• Title/Summary/Keyword: Acid treated

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Studies on the Natural Dyes (V) - Depression of Silk Yellowing and Destruction by the Treatment with Color of Camellia Leaf- (천연염료에 관한 연구 (V) - 동백잎색소처리에 의한 견직물의 광취화 억제효과에 관하여 -)

  • 조경래;장정대;박종범
    • Textile Coloration and Finishing
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    • v.5 no.2
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    • pp.91-98
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    • 1993
  • The silk fabrics were treated with color solution extracted from leaf of Camellia. The depression effect of destruction and yellowing of silk treated with color solution, shift of UV-VIS spectra of color solution, color difference of silk fabrics by dyeing with acid dyes and drycleaning fastness of silk treated with color solution were studied. UV-VIS spectra appeared to hypsochromic shift by irradiation. The decrease of tensile strength and the elongation of the silk treated with color solution showed depressed but those of untreated silk increased by irradiation. The yellowness index of silk treated with color solution showed a little change by irradiation. The color difference after dyeing with several acid dyes on treated and untreated silk showed not remarkable changes. Dsrycleaning fastness of silk treated by color solution was excellent.

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Acid Property and Catalytic Activity on Mordenites Treated by Hydrochloric Acid and Hydrofluoric Acid (염산 및 불산처리 모더나이트의 산특성과 촉매활성)

  • Han, Young-Taek;Ha, Baik-Hyon
    • Applied Chemistry for Engineering
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    • v.2 no.1
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    • pp.77-85
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    • 1991
  • A series of samples having different $SiO_2/Al_2O_3$ ratio were prepared by treating hydrogen mordenites with boiling hydrochloric acid and with hydrofluoric acid. The acidities of these samples were measured by TPD of $NH_3$ and by pyridine adsorption using IR, and the catalytic activities and selectivities of isomerization were measured for the reaction of ortho-xylene. For the samples treated by boiling hydrochloric acid, the acidities decreased with the increasing $SiO_2/Al_2O_3$ ratio caused by the extraction of framework aluminum. The sample having the $SiO_2/Al_2O_3$ ratio or 22 showed better activity than the others. For the samples treated by hydrofluoric acid, the content of chemically binding fluorine increased with the increasing contact time of hydrofluoric acid solution. The catalytic activities decreased with the hydrofluoric acid treatment due to the decreased acid sites resulted from the extraction of aluminum and silicon as well as the hydroxyl group replacement by the fluoride ion. The slightly increasing catalytic activities, however, came from the newly created acid sites, due to the removal of surface silicon, having enhanced by the inductive effect of binding fluorin with further acid treatment.

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Adsorption of Ammonia on the Sulfuric Acid Treated ACF

  • Kim, K.H.;Shin, C.S.
    • Carbon letters
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    • v.2 no.2
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    • pp.109-112
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    • 2001
  • For the adsorption of ammonia, activated carbon fibers (ACFs) were subjected to sulfuric acid treatment in order to modify the surface functional groups. The surface acid and base value of ACFs were measured using titration and FT-IR spectrometry. SEM was used to investigate the surface morphology. Acid treatments by $H_3PO_4$, $H_2SO_4$, and $HNO_3$ were performed to increase the adsorption capacity of $NH_3$. As a result, Cellulose-based ACF has high adsorption capacity for ammonia. The ammonia removal efficiency of ACF was the maximum which was treated by 15 wt% sulfuric acid at $100^{\circ}C$ for 60 min. The average pore diameter little increased from $19{\AA}$ to $20.8{\AA}$ and the specific surface area of ACF considerably decreased and acid values increased by 15 wt% sulfuric acid treatment. Ammonia reacted with sulfonyl radicals. After adsorption of ammonia, white material was grown on the surface of ACF through the adsorption of ammonia and it was determined to ammonium sulfate.

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Nitrogen Fixation and In Situ Dry Matter and Fibre Constituents Disappearance of Wheat Straw Treated with Urea and Boric Acid in Murrah Buffaloes

  • Dass, R.S.;Mehra, U.R.;Verma, A.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.8
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    • pp.1133-1136
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    • 2000
  • Wheat straw was treated with 4 per cent urea at a moisture level of 50 per cent alongwith different levels of boric acid viz. 1, 2, 3 and 4 per cent, under laboratory conditions to know the impact of boric acid on ammonia-N fixation in the straw. Murrah buffaloes were used for determining the disappearance of dry matter, CP and fibre constituents by nylon bag technique. Ammoniation increased CP content of wheat straw, which increased further due to addition of boric acid. Low level of boric acid (1%) had no adverse effect on fibre constituents disappearance but at higher levels there was a depressioon in the disappearance of fibre coonstituents. It can be concluded that low level of boric acid was sufficient to trap the excess ammonia released during urea ammoniation of wheat straw without affecting other constituents and their disappearance in the rumen of buffaloes.

Effects of Acrylamide Formation and Quality Characteristics Before Frying French Fries (튀김 전 후렌치후라이의 전처리가 아크릴아마이드 생성 및 품질특성에 미치는 영향)

  • Kim, Jin-Mam;Choi, Yun-Sang;Choi, Ji-Hun;Koo, Bon-Kou;La, Im-Joung;Kim, Cheon-Jei
    • Korean journal of food and cookery science
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    • v.28 no.4
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    • pp.407-412
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    • 2012
  • The objective of this research was to study the effect of pre-treatments before deep frying on the reduction in acrylamide formation, crispness and sensory properties of French fries. The acrylamide concentration was lower in pre-treated French fries before frying with citrus acid, ascorbic acid and salt solution than that in untreated French fries. Crispness, moisture and fat contents, color, texture and overall acceptability of pre-treated French fries were not significantly different compared to those in control. Therefore, French fries pre-treated with citrus acid, ascorbic acid and salt solution before frying had good sensory properties, and reduced acrylamide formation.

The Effect of Tannic Acid to the Cadmium on Mouse (Tannic acid가 랫드의 카드뮴독성에 미치는 영향)

  • 김판기;안령미;황성희
    • Journal of Food Hygiene and Safety
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    • v.13 no.2
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    • pp.87-93
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    • 1998
  • The tannic acid (0.5 mg/ml, 1.0 mg/mi, 2.0 mg/ml) and/or cadmium (20 mg/kg) were administered by oral administration. The results were as follows: 1. There were adverse effects on the weight changes and water consumption. But, the extent of adverse changes were decreased by tannic acid administration. 2. Also, there were some significant changes in organ weight, especially relative liver weight and relative brain weight by cadmium administration, but Ta1.0 group was significant changes in relative liver weight, relative lung weight and relative thymus weight compared with control group. 3. In the hematological patterns of administered mice, there were significant changes between cadmium treated groups and control group. Hemoglobin contents, packed cell volume, platelet count and neutrophill count were significantly change compared with control group. These changes were not shown in tannic acid treated group. 4. There were serological enzymatic changes in the cadmium treated mouse. In the tannic acid treated group 0.5, 1.0, 2.0 mg/ml, ALT, AST, BUN and creatinine were recovered to the extent of control group. From the above results, the tannic acid has some possible alleviative effects of cadmium toxicity upto the 2.0 mg/ml/day of oral dose for 4 weeks. But we need further study of mechanism for toxicty alleviating action of tannic acid to the heavy metals like cadmium.

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EFFECT OF PORCELAIN SURFACE TREATMENTS ON THE SHEAR BOND STRENGTH BETWEEN FORCELAIN AND COMPOSITE RESIN (도재 표면처리가 도재와 도재 수리용 복합레진간 전단결합강도에 미치는 영향)

  • Koh, Eun-Sook;Lee, Sun-Hyung;Chung, Heon-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.32 no.1
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    • pp.23-36
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    • 1994
  • Most investigators recommended that porcelain surface should be roughened with abrasives and/or be etched with acid in repairing the fractured porcelain with composite resin. This study was designed to evaluate the effect of porcelain surface treatments on the bond strength between porcelain and composite resin by measuring the shear bond strength and observing the porcelain surface with SEM. 48 porcelain disc were fabricated with Vintage porcelain and embedded in epoxy resin with the test surface exposed. The specimens were divided four groups at random and the test surfaces of the four groups were prepared as follows : Group 1 : Porcelain surface was roughened with a fine diamond and treated with 32% phosphoric acid gel for 10 seconds. Group 2 : Porcelain surface was roughened with a fine diamond and etched with 8% hydrofluoric acid gel for 5 minutes. Group 3 : Porcelain surface was roughened with a coarse diamond and treated with 32% phosphoric acid gel for 10 seconds. Group 4 : Porcelain surface was roughened with a coarse diamond and etched with 8% hydrofluoric acid gel for 5 minutes. All specimens were washed for 30 seconds. A representative specimen of each group was selected and the porcelain surface was observed with SEM at 1000 magnification. Remaining specimens were silanated, bonded with composite resin, thermocycled, and shear-tested on specially designed zig connected to Instron machine. The results were as follows : 1. The shear bond strength of the group etched with hydrofluoric acid was significantly higher than that of group treated with phosphoric acid(p<0.01). 2. The shear bond strength of the group roughened with a fine diamond was not significantly different from that of the group roughened with a coarse diamond(p>0.01). 3. SEM examination of prepared porcelain surfaces revealed that the surface etched with hydrofluoric acid showed numerous microporosities, undercut, and rougher surface than the surface treated with phosphoric acid. 4. All specimens etched with hydrofluoric acid showed cohesive failure within porcelain, but specimens treated with phosphoric acid mainly showed adhesive failure between porcelain and composite resin.

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Evaluation of Ascorbic Acid Treatment in Clinical and Subclinical Mastitis of Indian Dairy Cows

  • Naresh, Ram;Dwivedi, S.K.;Swarup, D.;Patra, R.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.6
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    • pp.905-911
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    • 2002
  • A study was carried out to assess the therapeutic effect of ascorbic acid in mastitis of dairy cows. The herd with a population of 250-275 lactating cows was screened for clinical and subclinical mastitis for a period of 5 months. Based on inclusion and exclusion criteria, eighteen animals each with clinical and subclinical mastitis in one quarter only were selected as study population. Twelve cows (group A) with normal udder and health were also selected as a healthy control. Clinical mastitis cows were grouped as B (n=12) and C (n=6). Cows of group B were treated with ascorbic acid at 25 mg/kg, subcutaneously for 5 consecutive days and intramammary infusion (Ampicillin sodium 75 mg and Cloxacillin sodium 200 mg/infusion) based on antibiotic sensitivity test, till complete recovery. Group C cows received only intramammary infusion till the complete recovery. Eighteen subclinical mastitis cows were divided in group D (n=12) and E (n=6). Cows of group D were treated with ascorbic acid at 25 mg/kg subcutaneously for 5 consecutive days while group E did not receive any treatment. California mastitis test (CMT), somatic cell count (SCC), physical changes of udder and milk were used to diagnose and classify the mastitis. Evaluation of the therapy was based on CMT score and physical changes of udder and milk. Sample size calculation was also performed but was not followed for control groups due to scarcity of cases. Adequate blinding was done when and where required to avoid the biases. Confounding variables like herd, age of the cow, stage of the lactation, season and geographical region were duly considered and adequate blocking was followed. Ascorbic acid was administered in clinical and subclinical cases even after cure considering its immunostimulatory and healing inducing effects. The recovery rate was faster in cases of clinical mastitis treated with ascorbic acid along with an intramammary infusion (group B) than the quarters of group C cows. Quarter wise the average duration/number (3.16${\pm}$0.11 days) of antimicrobial intramammary infusion was significantly (p<0.01) less in group B than that of average duration/number (5.33${\pm}$0.20 days) of group C. Subclinical mastitis cows treated with ascorbic acid showed 83.33% recovery while 16.77% did not respond to treatment till last day of study. Cows of group E (untreated) did not recovered from the mastitis. Subjective parameters viz. swelling, pain reflex of udder and physical changes in milk from quarter of ascorbic acid treated cows (group B) disappeared earlier than that of group C cows. It is concluded from this study that the ascorbic acid might be useful as an adjunct in case of clinical mastitis to get quick recovery with less number of intramammary infusions. High recovery rate in subclinical mastitis quarters of group D cows is appreciable and opens a new avenue to conduct further trials in a larger population in various field conditions. However, the pharmacology of ascorbic acid with particular reference to health of mammary gland needs to be investigated.

Effects of Oatrim on the Quality of Meat Products (일부재료(Oatrim)대체가 육류제품의 품질에 미치는 영향)

  • Jeon, Yoo-Shin;Sohn, Kyung-Hee
    • Korean journal of food and cookery science
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    • v.10 no.3
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    • pp.254-259
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    • 1994
  • Meat provides high quality proteins, lipids, minerals and vitamins. The meat protein is especially high in essential amino acids that are crucial for human health, growth & development and for the formation of enzymes, hormones and antibodies. Relatively cheap and nutritionally sound vegetable proteins that are similar to animal proteins are being developed to replace the animal proteins in texture, nutrition and food characteristics. In this study a nutritionally sound meat lipid replacing food Oatrim that has been produced by converting oat starch into maltodextrin by ${\alpha}$-amylase, have been partially substituted for beef and general component analysis, texture measurement and sensory tests have been conducted. The results are 1. Water content of the non-treated (0% treated) was 67.1% and the treated (10% treated) was 77%. The treated showed better water holding capacity. 2. Protein content of the non-treated was 21.2 g/100 g; the 4% treated, 18.4 g/100 g; the 6% treated, 18.2 g/100 g; the 8% treated, 17.2 g/100g; and the 10% treated, 16.0 g/100 g. The protein content tended significant. 3. Amino acid analysis results showed that glutamic acid content was the highest in Oatrim and as its amino acid make up is exellent, it is valuable as a fine low fat protein food. 4. Sensory tests show that the increased Oatrim content increased the appearance quality but food characteristics were high only in the 4% and 6% treated groups, indicating that the replacement ratio should not exceed 10%. 5. Texture measurement analysis results show that the higher the replacement content, lower the springness, cohesiveness, hardness, chewiness and gumminess, resulting in relatively soft overall texture. However, in order to better the food characteristics, more studies must be continuously done, and so by being able to increase vegetable substitution over meat, it may be able to contribute to the prevention of adult disease.

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Studies on Gibberellic Acid-promoted and Indole-3-acetic Acid-repressed Amylase Synthesis of Barley Seeds (대맥종자의 Amylase 생성에 미치는 Gibberellic Acid의 촉진효과와 Indole-3-acetic Acid의 억제효과의 해석)

  • 채인기
    • Journal of Plant Biology
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    • v.20 no.2
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    • pp.91-101
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    • 1977
  • Using barley seeds (Hordeum sativum Jess, var.), the influences of gibberellic acid (GA) and indole-3-acetic acid(IAA) on the amylase synthesis and that of the nucleic acid metabolism were investigated. 1. With the deembrynized barley seeds, the increase of amylase treated with a $10^{-5}M$ of GA and the decrease of amylase treated with $10^{-5}M$IAA were matched by a proportionate increase and decrease in the amount of RNA. The influence of the hormones on the RNA synthesis has appeared immediately after the treatment but on the amylase synthesis it has appeared 8 hours later. But no influence on the DNA synthesis was observed on both hormones. 2. The amylase from deembryonized barley seeds treated with GA and IAA have been fractionated by gel filteration on Sephadex G-100. The amylase components showed four fractions on both enzymes treated with GA and IAA. Fraction I(FI) was differed from fraction Ⅵ(FIV) in Km value and the effects of temperature, pH and metal ions. On the basis of their emzymatic properties, it was considered that the FI was $\beta$-amylase and FIV was $\alpha$-amylase. The influences of GA and IAA on each fractions appeared to be similar but on the amylase units per souble protein, IAA inhibited the production of amylase FIV while it promoted that of amylase FI. 3. An experiment was conducted to determine whether IAA inhibits GA-promoted amylase synthesis competitively or non-competitively. Using a Lineweaver-Burk plot, it was clear that IAA was acting in a non-competitive fashion. From this, IAA was probably not competing with GA at the same site, but it was acting at some other site which resutled in partial blocking of the action of GA on the amylase synthesis.

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