slica fume and fly ash, and natural material, such as rice husk ash, clay, volcanic ash, clayish pozzolan. Hwangtoh is a mineral which belongs to a group of matakaolin, especially halloysite, and the main elements is SiO$_2$, Al$_2$O$_3$, Fe$_2$O$_3$. The purpose of this study is to examine the application of Hwangtoh for the concrete admixtures, the composition of this study is shown as follows. Chapter I is analysis for properties of concrete as the kinds of admixture, and Chapter H is analysis for properties of concrete as the replacement ratio of activated Hwangtoh. As a result of this study, Hwangtoh is found to have high practical use as pozzolanic material, and the pertinent range of replacement ratios of Hwangtoh on cement are 10∼20 %.

• Architectural research
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• v.11 no.1
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• pp.25-33
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• 2009

This study presents the testing of 15 hwangtoh-based cementless concrete mixes to explore the significance and limitations of the development of eco-friendly concrete without carbon dioxide emissions while maintaining various beneficial effects. Hwangtoh, which is a kind of kaolin, was incorporated with inorganic materials, such as calcium hydroxide, to produce a cement-less binder. The main variables investigated were the water-to-binder ratio and fine aggregate-to-total aggregate ratio to ascertain the reliable mixing design of hwangtoh-based cementless concrete. The variation of slump with elapsed time was recorded in fresh concrete specimens. Mechanical properties of hardened concrete were also measured: including compressive strength gain, splitting tensile strength, moduli of rupture and elasticity, stress-strain relationship, and bond resistance. In addition, mechanical properties of hwangtoh-based cement-less concrete were compared with those of ordinary portland cement (OPC) concrete and predictions obtained from the design equations specified in ACI 318-05 and CEB-FIP for OPC concrete, wherever possible. Test results show that the mechanical properties of hwangtoh-based concrete were significantly influenced by the water-to-binder ratio and to less extend by fine aggregate-to-total aggregate ratio. The moduli of rupture and elasticity of hwangtoh-based concrete were generally lower than those of OPC concrete. In addition, the stress-strain and bond stress-slip relationships measured from hwangtoh-based concrete showed little agreement with the design model specified in CEB-FIP. However, the measured moduli of rupture and elasticity, and bond strength were higher than those given in ACI 318-05 and CEB-FIP. Overall, the test results suggest that the hwangtoh-based concrete shows highly effective performance and great potential as an environmental-friendly building material.

• Journal of the Korea Institute of Building Construction
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• v.14 no.2
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• pp.170-176
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• 2014

This study examined the effect of chemical attack on the stress-strain relationship of alkali-activated Hwangtoh concrete. Water-to-binder ratio and air content were selected as mixture parameters. The stress-strain relationship of concrete was measured at chemical immersion times of 0, 7, 28, 56, and 91 days from an age of 28 days. Based on the test results, the reduction in compressive strength of alkali-activated hwangtoh concrete owing to chemical attack was formulated. In sddition the present study demonstrated that the stress-strain behavior of concrete under chemical attack is significantly dependent on the air content and chemical immersion time, indicating the rate of decrease of modulus of elasticity was greater than that of compressive strength at the same immersion time. As a result, the stress-strain behavior of concrete under chemical attack was significantly inconsistent with the conventional models specified in the CEB-FIP provision.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.1
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• pp.134-141
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• 2017

Many studies have been conducted with respect to the materials to replace the cement in order to reduce the carbon dioxide emissions during the cement production. Activated hwangtoh as cement replacement material goes through calcination process of $850^{\circ}C$. PVA fibers and GFRP bars are used in order to compensate for the cracks of activated hwangtoh concrete(AHC). This paper presents an experimental study investigating the bond characteristic of GFRP bars in PVA fiber reinforced AHC under tensile loads. Experimental results showed that average bond strength factor of specimens with and without PVA fiber was 2.27~2.48 and was not significantly affected by the ratio of PVA fiber andactivated hwangtoh. In addition, as the bond length was increased, the bond strength was reduced.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.389-390
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• 2010

this study is preliminary experimental research for develop methods to utilize the natural Hwangtoh as replacement materials for the cement in concrete, via alkali activation at $60^{\circ}C$ using NaOH solution and liquefied $Na_2SiO_3$ in a manufacture process of Hwangtoh concrete binder.

• Journal of the Korea Concrete Institute
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• v.20 no.5
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• pp.619-626
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• 2008

There have been numerous studies to develop eco-friendly concrete. The attempt to reduce the amount of cement usage is suggested as one of the solutions for eco-friendly concrete. To reduce the amount of cement usage, the pozzolan-reaction materials such as ground granulated blast furnace slag, fly ash, and meta kaolin are widely used as the mineral admixture. Hwangtoh which deposited broadly in Korea is a well known eco-friendly material and the activated Hwangtoh with pozzolan-reaction can be practically used as a mineral admixture of concrete. Meanwhile, PET fiber made of recycled PET bottle is a type of recycled material, which can be used to control micro cracks in concrete. But the study about concrete mixed with recycled PET fiber is insufficient and the research of Hwangtoh concrete mixed with PET fiber is urgently needed presently. In this study, experiment and analysis flexural behavior of Hwangtoh concrete blended with recycled PET fiber are carried out. The results are discussed in detail.

• Advances in concrete construction
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• v.11 no.4
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• pp.307-314
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• 2021

Activated hwangtoh (ACT) is a natural resource abundant in South Korea, approximately 15.0% of soil. It is an efficient mineral admixture that has activated pozzolanic properties through high-temperature heating and rapid cooling. The purpose of this study is to improve a curb mixture that can reduce NOx outside and investigate durability performance. To this end, mortar curb specimens were manufactured by replacing OPC with ACT. The ACT substitution ratios of 0.0, 10.0, and 25.0% were considered, and mechanical and durability tests on the curb specimens were conducted at 28 and 91 days of age. Steam curing was carried out for three days for the production of curbs, which was very effective to strength development at early ages. The reduction in strength at early ages could be compensated through this process, and no significant performance degradation was evaluated in the tests on chloride attack, carbonation, and freezing and thawing. The mortar curb with an ACT of 10.0~25.0% replacement ratio exhibited clear NOx reduction through photocatalytic (TiO2) treatment. This is due to the increase in physical absorption through surface absorption and the photocatalyst-containing TiO2 coating. In this study, the reasonable range of the ACT replacement ratio for NOx reduction was quantitatively evaluated through a comprehensive analysis of each test.