• Title/Summary/Keyword: Acid treated

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The Heavy Metals Recovery from Carbonized CCA Treated Wood (CCA방부목재의 탄화가 중금속 회수에 미치는 영향)

  • Son, Dong-won;Cheon, Seon-Hae;Lee, Myung Jae;Lee, Dong-heub
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.6 s.134
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    • pp.95-100
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    • 2005
  • The using amount of preservative-treated wood equipments has been increased. Specially, chromate copper arsenate (CCA) has been widely used to exterior wood. We are faced to the disposal problem after service period of CCA treated wood due to its toxic heavy metals. For the disposal of end-used treated wood, land-filling and incinerating methods are mainly applied. The essential problem of incinerating is an arsenic release into atmosphere. Low pyrolysis is suggested as the methods of protecting arsenic release during incineration. The heavy metals were recovered after combustion of the treated wood at the low temperature which arsenic can not released. The recovery amounts of effectiveness compounds was determined in various solvents (citric acid, nitric acid, sulfuric acid, acetic acid, phosphoric acid) and different temperature (300, 400, $500^{\circ}C$). The higher temperature was applied, the more copper was recovered. The chromium was difficult to be recovered on the carbonized CCA treated wood at 0.5% acid concentration. The recovery mass of arsenic decreased on the higher combustion treated wood. The recovery of chromium was difficult due to the chemical change of the chromium arsenate during pyrolysis.

Microbial Removal Effects of Electrolyzed Acid Water on Lettuce by Washing Methods and Quality Changes during Storage (전해산화수에 의한 상치의 세척방법별 제균효과와 저장중 품질변화)

  • Jeong, Seong-Weon;Jeong, Jin-Woong;Park, Kee-Jai
    • Korean Journal of Food Science and Technology
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    • v.31 no.6
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    • pp.1511-1517
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    • 1999
  • Effects of washing methods using electrolyzed acid water on lettuce(Lactuca sativa) and quality changes during storage were investigated. The multi-stage immersion treated 3 times in 2 min showed more effective than others to remove microorganisms. Total count of lettuce after immersion in electrolyzed acid water was decreased to 1/100-1/300 of $5.8\;{\times}\;l0^5CFU/g$ of non-immersed lettuce and $2.3\;{\times}\;l0^5CFU/g$ of tap water immersed lettuce. Also coliforms was significantly decreased to 1/3,000 of $3.1\;{\times}\;10^3CFU/g$ after electrolyzed acid water washing. However, microbial levels of electrolyzed acid water treated one became to be similar to those of non-treated lettuce after 3 days of storage at $10^{\circ}C$. The color values of L and b of lettuce treated with electrolyzed acid water were somewhat higher than those of others. Though chlorophyll content of lettuce just after immersion in electrolyzed acid water was 9% lower than those of non-treated one, the content was decreased to the same level of other treatments during storage. Decaying ratio showed the lowest value in lettuce immersed in electrolyzed acid water until 6 days of storage. The sensory tests for overall acceptability and appearance of lettuce immersed in electrolyzed acid water showed higher than those of others until $3{\sim}6$ days of storage.

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Effects of Combined Treatment of Lactic Acid Bacteria and Cell Wall Degrading Enzymes on Fermentation and Composition of Rhodesgrass (Chloris gayana Kunth.) Silage

  • Ridla, M.;Uchida, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.5
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    • pp.522-529
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    • 1998
  • This experiment was conducted to study the effects of lactic acid bacteria (LAB) inoculation either alone or in combination with cell wall degrading enzymes on the fermentation characteristics and chemical compositions of Rhodesgrass silage. Over to 1 kg of fresh Rhodesgrass sample a treatment of inoculant LAB with or without addition of an enzyme of Acremoniumcellulase (A) or Meicelase (M) or a mixture of both enzymes (AM) was applied. The treatments were control untreated, LAB-treated (application rate $1.0{\times}10^5cfu/g$ fresh sample), LAB+A 0.005%, LAB+A 0.01%, LAB+A 0.02%, LAB+M 0.005%, LAB+M 0.01%, LAB+M 0.02 %, LAB+AM 0.005%, LAB+AM 0.01%, and LAB+AM 0.02%. The sample was ensiled into 2-L vinyl bottle silo, with 9 silages of each treatment were made. Three silages of each treatment were incubated at 20, 30 and $40^{\circ}C$ for 2-months of storage period. All silages were well preserved with their fermentation quality has low pH values (3.91-4.26) and high lactic acid concentrations (4.11-9.89 %DM). No differences were found in fermentation quality and chemical composition of the control untreated silage as compared to the LAB-treated silage. Combined treatment of LAB+cellulases improved the fermentation quality of silages measured in terms of lower (p < 0.01) pH values and higher (p < 0.05) lactic concentrations than those of LAB-treated silages. Increasing amount of cellulase addition resulted in decrease (p < 0.05) of pH value and increase (p < 0.05) of lactic acid concentration. LAB + cellulase treatments (all cellulase types) reduced (p < 0.01) NDF, ADF and in vitro dry matter digestibility of silages compared with the control untreated silages. The fermentation quality and the rate of cell wall reduction were higher (p < 0.01) in the silages treated with LAB + cellulase A than in the silages treated with either LAB+cellulase M or LAB + cellulase AM. Incubation temperature of $40^{\circ}C$ was likely to be more appropriate environment for stimulating the fermentation of Rhodesgrass silages than those of 20 and $30^{\circ}C$.

Cyclosporin-induced Hypeyuricemia and the Uricosuric Efficacy of Benzbromarone in Kidney Tyansplant Patients (신장이식 환자에서 발생되는 Cyclosporin에 의한 고요산혈증과 요산 배설 촉진제인 Benzbromarone의 효과)

  • Cha, Moon Sun;Oh, Jung Mi;Han, Duck Jong
    • Korean Journal of Clinical Pharmacy
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    • v.12 no.1
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    • pp.13-21
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    • 2002
  • After the introduction of cyclosporin, the graft survival rate of renal transplant and patients' life expectancy have been greatly improved. However, cyclosporin is known to cause several undesirable side effects, one of which is hyperuricemia, which may subsequently cause gouty nephropathy and graft dysfunction. The purpose of this study was to evaluate the frequency and predisposing factors of hyperuricemia in cyclosporin-treated patients within one year of kidney transplantation and uricosuric efficacy of benzbromarone. The patients who were treated with cyclosporin after kidney transplantation in 1998 and the patients who were treated with benzbromarone for the control of cyclosporin-induced hyperuricemia in 1999 were investigated retrospectively. Among the 76 patients in cyclosporin-treated patients in 1998, hyperuricemia occurred in 55 patients $(72.4\%)$ and the mean time from kidney transplantation to occurrence of hyperuicemia was $5.0\pm8.0$ months. In 1999, 22 patients were treated with benzbromarone for hyperuricemia and their mean time from kidney transplantation to occurrence of hyperuricemia was $4.5\pm10.4$ months. Acute rejection developed in one patient $(4.8\%)$ out of 21 normo-uricemic patients and 11 patients $(20.0\%)$ out of 55 hyperuricemic patients in 1998. The difference of rejection rate in these two groups was significant (p<0.001). There was no difference of rejection rate between before and after treatment of benzbromarone. Cyclosporin trough levels did not show a significant correlation with the serum uric acid levels among the three groups. However, hyperuricemic patients showed significantly higher serum creatinine levels than patients with normal uric acid levels (p<0.001). Benzbromarone decreased serum uric acid levels from $8.3\pm2.3\;mg/dl\;to\;5.1\pm2.0\;mg/dl$ (p<0.0001) and normalizing serum uric acid in all of 22 patients. Except for one patient $(4.5\%)$ who experienced diarrhea, no significant side effect was noted.

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Enzymatic Formation of 13,26-Dihexyl-1,14-dioxacyclohexacosane-2,15-dione via Oligomerization of 12-Hydroxystearic Acid

  • Lee, Chan-Woo;Kimura, Yoshiharu;Chung, Jin-Do
    • Macromolecular Research
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    • v.17 no.11
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    • pp.919-925
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    • 2009
  • The enzymatic polymerization of 12-hydroxystearic acid (12-HSA) was carried out with Lipase $CA^{(R)}$ in benzene to produce poly(12-hydroxystearate) (PHS) with a low molecular weight. When this polymerization was continued for a long reaction time, the PHS once formed was depolymerized into a cyclic diester, 13,16-dihexyl-1,14-dioxacyclohexacosane-2,15-dione (12-HSAD). Similar polymerization and depolymerization were observed when 12-hydroxyoleic acid (12-HOA) was treated with Lipase $CA^{(R)}$, whereas only polymerization occurred when 12-hydroxydodecanoic acid (12-HDA) was treated in a similar manner. The preferential formation of cyclic diesters for 12-HSA was attributed to the structural requirements due to the bulky n-hexyl side groups stemming from the ring systems.

Silver elimination effect by sulfuric acid for Ag pre-treated activated carbon

  • Oh, Won-Chun
    • Analytical Science and Technology
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    • v.19 no.2
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    • pp.121-130
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    • 2006
  • In this study, silver pre-treated activated carbons are transformed using sulfuric acid. From the results of adsorption, each isotherm shows a distinct knee band, which is characteristic of microporous adsorbents with capillary condensation in micropores. In order to reveal the causes of the differences in adsorption capacity and specific surface area after the samples were washed with various strengths of sulfuric acid, surface morphology and external pore structure were investigated by SEM. X-ray diffraction patterns indicated that Ag-activated carbons show better performance for silver and silver compounds removal by post-treatment with acid. The FT-IR spectra of silver-activated carbon samples show that the acid post-treatment was consequently associated with the removal of silver with an increased surface functional group containing oxygen of the activated carbon. The type and quality of oxygen groups are determined on the method proposed by Boehm. For the chemical composition microanalysis of silver-activated carbons transformed by post-treatment with sulfuric acid, samples were analyzed by EDX.

A Study on the Acid Drainage Neutralizing System for Ecological Vegetation on the Acid Drainage Slope (산성배수 비탈면의 생태적 녹화를 위한 산성배수 중화기법 연구)

  • Cho, Sung Rok;Shim, Sang Ryul;Kim, Jae Hwan
    • Journal of the Korean GEO-environmental Society
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    • v.20 no.1
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    • pp.27-33
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    • 2019
  • Research was initiated to find out acid drainage neutralizing techniques for ecological vegetative growth on the acid drainage slope. Four different acid drainage neutralizing techniques [no treatment, limestone layer treatment, phosphate treatment, and limestone layer + phosphate treatment] were treated on the acid drainage slope. There was a significant difference observed in treated acid neutralizing techniques for acidity, surface coverage rate, death rate and plant root status. Treated acid neutralizing techniques were effective for neutralizing acidity and vegetative growth in order of [first: limestone layer + phosphate treatment, second: phosphate treatment, third: limestone layer treatment and fourth: no treatment]. The limestone layer and the phosphate treatments were effective for neutralizing acidity and vegetative growth, respectively. However, the phosphate treatment was more effective compared to the limestone layer treatment on the acid drainage slope. We figured out that the phosphate treatment is more effective for neutralizing acidity and vegetative growth because of coating effect of sulfides.

Effects of Yeast Addition during Salting and Preparation on Fermentation of Kimchi (소금절임과 김치담금시 효모의 첨가가 숙성에 미치는 영향)

  • 김순동;김경희;오영애
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.6
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    • pp.1077-1085
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    • 1998
  • The effects of yeast on the fermentation of kimchi were investigated. The treatments were divided into two groups; yeast treatment during salting of Chinese cabbage(YS) and yeast treatment added in kimchi preparation(YF kimchi). The edible periods of the kimchi after yeast treatment during salting (YS kimchi) was extended 4~5 days by the results of pH, acidity, sensory quality. The activities of amylase, polygalacturonase and galactosidase of YS kimchi were retained at low levels compared to non treated condition throughout all fermentation periods, whereas protease activity was not significant different from the non treated condition. In addition, the contents of total hexose and uronic acid did not show remarkable change throughout fermentation, but total pentose was decreased by more than 7% at the early middle stage of fermentation(7~14 day after soaking). The change of free amino acid content was decreased by 16~44% than the non treated condition. In contrast, in the YF kimchi, the sensory quality was not good. The activities of amylase, protease, polygalacturonase and gal actosidase were appreciably higher than that of the non treated condition. Meanwhile, the contents of total hexose, total pentose and uronic acid, as products of degradation of cell wall constituents by the above enzymes, were decreased by 18~68% throughout fermentation than the non treated con dition, and total free amino acids were higher than the YS kimchi. Thus, yeast treatment during salting was found to be more effective to extend the edible periods of the kimchi.

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THE EFFECTS OF SURFACE TREATMENT AND THERMOCYCLING ON THE MICROLEAKAGE OF COMPOSITE RESIN CORES (치아표면 처리방법과 thernocycling이 콤포짓트 레진 코어의 미세누출에 미치는 영향)

  • Lim, Yong-Chul;Jin, Tai-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.2
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    • pp.255-263
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    • 2000
  • The purpose of this study was to compare the microleakage of the composite resin cores according to surface treatment, dentin bonding agents, and thermocycling. For this study, 120 extracted premolar teeth were used. Flat occlusal surfaces were prepared with diamond disk, and treated with air-abrasion, acid-etching, combination. The composite resin core was built with Z-100 after application of Scotchbond Multi-Purpose and All-Bond 2. Prepared specimens were thermocycled for 2,000 cycles. Specimens were immersed in 1% methylene blue solution for 24hours at $37^{\circ}C$. The microleakage was measured with a inverted metallurgical microscope(BHS313, Olympus, Japan). The following conclusions were drawn from this study: 1. The microleakages in the groups treated with air-abrasion and with acid etching were greater than that of the groups treated with combination method before thermocycling(p<0.05), the microleakages of the groups treated with air-abrasion were greater than that of the groups treated with acid-etching and combination method after thermocycling(p<0.05) 2. There were no significant difference between groups using Scotchbond Multi-Purpose and the groups using All-Bond 2. 3. Thermocycling didn't affect the change of microleakage in all cases.

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Effects of Chitosan Treatment on Properties of Wool Fabrics (키토산 가공이 모직물의 특성에 미치는 효과)

  • 모태화;이혜자;유혜자
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.1
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    • pp.87-95
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    • 2000
  • The changes on shrinkage, dyeability, antimicrobial activities and other physical properties of wool fabrics by chitosan treatment were investigated. A acid dye, a basic dye and natural artemisia were used for dyeing of wool fabrics. For Antimicrobial test of wool fabrics, S.Aureus was used. As the results, The wool fabrics treated with chitosan showed a marked decrease in shrinkage. Dyeability increased slightly as concentration of chitosan treatment increased, Dyeability of acid dye was the highest than other dyes. On the other hand, the dyeability of basic dye on chitosan treated fabrics was lower than untreated fabrics. Reduction rates of colony of chitosan-treated wool fabrics showed from 64.8% to 85.24% as chitosan concentration increased. Reduction rates of colony of the chitosan-treated fabrics decreased by dyeing with acid and basic dye. But increased by retreating with chitosan. Fabrics dyeing with atremisia showed above 90% reduction rate against S.Aureus on all chitosan concentrations. The Tensile properties of chitosan-treated fabrics showed little decrease. The moisture regain and the air permeability was decreased on chitosan concentration on 0.1% but recovered as chitosan concentration increased. The warmth retention was increased a little by chitosan treatment. The drapeability became hard as chitosan concentration increased.

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