• 제목/요약/키워드: Acidic treatment

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Cu, Pb, As 복합 중금속오염 토양의 전기동력학적 정화에서 전해질의 영향 평가 (Evaluation of Processing Fluids on Electrokinetic remediation of Cu, Pb, As-contaminated soil)

  • 박근용;김도형;백기태
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제15권5호
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    • pp.1-7
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    • 2010
  • Electrokinetic technology was applied to remediate Cu, Pb and As-contaminated paddy soil. Removal of metal is highly dependent on the processing fluid during electrokinetic treatment. Tap water, NaOH, $HNO_3$, $Na_2EDTA$, and citric acid were evaluated as the processing fluids to enhance metal removal. Cu and Pb were transported toward cathode, however, it did not removed from soil section, while 56.6% of As was removed at a acidic condition. The strong acidic condition with nitric acid as a processing fluid enhanced the desoprtion of As from soil surface. However, longer operation time is needed to get the higher removal of Cu and Pb, and the acidification of soil after electrokinetic treatment should be solved.

양모섬유의 염색시 디스아조계 산성염료의 변색현상 규명 (The Investigation on Color Change of Dis-azo Acid Dye in Wool Dyeing)

  • 김미경;김태경;윤석한;임용진
    • 한국염색가공학회지
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    • 제15권2호
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    • pp.86-92
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    • 2003
  • It is already known that the color of wool fabric dyed with disazo acid dyes could be changed in dyeing process and this is accelerated under alkaline condition. Focus was given to figuring out the mechanism of this color change, through the LC-MS analysis. In this study, no color change was seen in wool fabrics dyed with C. I. Acid Blue 113 under weak acidic, neutral and weak alkaline conditions for 1hour. However, the wool fabrics dyed under weak alkaline condition for a long time over 3 hours fumed reddish orange. When the wool fabrics dyed under weak acidic, neutral and weak alkaline conditions were treated with $0.5g/L\;Na_2C0_3$ solution, all of them turned reddish orange. On the other hand, the color of silk fabrics dyed with C. I. Acid Blue 113 were not changed after the same alkaline treatment. Wool contains cystine and cysteine, whereas silk does not. Due to the reversible reduction/oxidation process of cystine and cysteine in wool dyeing, the C. I. Acid Blue 113 of the dis-azo type is decomposed by reduction and consequently turned them into the reddish orange mono-azo types dye.

Adsorption Behaviors of Noxious Gases on Chemically Surface-treated Activated Carbons

  • Park, Soo-Jin;Shin, Jun-Sik
    • Carbon letters
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    • 제4권1호
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    • pp.31-35
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    • 2003
  • The specific adsorption behaviors of activated carbons (ACs) treated with 30 wt% $H_3PO_4$ or NaOH were investigated in the removals of NO or $NH_3$. The acid and base values were determined by Boehm's titration method. And, the surface properties of ACs were studied by FT-IR and XPS analyses. Also, $N_2/77K$ adsorption isotherm characteristics, including the specific surface area and micropore volume were studied by BET and t-plot methods, respectively. From the adsorption tests of NO and $NH_3$, it was revealed in the case of acidic treatment on ACs that the $NH_3$ removal was more effective due to the increase of acidic functional groups in carbon surfaces. Also, the NO removal was increased, in the case of basic treatment, due to the improvement of basic functional groups, in spite of significant decreases of BET's specific surface area and total pore volume. It was found that the adsorption capacity of ACs was not only determined by the textural characteristics but also correlated with the surface functional groups in the acid-base intermolecular interactions.

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Scolopendra Pharmacopuncture Ameliorates Behavioral Despair in Mice Stressed by Chronic Restraint

  • Choi, Yu-Jin;Lee, Hwa-Young;Kim, Yunna;Cho, Seung-Hun
    • 대한약침학회지
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    • 제20권4호
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    • pp.257-264
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    • 2017
  • Introduction: Pharmacopuncture, which combines acupuncture with herbal medicine, is one of the newly developed acupuncture techniques that has recently been put into use. The possible mechanisms of scolopendra pharmacopuncture, as well as its potential effects on depressive symptoms, were investigated in this study by using a mouse model of chronic immobilization stress (CIS). Methods: C57BL/6 male mice were randomly assigned into three groups: mice not stressed with restraint and injected with distilled water, mice stressed with restraint and injected with distilled water, and mice stressed with restraint injected with scolopendra pharmacopuncture at a cervical site. Behavioral tests (an open field test, tail suspension test, and forced swimming test) were carried out after two weeks of CIS and injection treatments. The expression levels of glial fibrillary acidic protein (GFAP) in the hippocampus were determined by using western blot and immunohistochemistry analyses. Results: Mice exposed to CIS showed decreased behavioral activity, while scolopendra pharmacopuncture treatment significantly protected against the depressive-like behaviors induced by CIS. Moreover, scolopendra pharmacopuncture treatment increased GFAP protein levels in the hippocampi of the mice stressed by chronic immobilization. Conclusion: Scolopendra pharmacopuncture has an ameliorating effect on depressive behavior, which is partially mediated through protection against glial loss in the hippocampus.

Analysis of Aluminum Stress-induced Differentially Expressed Proteins in Alfalfa Roots Using Proteomic Approach

  • Kim, Dong-Hyun;Lee, Joon-Woo;Min, Chang-Woo;Rahman, Md. Atikur;Kim, Yong-Goo;Lee, Byung-Hyun
    • 한국초지조사료학회지
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    • 제42권3호
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    • pp.137-145
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    • 2022
  • Aluminum (Al) is one of the major factors adversely affects crop growth and productivity in acidic soils. In this study, the effect of Al on plants in soil was investigated by comparing the protein expression profiles of alfalfa roots exposed to Al stress treatment. Two-week-old alfalfa seedlings were exposed to Al stress treatment at pH 4.0. Total protein was extracted from alfalfa root tissue and analyzed by two-dimensional gel electrophoresis combined with MALDI-TOF/TOF mass spectrometry. A total of 45 proteins differentially expressed in Al stress-treated alfalfa root tissues were identified, of which 28 were up-regulated and 17 were down-regulated. Of the differentially expressed proteins, 7 representative proteins were further confirmed for transcript accumulation by RT-PCR analysis. The identified proteins were involved in several functional categories including disease/defense (24%), energy (22%), protein destination (9%), metabolism (7%), transcription (5%), secondary metabolism (4%), and ambiguous classification (29%). The identification of key candidate genes induced by Al in alfalfa roots will be useful to elucidate the molecular mechanisms of Al stress tolerance in alfalfa plants.

An Acidic PATHOGENESIS-RELATED1 Gene of Oryza grandiglumis is Involved in Disease Resistance Response Against Bacterial Infection

  • Shin, Sang Hyun;Pak, Jung-Hun;Kim, Mi Jin;Kim, Hye Jeong;Oh, Ju Sung;Choi, Hong Kyu;Jung, Ho Won;Chung, Young Soo
    • The Plant Pathology Journal
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    • 제30권2호
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    • pp.208-214
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    • 2014
  • Wild rice, Oryza grandiglumis shows hyper-resistance response to pathogen infection. In order to identify genes necessary for defense response in plants, we have carried out a subtractive hybridization coupled with a cDNA macroarray. An acidic PATHOGENESIS-RELATED1 (PR1) gene of the wild rice is highly identical to the acidic PR1 genes of different plant species. The OgPR1a cDNA has an apparent single open reading frame with a predicted molecular mass 40,621 Da and an isoelectic point of 5.14. Both in silico analysis and a transient expression assay in onion epidermal cells revealed that the OgPR1a protein could be localized in intercellular space in plants. The OgPR1a mRNA was strongly transcribed by the exogenous treatment with ethylene and jasmonic acid as well as protein phosphatase inhibitors. Additionally, ectopic expression of the OgPR1a conferred disease resistance on Arabidopsis to the bacterial and fungal infections.

Sol-Gel법에 의한 강유전체 Pb(Zr, Ti)$O_3$의 제조 및 특성에 관한 연구 (Investigation on the property and preparation of ferroelectric Pb(Zr,Ti)$O_3$ by Sol-Gel method)

  • 임정한;김영식;장복기
    • E2M - 전기 전자와 첨단 소재
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    • 제7권6호
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    • pp.496-503
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    • 1994
  • In recent years Sol-Gel processing provides an interesting alternative method for the fabrication of ferroelectric thin layers and powder. PZT powder was prepared from an alkoxide-based solution by a Sol-Gel method. Gelation of synthesized complex solutions, microstructure, thermal analysis and crystallization behaviors of the calcined powder were studied in accordance with a water content and a catalyst. Especially gelation and crystallization behavior were analysed with the change of pH. The gelation time decreased as the pH of the mixed solution increased. For PZT powder with 650.deg. C heat treatment, 100% perovskite phase was formed by using either acidic or basic catalyst. By using either acidic or basic catalyst, we were able to get very fine powders of uniform shape with an average particle size of 0.8-1.mu.m.

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Effect of Heparin on the High Affinity KGF and aFGF Binding to the Chimeric KGFR-HFc

  • Cheon, Hyae-Gyeong
    • BMB Reports
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    • 제29권3호
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    • pp.205-209
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    • 1996
  • To investigate the role of heparin in keratinocyte growth factor (KGF) and acidic fibroblast growth factor (aFGF) high affinity binding to the KGF receptor (KGFR), a cell free system was established which utilized a secreted chimeric molecule between the KGFR extracellular domain and the immunoglobulin heavy chain Fc domain (KGFR-HFc). KGFR-HFc was purified from NIH 3T3 cells and demonstrated the binding of $[^3H]-heparin$ as well as heparin Sepharose. Scatchard analysis showed that the dissociation constant for heparin binding to KGFR-HFc was 140 nM. High affinity KGF and aFGF binding to KGFR-HFc remained unchanged after treatment with 0.6 M NaCl, which is the concentration sufficient to release any bound heparin to the KGFR-HFc. These results strongly suggest that although the KGFR interacts with heparin, the presence of heparin is not absolutely required for high affinity binding of either KGF or aFGF to the KGFR.

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나노세공 실리카 분말의 합성과 열적 특성에 관한 연구 (Study on the Synthesis and thermal Characteristics of Nano Porous Silica Powder)

  • 김종길;박진구;김호건
    • 한국분말재료학회지
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    • 제9권5호
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    • pp.365-369
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    • 2002
  • Silica hydrogel was synthesized by the reaction of liquid sodium silicate with sulfuric acid. The condensation polymerization of the synthesized hydrogel was carried out via an aging process under the acidic or alkaline conditions. Nano porous silica with the pore size below 3 nm and surface area of $715m^2/g$, was obtained by the above processes in acidic ranges(pH : 3~5). The pore size and surface area of the silica varied with pH, and in alkaline ranges(pH : 8~10), those were 21 nm and $300m^2/g$ respectively. The characteristics of the silica varied with the thermal treatment which caused the change of surface area, pore volume and pore diameter.

Heavy Metal Adsorption of Anodically Treated Activated Carbon Fibers in Aqueous Solution

  • Park, Soo-Jin;Kim, Young-Mi
    • Carbon letters
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    • 제4권1호
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    • pp.21-23
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    • 2003
  • In this work, the effect of anodic oxidation treatment on Cr(VI) ion adsorption behaviors of activated carbon fibers (ACFs) was investigated. The aqueous solutions of 10 wt% $H_3PO_4$ and $NH_4OH$ were used for acidic and basic electrolytes, respectively. Surface characteristics and textural properties of ACFs were determined by XPS and $N_2$ adsorption at 77 K. The heavy metal adsorption of ACFs was conducted by ICP. As a result, the adsorption amount of the anodized ACFs was improved in order of B-ACFs > A-ACFs > pristine-ACFs. In case of the anodized treated ACFs, the specific surface area was decreased due to the pore blocking or pore destroying by acidic electrolyte. However, the anodic oxidation led to an increase of the Cr(VI) adsorption, which can be attributed to an increase of oxygen-containing functional groups, such as, carboxylic, lactonic, and phenolic groups. It was clearly found that the Cr(VI) adsorption was largely influenced by the surface functional groups, in spite of the reduced specific surface area of the ACFs.

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