• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.876-885
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• 2018

Utilization of spent RHDM(Residue Hydrodemetallation) catalyst as de-NOx SCR(Selective Catalytic Reduction) catalyst was studied by conducting by heptane cleaning and high-temperature roasting for removal of deposited carbon and sulfur. Followed by oxalic acid leaching was carried out for controlling excess vanadium deposited on spent RHDM catalyst in search of appropriate vanadium loadings for the best SCR performance and the leaching conditions are 5~15wt% concentration of oxalic acid and 5min leaching time at $50^{\circ}C$ with the ultra-sonic agitator. De-NOx activities of prepared and commercial SCR catalyst were measured by the atmospheric SCR catalyst performance test unit, their residual content were also carried out by ICP, C&S Analysis and XRF. Acid leaching (AL-10) catalyst showed the highest de-NOx efficiency of all prepared catalysts and the de-NOx efficiency over wash coated catalyst(WC-AL-10) was equivalent to that of commercial SCR catalyst. Therefore the possibility of using as SCR catalyst for each application by adjusting treatment conditions of spent RHDM catalyst was found and further research will be needed in detail for the its commercialization.

• Mineral and Industry
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• v.25
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• pp.1-10
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• 2012

In this present work, the froth flotation of lithium ore from Boam mine located in Wooljin, Kyungbuk has been carried out to produce high-grade lithium concentrate. The sample ore-Lepidolite mainly contained silicate mineral (quartz, muscovite) and calcite. In consequences of the experiment, it has been possible to obtain relatively high-grade lithium while using anionic acid (oleic acid) to remove calcite before the froth flotation for lithium concentrate. Among the amines collectors (Armac-T, Armac-C, Armafloat-18, Armafloat-1597), Armac-T has been relatively effective than another ones. Under the optimum condition (collector : Armac-T 100g/t, frother : AF65 50g/t, depressants : $Na_2SiO_3$ 600g/t and Lactic acid 100g/t, pulp density : 20%, pH 5.5, number of cleaning : 2), it has been obtained relatively high-grade lithium concentrate ($Li_2O$) with recovery of 80.3% and with grade of 4.33%.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.4
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• pp.429-437
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• 2006

To establish the efficient treatment technology of chemical cleaning wastewater from power plant, several AOPs($UV/H_2O_2,\;UV/TiO_2/H_2O_2$, Photo-Fenton oxidation) were investigated. Treatment efficiencies and the electrical energy requirements based on the EE/O parameter(the electrical energy, required per order of pollutant removal in $1m^3$ wastewater) were evaluated. TOC removal efficiencies of $UV/H_2O_2,\;UV/TiO_2/H_2O_2$, Photo-Fenton oxidation at the optimum conditions were 95.5%, 92.3%, 91.5%, respectively. The electrical energy requirements of $UV/H_2O_2,\;UV/TiO_2/H_2O_2$, Photo-Fenton oxidation were $11.26kWh/m^3,\;3.85kWh/m^3,\;0.799kWh/m^3$, respectively. From these results, it could be concluded that all of the three oxidation processes were effective for the degradation of citric acid. Considering the treatment efficiency and economical aspect, photo-Fenton oxidation was the most efficient treatment process among the three processes tested.

• Journal of the Korean Society of Clothing and Textiles
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• v.23 no.6
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• pp.809-819
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• 1999

The scientific analysis of buried fabrics from the 16th century tomb of Kim HeumJo was conducted focusing on the conservation of fabrics, In order to find out the appropriate cleaning solvent and detergent for historical textiles physical chemical and biological analysis was conducted. The following results are obtained from this study : 1, The buried fabrics from the tomb of Kim HeumJo were composed of cotton silk and ramie. Most of fabrics had lost their original colors faded to brown. It was revealed variations in weaves and patterns were very developed at that times. 2. The chemical components of soils are hydrocarbons alkyl alcohols nitrogen compounds aromatic organic acid which is supposed to be from a human body microorganisms and their by-products. 3. Seven kinds of fungi Actinomycetes Corynebacterium spp Micrococcus luteus Bacillus Clostridium were isolated from the fabrics. The most common fungus was Bacillus.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.459-465
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• 2016

This study investigated reusability of costly guard column by ultrasonic. It also investigated various effects that affect to guard column generation by ultrasonic. When investigated 30 KHz of frequency, area of ascorbic acid is 73.0% compared to unused guard column. As a result of investigation of effect of pH, guard column by ultrasonic is effective at alkali area. As a result of investigation of solvent effect, when ethanol is used, generation rate is 81.9% as of peak area compared to the case of analysis in un used column. From the result, it indicates that regenerated guard by ultrasonic is reusable.

• Proceedings of the KWS Conference
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• 1999.10a
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• pp.297-298
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• 1999

Cemented carbides material (WC-Co hard alloy) were recognized very important and expensive tool or die assembly parts because of compose for the main elements of rare metal (W and Co etc). This research was developed to separate and recover of WC fine powder contained by WC-Co materials. Recycling process was a new method named by the Tin impregnation for decobaltification on cemented carbides. This reaction occurred to product a brittle Co-Sn intermetallic compounds, thereafter it carried out by acid cleaning solution and physical milling or powdering. New process was able to recover about 60％ WC fine powder from 1 to 5 ${\mu}{\textrm}{m}$.

• Economic and Environmental Geology
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• v.12 no.1
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• pp.13-15
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• 1979

Iron ore waste discarded around Choong-ju iron district, Choongchong-Bukdo is as low as 25 per cent of iron, mainly consisting of hematite and magnetite. In this mineral dressing test procedure 93 per cent of magnetite was separated and concentrated into the magnetite concentrate as high as 62 per cent. The remaining sample, mostly, hematite averages about 19.8 per cent of iron which can be concentrated with very good results with the optimum flotation conditioning-pH 3.0 and 3 cc per litre of aero-promoter #845 (0.5% sol.) and 1.5cc per litre of hydro-fluoric acid (40% sol.) and four times of cleaning flotation. Hematite concentrate averages 64.2 per cent of iron. The overall iron concentrate averages 63 per cent of iron with recovery 86 per cent of iron contained.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.380-380
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• 2011

ZnO nanorod (NR) arrays prepared via simple ammonia hydrothermal method exhibiting superhydrophilicity, high transmittance and antireflection. These properties result from the unique surface structure and material property of ZnO NR arrays. Highly rough surface due to ZnO NRs enhanced hydrophobicity/hydrophilicity of the films and short NRs (about 300 nm) made ZnO arrays transparent. ZnO NR films were chemically modified by dipping the sample into 5mM stearic acid/ethanol solution for 3 hours. Then the ZnO NRs became superhydrophobic surfaces, whose contact angle reached 159.2$^{\circ}$ maintaining their high transmittance. These biomimetic ZnO NR arrays can be used in diverse field, such as antifogging/self-cleaning surfaces and optical devices.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2013.05a
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• pp.117-118
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• 2013

증기발생기 화학세정 모사 장치를 이용하여 고농도 화학세정(EPRI/SGOG) 용액인 EDTA(20%)가 인위적으로 제작한 결합 시편에 미치는 영향 평가를 수행하였다. 평가 방법은 세정 전 후 표면 산화막 성분, ECT 분석값 비교, 증기발생기 구성 재료 부식률를 이용하였다. 화학세정 전후 부식률은 A508은 $8.023{\mu}m$, Alloy 600(HTMA)은 $0.007{\mu}m$이며 갈바닉 시편의 경우 $63.193{\mu}m$로 모두 부식 허용치 이내이다. 표면 산화막 성분 및 ECT 분석값 역시 변함이 없었다. 이와 같은 결과로 화학세정 용액인 EDTA는 결함 튜브에 미치는 영향이 없는 것으로 판단된다.

• Journal of Environmental Impact Assessment
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• v.9 no.1
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• pp.75-86
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• 2000

The purpose of this work was to document the conditions regarding organic solvent exposure to the workers in paint industry. Air concentrations of organic solvents were measured by passive personal samplers and analyzed by a gas chromatography. Urine samples for hippuric test were also taken from 330 workers who have worked at seven domestic factories for more than two years. Amongst 25 organic elements detected in the indoor environment of working places, toluene was the most common element, and methanol showed the highest mean concentration(18.2ppm). A few elements including methylethyl ketone and toluene partially exceeded the Korean Permissible Exposure Limit. A lack of environmental facilities such as exhaust ventilation, automatic cleaning system, and personal safety devices at present work plaus brings about various occupational diseases.