• 제목/요약/키워드: Acid deposition

검색결과 559건 처리시간 0.024초

3차원 구조의 다공성 금 박막을 이용한 GABA의 전기화학적 측정 (Electrochemical Determination of GABA using a 3-D Nanoporous Gold Thin Film)

  • 표수현;이진호;오병근
    • 공업화학
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    • 제22권5호
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    • pp.575-578
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    • 2011
  • 전기화학적 증착 기법을 이용하여 간단하고 빠르게 3차원적 구조를 가지는 다공성 금 박막(NPGF : nanoporous gold thin film)을 금 기판 위에 제작하였다. 제작된 3차원적 구조의 NPGF는 주사 전자 현미경(SEM)을 이용하여 표면을 분석하였고, 이를 통하여 표면상에 30~50 nm 크기의 균일한 다공성 박막이 생성되었음을 확인하였다. Differential pulse voltammetry(DPV) 기법을 기반으로 3차원적 구조체를 가진 NPGF기판을 전극으로 사용하여 GABA를 농도별($10{\sim}100{\mu}M$)로 측정하였다. 본 연구에서 제안된 방법은 향후, 바이오센서 응용분야에 널리 사용될 수 있을 것으로 기대된다.

Potassium formate, Glycine, Oxalic acid가 황화물계 3가 크롬도금층의 조성과 전류효율에 미치는 영향 (Effect of Potassium Formate, Glycine and Oxalic Acid in Sulfate Bath on Trivalent Chromium Deposition Composition and Current Efficiency)

  • 김만;김대영;박상언;권식철;최용
    • 한국표면공학회지
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    • 제37권2호
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    • pp.86-91
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    • 2004
  • Effect of potassium formate, glycine and oxalic acid in a sulfate solution on the deposit composition and current efficiency of trivalent chromium plating was studied. The trivalent chromium layers prepared by solutions with potassium formate, glycine and oxalic acid contain a few carbon inside. The solutions containing potassium formate, glycine and oxalic acid are relatively stable with pH change. The solution with the potassium formate shows 6-30% current efficiency with current density, whereas, the solutions with oxalic acid and glycine show about 5% current efficiency, respectively. The improved current efficiency is related to enough supply of chromium ions to the electrode due to the increase of pH at the front of electrode.

A study of deterioration of reinforced concrete beams under various forms of simulated acid rain attack in the laboratory

  • Fan, Yingfang;Hu, Zhiqiang;Luan, Haiyang;Wang, Dawei;Chen, An
    • Structural Engineering and Mechanics
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    • 제52권1호
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    • pp.35-49
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    • 2014
  • This paper studies the behaviour of deteriorated reinforced concrete (RC) beams attacked by various forms of simulated acid rain. An artificial rainfall simulator was firstly designed and evaluated. Eleven RC beams ($120mm{\times}200mm{\times}1800mm$) were then constructed in the laboratory. Among them, one was acting as a reference beam and the others were subjected to three accelerated corrosion methods, including immersion, wetting-drying, and artificial rainfall methods, to simulate the attack of real acid rain. Acid solutions with pH levels of 1.5 and 2.5 were considered. Next, ultrasonic, scanning electron microscopy (SEM), dynamic, and three-point bending tests were performed to investigate the mechanical properties of concrete and flexural behaviour of the RC beams. It can be concluded that the designed artificial simulator can be effectively used to simulate the real acid rainfall. Both the immersion and wetting-drying methods magnify the effects of the real acid rainfall on the RC beams.

PET 기질의 전처리효과가 상온 ECR 화학증착법에 의해 증착된 구리박막의 계면접착력에 미치는 영향 (Effects of Pretreatments of PET Substrate on the Adhesion of Copper Films Prepared by a Room Temperature ECR-MOCVD Method)

  • 현진;전법주;변동진;이중기
    • 한국재료학회지
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    • 제14권3호
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    • pp.203-210
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    • 2004
  • Effects of various pretreatments on the adhesion of copper-coated polymer films were investigated. Copper-coated polymer films were prepared by an electron cyclotron resonance-metal organic chemical vapor deposition (ECR-MOCVD) coupled with a DC bias system at room temperature. PET(polyethylene terephthalate) film was employed as a substrate material and it was pretreated by industrially feasible methods such as chromic acid, sand-blasting, oxygen plasma and ion-implantation treatment. Surface characterization of the copper-coated polymer film was carried out by AFM(Atomic Force Microscopy) and FESEM(Field Emission Scanning Electron Microscopy). Surface energy was calculated by based on the value of the contact angle measured. The adhesion of copper/PET films was determined by a pull-off test according to ASTM D-5179. It was found that suitable pretreatment of the PET substrate was required for obtaining good adhesion property between copper films and the substrate. In this study the highest adhesion was observed in sand-blasting, and then followed by those of acid and oxygen plasma treatment. However, the effect of surface energy was insignificant in our experimental range. This is probably due to compensating the difference in surface energy from various pretreatments by exposing substrate to ECR plasma for 5 min or longer at the early stage of the copper deposition. Therefore, it can be concluded that surface roughness of the polymer substrate plays an important role to determine the adhesion of copper-coated polymer for the deposition of copper by ECR-MOCVD.

전산화단층영상을 이용한 그물형 손목 부목의 3D 프린팅 (3-Dimensional Printing for Mesh Types of Short Arm Cast by Using Computed Tomography)

  • 성열훈
    • 한국콘텐츠학회논문지
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    • 제15권1호
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    • pp.308-315
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    • 2015
  • 본 연구는 3D 프린터를 이용하여 통풍이 원활하고 위생적이며 선명한 방사선영상을 구할 수 있는 그물형 손목 부목을 제작하고자 하였다. 스캐너는 의료용 다중단층영상장치(MDCT)를 이용했으며, 3D 프린터 기기는 용융 적층 조형술(fused deposition modeling, FDM)의 프린팅 방식을 이용했다. 소재는 분해성 플라스틱 (poly lactic acid, PLA)을 사용하였다. 손목의 3 차원 볼륨렌더링은 MDCT에서 획득된 단층영상으로 구현하였다. 구현된 손목 3 차원 영상을 바탕으로 가상의 그물형 부목 모형을 디자인하고 출력하였다. 그 결과 3D 프린터로 출력된 부목이 기존 부목보다도 우수한 방사선 손목영상을 획득할 수 있었으며 가려움증 및 비위생적인 단점을 개선하고 부목 해체 작업이 용이하였다. 결론적으로 본 연구에서 모델링된 3D 부목 모형은 향후 3D 프린팅 부목 제작에 기초자료로 활용할 수 있으며 환자들의 실생활에 도움을 줄 것으로 기대한다.

압출 적층 조형법과 입자 추출법을 결합한 이중 공극 BCP/Silica 인공지지체의 제작 (Fabrication of BCP/Silica Scaffolds with Dual-Pore by Combining Fused Deposition Modeling and the Particle Leaching Method)

  • 사민우;김종영
    • 대한기계학회논문집A
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    • 제40권10호
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    • pp.865-871
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    • 2016
  • 조직 공학에서는 전통적인 인공지지체 제작 방식인 가스 발포, 염 침출, 스폰지 복제 그리고 동결주조 법 등이 이용되고 있다. 하지만 다양한 공극 형태 및 크기를 가지고 있어서 세포 상호 작용 효과 및 충분한 기계적 특성에 한계가 있다. 그러나 열 용해 적층 법은 조직공학에서 폴리머 재료를 이용하여 다양한 3차원 인공지지체를 제작할 수 있는 가장 적절한 기술이다. 따라서 본 연구에서는 PCL 몰드를 제작하고 실리카와 알긴산 나트륨 염을 포함하는 세라믹 슬러리를 제조하여 몰드에 주입시켰으며, 1일 동안 자연 건조를 시켰다. 제작된 3차원 슬러리 몰드는 PCL 몰드의 제거 및 슬러리를 경화시키기 위해 $100^{\circ}C$의 오븐에서 2시간 열처리 되었고, 열처리 후에 $1100^{\circ}C$에서 소결되었다. 제작된 인공지지체는 주사전자현미경을 통해 관찰되었고, 압축 시험을 통해 알긴산 나트륨 염의 혼합량에 따른 인공지지체의 기계적 특성은 평가되었다.

압출적층조형 공정 기반 3D 프린팅 제품 기계적 특성의 지배적 공정인자 도출 및 최적화에 관한 연구 (Identification and Optimization of Dominant Process Parameters Affecting Mechanical Properties of FDM 3D Printed Parts)

  • 김정섭;조난현;남정수;이상원
    • 대한기계학회논문집A
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    • 제41권7호
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    • pp.607-612
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    • 2017
  • 최근 다양한 분야에 적용되고 있는 적층 가공 기술(AM)은 복잡한 형상 제조 및 재료 비용 절감으로 인해 혁신적인 제품 생산 방법으로 각광을 받고 있다. 그 중에서도 압출적층조형(Fused Deposition Modeling, FDM) 공정을 통한 친환경 부품 제조는 의료 분야산업에서 많은 주목을 받고 있다. 따라서, 본 논문에서는 친환경 생분해성 재료인 Poly Lactic Acid(PLA)를 사용한 FDM 공정 실험을 수행하고 제작된 적층 시편에 대한 인장 시험을 적용하여 주요 FDM 공정 변수인 적층 두께, 적층 방향, 적층 충진량이 인장 시편의 기계적 성질에 미치는 영향을 정량적 및 정성적으로 분석하고 이를 극대화하는 각 공정 변수의 최적값을 도출하였다.

산성강하물의 침착량과 동태 해명에 관한 연구 - 필터팩을 이용한 춘천과 서울의 건성강하물의 농도 측정 (A Study on the Behavior and Deposition of Acid Precipitation-Measurement of Dry Deposition in Chunchon and Seoul by Using Filter Pack Method)

  • 김만구;박기준;강미희;황훈;이보경;이동수
    • 한국대기환경학회지
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    • 제15권1호
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    • pp.53-61
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    • 1999
  • Acid aerosol and gas concentrations ($SO_4^{2-}$, $NO_3^-$, $HNO_3$, $SO_2$, and $NH_3$) were measured at Chunchon and Seoul, Korea using filter pack method during one year from October 1996 to september 1997. The samples were collected during 24 hours every Wednesday in a week from 10 A.M. with 10$\ell$/min of sample flow. Concentration of $HNO_3$, $SO_2$ and $NH_3$ gases showed typical seasonal variation. The $HNO_3$ showed the highest in summer and annual mean concentrations were 0.42 ppb and 0.57 ppb at Chunchon and Seoul, respectively. The $SO_2$ showed the highest in winter and annual mean concentration was 5.59 ppb at Chunchon. The $NH_3$ showed the highest in early summer and annual mean concentration were 5.15 ppb and 6.28 ppb at Chunchon and Seoul, respectively.

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Chemical Composition Characteristics of Precipitation at Two Sites in Jeju Island

  • Kang, Chang-Hee;Kim, Won-Hyung;Lee, Won
    • Bulletin of the Korean Chemical Society
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    • 제24권3호
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    • pp.363-368
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    • 2003
  • The major ionic components of precipitation collected at the 1100 Site of Mt. Halla and Jeju city have been determined. The reliability of the analytical data was verified by the comparison of ion balances, electric conductivities and acid fractions; all of their correlation coefficients were above 0.94. Ionic strengths lower than $10^{-4}$ M were found in 53% of the 1100 Site samples and 28% of the Jeju city samples. Compared with other inland areas, the wet deposition of $Na^+,\;Cl^-\;and\;Mg^{2+}$ was relatively larger, but that of $NH_4^+,\;nss-SO_4^{2-}$(non-sea salt sulfate) and $NO_3^-$ was lower. Especially the wet deposition increase of $Ca^{2+}$ in the spring season supports the possibility of the Asian Dust effect. The acidification of precipitation was caused mostly by $SO_4^{2-}\;and\;NO_3^-$ in the Jeju area, and the organic acids have contributed only about 7% to the acidity. The neutralization factors by NH₃were 0.47 and 0.48, and that of CaCO₃was 0.31 and 0.25 at the 1100 Site and Jeju city, respectively. Investigation into major influencing sources on precipitation components by factor analysis showed that the precipitation at the 1100 Site had been influenced mostly by an anthropogenic source, followed by soil and seawater sources. The precipitation at Jeju city was mainly influenced by oceanic sources, followed by anthropogenic and soil sources.

Screening and functional validation of lipid metabolism-related lncRNA-46546 based on the transcriptome analysis of early embryonic muscle tissue in chicken

  • Ruonan, Chen;Kai, Liao;Herong, Liao;Li, Zhang;Haixuan, Zhao;Jie, Sun
    • Animal Bioscience
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    • 제36권2호
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    • pp.175-190
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    • 2023
  • Objective: The study was conducted to screen differentially expressed long noncoding RNA (lncRNA) in chickens by high-throughput sequencing and explore its mechanism of action on intramuscular fat deposition. Methods: Herein, Rose crown and Cbb broiler chicken embryo breast and leg muscle lncRNA and mRNA expression profiles were constructed by RNA sequencing. A total of 96 and 42 differentially expressed lncRNAs were obtained in Rose crown vs Cobb broiler chicken breast and leg muscle, respectively. lncRNA-ENSGALT00000046546, with high interspecific variability and a potential regulatory role in lipid metabolism, and its predicted downstream target gene 1-acylglycerol-3-phosphate-O-acyltransferase 2 (AGPAT2), were selected for further study on the preadipocytes. Results: lncRNA-46546 overexpression in chicken preadipocyte 2 cells significantly increased (p<0.01) the expression levels of AGPAT2 and its downstream genes diacylglycerol acyltransferase 1 and diacylglycerol acyltransferase 2 and those of the fat metabolism-related genes peroxisome proliferator-activated receptor γ, CCAAT/enhancer binding protein α, fatty acid synthase, sterol regulatory element-binding transcription factor 1, and fatty acid binding protein 4. The lipid droplet concentration was higher in the overexpression group than in the control cells, and the triglyceride content in cells and medium was also significantly increased (p<0.01). Conclusion: This study preliminarily concludes that lncRNA-46546 may promote intramuscular fat deposition in chickens, laying a foundation for the study of lncRNAs in chicken early embryonic development and fat deposition.