• Journal of Soil and Groundwater Environment
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• v.23 no.1
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• pp.14-24
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• 2018

In soil washing, there are many variables including types of reagent and contaminant, washing time, soil-liquid ratio, washing cycles, washing agent concentrations, and etc. To identify the most influencing factors on soil washing process, regression analysis was performed for eight single variables and five combined variables. A quantitative model that employs W/H (molar ratio of washing agent to heavy metal) as a major variable was established based on the regression. The validity of the model was demonstrated by conducting lab experiments with Cu, Pb, Zn, Ni and As-contaminated soils, and various washing reagents including acetic acid, citric acid, malic acid, oxalic acid, ethylenediamine tetraacetic acid (EDTA) and nitriloacetic acid (NTA). The washing efficiencies were compared with the EDTA washing data reported in the literature. The correlation between W/H and removal efficiency was analyzed after dividing data into two groups according to the heavy metal mobility.

• Journal of Environmental Science International
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• v.9 no.5
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• pp.437-441
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• 2000

A study on the removal of Pb ion from Pb-contaminated soil was carried out using ex-site extraction process. Tartaric acid (TA) and iminodiacetic acid sodium salt(IDA) as a washing agent were evaluated as a function of concentration reaction time mixing ratio of washing agent and recycling of washing agent. TA showed a better extraction performance than IDA. The optimum washing condition of TA and IDA were in the ratio of 1:15 and 1:20 between soil and acid solution during 1 hr reaction. The total concentrations of Pb ion by TA and IDA at three repeated extraction were 368.8 ppm and 267.5 ppm respectively. The recovery of Pb ion from washing solution was achieved by adding calcium hydroxide and sodium sulfide form the precipitation of lead hydroxide and lead sulfide and optimum amounts of sodium sulfide and calcium hydroxide were 7 g/$\ell$ for the TA washing solution and 4 g/$\ell$, 5g/$\ell$ for the IDA washing solution respectively. The efficiency of recycle for TA and IDA washing solution were 78.8% , 95.1%, and 89.2%, 96.6% at third extractions under $Na_2S$ and $Ca(OH)_2$, respectively.

• Journal of Soil and Groundwater Environment
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• v.22 no.2
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• pp.33-40
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• 2017

In typical remediation practices, separate washing systems have to be applied to clean up the soils contaminated with both oil and heavy metals. In this study, we evaluated the efficiency of successive two-stage soil washing in removal of mixed-contaminants from soil matrix. Two-stage soil washing experiments were conducted using different combinations of chemical agent: 1) persulfate oxidation, followed by organic acid washing, and 2) Fenton oxidation, followed by inorganic acid washing. Persulfate oxidation-organic acid washing efficiently removed both organic and inorganic contaminants to meet the regulatory soil quality standard. The average removal rates of total petroleum hydrocarbons (TPH), Cu, Pb, and Zn were 88.9%, 82.2%, 77.5%, and 66.3% respectively, (S/L 1:10, reaction time 1 h, persulfate 0.5 M, persulfate:activator 3:1, citric acid 2 M). Fenton oxidation-inorganic acid washing also gave satisfactory performances to give 89%, 80.9%, 87.1%, and 67.7% removal of TPH, Cu, Pb, and Zn, respectively (S/L 1:10, reaction time 1 hr, hydrogen peroxide 0.3 M, hydrogen peroxide:activator 5:1, inorganic acid 1 M).

• Journal of the Korean Society of Clothing and Textiles
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• v.21 no.2
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• pp.471-481
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• 1997

Denims were treated with neutral cellulase, acid cellulase, stone, and stone-neutral cellulase respectively at different cellulase concentrations varying treatment times in rotary washer. The effect of washing on denim was estimated by the changes in weight, color, back staining, tear strength, flex stiffness, and surface characteristics. Also the comparison of neutral cellulase, acid cellulase, stone, and stone-neutral cellulase washings was studied. Washing removes surface fibers and provides weight loss, color difference, back staining, and a decrease in tear strength and in flex stiffness. Stone-neutral cellulase washing and acid cellulase washing have a larger washing effect than neutral cellulase washing and stone washing.

• Resources Recycling
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• v.20 no.1
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• pp.61-68
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• 2011

Impurity removal from metallurgical grade silicon by acid washing at $50^{\circ}C$ was investigated by employing sulfuric, nitric acid and the mixture of hydrochloric and hydrofluoric acid. Acid washing treatment had no effect on the removal of boron and the concentration of this clement after treatment was rather increased. In our experimental range, the removal percentage of phosphorus was 60%. In the acid washing with sulfuric and nitric acid, the removal percentage of major impurities was below 50%, which indicates that refining effect was not great with these acids. Acid washing with the mixture of hydrochloric and hydrofluoric acid led to removal percentage of higher than 90%. Data on the purity of silicon after acid washing at various conditions are reported.

• Journal of Soil and Groundwater Environment
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• v.25 no.1
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• pp.74-83
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• 2020

In this study, the effect of hydrochloric acid (HCl) concentrations on removal efficiency and chemical forms of heavy metals in dredged sediment during acid washing was investigated. The removal efficiencies of Zn, Cu, Pb, Ni and Cd by acid washing were 18.4-92.4%, 7.2-83.7%, 9.4-75%, 8.1-53.4% and 34.4-70.8%, respectively. Overall, the removal efficiencies of heavy metals were remarkably enhanced with the increase of the acid strength. However, the removal efficiencies for 0.5 and 1.0 M HCl were comparable, and both cases met the Korean soil contamination standard. Based on the sequential extraction results, concentration of the exchangeable fraction (F1), the most labile fraction, increased whereas concentrations of the other fractions decreased with increasing acid strength. Particularly, the carbonate (F2) and Fe/Mn oxides (F3) fractions drastically decreased by using 0.5 M or 1.0 M HCl. The current study results verified that acid washing could effectively reduce heavy metal concentrations and its potential mobility in dredged sediments. However, the study also found that acid washing may cause significant increase in bioavailable fraction of heavy metals, suggesting the need to evaluate the changes in chemical forms of heavy metals by acid washing when determining the acid strength to be applied.

• Journal of Environmental Science International
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• v.27 no.1
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• pp.1-10
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• 2018

A continuous process of persulfate oxidation and citric acid washing was investigated for ex-situ remediation of complex contaminated soil containing total recoverable petroleum hydrocarbons (TRPHs) and heavy metals (Cu, Pb, and Zn). The batch experiment results showed that TRPHs could be degraded by $Fe^{2+}$ activated persulfate oxidation and that heavy metals could be removed by washing with citric acid. For efficient remediation of the complex contaminated soil, two-stage and three-stage processes were evaluated. Removal efficiency of the two-stage process (persulfate oxidation - citric acid washing) was 83% for TRPHs and 49%, 53%, 24% for Cu, Zn, and Pb, respectively. To improve the removal efficiency, a three-stage process was also tested; case A) water washing - persulfate oxidation - citirc acid washing and case B) persulfate oxidation - citric acid washing (1) - citric acid washing (2). In case A, 63% of TRPHs, 73% of Cu, 60% of Zn, and 55% of Pb were removed, while the removal efficiencies of TRPHs, Cu, Pb, and Zn were 24%, 68%, 62%, and 59% in case B, respectively. The results indicated that case A was better than case B. The three-stage process was more effective than the two-stage process for the remediation of complex-contaminated soil in therms of overall removal efficiency.

• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.20-24
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• 2022

In the process of long-term use of PEMFC (Proton Exchange Membrane Fuel Cells), chemical degradation of membrane electrode assembly (MEA) occurs due to corrosion of stack elements and contamination of supply gas. In this study, we investigated whether chemically degraded MEA can be recovered by acid washing. The performance was measured and compared in a PEMFC cell after contamination with iron ions and washing with an aqueous sulfuric acid solution. The performance was reduced by about 25% by 0.5 ppm iron ion contamination, and 97.1% performance recovery was possible by washing of 0.15 M sulfuric acid. The membrane resistance was increased due to iron ion contamination of the polymer membrane, and the ionic conductivity was restored by washing the iron ions from the membrane while minimizing the loss of the electrode catalyst by washing with a low-concentration sulfuric acid aqueous solution. The possibility of solving the decrease in durability caused by chemical contamination of PEMFC MEA by the acid washing was confirmed.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.40 no.4
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• pp.51-58
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• 2008

This paper presents the effect of acid treatment on the removal of metals and the brightness of pulp. The bleached kraft pulps, metal-absorbed pulps and recycled pulps((ONP, OCC, MOW, and SC) were treated with the acidic solutions. Among metals in the bleached kraft pulps, Cu, Ca and Mg were removed easily by the acid washing, whereas Fe, Al and Si were not removed. The acid washing also removed distinctly metals from the metal-absorbed pulps. The metals absorbed in pulps reduced the brightness (%, ISO). Especially, Fe was the most detrimental metal. However, the brightness which was decreased by metals was restored to the status quo by the acid washing. The level of metals in recycled pulps was gradually reduced after the first flotation and acid treatment. Hence, the degree of metal removal by the acid washing was mainly dependent upon the kinds of waste pulps and metal ions.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.337-339
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• 2003

The technology removing radionuclides from soil using soil washing was studied. The main radionuclides contaminated in the soil are Cs$^{137}$ and Co$^{60}$ . It is suitable that scrubbing time is 4 hours and a mixing ratio of soil weight and washing solution volume is 1:10. more than two times continuous scrubbing method with 0.5 M oxalic acid was needed to remove Cs$^{137}$ and Co$^{60}$ from soil more than 70%. Radionuclides removal efficiencies of recycling washing solutions recycled with strong acid resins until 5 times are similar to that of 0.5 M oxalic acid.