• 한국응용과학기술학회지
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• 제17권4호
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• pp.233-239
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• 2000

To prepare an environmental friendly high-solid coatings an acrylic resin containing 80% of solid content was synthesized by addition polymerization of caprolactone acrylate, n-butyl acrylate, ethyl methacrylate, and 2-hydroxyethyl methacrylate. The conversion was $78{\sim}93%$ and the prepared resin's physical properties are as follows: viscosity, $212{\sim}3424cps: $M_{n}$ $1740{\sim}2400$. There was a trend that viscosity and molecular weight of the resin increased with Tg, but no direct proportionality was observed.

• 대한치과보철학회:학술대회논문집
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• 대한치과보철학회 2001년도 추계학술대회
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• pp.69-69
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• 2001

• 한국응용과학기술학회지
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• 제31권3호
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• pp.500-508
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• 2014

본 연구에서는 ethyl acrylate monomer(EAM)을 사용한 수용성 아크릴 수지를 합성한 후 monoammonium phophate를 수용액 상태로 녹인 뒤 이를 아크릴 수지에 함양을 달리한 시료를 준비하여 각각의 필름 상태 및 피혁 외부에 코팅하여 기계적 물성측정 및 열안정성 물성 측정 실시하여 각각의 시료를 비교 검토 하였다. DSC를 이용한 열안정성 측정 결과 monoammonium phosphate 함량이 높은 시료(WAC-APS3)의 Tm 값이 $410^{\circ}C$ 로 가장 높은 열안정성을 확인할 수 있었다. 내용제성 측정결과 아크릴 수지 및 브랜딩 된 수지 모두 높은 내용제성을 확인 할 수 있었다. 내마모성 측정결과는 monoammonium phosphate 함량이 높은 수지가 우수한 물성(68.729 mg.loss)을 보였으나, 인장 강도, 연신율 측정치에서는 monoammonium phosphate 함량이 높아질수록 물성이 저하되어 아크릴 수지의 인장력인 $1.505kgf/mm^2$ 보다 낮은 $1.275kgf/mm^2$ 이 측정되었으며, 연신율의 경우 수용성 아크릴 수지 단독 시료의 연신율인 425% 보다 낮은 384% 가 측정되었다.

• 대한치과기공학회지
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• 제5권1호
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• pp.19-26
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• 1983

I got a conclusion as a result of that in case of constructing a full denture using acrylic resin teeth, porcelain teeth, and forming posterior occlusal surface of the artificial teeth by Type III Gold and Nickel crome alloy thus construdting a full denture and therefore comparing the above case with abrasion of Natural teeth. The result were as follows : 1. The abrasion of Natural teeth and the abrasion of full denture constructed by Type III gold has a close resemblance. 2. The one that has the hightest degree of abrasion is full denture that's using, with acrylic resin teeth, maxillary and mandibular And the lowest abrasion is natural teeth-natural teeth. 3. In case of single denture, that's opposing to natural teeth, the one that has the hightest degree of abrasion is a full denture that's using Acrylic resin teeth and the lowest abrasion is a full denture that's forming occlusal surface by Type III gold. 4. The single denture, which is opposing to type III gold teeth, was abraded above everything by full denture which is constructed by porcelain teeth. 5. In the same teeth, the abrasion of mandibular teeth was greater than that of mandibular teeth was greater than that of maxillary teeth. 6. The abrasion degree of Acrylic resin teeth has no direct mutual connection with material hardness which is opposing to.

• 대한치과보철학회지
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• 제27권1호
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• pp.193-211
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• 1989

The purpose of this study was to investigate the effect of secondary heat treatment on dimensional changes of acrylic resin partial denture base. For this study, 6 specimens were made: 2 groups of 2 specimens, each was treated with $125^{\circ}C$ dry heat and glycerine heat for 3 minutes, and the others were prepared for control group. The change of the internal diameter of specimens were measured after 3 hrs, 1 day, 1 week, 2 weeks, 4 weeks by three-dimensional space analyzer. The results were as follows : 1. All of the acrylic resin denture bases showed tissue ward thermal contraction. 2. Thermal contraction of the mesial area reinforced with metal framework was lesser than that of the distal area without metal framework. 3. Thermal contraction of the lingual flange reinforced with metal framework occured more slowly than that of the buccal flange without the metal framework. 4. The thermal contraction of dry heat treated acrylic resin base, compared to glycerine heat group, was moderately greater and occurred acutely.

• 대한치과기공학회지
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• 제13권1호
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• pp.27-31
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• 1991

The purpose of this study was to evaluate the effect of curing time and curing temperature on the hear - Curing of acrylic resin using ring furnace. Specimens were fabricated from 2 kinds(Laboron, Bertex) heat-cured resin. Total 200 samples were divided into 4 groups(70$^{\circ}C$, 100$^{\circ}C$, 13$^{\circ}C$, 150$^{\circ}C$) and each group was divided into 5 small groups(30 min., 45min., 60min., 75min., 90min.). A microscope(Olympus Coll Co. Japan) was used to examine a randomly selected central zone, midzone and surface for each complete specimen. The results of the experiment were as follows : 1. To obtain non-polymerzation, cure the resin for 30 minutes at 70$^{\circ}C$ and 100$^{\circ}C$ in a ring furnace. 2. To obtain with porosity, cure the resin for 45 minutes, 60 minutes and 75 mintes at 70$^{\circ}C$ and for 90 minutes at 150$^{\circ}C$ in ring furnace. Porosity appears in Laboron for 30 minutes, 45 minutes at 150$^{\circ}C$ in a ring furnace. 3. Every other specimens connot get a sight of special problem with makes eye in the made surface.

• 대한치과기공학회지
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• 제12권1호
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• pp.103-106
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• 1990

The purpose of this study was to determine if homogeneity of the resin associated with benchcuring could be obtained in the curing unit as the water increased from room temperature to curing temperature. The results of the experiment were as follows : 1. Long periods of bench-curing are not necessary. 2. Bench-curing can take place in the water bath of the curing unit. When this procedure is used, the water should be far enough below the temerature at which active polymerization of the resin proceeds to allow the bench-curing to occur.

• 대한소아치과학회지
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• 제35권3호
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• pp.477-486
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• 2008

치과 임상에서는 여러 목적으로 Polymethyl methacrylate를 주성분으로 한 아크릴릭 레진이 사용되고 있으며, 특히 가철성 교정장치는 대부분 이것을 사용한다. 그러나 아크릴릭 레진은 중합이 완벽하게 이루어지지 않을 경우 인체에 악영향을 줄 수 있는 미반응 모노머가 레진에 잔존할 수 있다. 본 연구에서는 다양한 방법(온도, 압력, 수중 혹은 공기 중)으로 중합 조건과 시간을 달리 하여 교정용 아크릴릭 레진에서 발생하는 미반응 모노머의 용리량을 고성능 액체 크로마토그래피를 이용하여 정성 및 정량분석 하고자 하였다. 연구 결과, 모든 군에서 MMA를 제외한 다른 모노머는 용리되지 않았으며, 중합 방법에 따른 모든 실험군에서 미반응 모노머의 용리는 유의하게 감소하였고(P<0.05) 중합 방법을 한 가지만 사용하였을 때보다 2가지 이상 복합적으로 변화시켰을 때 모노머의 용리량이 더 감소함을 알 수 있었다. 또한 시간경과에 따라 모노머의 용리량이 유의하게 감소하여, 특히 1일 후 부터 급격한 감소를 보였다. 이상의 결과를 보아 중합 방법을 달리하였을 때 모노머의 용리량을 더 많이 감소시키고, 다른 중합 조건들도 복합적으로 사용하는 것이 용리량을 더 효과적으로 줄일 수 있을 것으로 생각된다. 그리고 중합 과정에서 온도, 수분, 압력의 조건을 강화하여 3일 이상 중합 시간을 가지는 것이 미반응 모노머의 용리량을 최소화할 수 있을 것으로 생각되었다.

• 한국응용과학기술학회지
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• 제38권2호
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• pp.476-487
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• 2021

고형분 70% 아크릴수지를 합성하기 위해 n-butyl methacrylate(BMA), methyl methacrylate(MMA), 2-hydroxyethyl methacrylate(2-HEMA) 및 acetoacetoxyethyl acrylate(AAEA)와 caprolactone acrylate(CLA)를 사용하여 공중합체의 유리전이온도(T_g)를 50 ℃로 조정하여 합성하였으며, 합성한 아크릴수지의 점도와 분자량은 수산기가(OH values)의 증가에 따라 증가되었다. 높은 고형분의 아크릴수지 합성에 적합한 반응개시제는 di-tert-amyl peroxide 이었으며, 최적의 합성조건은 반응 개시제 5 wt%, 연쇄이동제 4 wt%, 반응온도 140 ℃에서 적하시간은 4시간이었다. 합성수지의 구조는 FT-IR과 ¹H-NMR spectroscopy로 확인하였고, 수평균 분자량은 1900~2600, 분자량 분포도 1.4~2.1을 얻었다. 합성한 아크릴수지와 무황변성 폴리이소시아네이트인 hexamethylene diisocyanate trimer(Desmodur N-3300)의 NCO/OH 당량비를 1.2/1.0으로 조절하여 아크릴-우레탄 투명도료를 제조하였다. 도료의 물리적 특성으로 점도, 부착성, 건조시간, 가사시간, 연필경도 및 광택을 비교 검토한 결과 부착성, 건조시간, 가사시간, 연필경도 및 광택이 양호한 결과를 나타내었고, 특히 CLA를 10 % 도입한 도료는 부착성이 우수하고 낮은 점도와 높은 경도를 나타내었다.

• 대한치과보철학회지
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• 제35권1호
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• pp.1-14
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• 1997

The purpose of this study was to investigate the physical effect of tissue conditioner on polymerized acrylic resins. Surface hardness and transverse strength were measured for evaluating physical effect of tissue conditioner on polymerized acrylic resins. 1) To measured surface hardness, the resin specimens($65{\times}10{\times}10mm$ size) of each resin material were made, applied tissue conditioner, stored in $37^{\circ}C$ water for 1 week, and changed tissue conditioner every week for 3 weeks. Surface hardness was measured every week with Shore hardness tester for 4 weeks. 2) To measured transverse strength, the resin specimens($65{\times}10{\times}3mm$ size & $65{\times}10{\times}1.5mm$) of each resin material were made. The specimens were divided into four groups, and measured by universial testing machine. Group I(control group) : The resin specimens were stored in $37^{\circ}C$ water for 5 weeks. Group II : The resin specimens were stored in $37^{\circ}C$ water for 5 weeks, and relined in 1.5mm thickness with same resin. Group III : The resin specimens were stored in $37^{\circ}C$ water for 1 week, applied tissue conditioner in 1.5mm thickness, stored in $37^{\circ}C$ water for 1 week, changed tissue conditioner and water every week for 3 weeks, removed tissue conditioner, reduced 1.5mm thickness from resin surface which was applied tissue conditioner, and relined in 1.5mm thickness with same resin. The following conclusions were obtained : 1. Surface hardness changes of Vertex RS and Vertex SC were not different significantly(p>0.01). 2. Surface hardness of K-33, Tokuso rebase, and Kooliner were decreased(p<0.01). 3. With the exception of Kooliner, transverse strength of all resin materials between control group and groups which applied with tissue conditioner were not different significantly(p>0.01).