• 제목/요약/키워드: Acid solution

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가압수열 수용액중에서 인산석고로부터 $\alpha$형 반수석고의 생성에 미치는 염류의 영향 (Effects of Salts on the Formation of $\alpha$-Calcium Sulfate Hemihydrated from by-Product Gypsum of Phosphoric Acid Process at Hydrothermal Condition)

  • 이구종;최상흘
    • 한국세라믹학회지
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    • 제24권4호
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    • pp.343-348
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    • 1987
  • The effects of salts such as aluminum sulfate as inorganic salt(2-4%), and sodium salts of citrate, tartrate, succinate, potassium tartrate and gelatin as organic salts(0.1%) on the formation of ${\alpha}$-calcium sulfate hemihydrate from by-product gypsum of phosphoric acid process under hydrothermal condition at 123$^{\circ}C$ and 133$^{\circ}C$ were investigated. Aluminum sulfate solution exhibited the catalystic effected on the crystallization of ${\alpha}$-calcium sulfate hemihydrate of which was assumed in the prismatic form, and organic salts solution exhibited little effect on the catalystic action to the crystallization, than inorganic salts. In the acidic solution with sulfuric acid(pH=2), needle like crystal of calcium sulfate hemihydrate was obtained. Hydrothermal process with aluminum sulfate solution also showed certain amounts of impurity removal such as phosphorus penataoxide from calcium sulfate hemihydrate.

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다결정 실리콘 태양전지의 광학적 손실 감소를 위한 표면 텍스쳐링에 관한 연구 (Investigation of surface texturing to reduce optical losses for multicrystalline silicon solar cells)

  • 김지선;김범호;이수홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.264-267
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    • 2007
  • It is important to reduce optical losses from front surface reflection to improve the efficiency of crystalline silicon solar cells. Surface texturing by isotropic etching with acid solution based on HF and $HNO_3$ is one of the promising methods that can reduce surface reflectance. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its various grain orientations. In this paper, we textured multicrystalline silicon wafers by simple wet chemical etching using acid solution to reduce front surface reflectance. After that, surface morphology of textured wafer was observed by Scanning Electron Microscope(SEM) and Atomic Force Microscope(AFM), surface reflectance was measured in wavelength from 400nm to 1000nm. We obtained 29.29% surface reflectance by isotropic texturing with acid solution in wavelength from 400nm to 1000nm for fabrication of multicrystalline silicon solar cells.

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A Study on the Antibacterial Activity of Chitosan on the MRSA by the AATCC Test Method 100 and Modified AATCC Test Method 100

  • Choi, Jeong-Im;Jeon, Dong-Won
    • 한국의류산업학회지
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    • 제4권6호
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    • pp.557-563
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    • 2002
  • Water-soluble chitosan and water-insoluble chitosan with molecular weight of 2,000,000, 500,000, 80,000, and 40,000 with more than 90%of degree of deacetylation were produced to test antibacterial activity of chitosan against a pathogenic bacteria, Methicillin Resistant Staphylococcus aureus(MRSA). the AATCC Test Method 100and Modified AATCC Test Method 100 were used to evaluate the antibacterial activity of chitosan. Antibacterial activity of chitosan/acetic acid solution was the same when they were tested by two different methods, but those of polyester fabrics treated with chitosan/acetic acid solution were different in different antibacterial test. So several problems were found in the experimental methods. The AATCC Test Method 100 seems that excessive nutrition exists in inoculum solution by quantitative analysis on the basis the result of antibacterial activity on chitosan/acetic acid solution and amount of chitosan attached to the surface of treated fabrics.

호 알칼리성 Alcaligenes sp.가 생산하는 ${\gamma}$-Polyglutamic Acid의 용액 특성 (Solution Properties of ${\gamma}$-Polyglutamic Acid Produced by Alkalophilic Alcaligenes sp.)

  • 이신영;강태수김갑수
    • KSBB Journal
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    • 제10권4호
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    • pp.386-392
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    • 1995
  • The high viscous ${\gamma}$-polyglutamic acid(${\gamma}$-PGA) from alkalophilic Alcaligenes sp. was purified and its solution property was investigated. The intrinsic viscosities for Na+ form and H+ form of ${\gamma}$-PGA were 31.1 and 0.38d$\ell$/g, respectively. The viscosity of H+-PGA was not influenced by pH or salts while that of Na+-PGA was influenced. The intrinsic viscosity of Na+-PGA solution decreased remarkably at the alkaline or acidic pH and showed the sharp decrease when salts were added. ${\gamma}$-PGA exhibited the property of the polyelectrolyte showing the .sharp decrease of intrinsic viscosity by the addition of NaCl, and intrinsic viscosity of dilute solution with the low concentration of NaCl was exponentially dependent on temperature and its temperature dependency increased with increasing NaCl concentration. The chain stiffness, coil overlap parameter and critical concentration of Na+-PGA were 0.08, 5.25 and 0.07g/d$\ell$, respectively.

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천연염료에 관한 연구 ( I ) -자근색소의 추출 및 자외가시분광특성- (Studies on the Natural dyes( I ) -extraction and UV, VIS spectrum of coloring matter of gromwell-)

  • 조경래
    • 한국의류학회지
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    • 제11권3호
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    • pp.25-32
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    • 1987
  • The purpose of this study is to investigate optical behaviour of coloring matter of gromwell -extracted by water, acetic acid/methanol, and the other solvents. The results were as following: UV, VIS spectra of the solution of coloring matter of gromwell extracted by water at below $80^{\circ}C$ did not reveal in the range of the visible light wavelength and coloring matter of gromwell decomposed to blue particle at $95^{\circ}C$. The solution extracted by acetic acid/methanol was tinged with reddish purple and its spectra shifted to the longer wavelength according to increase of the solvent temperature. The color of the solution extracted by water became extinct as time went by, but that extracted by acetic acid/methanol kept up original color. In case of dried gromwell, extraction by acetic acid/methanol was easier than by water, and variation of spectra did not appear but showed hypochromic shift.

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퍼머넨트 웨이브의 형태 변화에 미치는 환원제의 영향 (A Study on Permanent Wave Form According to the Reductant)

  • 배영실
    • 한국의류산업학회지
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    • 제7권6호
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    • pp.641-649
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    • 2005
  • This study is to make pH 9 reduction by adding NaOH to 1, 3, 5, 7, 9, 11% solution of thioglycollic acid, cysteine, cysteamin, to add it on helically winded natural hair and colored hair and leave them for 20, 40, 60 minutes, to add $NaBrO_3$ oxidant for 15 minutes and to compare and analyze the wave form. This study showed the results of permanent using thioglycollic acid, cysteine, cysteamin. In the permanent wave form according to the kind of reductant, concentration, and processing time, there were a little difference between thioglycollic acid and cysteine. But cysteamine not only showed apparent difference but also formed strong and elastic wave. The permanent wave is affected by the diagonosis of hair, the choice of permanent solution and the processing time. Therefore the scientific diagonosis of hair is to be considered first of all. By choosing the kind of solution, the concentration and the processing time according to the results of hair diagonosis and wave form, we can prevent the lengthening and damage of hair.

산-염소이온 분위기의 인자전위에 따른 내후성강 용접부의 부식파괴에 관한 연구 (A Study on Corrosion Failure of a Weathering Steel Weldment with Various Applied Potentials in Acid-chloride Solution)

  • 최윤석;김정구;김종집;이병훈
    • Journal of Welding and Joining
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    • 제18권3호
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    • pp.97-105
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    • 2000
  • The stress corrosion cracking(SCC) and hydrogen embrittlement cracking(HEC) characteristics of a weathering steel weldment were investigated in aerated acid-chloride solution. The electrochemical properties of weldment were investigated by polarization test and galvanic corrosion test. Weathering steel did not show passive behavior in the acid-chloride solution. Galvanic corrosion between the weld metal and the base metal was not observed because the base metal was anodic to the weld metal. The slow-strain-rate tests(SSRT0 were conducted at a constant strain rate o 7.87×{TEX}$10^{-7}${/TEX}/s at corrosion potential, and at potentiostatically controlled anodic and cathodic potentials. The weldment of weathering steel was susceptible to both anodic dissolution SCC and hydrogen evolution HEC.

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산성 광산 배수의 처리를 위한 철(Fe) 성분의 플럭 형성 특성 (The Characteristics of Iron(Fe) Floc Formation for Treatment of Acid Mine Drainage)

  • 송근호;이광래
    • 산업기술연구
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    • 제33권A호
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    • pp.89-92
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    • 2013
  • The characteristics of floc formation of the iron(Fe) ions was studied for developing the process treating the acid mine drainage. The metal ions in aqueous solution oxidized with oxygen in air, which generated hydrogen ion and lowered the pH of the aqueous solution. The iron(Fe) ions were formed into flocs by the acid-base reaction with the added $Ca(OH)_2$ for the neutralizing the solution. There were several variables affecting the formation, size and color of floc; whether air was present or not, air feeding rate, oxidizing time, concentration of $Ca(OH)_2$, the acid-base reaction time of the $iron(Fe)-Ca(OH)_2$. For proper formation of the $iron(Fe)-Ca(OH)_2$ flocs and developing the floc treating system, the control variables mentioned above should be considered.

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L-ascorbic acid가 포집된 BGsome의 특성 및 안정화 효과 (Characteristics of L-Ascorbic Acid Encapsulated BGsome and its Stabilization Effect)

  • 황수연;진병석
    • 한국응용과학기술학회지
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    • 제28권3호
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    • pp.313-320
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    • 2011
  • Encapsulation of L-ascorbic acid(AA) into BGsome was attempted to improve its stability. BGsome is a bio-compatible vesicular system prepared by dispersion of hydrated liquid crystalline phase formed through hydration of 1,3-butylene glycol(BG)-dissolved lecithin with an aqueous solution containing hydrophilic component. The characteristics of AA encapsulated BGsome, such as droplet size, surface charge, and solution appearance, was investigated. The concentration of AA solution had considerable effect on droplet size and surface charge of BGsome. Several tens nanometer droplet made by sonication treatment did not showed any change of size with storage time. Stability of AA was improved by encapsulation into BGsome, which was verified through DPPH test and HPLC assay.

Polyaniline을 이용한 코팅막의 전기적 특성 (Electrical Properties of Coatings of Polyaniline)

  • 김언령;김종은;서광석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.310-313
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    • 2000
  • Polyaniline Emeraldine Base (PANI EB) polymerized by chemical oxidative polymerization was doped with Camphorsulfonic Acid(CSA). Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) solutions were solved in organic solvents and sonificated at the room temperature for different solvents in PANI-CSA ES solution and sonification time. PANI-CSA ES solutions was coated on PET films using bar coater. 1-Step oxidatively-polymerized Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) was solved in m-cresol:chloroform 1:1 co-solvents and their solution was bar-coated on PET film. The surface resistivities of these coated films were measured, The surface resistivity of PANI-CSA ES solution in m-cresol:chloroform 1:1 co-solvent system was 5${\times}$10$^2$$\Omega$/$\square$.

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