• Title/Summary/Keyword: Acid.Alkaline treatment

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2, 4, 6-Trinitrotoluene(TNT) Treatment by the Alkaline Hydrolysis (가수분해에 의한 2, 4, 6-Trinitrotoluene(TNT) 처리)

  • Kwon, Bumgun;Kim, Jongoh
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.9
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    • pp.69-74
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    • 2012
  • This study investigated the TNT decomposition by the treatment of alkaline hydrolysis. To obtain this objecitive, spectrum shift characteristics, pH effect, kinetics, and product analysis were examined during the alkaline hydrolysis by means of hydroxide ions. At pH = 12, an aqueous solution of TNT was changed into yellow-brown coloring, in which its absorbances were newly increased in a range of wavelength 400-600 nm. From the kinetic data, pseudo-first-order rate constant in a excess of hydroxide ion, in contrast to TNT concentration, was $0.0022min^{-1}$, which means that the reaction rate between TNT and hydroxide ion can be very slow, and that 1,047 min is necessary to achieve a 90% reduction of the initial TNT. In products analyses, nitrite ions and formic acid were mainly produced by the alkaline hydrolysis, nitrate ions and oxalic acid as minor products were generated.

A Study on the Tannin Treatment of Silk Fabrics(III) - Comparion Condensed Tannin with Hydrlyzable Tannin - (견의 탄닌처리에 관한 연구(III) - 축합형 탄닌과 가수분해형 탄닌의 비교 -)

  • 설정화;최석철;조경래
    • Textile Coloration and Finishing
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    • v.7 no.3
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    • pp.60-67
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    • 1995
  • This study was made to investigate the effect of silk fabrics treated with mimosa and tannic acid-weighting effect, surface color according to temprature, treatment time, concentration, pH. The results were as follows ; 1. The wavelength of maximum absorption of mimosa and tannic acid solution appeared at 278.5nm and 275.0nm, respectively. By the irradiation, spectra at wavelength of maximum absorption of mimosa solution disappeared, but those of tannic acid solution decreased after 48hr irradiation. 2. The tannin weighting increased with the increase of concentration, treatment temperature at 8$0^{\circ}C$, acidic condition. In case of tannic acid, it was higher than mimosa. 3. Surface color of silk fabric with mimosa changed from 2.8YR to 5.8YR acc-ording to the increase o( tannin concentration but in case of tannic acid itchanged from 4.2Y to 3.9Y. It was more changed acidic or alkaline conditionthan origine solution.

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THE EFFECTS OF MECHANICAL STRESS ON CULTURED BONE CELL POPULATIONS (Mechanical stress가 골조직세포군에 미치는 영향)

  • Kim, Sang-Tae;Cha, Kyung-Suk
    • The korean journal of orthodontics
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    • v.24 no.1 s.44
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    • pp.105-114
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    • 1994
  • The movement of teeth during orthodontic treatment requires bone remodeling process of bone formation and bone resolution. To find out the changes occuring in the cell itself, mechanical stress was applied to the cell populations involved in the bone metabolism. Bone tissue cell populations were isolated from fetal rat calvaria and divided into OC and OB groups. Following results were obtained from measuring the changes in acid & alkaline phosphatease activity, cyclic AMP and $PGE_2$ production in time lapse after the application of mechanical stress. 1. In case of the marker enzyme of specific bone tissue cell, acid phosphatase activity was high in OC group and alkaline phosphatase activity was high in OB group. 2. After the mechanical stress was applied, acid phosphatase activity was decreased in both OC and OB groups and alkaline phosphatase activity was increase in OB group. 3. When the mechanical stress was applied for 15, 30 and 60 minutes, the production of $PGE_2$ increased in both OC and OB groups, as the time span increased. 4. When the mechanical stress was applied for 20 and 40 minutes, the production of $PGE_2$ increased in both OC and OB groups, as the time span increased.

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Studies on the Coated Broke Recycling in the Papermaking(II)-Effect of Sulfuric acid Treatment on Coated Broke Recycling - (도공파지의 재생에 관한 연구(제 2보)-황산처리가 도공파지 재생공정에 미치는 영향)

  • 이용규;김창근
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.23-29
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    • 1999
  • The effect of dilute sulfuric acid treatment was examined to improve recyclability of coated brokes. Turbidity , electric conductivity , and cationic demand of the white water from coated broke prepared from an alkaline base paper was determined. Sulfuric acid treatment was found to be effective in dissolving undisintegrated substances such as binders, pigments, and fibers. The properties of papers prepared by adding the broke to pulp stock up to 30% dry weight were examined . With the increase of broke addition, retention, sizing degree and smoothness were improved ; on the other hand, formation uniformness, air permeability and internal bonding strength were decreased. The extent of improvement by broke addition was greater for the surfuric acid-treated broke than the control broke. It was concluded that the use of coated broke should be limited within 10-15% weight of the product for either type of broke.

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Effects of Korean Ginseng on the Visceral Alkaline Phosphatase Activity and Blood Inorganic Phosphorus Level (인삼이 장기의 Alkaline Phosphatase활성과 혈중 무기 인량에 미치는 영향)

  • Jung, Noh-Pal
    • The Korean Journal of Physiology
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    • v.7 no.1
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    • pp.1-11
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    • 1973
  • To study the effects of Korean ginseng on mice visceral alkaline phosphatase activity and inorganic phosphate phosphorus level in the blood, the experimental groups of male and female mice were injected subcutaneously with 0.01 ml or 0.02 ml of Tyrode solution per 10 g of body weight daily, and 0. 1 mg or 0.2 mg of alcohol extract of ginseng which was diluted with Tyrode solution. After groups of mice were treated for 7 days or 14 days, the alkaline phosphatase activity in the jejunum, kidney and liver homogenate and serum were determined with sodium ${\beta}-glycerophophosphate$ as substrate, and quantified the content of inorganic phosphate phosphorus in the blood of above mice. 1. Alkaline phosphatase activity in the jejunum, kidney, liver and serum of male mice for the 7 day treatment with ginseng extract (0.1 mg/10 g) was increased by 15.28%, 12.86%, lg.05% and 11.70% respectively, compared with Tyrode solution group. 2. Alkaline phosphatase activity in the jejunum, kidney, liver and serum of female mice for the 7 day treatment with ginseng extract (0.2 mg/10 g) was increased 3.46%, 6.94%, 20.37% and 4.05 % respectively. 3. Alkaline phosphatase activity in the jejunum, kidney, liver and serum of male mice for the 14 day treatment with ginseng extract(0.1 mg/10 g) was increased·15.92%, 19.76f, 10.16% and -1.63 % respectively. 4. Alkaline phosphatase activity in the jejunum, kidney, liver and serum of female mice for the 14 day treatment with ginseng extract(0.2 mg/10 g) was increased 18.89%, 24.55%, 16.97% and 27.59% respectively. 5. Increasing activity of the enzyme in the liver of both male and female mice for the 7 day treatment was declined to some extent at the 14 day treatment, on the other hand, increasing activity of the enzyme in the jejunum, kidney and serum of mice for the 7 day treatment was more promoted at the 14 day treatment. 6. The 7 day and 14 day treatment with ginseng extract increased 20.20% and 20.96% of inorganic phosphate phosphorus in male blood, 22.38% and 17.57f in female blood respectively. In accordance with the results mutual relationships of ginseng, internal secretion, nucleic acid and alkaline phosphatase activity were disscussed.

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Cotton Linter Crystallinity Variations Caused by Electron Beam Irradiation and Acid Treatment (물리화학적 처리에 의한 린터의 결정성 변화에 관한 연구)

  • Park, Hee Jung;Sohn, Ha Neul;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.4
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    • pp.37-43
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    • 2014
  • The crystallinity and molecular weight of cotton linter need to be controlled to be more easily dissolved in NMMO during manufacture of clothing fabrics. Electron beam irradiation and sulfuric acid treatment were used as pre-treatment to reduce molecular weight of cotton linter more efficiently, and after the pre-treatment, peroxide bleaching was followed in alkaline condition. After those processes, the crystalline indices of the cotton linters were measured by XRD method, and other properties such as their alpha cellulose contents and degree of polymerization were measured. It was found that the crystallinity index of cotton linter was decreased as the irradiation of electron beam increased while increased as the dose of sulfuric acid increased. These results strongly suggested that electron beam damaged the crystalline structure of the cellulose directly while sulfuric acid dissolved mostly non-crystalline area of the cellulose structure.

Production and Purification of Alkaline Lipase from Serratia sp. AL-11 (Serratia sp. AL-11이 생산하는 Alkaline Lipase의 생산 및 정제)

  • Choi, Cheong;Kim, Tae-Wan;Cho, Young-Je
    • Microbiology and Biotechnology Letters
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    • v.23 no.6
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    • pp.695-701
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    • 1995
  • An alkaline lipase producing bacteria was isolated from soil and identified as Serratia liquefaciens AL-11. from the results of analysis of its morphological, biochemical and physiological properties. This strain showed the highest productivity of alkaline lipase when grown at pH 9.0 and 30$\circ$C for 42 hours in the medium of 1% peptone, 0.5% tryptone, 0.9% yeast extract, 1% starch, 1% tween 80, 0.05% CaCl$_{2}$ and 0.05% NaCl. The enzyme was purified by ammonium sulfate treatment, Sephadex G-100 gel filtration and DEAE-Sephadex A-50 column chromatography. The specific activity of the purified enzyme was 27 unit/mg protein and the yield of enzyme activity was 61.3%. The homogeneity of the purified enzyme was verified by polyacrylamide gel disc electrophoresis. Molecular weight of the purified enzyme was estimated about 53,000 by sodium dodecyl sulfate- polyacrylamide gel electrophoresis. This enzyme is composed of 17 amino acids of which glycine, proline and glutamic acid were three miajor acids.

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Case Study on the Treatment of Acid Rock Drainage from an Embankment with Pyrite Rocks (황철석 암버럭을 이용한 고속도로 성토체의 산성배수 처리 사례 연구)

  • Gong, Jeong-Sik;Kim, Tae-Hyung;Song, Young-Suk
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.523-532
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    • 2021
  • The treatment of acid rock drainage was reviewed and evaluated for the case of pyrite rocks distributed in a highway embankment. During the highway's construction, neutralization using alkaline water repellent was applied to the embankment section to prevent acid rock drainage. However, it still occurred long after the construction was completed owing to rain infiltration, and the acid rock drainage polluted the surrounding soils and streams. To solve this problem, treatment facilities such as SAPS (Successive Alkalinity Producing Systems) or ecological wetlands and sand filtration were installed. After the installation of the treatment facilities, the effluent and soils contaminated by acid rock drainage nearby the outlet of the facilities were analyzed and evaluated for a period of years. Measurements of the pH of the effluent and analysis of the heavy metal contamination of the soils confirmed that the neutralization treatment for acid rock drainage is being performed properly and that contamination of heavy metals in the acid rock drainage is also being stably controlled by the treatment facilities.

Effects of Sodium Butyrate on the Biosynthesis of Sphingolipids in HT29, a Human Colon Cancer Cell Line (Sodium Butyrate 처리가 대장암 세포주인 HT29 Cell의 Sphingolipid 생합성에 미치는 영향)

  • 김희숙
    • Journal of Life Science
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    • v.9 no.2
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    • pp.160-168
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    • 1999
  • Butyrate is one of the short-chain fatty acids that are present in the colon of mammals in millimolar concentration as a result of microbial anaerobic fermentation of dietary fiber, undigested starch, and proteins. In this study, sodium butyrate was examined in HT29 cell, human colonic cancer cell line, on cell viability, alkaline phosphatase activity, PLC-${\gamma}$1 expression and complex sphingolipid biosynthesis. Treatment with butyrate showed that the decrease of cell adhesion and viability was time-dependent. Sodium butyrate also induced to increase the activity of alkaline phosphatase which is a differentiation marker enzyme and decrease the expression of PLC-${\gamma}$1. Biosynthesis of sphingomyelin and galactosylceramide by butyrate treatment were decreased so fast but ceramide was increased 680dpm/mg protein% more than untreated group on first day and then decreased fast. In addition, acid ceramidase and neutral ceramidase activity were inhibited early stage by sodium butyrate. These results suggest that sodium butyrate causes cell differentiation or cell growth arrest of HT29 cell accompanied by early increase of ceramide content and alkaline phosphatase activity and decrease of galactosylceramide content and PLC-r1 expression.

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Effects on Ultrastructural Changes and Several Phosphatase Activities by Actinomycin D in Migrating Primordial Germ Cells of Developing Rat (발생중인 흰쥐 원생식세포의 이동과 미세구조 및 몇몇 Phosphatase의 활성에 미치는 Actinomycin D의 영향)

  • Choi, C.K.
    • Applied Microscopy
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    • v.15 no.1
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    • pp.1-12
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    • 1985
  • In this study, the pathway and date of migrating Primordial germ cells (PGCs) were observed light microscopically and ultrastructural changes of them during migration were observed by electron microscopic examination. For these purpose, alkaline phosphatase reactions were used for identifying the PGCs and acid phosphatase reactions were used for observing their degenerating activities. Also, effects of actinomycin D on the migration of PGCs were examined. According to these results, at the 9th gestation day, PGCs were observed in the endodermal cells of yolk sac, at the 11th gestation day, they were seen in the hindgut and then entered into the dorsal mesentery by the 13th gestation day. At the 14th gestation day, they were located in the genital ridges. When PGCs were located in the hindgut and genital ridges, the positive reactions of alkaline phosphatase were dominated, but acid phosphatase reactions were limited in all stage except they were in dorsal mesentery. However, these reactions were lessened in case of actinomycin D treatment. By electron microscopic examination, PGCs had pseudopodia, tail process, trailing cytoplasm and nuage as the ultrastructural characteristics. In addition, these morphological features were damaged by actinomycin D treatment.

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