• Title/Summary/Keyword: Acidic chemical

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Effect of pH and Concentration on Electrochemical Corrosion Behavior of Aluminum Al-7075 T6 Alloy in NaCl Aqueous Environment

  • Raza, Syed Abbas;Karim, Muhammad Ramzan Abdul;Shehbaz, Tauheed;Taimoor, Aqeel Ahmad;Ali, Rashid;Khan, Muhammad Imran
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.213-226
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    • 2022
  • In the present study, the corrosion behavior of aluminum Al-7075 tempered (T-6 condition) alloy was evaluated by immersion testing and electrochemical testing in 1.75% and 3.5% NaCl environment at acidic, neutral and basic pH. The data obtained by both immersion tests and electrochemical corrosion tests (potentiodynamic polarization and electrochemical impedance spectroscopy tests) present that the corrosion rate of the alloy specimens is minimum for the pH=7 condition of the solution due to the formation of dense and well adherent thin protective oxide layer. Whereas the solutions with acidic and alkaline pH cause shift in the corrosion behavior of aluminum alloy to more active domains aggravated by the constant flux of acidic and alkaline ions (Cl- and OH-) in the media which anodically dissolve the Al matrix in comparison to precipitated intermetallic phases (cathodic in nature) formed due to T6 treatment. Consequently, the pitting behavior of the alloy, as observed by cyclic polarization tests, shifts to more active regions when pH of the solutions changes from neutral to alkaline environment due to localized dissolution of the matrix in alkaline environment that ingress by diffusion through the pores in the oxide film. Microscopic analysis also strengthens the results obtained by immersion corrosion testing and electrochemical corrosion testing as the study examines the corrosion behavior of this alloy under a systematic evaluation in marine environment.

Preparation and Effects of Acidic Cleaning Agents; for Aluminum (알루미늄용 산성세정제의 제조 및 세정효과)

  • Shim, Il-Woo;Jo, Hye-Jin;You, Hyuk-Jae;Wu, Jong-Pyo;Kim, Myung-Soo;Hahm, Hyun-Sik;Park, Hong-Soo;Baik, Woon-Phil
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.306-312
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    • 2004
  • An acid cleaning agent (AACA) for aluminum was prepared by blending of sorbitol, n-octanoic acid, MJU-100A, Tetronix T-701, PPA-23, C8-83 and phosphoric acid. With the prepared AACA, degreasing, foam height, etching and derusting tests were carried out. As a result, AACA-4 and AACA-7 showed better cleaning ability than commercial acid cleaning agents.

ACIDIC GLYCOSAMINOGLYCANS IN BOVINE GINGIVA (한우치근의 산성뮤코다당에 관한 연구)

  • Chung, Tai-Young;Choi, Keun-Bae;Oh, Sae-Yoon
    • The Journal of the Korean dental association
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    • v.15 no.12
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    • pp.1031-1035
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    • 1977
  • Acidic glycosaminoglycans were isolated from the bovine gingiva and analyzed by chemical methods and by two dimensional electrophoresis on cellulose acetate strip. The average total amount of acidic glycosaminoglycans-expressed as glucuronic acid-was 0.36% of dry gingival tissue. By using colorimetric analysis with two dimenional electrophoresis, the distribution of dermatan sulfate was calculated to be 33% of whole acidic glycosaminoglycans, chondroitin sulfate A to be 26% ad hyaluronic acid to be 38%, respectively.

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Petrology and Petrochemistry of Pajoo Acidic Igneous pluton (파주(波州) 산성화성암체(酸性火成岩體)의 암석학적(岩石學的) 연구(硏究))

  • Oh, Mihn Soo
    • Economic and Environmental Geology
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    • v.11 no.1
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    • pp.1-9
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    • 1978
  • The study is on petrology and petrochemistry of Pajoo Acidic Igneous pluton which intruded into Precambrian metasediments of basement of the area. The geologic sequence of studied area was shown in table 1 and 10 modal analyses and 7 chemical analyses on the rock samples taken from the body. Pajoo Acidic Igneous rock consist of hypersthene-quartz-diorite and porphyritic adamellite which based on the classification of the subcommision on systematics of igneous rocks of IUGS. And porphyritic adamellite which occured as a small stock was intruded into hypersthene quartz diorite. The rock forming minerals of hypersthene quartz diorite are composed of plagioclase, perthite, quartz, hypersthene, hornblende, biotite and porphyritic adamellite is composed of perthite, quartz, plagioclase and biotite. And the former is hypidiomorphic granular texture and later is porphyritic texture with microcline phenocrysts. In silica-oxides variation diagram, the Pajoo acidic igneous rocks are similar to the trend of Daly's average composition and equivalent to the calc-alkalic rock series. In AMF diagram, these rocks are stock of fissure filling vein type by cooling in magmatic differentiation.

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Continuous Ion Exchange Characteristics of Ni, Co and Ag Ions in Acidic-Oxidizing Conditions (산성-산화성 분위기에서 니켈(Ni), 코발트(Co) 및 은(Ag) 이온의 연속식 이온교환 특성)

  • Kim, Young H.;Yang, Hyun S.;Kim, Woong K.
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.218-224
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    • 1999
  • Continuous ion exchange characteristics of the synthetic coolant contained Ni, Co and Ag ions of low concentration in acidic-oxidizing conditions have been studied to suggest the guideline for the optimum operation of mixed-bed demincralizer during the shutdown period of a pressurized water reactor (PWR). In the effect of the form of cation resins on the removal capacity of metal ions, the performance of a $H^+$-form resin was about 6% higher than that of a $Li^+$-form resin. Mixed-bed of cation and anion resins in comparison with nonmixed-bed of them, had no affected on the removal capacity of metal ions but very slightly increased the slope of breakthrough curves of metal ions. In the effect related to acidic-oxidizing conditions of the coolant, the addition of boric acid very slightly decreased the slope of breakthrough curves of metal ions, while the addition of hydrogen peroxide slightly decreased the removal capacity of metal ions.

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A Study on the Effect of Polyamine on the Adsorption of Asphalt-Like Functionalities onto Silica Surface

  • Jo, Myung-Chan;Kim, Jong-Sung;Park, Sang-Joon
    • Journal of Environmental Science International
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    • v.16 no.2
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    • pp.143-149
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    • 2007
  • The effect of precoating of silica with polyamine surfactants on the adsorption of five model compounds containing asphalt-like functionalities was studied. Hexadecyltrimethylammonium chloride (HDTMA) and 1-hexadecylamine were used for silica precoating. The model compounds representing five asphalt functionalities were benzoic acid, phenol, benzylbenzoate, benzophenone, and quinoline. All the adsorption isotherms conformed well to the Langmuir adsorption model. All the model compounds showed decreased adsorption with the HDTMA precoating. However, two acidic compounds, benzoic acid and phenol, showed enhanced adsorption on the silica precoated with 1-hexadecylamine. In aqueous solutions, the adsorption of the acidic compounds were in the following order: silica precoated with 1-hexadecylamine > silica precoated with HDTMA > uncoated silica.

Effects of organic amendments on lettuce (Lactuca sativa L.) growth and soil chemical properties in acidic and non-acidic soils

  • Yun-Gu Kang;Jun-Yeong Lee;Jun-Ho Kim;Taek-Keun Oh;Yeo-Uk Yun
    • Korean Journal of Agricultural Science
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    • v.50 no.4
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    • pp.713-721
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    • 2023
  • Soil acidification challenges global food security by adversely influences soil fertility and agricultural productivity. Carbonized agricultural residues present a sustainable and ecofriendly way to recycle agricultural waste and mitigate soil acidification. We evaluated the effects of organic amendments on lettuce growth and soil chemical properties in two soils with different pH levels. Carbonized rice husk was produced at 600℃ for 30 min and rice husk was treated at 1% (w·w-1). Carbonized rice husk increased soil pH, electrical conductivity, total carbon content, and nitrogen content compared with untreated and rice husk treatments. Furthermore, this study found that lettuce growth positively correlated with soil pH, with increasing soil pH up to pH 6.34 resulting in improved lettuce growth parameters. Statistical correlation analysis also supported the relationship between soil pH and lettuce growth parameters. The study findings showed that the use of carbonized rice husk increased the constituent elements of lettuce, such as carbon, nitrogen, and phosphate content. The potassium content of lettuce followed a similar trend; however, was higher in acidic soil than that in non-acidic soil. Therefore, improving the pH of acidic soil is essential to enhance agricultural productivity. It is considered advantageous to use agricultural residues following pyrolysis to improve soil pH and agricultural productivity.

Removal of BrO3- from aqueous solution (수용액에서 브롬산 이온을 제거하는 방법)

  • Lim, Heon-Sung;Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.401-405
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    • 2011
  • The efficient removal of bromate ($BrO_3^-$) from aqueous solutions was investigated using activated alumina. Bromate is a disinfection by-product, generally formed by the reaction of ozone and bromide in drinking water during ozonation process. The removal efficiency was about 90% for bromate (500 ng/mL) ion with acidic activated alumina but over 95% with silver or aluminum treated acidic activated alumina without any treatments of neutral water within 1~2 min.

Preparation of Hydrophilic Coating Film Using GPS(Glycidoxypropyl Trimethoxysilane) (GPS(Glycidoxypropyl Trimethoxysilane)을 이용한 친수성 코팅 필름의 제조)

  • Park, Jung Kook;Song, Ki Chang;Kang, Hyun Uk;Kim, Sung Hyun
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.735-740
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    • 2002
  • In order to improve the anti-fogging property of polymer films, organic-inorganic hybrid coating solutions which have good hydrophilic property and transmission in the range of visible light were synthesized by the sol-gel method. The coating solutions were prepared by adding glycidoxypropyl trimethoxysilane(GPS) to a colloidal silica(15 nm) suspension(Ludox). GPS as silane coupling agent forms strong bonds to the colloidal silica and surrounding polymer matrix and links two different materials together. Solutions prepared by addition of GPS at the acidic condition resulted in coatings that were less prone to cracking, while those at the basic condition caused coatings with more cracking. These resulted in better hydrophilic property and transmission in the range of visible light for the solution prepared at the acidic condition(pH 2). Compared with coatings under acidic conditions, coatings prepared at basic conditions showed worse hydrophilic property and transmission in the range of visible light.

Electrosorption of U(IV) by Electochemically Modified Activated Carbon Fibers

  • Jung, Chong-Hun;Oh, Won-Zin;Lee, Yu-Ri;Park, Soo-Jin
    • Carbon letters
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    • v.6 no.1
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    • pp.25-30
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    • 2005
  • The electrosorption of U(VI) from waste water was carried out by using an activated carbon fiber (ACF) felt electrode in a continuous electrosorption cell. In order to enhance the electrosorption capacity at a lower potential, the ACF was electrochemically modified in an acidic and a basic solution. Pore structure and functional groups of the electrochemically modified ACF were examined, and the effects of the modification conditions were studied for the adsorption of U(VI). Specific surface area of all the ACFs was decreased by this modification. The amount of the acidic functional groups decreased with a basic modification, while the amount increased a lot with an acidic modification. The electrosorption capacity of U(VI) decreased on the acid modified electrode due to the shielding effect of the acidic functional groups. The base modified electrode enhanced the capacity due to a reduction of the acidic functional groups. The electrosorption amount of U(VI) on the base modified electrode at .0.3 V corresponds to that of the as-received ACF electrode at .0.9 V. Such a good adsorption capacity was due to a reduction of the shielding effect and an increase of the hydroxyl ions in the electric double layer on the ACF surface by the application of negative potential.

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