• Title/Summary/Keyword: Activated energy

Search Result 987, Processing Time 0.029 seconds

Effect of Surface-Modification of Activated Carbon for Adsorption of Uranium in Radioactive Liquid Wastes (방사성 액체 폐기물 내 우라늄 흡착에 대한 활성탄의 표면 처리 영향)

  • Jang, J.D.;Lee, K.W.;Song, K.C.;Kang, H.;Oh, W.Z.
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.5
    • /
    • pp.827-835
    • /
    • 2000
  • Adsorption characteristics of uranium on activated carbon whose surface is modified with $HNO_3$ and/or NaOH were investigated. Na-OAC, which was the activated carbon treated with both $HNO_3$ and NaOH. showed higher adsorption capacity than OAC, which was treated with $HNO_3$, as well as Na-AC, which was treated with only NaOH. This can be explained based on the surface functional groups increased by surface modification of activated carbon and the change of solution pH as adsorption proceeds. From these experimental results, it is thought that the pH of uranium solution and surface functional groups on the activated carbon surface are the governing factors in the uranium adsorption system.

  • PDF

Study on Adsorption Kinetic of Amaranth Dye on Activated Carbon (활성탄에 의한 아마란스 염료의 흡착동력학에 관한 연구)

  • Lee, Jong-Jib
    • Clean Technology
    • /
    • v.17 no.2
    • /
    • pp.97-102
    • /
    • 2011
  • The adsorption characteristics of amatanth dye by granular activated carbon were experimently investigated in the batch adsorption. Kinetic studies of adsorption of amaranth dye were carried out at 298, 308 and 318 K, using aqueous solutions with 100, 200 and 300 mg/L initial concentration of amatanth. It was established that the adsorption equilibrium of amaranth dye on granular activated carbon was successfully fitted by Langmuir isotherm equation at 298 K. The pseudo first order and pseudo second order models were used to evaluate the kinetic data and the pseudo second order kinetic model was the best with good correlation. Values of the rate constant ($k_2$) have been calculated as 0.1076, 0.0531, and 0.0309 g/mg h at 100, 200 and 300 mg/L initial concentration of amatanth, respectively. Thermodynamic parameter such as activation energy, standard enthalpy, standard entropy and standard free energy were evaluated. The estimated values for standard free energy were -5.08 - -8.10 kJ/mol over activated carbon at 200 mg/L, indicated toward a spontaneous process. The positive value for enthalpy, 38.89 kJ/mol indicates that adsorption interaction of amatanth dye on activated carbon is an endothermic process.

Component Analysis of Thermally Activated Building System in Residential Buildings

  • Chung, Woong June;Lee, Yu Ji;Yoo, Mi Hye;Park, Sang Hoon;Yeo, Myoung Souk;Kim, Kwang Woo
    • Architectural research
    • /
    • v.16 no.4
    • /
    • pp.203-210
    • /
    • 2014
  • The packaged terminal air conditioner, the typical cooling system for the residential buildings, consumes a large amount of electricity in a short period time during peak hours. In order to reduce the peak load and conserve the electricity, the thermally activated building system can be used as a secondary system to handle the partial cooling load. However, the thermally activated building system may cause condensation and under-cooling. Thus, design of both systems should be performed with careful investigation in characteristics of both systems to amplify the advantages. Since the thermally activated building system has the time-delay effect which may cause under-cooling, the system is designed to handle the base load of the building. Hence, simple simulation with EnergyPlus was performed to observe the characteristics of cooling load in residential buildings. Once the possible range of the load handling ratio of the thermally activated building system was decided, characteristics of system was analyzed in terms of hardware component and operation parameters. The hardware components were analyzed in plant and system aspects and the operation parameter was evaluated in the thermal comfort aspect. As the load handling ratio increased, the thermal comfort increased due to the lower radiant mean temperatures. Within the range of thermal comfort, the several adjustments were made in setpoint temperature and electricity consumptions of difference cases were observed to decide which components and parameters were important for designing the systems.

Apparatus and Method for Wave Energy Convertor using Under-water Pressure Oscillation (해수압 진동을 이용한 파력발전 장치 및 방법)

  • Song, Seung-Kwan;Park, Jin-Bae
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.60 no.12
    • /
    • pp.2260-2264
    • /
    • 2011
  • This paper describes the development of an wave energy convertor. We devise a new type of the wave energy convertor which generates electricity by means of under-water pressure oscillation. This wave energy convertor is installed on the seabed floor. That is, there is no exposed body on the surface of the sea. The wave energy convertor comprises an activated assembly which is adapted to be displaced in response to water pressure oscillation to vary the volume of bellows cavity and a power take off assembly which generates electricity in response to movement of the activated assembly.

Quality Improvement of Crude Glycerol from Biodiesel Production Using Activated Carbon Derived from Krabok (Irvingia malayana) Seed Shells

  • Wuttichai Roschat;Sarunya Donrussamee;Phatcharanan Smanmit;Samlit Jikjak;Tappagorn Leelatam;Sunti Phewphong;Krittiyanee Namwongsa;Preecha Moonsin;Vinich Promarak
    • Korean Journal of Materials Research
    • /
    • v.34 no.1
    • /
    • pp.1-11
    • /
    • 2024
  • This research investigated the preparation of activated carbon derived from Krabok (Irvingia malayana) seed shells to improve the quality of crude glycerol obtained during biodiesel production. The activated carbon was prepared using a dry chemical activation method with NaOH, utilizing an innovative biomass incinerator. The results revealed that the resulting KC/AC-two-step exhibited favorable physicochemical adsorption properties, with a high surface area of 758.72 m2/g and an iodine number of 611.10 mg/g. These values meet the criteria of the industrial product standard for activated carbon No. TIS 900-2004, as specified by the Ministry of Industry in Thailand. Additionally, the adsorption efficiency for methylene blue reached an impressive 99.35 %. This developed activated carbon was then used to improve the quality of crude glycerol obtained from biodiesel production. The experimental results showed that the KC/AC-two-step increased the purity of crude glycerol to 73.61 %. In comparison, commercially available activated carbon (C/AC) resulted in a higher crude glycerol purity of 81.19 %, as analyzed by the GC technique. Additionally, the metal content (Zn, Cu, Fe, Pb, Cd, and Na) in purified glycerol using KC/AC-two-step was below the standards for heavy metals permitted in food and cosmeceuticals by the Food and Drug Administration of Thailand and the European Committee for Food Contact Materials and Articles. As a result, it can be inferred that Krabok seed shells have favorable properties for producing activated carbon suitable as an adsorbent to enhance crude glycerol purity. Furthermore, the improved crude glycerol from this research has potential for various industrial applications.

Prediction the Phase Transformation Time of Binary Alloy System by calculating the Input Energy of Mechanical Alloying (기계적 합금화 투입에너지 계산에 의한 이원합금계의 상변태 시간 예측)

  • Park, Dong-Kyu;Ahn, In-Shup
    • Journal of Powder Materials
    • /
    • v.26 no.2
    • /
    • pp.107-111
    • /
    • 2019
  • The activation energy to create a phase transformation or for the reaction to move to the next stage in the milling process can be calculated from the slop of the DSC plot, obtained at the various heating rates for mechanically activated Al-Ni alloy systems by using Kissinger's equation. The mechanically activated material has been called "the driven material" as it creates new phases or intermetallic compounds of AlNi in Al-Ni alloy systems. The reaction time for phase transformation by milling can be calculated using the activation energy obtained from the above mentioned method and from the real required energy. The real required energy (activation energy) could be calculated by subtracting the loss energy from the total input energy (calculated input energy from electric motor). The loss energy and real required energy divided by the reaction time are considered the "metabolic energy" and "the effective input energy", respectively. The milling time for phase transformation at other Al-Co alloy systems from the calculated data of Al-Ni systems can be predicted accordingly.

Activated Carbon-Photocatalytic Hybrid System for the Treatment of the VOC in the Exhaust Gas from Painting Process (도장공정 배기가스 내 VOC 처리를 위한 활성탄-광촉매 복합시스템)

  • Lee, Chan;Cha, Sang-Won;Lee, Tae-Kyu
    • Journal of Energy Engineering
    • /
    • v.14 no.2 s.42
    • /
    • pp.133-139
    • /
    • 2005
  • An activated carbon-photo catalysis hybrid system is proposed for the treatment of VOC produced from paint booth. and its VOC removal performance is experimentally evaluated. Activated carbon tower is designed on the basis of the adsorption characteristics of toluene. Photocatalytic system is designed as the series of $TiO_2/SiO\_2$ fluidized bed reactor and $TiO_2$-coated filters. The present activated carbon-photo catalysis hybrid system shows the VOC removal efficiency within $75\~100\%$ under different VOC species and concentrations.

A Study on the Pretreatment of Activated Sludge for Bio-hydrogen Production Process (생물학적 수소생산 공정 개발을 위한 오니 슬러지 전처리에 대한 연구)

  • Park, Dae-Won;Kim, Dong-Kun;Kim, Ji-Seong;Park, Ho-Il
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.15 no.3
    • /
    • pp.187-193
    • /
    • 2004
  • In this study, Anaerobic sewage sludge in a batch reactor operation at $35^\circ{C}$ was used as the seed to investigate the effect of pretreatments of waste activated sludge and to evaluate its hydrogen production potential by anaerobic fermentation. Various pretreatments including physical, chemical and biological means were conducted to utilize for substrate. As a result, SCODcr of alkali and mechanical treatment was 15 and 12 times enhanced, compared with a supernatant of activated sludge. And SCODcr was 2 time increase after re-treatment with biological hydrolysis. Those were shown that sequential hybridized treatment of sludge by chemical & biological methods to conform hydrogen production potential in bath experiments. When buffer solution was added to the activated sludge, hydrogen production potential increased as compare with no addition. Combination of alkali and mechanical treatment was higher in hydrogen production potential than other treatments.

Micro-Structural and Electrochemical Properties of Activated Carbon Synthesized from Natural Bamboo (천연 대나무로부터 합성된 활성 탄소의 미세구조 및 전기화학적 특성)

  • YANG, DONG-CHEOL;KIM, SU-WON;CHOURASHIYA, M.G.;PARK, CHOONG-NYEON;PARK, CHAN-JIN
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.30 no.5
    • /
    • pp.418-427
    • /
    • 2019
  • Activated carbon was synthesized from bamboo charcoal by KOH activation at various temperatures for electrochemical double layer capacitor applications. The micro-structural and surface properties of all the samples were characterized by X-ray diffraction, scanning electron microscopy and N2 adsorption/desorption isotherm method. The electrochemical properties of the activated bamboo charcoal were examined by cyclic voltammetry in the potential window of -1.0 to 0.2 V in 6 M KOH electrolyte at different scan rates. An electrode made from the sample activated with 7.5 M KOH and heat treated at $750^{\circ}C$ for 3 h gave a maximum capacitance of 553 F/g at 1 mV/s and 450 F/g at 10mV/s.

A study on the Simultaneous Removal of Nitrogen and Phosphorus on Reactor Configuration in Intermittently Aerated Activated Sludge System (간헐폭기 활성슬러지 시스템에서 반응조 형태에 따른 질소 및 인의 동시제거 특성에 관한 연구)

  • Lee, Won-Ho;Seo, In-Seok;Kim, Kwang-Yul
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.12 no.2
    • /
    • pp.106-114
    • /
    • 1998
  • In this research, single-, two- and four-stage intermittently aerated activated sludge system were investigated for simultaneous removal of nitrogen and phosphorus with swine wastewater. For the comparison of removal efficiency, conventional activated sludge system was operated. Operational conditions of intermittently aerated activated sludge system were SRT 20day, HRT 24hr and aeration/nonaeration time 1hr/1hr, respectively. Nitrogen and phosphorus removal efficiency in Intermittently aerated activated sludge system was upgraded compare with conventional activated sludge system. In single-stage intermittently aerated activated sludge system, release-uptake of $PO_4^{3-}-P$ was observed very well but, phosphosrus removal in effluent was not effective. In single-stage intermittently aerated activated sludge system, release-uptake of $PO_4^{3-}-P$ in first reactor, was observed very well but, in following reactor, $PO_4^{3-}-P$ concentation showed almost no change. T-N removal efficiency in conventional activated sludge system, single-, two-, and four-stage intermittently aerated activated sludge system were 48, 87, 90.9 and 95.5%, respectively, and phosphorus removal efficiency were 48, 75, 97 and 95%, respectively. Intermittently aerated activated sludge system as a alternative processes of conventional system leads to meet satisfactory effleunt with only on/off aeration regulation and save energy for aeration.

  • PDF