• Journal of Pharmaceutical Investigation
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• 제18권3호
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• pp.133-137
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• 1988

In vitro studies were performed on the interaction of indomethacin with cholestyramine, a hypocholesterolemic substance. Cholestyramine showed a marked affinity for indomethacin among tested acidic drugs and the intensity of adsorption was dependent on pH, temperature and sodium chloride. Moreover, the combination of indomethacin with some acidic drugs that formed complexes with cholestyramine, considerably inhibited the adsorption of indomethacin on the resin.

• Bulletin of the Korean Chemical Society
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• 제3권3호
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• pp.110-115
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• 1982

Thermochemistry and photochemistry of picolyl chlorides were studied. The thermal reaction of 2-picolyl chloride in benzene afforded intermolecular condensation product. In the case of 3-picolyl chloride, this type of the reaction did not occur, but polymers were obtained. A cyclic hexamer, suggested by a molecular model, was not formed because of the steric strain and low reactivity. The thermal reaction of 4-picolyl chloride gave a cyclic hexamer as well as a polymer. The cyclic hexamer, identified by NMR spectrum, showed ${\lambda}_{max}$ at 460 nm. The cyclic hexamer was cloven to the linear structure. Photolysis of 2-picolyl chloride at 253.7 nm gave a para-isomer followed by polymerization. When a methyl hydrogen of 2-methylpyridine is substituted by $CH_3O$, iso-PrO, and EtO group, the photoisomerization to the corresponding anilines or para-substituted pyridines did not occur within the range of the time used for 2-picolyl chloride. Thermolysis of picolyl chlorides in an acidic methanol solution did not afford any product.

• 한국의류학회지
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• 제26권2호
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• pp.263-269
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• 2002

This research was conducted to establish the efficient use of the colored rice bran fur dyeing textiles. To investigate the fabric dyeability of the colored rice bran extract, the anthocyanin pigments were extracted with water of different temperature ranges of 40 ~ 8$0^{\circ}C$ and were dyed on silk fabrics with different dyeing temperature $25^{\circ}C$~6$0^{\circ}C$, at acidic pH and neutral pH, respectively. Aluminum chloride was preheated with mordant K/S value and dyeing fastness of dyed silk fabrics were examined. The anthocyanins of the colored rice bran were stable and red color at acidic pH, red purple or purple blue at neutral pH, but unstable, blue color at alkaline pH. If extracting temperature and dyeing temperature of dyeing solution were higher, the dyeability was high, but the color of dyed fabric showed red tone. When extracting temperature was 8$0^{\circ}C$ and dyeing temperature of dyeing solution was 6$0^{\circ}C$, the dyeability was best. Without mordant, the dyeability of silk fabrics was higher in acidic pH than in neutral pH solution. With mordant, the dyeability was higher than without mordant, and also higher in acidic pH. Pretreatment of aluminum chloride resulted in the increase of color intensity and stability. The laundering fastness of dyed fabrics was good from grade 5 to grade 3-4. Because of the anthocyanins sensitivity on light radiation, the light fastness of dyed fabrics was poor from grade 3 to grade 1-2.

• 상하수도학회지
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• 제12권3호
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• pp.30-40
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• 1998

Increasing water consumption produced sludge problems of the water treatment plants. The objective of this study is to investigate aluminium coagulants recovery n acidic and alkaline conditions. Water treatment plant sludge produced in Pusan Metropolitan City were tested for the aluminium extraction process. Experiment samples were obtained in summer from water treatment plants of Deoksan and Myongjang. Aluminium coagulants used in these plants during the test period were polyaluminium chloride(PAC), polyaluminium sulfate organic(PSO), polyaluminium sulfate silicate(PASS). Aluminium contents of water treatment sludge were in the range of 7.2~10.9% of the total solids. The recovery percentages for aluminium and iron by acidic extraction method was evaluated to 88% and 42% respectively. Extracted mass variation for other materials such as iron, manganese, total organic carbon was observed during the extraction operation. Alkaline extraction produced more than two times amount of total organic carbon than that in the acidic extraction process.

• 대한약학회:학술대회논문집
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• 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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• pp.401.1-401.1
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• 2002

Potentiometric sensors are important and viable devices for use in pharmaceutical analysis. liquid polymeric membrane electrodes for many basic drugs and a few acidic drug were reported. The acidic drug-metal(Ⅱ)-triethylene tetramine ion pair complexes were prepared and used in poly(vinyl chloride) membrane electrodes to analyze anionic drugs such as mefenamic acid and ibuprofen. Metal ion used were Fe2＋. Co2＋. Ni2＋ and Cu2＋. Plasticizer used was o-nitrophenyl octyl ether.. (omitted)

• Membrane and Water Treatment
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• 제15권3호
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• pp.139-152
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• 2024

Mixed matrix membranes have gained significant recognition in the wastewater treatment industry for their effectiveness in removing dyes, proteins, and heavy metals from water sources. Researchers have developed an innovative technique to enhance properties of these membranes by incorporating amine-functionalized carbon nanotubes into the polymer matrix. This approach introduces amine functional groups onto the membrane surface, which are then modified with trimesoyl chloride and cyanuric chloride. The modified membranes are characterized by XPS to confirm successful bonding of amines with the trimesoyl chloride and cyanuric chloride. The surface charge of the modified membrane also plays a role in the modification process; the membrane modified with trimesoyl chloride has a negative surface charge, while the one modified with cyanuric chloride has a more positive charge. At the same acidic pH, the positive or negative charge of the mixed matrix membranes assists in enhancing the rejection of heavy metals. This results in improved antifouling properties for both modified membranes. The heavy metal rejection for all modified membranes is higher than for unmodified membranes, due to both adsorption and complexation abilities of the functional groups on the membrane surface with heavy metal ions. As the membrane surface functionalities increase through modification, the separation due to complexation also increases. The bulk morphology of the membrane remains unchanged, while roughness slightly increases due to the surface treatment.

• Journal of Electrochemical Science and Technology
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• 제11권3호
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• pp.257-272
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• 2020

This study covers the stages of testing whether the azo dye with chemical name (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc (II) chloride (DMT), known as Maxilon Red GRL in the dye industry, can be used as an anticorrosive feasible inhibitory agent, especially in industrial areas other than carpet, yarn and fibre dyeing. These test stages consist of the electrochemical measurement techniques such as potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and linear polarization resistance (LPR) for diverse concentrations and durations. The adsorption of the viewed DMT molecule on the mild steel surface obeyed the Langmuir isotherm. The zero charge potential (PZC) of mild steel was also found to assess the inhibition mechanism in containing DMT solution. The inhibition performance of DMT on the mild steel in a 1.0 M HCl solution was also investigated using methods such as metal microscope, atomic force microscope (AFM) and field emission scanning electron microscope (FE-SEM).

• 한국식품과학회지
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• 제23권2호
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• pp.161-166
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• 1991

미생물을 이용한 유용물질 생산연구의 일환으로 토양으로부터 생물고분자 생산균주를 분리하고, 이 분리균에 대한 균학적 성질 및 생성 생물고분자의 이화학적 성상을 검토하였다. 분리균주는 Bacillus속의 한 균종으로 동정 하였으며, 알칼리 내성균주의 특징을 나타내었다. 이 균주로부터 생성된 생물고분자는 성분분석, 정색반응 및 I.R. spectrum 분석결과 단백질 함량이 높고, 일부 amino sugar가 존재하나 uronic acid는 함유하지 않았다. 그러나 cetyl pyridinium chloride에는 침전되어 산성의 생물고분자인 것으로 추정되었다.

• KSBB Journal
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• 제8권3호
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• pp.209-216
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• 1993

미생물을 이용한 생분해성 고분자 생산연구의 일환으로 토양으로부터 고점성의 생물고분자 생산균주를 분리하고, 이 분리균에 대한 분류학적 성질 및 생성 생물고분자의 이화학적 성상을 검토, 규명하였다. 분리균주는 Alcaligenes속의 한 균종으로 동정하였으며, 호알카리성 균주의 특성을 나타내었다. CPC(cetylpridinium chloride)침전 및 acetone처리하여 정제한 산성 고분자 물질은 carboxyl기를 갖고 자외 흡수가 강한 glutamic acid만을 구성성분으로 하였고, glutamic acid는 $\gamma$-peptide 결합의 $\gamma$-polyglutamic acid로 존재하였다. 중화당량은 약 350으로 $\gamma$-PGA 2.7잔가당 1개의 음이온이 존재하였으며, 분자량은 약 $6.5{\times}10^5$Daltons이었다.

• 한국토양비료학회지
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• 제14권1호
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• pp.17-23
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• 1981

요소(尿素)와 병용(倂用)된 염화가리나 황산가리(黃酸加里)가 담수(湛水) 치원조건하(置元條件下)에서 암모니아의 휘산(揮散)에 주는 영향(影響)을 밝히기 위(爲)하여 pH가 낮은 (4.85) 산성식질답토양(酸性埴質畓土壤)과 pH가 높은(6.70) 간척지사질식양토(干拓地砂質埴壤土)를 공시(供試)하여 질내(窒內)에서 시험(試驗)한 결과(結果)는 다음과 같다. 1. 산성토양(酸性土壤)에 사용(使用)한 가리(加里)는 pH를 높이고 암모니아의 휘산(揮散)을 증가(增加)하였다. 2. pH가 높은 간척지염류토양에서는 가리(加里)의 시용(施用)으로 pH를 낮추고 암모니아의 휘산(揮散)을 줄이는데 그 효과는 황산가리(黃酸加里)가 염화가리보다 컸다. 3. 황산가리(黃酸加里)보다 염화가리를 시용(施用)한 토양(土壤)에서 암모니아의 휘산(揮散)이 많은 것 같다. 그러나 pH가 높은 간척지토양(干拓地土壤)에서는 염화가리의 이 효과가 높은 염농도에 덮여 버리는 것 같다. 4. 요소(尿素)는 토양(土壤)의 pH를 크게 높였다. 산성(酸性) 토양(土壤)에서는 황산가리(黃酸加里)가 염화가리보다 토양(土壤)의 pH를 더 높였으나 원래(原來)의 pH가 높은 간척지토양(干拓地土壤)에서는 반대(反對)로 황산가리(黃酸加里)가 염화가리보다 pH를 낮추었다. $SO_4$의 환원(還元)에 기인(基因)하는 것으로 생각된다.