• Journal of the Korean Chemical Society
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• v.29 no.5
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• pp.465-471
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• 1985

The rate constants for the solvolysis of anthraquinone-2-carbonyl chloride in binary solvent mixtures, methanol-acetonitrile, methanol-acetone, ethanol-acetonitrile and ethanol-acetone, have been studied by means of conductometry. Maximum rate phenomena were observed at the methanol mole fraction, $X_{MeOH}$ = 0.73~0.81 for methanol-acetonitrile and at $X_{MeOH}$ = 0.83 for methanol-acetone mixtures. The Kivinen and Grunwald-Winstein plots indicated that the reaction proceeds via $S_N2$ type mechanism. Application of Taft's solvatochromic correlation on the solvolysis rate revealed that both $\alpha$ and ${\pi}^*$ are important for reactions in methanol-acetonitrile and methanol-acetone mixtures, while only ${\alpha}$ influences significantly on the rate in ethanol-acetonitrile and ethanol-acetone mixtures.

• Corrosion Science and Technology
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• v.23 no.2
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• pp.154-165
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• 2024

Acetic acid and acetonitrile produced in the chemical process of petrochemical plants are used at high temperatures and pressures. They are exposed to harsh corrosive environments. The present investigation aimed to evaluate corrosion characteristics of metals with excellent corrosion resistance by performing immersion and electrochemical experiments with different composition ratios of acetic acid and acetonitrile in a high-temperature and high-pressure environment. Results of immersion experiment revealed that as acetic acid concentration increased, surface damage and corrosion also increased. In immersion experiments under all conditions, super austenitic stainless steel (UNS N08367) had the best corrosion resistance among various metals. The maximum damage depth under the most severe immersion conditions was observed to be 4.19 ㎛, which was approximately 25.25 ㎛ smaller than that of highly damaged stainless steel (UNS S31804). As a result of electrochemical experiments, electrochemical characteristics of various metals presented some differences with different composition ratios of acetic acid and acetonitrile. However, super austenitic stainless steel (UNS N08367) had the best corrosion resistance at a high pressure condition with a high concentration of acetic acid.

• Journal of the Korea Institute of Military Science and Technology
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• v.5 no.3
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• pp.105-112
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• 2002

A combined process of non-thermal plasma and catalytic techniques has been investigated to treat toxic gas compounds in air. The treated gas in the present study is $CH_3$CN that has been known to be a simulant of toxic chemical agent. A planar type dielectric barrier discharge(DBD) reactor has been used to generate non-thermal plasma that produces various chemically active species, O, N, OH, $O_3$, ion, electrons, etc. Several different types of adsorbents and catalysts, which are MS 5A, MS 13X, Pt/alumina, are packed into the plasma reactor, and have been tested to save power consumption and to treat by-products. Various aspects of the present techniques, which are decomposition efficiencies along with the power consumption, by-product analysis, reaction pathways modified by the adsorbents and catalysts, have been discussed in the present study.

• Journal of the Korean Applied Science and Technology
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• v.11 no.1
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• pp.39-44
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• 1994

A Stability to the Spreading solvents, Which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene(1:1, v/v) of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex was investigated by UV-visible Spectrometer and was confirmed stabilized on acetonitrile, acetonitrilbenzene(1:1, v/v) for five hours. Using Ultra pure water as subphase for Langmuir-Blodgett (LB) Films, it was achived successively to fabricate the Y-type LB films of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex. For the identification of deposition of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex, UV-visible spectra was recorded on HP 8452A spectrometer.

• Journal of the Korean Chemical Society
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• v.16 no.3
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• pp.149-156
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• 1972

The responsive characteristics of hydrogen-responsive glass electrode in various buffer solutions of methanol, N,N-dimethylformamide and acetonitrile were examined. The potentials were attained more rapidly with an electrode stored in the same solvent medium than that stored in water before use. However, the time to be required for a stable potential increased with the basicity of buffer solution, and it was not provide a constant potential in the strong basic solution of these solvent. Even in acidic solution, the potential was varied according to the past usage of the electrode.

• Journal of Photoscience
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• v.12 no.3
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• pp.119-122
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• 2005

The photophysical properties of coumarin 6 laser dye have been studied in two solvents; ethanol and acetonitrile using steady-state fluorescence depolarization technique. The experimentally measured reorientation time of coumarin 6 is more or less the same in given solvents at particular temperature. It is found that coumarin 6 rotates slower in acetonitrile than in ethanol especially at higher values of viscosity over temperature. We also measure the ground and excited state dipole moments of coumarin 6 by solvent perturbation method. The results found that excited state dipole moment is greater than ground state dipole moment, which indicates that excited state is more polar than the ground state.

• Resources Recycling
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• v.8 no.3
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• pp.31-36
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• 1999

In the process of manufacturing acrylonitrile, azeotrope of water-acetonitrile is formed as by-product. To1uene-ethylacetate mixture was selected as solvent to determine the liquid-liquid equilibria for to1uene(l)-water(2)-acetomtrile(3)-ethyjacetate(4) system. The experimental he-line data were correlated with the UNIFAC model. The distribution and selectivity for quaternary system was also studied.

• Journal of the Korean Chemical Society
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• v.57 no.2
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• pp.210-215
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• 2013

Kinetics of oxidation of indole by peroxomonosulphate (PMS) in aqueous acetonitrile medium has been investigated. The reaction follows a total second order, first order each with respect to [Indole] and [PMS]. The rate of the reaction was not affected by added [$H^+$]. Variation of ionic strength (${\mu}$) had no influence on the rate. Increase of percentage of acetonitrile decreased the rate. Absen ce of any polymerization indicated a nonradical pathway. Activation and thermodynamic parameters have bee n computed. A suitable kinetic scheme based on these observations is proposed. The reactivity of PMS towards Indole was found to be higher than that with peroxodisulphate.

• Food Science of Animal Resources
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• v.21 no.1
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• pp.64-70
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• 2001

The extraction procedure and HPLC condition were modified to analyze the residues of oxytetracycline, sulfamethoxazole and chloramphenicol in pork, simultaneously. The antibacterial agents in pork were extracted with 0.02M EDTA-Mcilivine buffer:ethanol:acetonitrile (5:3:2). After the removal of fat with n-hexane, the extracts were evaporated and purified with Sep-pak $C_{18}$ cartridge column using 0.01M oxalic acid 0.1% (v/v) triethylamine (TEA) in acetonitrile. The peak of antibacterial agents was detected with $\mu$ Bondapak C18 column, UV detector (280nm) and 0.01M oxalic acid: methanol: acetonitrile (7.5:2.0:0.5). Detection limits for three antibacterial standards were 0.03 ppm. Calibration curves were linear between 0.03 and 2.0 ppm (R$^2$>0.999). When spiked the level of 1.0 ppm of oxytetracycline, sulfamethoxazole and chloramphenicol into meats, the recoveries from meats were 77.3%, 79.7% and 59.3%, respectively. These results showed that the modified extraction method provided good analytical resolution and the recoveries of the above antibacterial agents in meats.

• Archives of Pharmacal Research
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• v.15 no.2
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• pp.142-145
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• 1992

A novel preparative method for hexaprofen, which is a potent antiinflammatory agent, is described. Friedel-Crafts reaction of cyclohexylbenzene with ethyl $\alpha$-chloro-$\alpha$-(methylthio) acetate 1 and $\alpha$-chloro-$\alpha$-(methylthio) acetonitrile 2 afforded ethyl 2-(methylthio)-2-(4-cyclohexylphenyl) acetate 7 and 2-methylthio-2-(4-cyclohexylphenyl) acetonitrile 8, respectively. Compounds 7 and 8 were converted into the corresponding ethyl 2-methylthio-2-(4-cyclohexylphenyl) propionate 9 and 2-methylthio-2-(4-cyclohexylphenyl) propionitrile 10 by methylation with sodium hydride and methyl iodide. Hexaprofen 13 was prepard by hydrolysis of ethyl 2-(4-cyclohexylphenyl) propionate 11 and of 2-(4-cyclohexylphenyl) propionitrile 12 followed by desulfurization of compounds 9 and 10.