• 한국물환경학회지
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• 제27권2호
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• pp.141-146
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• 2011

Loess, a natural clay, was evaluated as an adsorbent for the decolorization of Acid Orange II, an azo and reactive dye, from aqueous solution. Adsorption studies were performed at $30^{\circ}C$ and the effect of reaction time, loess dosage, initial concentration, loess particle size, pH, agitation rate were investigated to determine the optimum operation conditions. The removal efficiencies of color were measured to evaluate the effectiveness of loess. From this study, it was found that optimal reaction time was 10 min. Color removal efficiencies of Acid Orange II were increased as higher loess dosage, initial concentration and agitation rate. However, color removal efficiencies decreased when pH is high and loess particle becomes large. Adsorption of Acid Orange II fitted to the pseudo-second-order rate kinetics more than first-order rate kinetics. Langmuir and Freundlich adsorption isotherm constants and correlation coefficients were calculated and compared. It was concluded that the adsorption data of Acid Orange II onto loess fitted to the Freundlich model more than Langmuir model.

• 한국염색가공학회지
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• 제6권3호
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• pp.60-66
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• 1994

With the view of studying on the dual adsorption mechanism of acid dyes in connection with the structural difference of silk fibroin, silk fiber and silk fibroin memberane were used for equilibrium dyeing at $60^{\circ}C$, $70^{\circ}C$, $80^{\circ}C$ and pH 3.2, pH 5.0. The dyes used were C.I.Acid Orange 7 and C.I.Acid Red 88 introduced aromatic hydrocabon into Acid Orange 7. From the adsorption isotherm experiment, the total uptake of dyes can be described by Langmuir sorption and Nernst partition. Nernst partition. Nernst partition coefficient $K_1$ decrease of crystalline regions and orientation. The saturation value S of Acid Red 88 were large than total amino group contents and it was attributed it hydrophobic bond. On the other hand, the standard afficity and enthalpy were increased with the in crease of hydrophobic part of dyes. Both $k_1$ and $K_2$ were decreased with the increase of pH, but $k_2$ were more effected than $K_1$.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2001년도 가을 학술발표회 발표논문집
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• pp.97-98
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• 2001

Acid Orange 7과 Methyl Orange의 경우, UV 빛을 조사하고 $TiO_2$ powder를 투여하였을 때 120분 이내에 탈색이 완전히 이루어짐으로써 색도를 80% 이상 제거할 수 있었다. 광촉매량이 증가할수록 촉매표면적이 증가하여 광반응 속도의 증가를 가져오나, 과도한 촉매량의 투입은 오히려 UV 빛의 효과적인 투과를 방해함으로써 광반응 속도를 감소시킨 것으로 사료된다. 초기 pH는 반응 속도에 큰 영향을 미치지 못하는 것으로 나타났으며, Orange II는 Methyl Orange보다 초기 pH에 다소 큰 영향을 받았다. 초기 농도가 낮을수록 초기 반응 속도는 증가하여 염료 분해 속도가 빠름을 알 수 있었다.

• 한국염색가공학회지
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• 제2권2호
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• pp.33-38
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• 1990

Nitrocellulose [NC]-Poly(vinylamine) [PVAm] blended membranes with the change of amino group contents were prepared. The sorption and permeation of a mono-sulfonic acid dye, Orange II, in the membranes were investigated by the steady-state permeation method at $50^{\circ}C$ and pH 2.2. The results were discussed in the framework of dual sorption and diffusion theory. It was found that thesorption isotherms comprise a partition and two Langmuir type adsorption having similar binding constants. One of the latter sorption modes is due to unknown adsorption sites in NC and the other is due to the amino groups in PVAm. Apparent diffusion coefficients for collective P and L dye species, $D_P\; and D_L$, were obtained. Interpretation of $D_P$ values leads to two modes of partitions; one is such that dye is immobilized in NC and the other is the dissolution of the dye into the internal water phase.

• Advances in environmental research
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• 제5권3호
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• pp.189-200
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• 2016

This study aimed at advanced oxidation of hetero tri-functional reactive dye Acid orange 7 using photo-Fenton conditions in a lab-scale experiment. Decolourisation of Acid Orange 7 dye by Fenton's process was dependent on concentration of Hydrogen peroxide, Ferrous sulphate, pH, and contact time. A $2^3$ factorial design was used to evaluate the effects of these key factors: pH, Fe(II), and $H_2O_2$ concentration, for a dye concentration of 50 mg/L with COD of 340 mg/L at pH 3.0. The response function was removal of colour under optimised conditions; pH 3.0, [Fe(II)] 40.83 mg/L, [$H_2O_2$] 4.97 mmol/L; 13.6 min. of treatment resulting in 100% colour removal. The final COD of treated wastewater was nil suggesting that AOP is a potentially useful process of color removal and dye degradation/mineralisation of effluent having AO7. Minimum contact time for complete decolourisation was at 5 mmol/l $H_2O_2$ concentration. Increase in $FeSO_4$ (mg/l) concentration resulted in decrease of time for complete decolourisation. Box-Behnken Design was used to optimize the process variables. Maximum and minimum levels of pH (3-5), $H_2O_2$ (4-6 mmol/l), $FeSO_4$ (30-46 mg/l) and contact time (5-15 minutes) were used. The statistical analysis revealed a value of 0.88 for coefficient of regression ($R^2$) indicating a good fit of model. Calculated F-value was found higher than the tabulated value confirming to significance of the model. Based on student's t-test, Ferrous sulphate, pH, and contact time have a positive effect on the percent decolourisation of Acid Orange 7.

• 한국염색가공학회지
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• 제1권1호
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• pp.47-53
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• 1989

The effect of organic solvent in the dyeing of silk fiber by acid dye was investigated. Acetophenone and benzyl alcohol were shown to be the most effective for the rate of dyeing of silk fiber by Milling Cyanine 5R (C.I. Acid Blue 113), a milling type acid dye, but, with benzyl alcohol, the equilibrium dye uptake was much lower than that in the absence of it. In the presence of solvent, maximum dye uptake shifted to lower temperature than 6$0^{\circ}C$, while without solvent, it was shown at about $60^\circ{C}$. When dyed by Orange II (C.I. acid Orange 7) under same condition equilibrium dye uptake of silk fiber was lower than that for milling type acid dye, and in the presence of benzyl alcohol, still much lower uptake resulted. All these fact reveals that organic solvents in the solvent-assisted dyeing of silk fiber broaden micelle spacings too much, resulting in increased rate of dyeing, and decreased equilibrium dye uptake, contrary to wool.

• 한국염색가공학회지
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• 제4권3호
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• pp.131-135
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• 1992

Quaternary aminized cellulosic adsorbents (C $A_{QA}$ ) which exhibit adsorption capacities for anionic dyestuffs for the treatment of colored waste water and re-use of the treated water were studied. The isotherms and thermodynamic parameters of C.I. Acid Orange 7, solution considered as a model of negatively charged coloring matters for C $A_{QA}$ , were determined. Batch method and flow method were employed to determine decoloring capacity of cellulosic adsorbents for Orange 7. The cellulosic adsorbents exhibited much better adsorption capacity than activated carbon. Furthermore the exhausted cellulosic adsorbents could be readily regenerated by washing with dilute sodium hydroxide.

• 한국잠사곤충학회지
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• 제49권2호
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• pp.71-73
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• 2007

인공사료로 먹인 누에에 천연염료와 화학 염료를 각각 혼합하여 5령 3일 째부터 먹인 누에의 유색고치 생산을 검토한 결과 다음과 같다. 1. 천연염료와 인공사료를 혼합 할 경우에 치자 색소만 청자색으로 변환하여 유색 견을 생산하였고 고치의 중량은 대조 보다 낮았다. 2. 화학 염료 혼합 인공사료는 Orang II, Methyl Orang, Acid Blue R의 유색고치 생산은 주황색 노란색, 파란색 순서로 유색 고치를 생산하였다.

• 한국염색가공학회지
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• 제2권3호
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• pp.36-42
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• 1990

The effect of urea and its derivatives, which are known as structure breakers of water, in the dyeing of silk with acid dyes was investigated. Without ureas the maximum dye uptake was observed at $60^{\circ}C$ when dyed with Milling Cyanine 5R, but in the presence of ureas the maximum dye uptake was decreased and its temperature also shifted to lower regin in the order of urea >N-methyl urea > N,N-dimethyl urea>tetramethyl urea. These tendencies were more marked in the dyeing of silk fiber with Orange II, a typical levelling type acid dye. These can be interpreted as the decrease in the hydropholic interaction between fiber molecules which results in the broadening of the inter micelie spacing. The increased partition coefficient of dye molecules in the bath by the action of ureas also contributes to dyeing results, and it can be seen from the spectral characteristics of dyes in aqueous urea solution.

• Journal of Microbiology
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• 제34권1호
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• pp.1-6
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• 1996

The nucleic acid of Synechococcus sp. cyanophage was identified as double-stranded DNA by the result of digestion with enzymes such as exonucleases, DNase, and S1 nuclease, and by acridine orange staining. The cyanophage DNA was cleaved with several restriciton ehdonucleases such as ApaI, BamHI, Bg/II, HaeIII, Eco RI, HindIII, PstI, AND aPAI gave the clearest sets of bands on agarose gels and the fragment numbers for each were 12, 20, 29, 20, and 7, respectively. The sums of the size from Bam HI and PstI digestions were estimated approximately 227$\pm$4 kb, which are in agreement with the result of the pulsed field gel electrphoresis. This virus is thought to have the largest genosome among those of known cyanophages, which corresponds to the largest haed ot 90 nm when compared with the head sizes of cyanophages discovered since 1963.