• 산업기술연구
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• 제22권B호
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• pp.13-20
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• 2002

The purpose of this study is to investigate the effect of acid fog on the rust formation behavior of weathering steel (SMA50) which is used in uncoated bridges. Weathering steel didn't form the passive film under the environment of acid fog(pH5,6), whereas the environment of distilled water formed the protective oxide film. Therefore, the construction of weathering steel under the environment extremely exposed to SOx and NOx which are the main compositions of acid fog is not adequate. Fatigue limits of weathering steel under acid fog environment are remarkably decreased as compared with environment of distilled water. The corrosive constituents in acid fog has piled up the corrosion products on specimen surface and generated the corrosion pits. Because of the high stress concentration arising at this corrosion pit, relatively low fatigue limits were obtained for acid fog specimens.

• 대한기계학회논문집A
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• 제32권1호
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• pp.13-20
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• 2008

The purpose of this study is to investigate the effect of acid fog on the rust formation behavior of weathering steel (SMA50) which is used in un-coated bridges. Weathering steel didn't form the passive film under the environment of acid fog(pH5,6), whereas the environment of distilled water formed the protective oxide film. Therefore, the construction of weathering steel under the environment extremely exposed to SOx and NOx which are the main compositions of acid fog is not adequate. Fatigue limits of weathering steel under acid fog environment are remarkably decreased as compared with environment of distilled water. The corrosive constituents in acid fog has piled up the corrosion products on specimen surface and generated the corrosion pits. Because of the high stress concentration arising at this corrosion pit, relatively low fatigue limits were obtained for acid fog specimens.

• 한국자동차공학회논문집
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• 제8권5호
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• pp.181-187
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• 2000

Fatigue tests under acid fog environment were carried out to investigate the effect of acid fog on the corrosion fatigue strength of SM55C in comparison with distilled water. Main results obtained are as follows. The fatigue strength of SM55C under acid fog environment are remarkably decreased as compared with that of distilled water specimen. The corrosive effect of acid fog on fatigue strength are more serious under low stress amplitude level than under high stress amplitude level, and this leads to continuous reduction of fatigue strength. Under acid fog environment in early stage of crack growth. because the corrosive components dissolve the crack face offensively. the unstable fracture surface appears. But, the stable corrosion precipitation and products layer are formed on the fracture surface in accordance with the time pass.

• 한국대기환경학회지
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• 제8권1호
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• pp.45-51
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• 1992

A study on acidity in fog, dew and frost was carried out. Samples were taken during May 1990-February 1991 at two sites in Chongwon, Choongbook. The acidity of dew and of fog collected from grass at site A was 4.89 and 5.46, respectively. Dew in summer showed very strong acidity. The volume of dew deposited on grass was much less than the volume of rain, but dew is effective to diffuse acid predursors and acid materials. Dew and fog can remove more effectively atmospheric acid materiasl deoposited on grass by diurnal turbulent motion rather than direct absorption of acid predursors and materials in the atmosphere. In a polluted area, acidic dew and fog can be occurred by the direct absorption and oxidation of acidic predursors in the atmosphere as well as the role of wet removal on grass surface. Acidity of frost collected on teflon surface showed little difference to acidity of dew and fog on teflon surface. This suggests a similar absorption mechanism of atmospheric precursors and materials into dew and frost in the atmosphere. Strong acidity in dew, fog and frost appeared to occur from local pollution sources of several ten kilometres. In particular, strong acidity in dew, fog, and frost together with acid rain can accelerate a damage in ecosystems. Discussion is made on scientific analyses and seasonal variations of acidity of fog, dew and frost. A mechanism on acidification of fog, dew and frost is also discussed.

• 대한기계학회논문집A
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• 제24권7호
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• pp.1841-1846
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• 2000

To examine the effect of acid fog on the corrosion fatigue behavior in structural steel, fatigue tests under acid fog atmosphere were carried out in comparison with distilled water. The corrosive c omponents contained in acid fog pile up the corrosion products on crack face and show a crack branching and crack tip blunting. Therefore, due to these workings crack growth rate was reduced by decreasing the effective stress range in crack tip rather than under distilled water. Also the effect of sulfuric acid, which is the main component of acid fog, and testing speed on fatigue crack growth were examined. It was found that corrosion behavior was remarkably dependent upon pH and Hz rather than components of acid fog. According as pH and testing speed decrease below a specific value, crack growth was accelerated in comparison with distilled water. This reveals that due to liquid having strong acidity and slow speed of test the crack face dissolution was promoted, so crack closure was disturbed in the process of stress descent.

• 한국대기환경학회지
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• 제12권1호
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• pp.15-21
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• 1996

Daily measutements of visibility on 09 LST have been made at a rural site in Chong-won, Chong-book since 1991 to find out a possible influence of emissions of anthropogenic pollutants and water vapout in urban and rural environments. Daily visibility data collected over four-year period were compared with the available visibility and air quality data obtainde from other stations. Detailed examinations of our data showed that the frequency of fog occurrence (visibility .leq. 1 km) at a rural site (KNUE) was at least three times higher (77 days per year) than the frequency of fog both in Chong-ju city (19 days) and at the Air Force Base(AFB) in the rural area. We interpret that the higher frequency of fog at KNUE was due to abundant water vapour in the Mieho River (upstream of the Keum River) area. In Chong-ju city, fog usually continued for a relatively long duration, while it dissipated simewhat faster in the rural environment due to higher solar radiation in the countryside area. The number of misty (.leg. 6 km) days (including foggy days) at KNUE were 235 days as compared with 135 days at the AFB and 67 days in Chong-ju city. In turn the number of days with low visibility (less than 6 km) at KNUE was about 64% per year. Since the moisture alone in a calm morning does not produce a visibility impairment, there must had abundant condensation nuclei including anthropogenic air pollutants. Air pollution was examined, for instance, average values of TSP for November and December 1993 were 115 and 116.mu.g/m$^{3}$, respectively. We conclude that the above mentioned environmental conditions with moisture are favourable for the formation of fog and mist in the rural sampling site at KNUE. Additionally, we found at least 10 days of acid fog at KNUE in September 1994 alone. Measured pH values in the acid for water were in the range of 4.36 .sim. 5.01 with the mean value of 4.51 Our observations suggested that strikingly acid fog do occur occasionally even in the rural environment.

• 산업기술연구
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• 제17권
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• pp.291-295
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• 1997

The tests of stress corrosion cracking in structural carbon steel were carried out under the conditions of acid fog and general water. As the result of measurement SCC rupture time under acid fog was observed to be much shorter than that of general water at the same stress level. Therefore, acid fog drops the SCC strength in structural carbon steel due to strong corrosion. In the SCC process by acid fog, crack initiation was caused by pit corrosion and local stress concentration, and distinctive feature of crack growth shows branching since crack grows to the corrosion direction. Moreover, corrosion products were observed by clevage corrosion on the crack surfaces.

• Journal of Korean Society for Atmospheric Environment
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• 제17권E1호
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• pp.17-24
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• 2001

For the purpose of collecting fog droplets as a function of size a new sampling method was developed in this study. Formation of 100$\pm$10㎛ thickness of polymeric water absorbent film (PWAF) on a nuclepore filter could be successfully realized. Also applicability of particle induced X-ray emission (PIXE) method to the chemical analysis of size-segregated fog droplets collected on PWAF was examined experimentally with synthetic fog droplets generated from a nebulizer. Absorption capacity of S-PAAS polymeric water absorbent shows marked decreases in the range less than 1 wt% and slight decrease between 1 and 3.5 wt% of every salt concentration. Dependency of absorption capacity on pH shows the maximum at pH 7. No apparent peak which can influence the quantitative analysis of elements dissolved and suspended in fog droplets was found at PIXE spectrum of PWAF blank. PWAF kept the original shape without rupture under the PIXE analytical conditions of beam intensity for 10 to 60 nA and irradiation time of 4∼5 min. It should be said that the proposed new technique in the work is helpful to get more detailed information of fog droplets, to clarify the fog formation processes, and to develop a model of acid deposition process.

• 대한기계학회논문집A
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• 제26권2호
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• pp.374-379
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• 2002

Corrosion fatigue tests were carried out to clarify the influence of acid fog as environmental factor on the fatigue strength of SM55C using rotary bending fatigue tester. The fatigue strength of acid fog specimen extremely decreased about 80% compared to that of distilled water specimen. In acid fog environment, a number of cracks commenced at corrosion pit and coalesced with the adjacent cracks during they propagate, and they formed a single non-propagating circumferential crack under the endurance stress of N=5$\times$10$\^$7/ cycles. Also, the depth of the crack is smaller than that of normal fatigue crack, so the crack has a veil small aspect ratio. The reason of this peculiar crack growth characteristics is that the crack opening-closure behaviors are hindered by corrosion products on the surface crack faces, and hence it is thinkable that the strong corrosion action like anodic dissolution for crack growth in depth direction is weaker compared with surface, resulting from faint pumping action of crack during loading-shedding processes.

• 한국대기환경학회지
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• 제14권5호
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• pp.491-498
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• 1998

Fog water samples were collected at Chunchon, Korea, by using active fog sampler during foggy Period in fall of 1996 and 1997. The average annual foggy days at Chunchon increased from 37 days, for the yearn 1963 ∼ 1973, to 63 days , for the year 1974∼1993 that followed the construction of Lake Soyang. Volume weighted mean pH of fog water was 5.5 with a range of 4.8 to 7.0 in 1996, and 5.0 with a range of 4.1 to 6.6 in 1997. These pH values were higher than those of rain water sampled in corresponding years. However the concentration of ionic species in fog water were 26 times higher than those of rain water. The major anions in fog water were in order of SO42-, NO3- and Cl-, and their average concentrations were 1770.6meq/ml, 346.2 meq/ml, 216 meq/ml in 1996, and 901.8meq/ml, 269.6meq/ml, 141.0meq/ml in 1997, respectively. The major cations were Ca2+, NH4+, Mg2+ and K+, and their average concentrations frere 408.5meq/ml, 280.0meq/ml, 43.8meq/ml, 45.2meq/ml in 1996, and 400.4 meq/ml, 299.0meq/ml, 73.1meq/ml, 44.5meq/ml in 1997, respectively. The fraction acidity of fog water was 0.006 and that of rain water was 0.2, which means fog water was much more neutralized than rain water.