• Title/Summary/Keyword: Acid-sensitivity

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BOD Determination by Heavy Metal Tolerant Candida sp. LSY2 (Candida sp. LSY2 중금속 내성주를 이용한 BOD 분석)

  • 김말남;이선영
    • Korean Journal of Environmental Biology
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    • v.17 no.4
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    • pp.415-420
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    • 1999
  • A biochemical oxygen demand (BOD) sensor loaded with Candida sp. was designed and constructed for the quick measurement of the concentrations of biologically assimilable organic substances dissolved in water. The sensitivity of the sensor was higher for glucose, acetic acid, aspartic acid and glutamic acid than that for lactose, sucrose and lactic acid. The sensitivities of BOD sensors loaded with $Zn^{2+}$ tolerant and intact strains were almost identical while the sensitivity of sensor loaded with Cd$^{2+}$ tolerant strain was considerably lower. The sensitivities of the sensors loaded with intact or $Zn^{2+}$ tolerant strains did not change with the concentration of $Cd^{2+}$ in the aqueous solution while the sensitivity of the sensor loaded with $Cd^{2+}$ tolerant strain decreased slightly. The sensitivities of the sensors loaded with intact strain, $Zn^{2+}$ or $Cd^{2+}$ tolerant strains were not affected by the concentration of $Zn^{2+}$ in the aqueous solution.n.

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pH-dependent Swelling Properties of Methacrylic Acid Copolymer Hydrogels (pH 의존성 Methacrylic acid 공중합체의 팽윤특성)

  • Kim, Kyung-Chung;Lee, Seung-Jin
    • YAKHAK HOEJI
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    • v.33 no.6
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    • pp.372-376
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    • 1989
  • Equilibrium swelling and pH-sensitivity of a polyelectrolyte copolymer hydrogel were controlled by employing copolymers with different hydrophilic-hydrophobic balances. Model pH-sensitive hydrogels, e.g., poly(methacrylic acid), poly(methacrylic acid-co-acrylamide), poly(methacrylic acid-co-2-hydroxyethylmethacrylate), poly(methacrylic acid-co-styrene) were synthesized at various monomer compositions. As hydrophobicity of the copolymer hydrogels increased, the equilibrium swelling decreased while the pH-sensitivity increased. In the case of poly(methacrylic acid-co-acrylamide), polymer-polymer interaction significantly affected the equilibrium swelling and provided a wide range control of pH-sensitivity.

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Acid-Sensitivity and Physical Properties of Polymethylmethacrylate and Polyurethane Films Containing Polymeric Styryl Dye

  • Cho, Jae-Whan;Lee, Sun-Hwa;So, Jung-Hyun;Jaung, Jae-Yun;Yoon, Kee-Jong
    • Fibers and Polymers
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    • v.5 no.3
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    • pp.239-244
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    • 2004
  • Solution-cast films of polymethylmethacrylate (PMMA) and polyurethane (PU) containing polymeric styryl dye up to 5 % by weight were prepared to investigate their acid-sensitivity and mechanical and thermal properties. Original red samples due to styryl dye turned out yellow very rapidly as they were exposed to acid vapor of hydrochloric acid or p-toluenesulfonic acid. According to UV/VIS spectroscopic measurements, characteristic peak intensities near 430 nm and 520 nm increased or decreased relatively with exposed amounts of acid, respectively. Both PMMA and PU samples showed uniform color distribution due to a good miscibility between polymer and dye which can be evidenced by measurements of glass transition temperature. No significant difference in acid-sensitivity was found between PU and PMMA except relative absorbance. However, dependence of their mechanical properties on dye content was somewhat different with PU or PMMA. In case of PMMA, modulus and breaking stress increased up to about 50 % with increasing dye content, whereas those of PU samples showed only slight increase. It was ascribed to whether the matrix polymer was in the glassy or rubbery state.

The Acid Sensitivity of Gulose and Mannose in Chemically-Reduced Alginates Obtained from Pseudomonas syringae

  • Ashby, Richard D.;Day, Donal F.;Kim, Du-Woon
    • Food Science and Biotechnology
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    • v.15 no.4
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    • pp.555-558
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    • 2006
  • The chemical reduction of Pseudomonas syringae subsp. phaseolicola alginates produces neutral polymers of D-mannose and L-gulose in source specific ratios. L-Gulose was highly sensitive to degradation by 1N HCl at $100^{\circ}C$. As hydrolysis time increased, gulose recovery decreased to 22% after 4 hr, whereas 98% of the D-mannose was recovered under the same conditions. Thin layer chromatography showed the formation of a second product upon L-gulose acid hydrolysis. This new product had a rate of flow (Rf) value of 0.58, identical to that of 1,6 anhydro-${\beta}$-D-mannopyranose and very close to that of 1,6 anhydro-${\beta}$-D-glucopyranose (Rf=0.60). Because of the difference in acid sensitivity between L-gulose and D-mannose, normal acid hydrolytic techniques applied to reduced alginates produces erroneous mannuronic acid (M): guluronic acid (G) ratio's unless one accounts for the differential rates of destruction of each sugar.

Reasons for Variation in Sensitivity and Specificity of Visual Inspection with Acetic Acid (VIA) for the Detection of Pre-Cancer and Cancer Lesions of Uterine Cervix

  • Parashari, Aditya;Singh, Veena
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.12
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    • pp.7761-7762
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    • 2013
  • Alternative strategies such as visual inspection of cervix with acetic acid, are real time, economical and easily implemented methods for cervical cancer screening. However, variable sensitivity and specificity have been observed in various community based studies. The possible reasons could include variation in man power training, light source used for visualization, and preparation of diluted (4-5%) acetic acid and its storage. A standardized protocol for training, teaching material (easy to understand in the local language) for trainees, supervision and reinforcement by intermittent and supplementary training to check the quality of their observation, a standard protocol for preparation dilute acetic acid and its storage and a standard good light source (equivalent to day light) are needed to minimize the variation in sensitivity and specificity of VIA in community settings.

The Effects of Hydroxymethane Sulfonic Acid Sodium Salt and 5,5-Dimethylhydantoin on the Photographic Characteristics of Silver Halide Emulsion (할로겐화은(化銀) 유제(乳劑)의 사진특성(寫眞特性)에 미치는 Hydroxymethane Sulfonic Acid Sodium Salt와 5,5-Dimethylhydantoin의 첨가효과(添加效果))

  • Kang, Tai-Sung
    • Journal of radiological science and technology
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    • v.6 no.1
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    • pp.43-67
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    • 1983
  • In order to increase the sensitivity of the photographic emulsion, one of the chemical sensitizers hydroxymethane sulfonic acid sodium salt(HMS) was applied through the chemical ripening process and following four types of emulsion were prepared. Their grain sizes were determined through the electron microscope. The ranges of average grain sizes were $0.05-0.40{\mu}m$ for silver chlorobromide emulsion of low sensitivity $0.10-0.45{\mu}m$ for the silver chlorobromide emulsion of medium sensitivity, $0.60-1.05{\mu}m$ for the silver iodobromide emulsion of high sensitivity, and $0.90-1.55{\mu}m$ for the ammonical silver iodobromide emulsion of high sensitivity. Through the reduction sensitization with HMS, they showed significant sensitivity enhancement by the increment of HMS concentration above pH 5.5 and pBr 3.0. Required sensitivity was obtained above pH 6.2 and pBr 3.3 when sulfur and gold sensitization were applied. Fog formed along the reduction sensitization was successfully prevented by the addition of 5.5-dimethylhydantion.

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Sensitivity Changes of Auxin Transport System in Maize Coleoptile Segments

  • 윤인선
    • Journal of Plant Biology
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    • v.36 no.1
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    • pp.59-66
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    • 1993
  • In maize coleoptile segments where auxin transport capacity decreases with time following excision, susceptability of the tissue to transport inhibitors such as N-1-naphthylphthalamic acid (NPA), 3,4,5-triiodobenzoic acid (TIBA) or high concentrations of IAA was found to be rather increased. A time-dependent increase in the sensitivity to NPA can be postulated since the dose-response curve for NPA was shifted in the‘aged’tissue to the left (i.e. lower concentration). Preincubation of the tissue at a low temperature abolished the time-dependent sensitivity change, suggesting that cellular metabolism could be involved. The NPA-sensitive state was also brought about by calcium depletion of the tissue, which can be partially reversed by addition of calcium. Presence of exogenous IAA in the preincubation medium kept the auxin transport system from decay, implicating auxin as an endogenous controlling factor. Results of our experiments indicate a reversible, time-dependent changes of auxin transport system in which transport capacity and sensitivity to NPA are tightly coupled. Changes in the sensitivity to NPA were also seen in auxin action as well.

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Synthesis and Characterization of Novel Acid Amplifiers with a Low Absorbance at 193 nm (193 nm에서 낮은 흡수도를 갖는 새로운 산 증식제의 합성 및 특성연구)

  • 소진호;정용석;최상준;정연태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.8
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    • pp.806-811
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    • 2004
  • 1-Hydroxy-4-(2-naphthalenesulfonyloxy) cyclohexane(1), 1,4-di-(2-naphthalenesulfonyloxy) cyclohexane(2), 1-hydroxy-4-(2-thiophenesulfonyloxy) cyclohexane(3), 1,4-di-(2-thiophenesulfonyloxy) cyclohexane(4) were synthesized and evaluated for their performance as novel acid amplifiers for 193 nm photoresists. These acid amplifiers(1-4) showed reasonable thermal stability at the usual resist-processing temperature, 9$0^{\circ}C$-12$0^{\circ}C$. And estimated by the sensitivity curve, (1)-(4) enhanced the sensitivity of poly(tert-butyl methacrylate) film by 1.2-1.4 times, compared to poly(tert-butyl methacrylate) film whithout acid amplifiers, in the presence of a photoacid generator.

Electron Capture Dissociation Mass Spectrometry for Gaseous Protonated Melittin Ions and Its Single Amino Acid Substituted Variants

  • Yu, Seonghyun;Jang, Hwa-yong;Oh, Han Bin
    • Mass Spectrometry Letters
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    • v.10 no.4
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    • pp.117-122
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    • 2019
  • This study demonstrated the sensitivity of electron capture dissociation mass spectrometry (ECD-MS) to probe subtle conformational changes in gaseous melittin ions induced by the substitution of an amino acid. ECD-MS was performed for triply and quadruply-protonated melittin and its variants obtained by a single amino acid substitution, namely, D-Pro14, Pro14Ala, and Leu13Ala. Although native triply-protonted melittin showed only a few peptide backbone cleavage products, the D-Pro14 and Pro14Ala variants exhibited extensive backbone fragments, suggesting the occurrence of a significant structural or conformational change induced by a single amino acid substitution at Pro14. On the contrary, the substitution at Leu13, namely Leu13Ala (+3), did not cause significant changes in the ECD backbone fragmentation pattern. Thus, the sensitivity of ECD-MS is demonstrated to be good enough to probe the aforementioned conformational change in melittin.

Cation Leaching from Soils Percolated with Simulated Sulfuric Acid Rainn (人工酸性 빗물에 의한 여러 土壤으로부터의 이온 洗脫)

  • Rhyu, Tae-Cheol;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • v.16 no.2
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    • pp.169-180
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    • 1993
  • Soils of four combinations, sand with high content of organic matter(SL), sand with low content of OM(SS), siltyl loam with high content of OM(LL) and silty loam with low content OM (LS), were filled on column and then percolated with simulated sulfuric acid rain with pH 5.6, 4.0, 3.5, 3.0 and 2.5. From soil leachates, pH and concentrations of basic cations and Al were determined. Cation concentrations in the leachates increased as pH of the rain decreased. The orders of buffering capacity of soil, leachability of cation from soil, leaching sensitivity of ion andbase saturation sensitivity of soil to acidity of the rain water were SS$\leq$K <$\leq$LL

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