• 제목/요약/키워드: Accelerated Degradation

검색결과 514건 처리시간 0.034초

형광증백제가 종이 셀룰로오스의 화학적 열화특성에 미치는 영향 (Effects of Optical Brightening Agent on the Chemical Degradation Characteristics of Paper Cellulose)

  • 이재훈;최경화;조병욱
    • 펄프종이기술
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    • 제47권6호
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    • pp.66-72
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    • 2015
  • This study was conducted to investigate the effects of optical brightening agents (OBA) on the chemical degradation characteristics of paper cellulose during humid heating aging. Three different types of OBAs were applied to a filter paper by dipping it in OBA solutions whose concentrations were controlled to 1% and 2%. The filter papers with an OBA were artificially aged at $80^{\circ}C$ and 65% RH, and the changes in pH of paper and viscosity of cellulose were evaluated. Their functional groups were also analyzed by ATR-FTIR (at-tenuated total reflectance fourier transform infrared spectroscopy). It was found that OBAs influenced the chemical degradation of paper cellulose during humid heating aging. Higher concentration of OBA solutions accelerated the degradation of paper cellulose. Especially, after aging for 12 days, the paper cellulose treated with the tetra-type OBA were the most significantly aged among the three types of OBAs. It was assumed that pH of OBA solutions affected the aging characteristics.

빛이 홍화씨기름 산화 및 토코페롤 분해의 온도의존성에 미치는 영향 (Effects of Light on Temperature Dependence of Safflower Oil Oxidation and Tocopherol Degradation)

  • 왕선영;최은옥
    • 한국식품과학회지
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    • 제44권3호
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    • pp.287-292
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    • 2012
  • 홍화씨기름의 과산화물값과 공액이중산값은 빛의 존재와 상관없이 산화시간과 산화온도가 증가함에 따라 증가했으나, 동일한 온도에서는 빛의 존재 하에서 높은 과산화물값과 공액이중산값을 보여 빛은 홍화씨기름의 산화를 촉진시켰다. 빛은 홍화씨기름 산화 및 토코페롤 분해 속도의 온도의존성을 감소시켰으며, 따라서 산화온도는 광산화에서보다는 자동산화에서 더욱 중요한 인자로 작용했다.

고속 광통신 시스템용 비대칭 분포귀환형 레이져 다이오드의 신뢰성에 관한 연구 (Reliablity of Distributed Feedback Laser Diodes for High-speed Optical Communication Systems)

  • 전수창;주한성;윤일구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 춘계학술대회 논문집 디스플레이 광소자 분야
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    • pp.96-99
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    • 2005
  • As the demand of internet networks using backbone communication systems recently increased, the researches on the high-speed wideband optical communication systems are required. For high-speed optical communication systems, asymmetric sampled grating distributed feedback laser diodes (DFB-LDs) are developed and the reliability of DFB-LDs is examined. The reliability of DFB-LDs is performed by monitoring I-V and L-I characteristics and two degradation phenomena related to the electrical characteristics of LDs are observed during the life tests. The first degradation phenomenon by increasing the reverse current is considered as a formation of leakage current path enough to prevent lasing operation in lateral blocking layer near active region of lasers. The second degradation phenomenon by decreasing the forward current is considered as activation of non-radiative Auger recombination process by thermal energy and the second degradation phenomenon is recovered after the off-test period at room temperature Eventually, evaluating the reliability of DFB LDs can allow us to improved the manufacturability in high-volume manufacturing.

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Thermal Decomposition Behavior and Durability Evaluation of Thermotropic Liquid Crystalline Polymers

  • Shin, Sang-Mi;Kim, Seong-Hun;Song, Jun-Kwang
    • Macromolecular Research
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    • 제17권3호
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    • pp.149-155
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    • 2009
  • The thermal decomposition behavior and degradation characteristics off our different thermotropic liquid crystalline polymers (TLCPs) were studied. The thermal decomposition behavior was determined by means of thermogravimetric analysis (TGA) at different heating rates in nitrogen and air. The order of the thermal stability was as follows: multi-aromatic polyester > hydroxybenzoic acid (HBA)/hydroxynaphthoic acid (HNA) copolyester > HNA/hydroxyl acetaniline (HAA)/terephthalic acid (TA) copolyester > HBA/Poly(ethylene terephthalate) (PET) copolyester. The activation energies of the thermal degradation were calculated by four multiple heating rate methods: Flynn-Wall, Friedman, Kissinger, and Kim-Park. The Flynn-Wall and Kim-Park methods were the most suitable methods to calculate the activation energy. Samples were exposed to an accelerated degradation test (ADT), under fixed conditions of heat ($63{\pm}3^{\circ}C$), humidity ($30{\pm}4%$) and Xenon arc radiation ($1.10\;W/m^2$), and the changes in surface morphology and color difference with time were determined. The TLCPs decomposed, discolored and cracked upon exposure to ultraviolet radiation.

Experimental study on shear damage and lateral stiffness of transfer column in SRC-RC hybrid structure

  • Wu, Kai;Zhai, Jiangpeng;Xue, Jianyang;Xu, Fangyuan;Zhao, Hongtie
    • Computers and Concrete
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    • 제23권5호
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    • pp.335-349
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    • 2019
  • A low-cycle loading experiment of 16 transfer column specimens was conducted to study the influence of parameters, likes the extension length of shape steel, the ratio of shape steel, the axial compression ratio and the volumetric ratio of stirrups, on the shear distribution between steel and concrete, the concrete damage state and the degradation of lateral stiffness. Shear force of shape steel reacted at the core area of concrete section and led to tension effect which accelerated the damage of concrete. At the same time, the damage of concrete diminished its shear capacity and resulted in the shear enlargement of shape steel. The interplay between concrete damage and shear force of shape steel ultimately made for the failures of transfer columns. With the increase of extension length, the lateral stiffness first increases and then decreases, but the stiffness degradation gets faster; With the increase of steel ratio, the lateral stiffness remains the same, but the degradation gets faster; With the increase of the axial compression ratio, the lateral stiffness increases, and the degradation is more significant. Using more stirrups can effectively restrain the development of cracks and increase the lateral stiffness at the yielding point. Also, a formula for calculating the yielding lateral stiffness is obtained by a regression analysis of the test data.

태양광 모듈용 봉지재 종류에 따른 자외선 광열화 연구 (Research on Ultraviolet Light Degradation According to Types of Encapsulants for PV Modules)

  • 어승아;정낙현;김주휘;이찬용;이재형
    • Current Photovoltaic Research
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    • 제11권4호
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    • pp.108-113
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    • 2023
  • Pressure to reduce costs in the current solar market is driving the development and implementation of new module designs and prompting the use of new materials and components. In order to utilize the variability of each material that makes up the module, it is essential to understand the basic characteristics of the material. In this article, we evaluate light degradation after UV irradiation as an encapsulation material. Measure and analyze the results of various characteristic tests for discoloration, optical and electrical property degradation before and after UV accelerated testing. To evaluate weathering stability, UV tests were performed comparing existing EVA and UVT-EVA, POE and improved low-cost POE. Even in the weather resistance test with a total UV exposure of 60 kW/m2, the properties of the encapsulants were mostly stable. EVA and POE-based encapsulants showed slight differences, and these slight differences are believed to pose a threat to long-term stability. This study is a basic analysis of encapsulation research for PV modules and will be helpful in understanding future development and encapsulant properties.

Simvastatin Reduces Lipopolysaccharides-Accelerated Cerebral Ischemic Injury via Inhibition of Nuclear Factor-kappa B Activity

  • Jalin, Angela M.A. Anthony;Lee, Jae-Chul;Cho, Geum-Sil;Kim, Chunsook;Ju, Chung;Pahk, Kisoo;Song, Hwa Young;Kim, Won-Ki
    • Biomolecules & Therapeutics
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    • 제23권6호
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    • pp.531-538
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    • 2015
  • Preceding infection or inflammation such as bacterial meningitis has been associated with poor outcomes after stroke. Previously, we reported that intracorpus callosum microinjection of lipopolysaccharides (LPS) strongly accelerated the ischemia/reperfusionevoked brain tissue damage via recruiting inflammatory cells into the ischemic lesion. Simvastatin, 3-hydroxy-3-methylgultaryl (HMG)-CoA reductase inhibitor, has been shown to reduce inflammatory responses in vascular diseases. Thus, we investigated whether simvastatin could reduce the LPS-accelerated ischemic injury. Simvastatin (20 mg/kg) was orally administered to rats prior to cerebral ischemic insults (4 times at 72, 48, 25, and 1-h pre-ischemia). LPS was microinjected into rat corpus callosum 1 day before the ischemic injury. Treatment of simvastatin reduced the LPS-accelerated infarct size by 73%, and decreased the ischemia/reperfusion-induced expressions of pro-inflammatory mediators such as iNOS, COX-2 and IL-$1{\beta}$ in LPS-injected rat brains. However, simvastatin did not reduce the infiltration of microglial/macrophageal cells into the LPS-pretreated brain lesion. In vitro migration assay also showed that simvastatin did not inhibit the monocyte chemoattractant protein-1-evoked migration of microglial/macrophageal cells. Instead, simvastatin inhibited the nuclear translocation of NF-${\kappa}B$, a key signaling event in expressions of various proinflammatory mediators, by decreasing the degradation of $I{\kappa}B$. The present results indicate that simvastatin may be beneficial particularly to the accelerated cerebral ischemic injury under inflammatory or infectious conditions.

산업용 청소기 모터의 가속수명시험 (Accelerated Life Test of Industrial Cleaner Motor)

  • 엄학용;이기천;장무성;박종원;이용범
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제18권3호
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    • pp.193-200
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    • 2018
  • Purpose: In this study, the life of the motor is investigated by performing the accelerated life test with the brush wear of the industrial cleaner motor as the main failure mode. Methods: The accelerating stress factor of the accelerated life test is a voltage, which can increase the number of revolutions of the motor to accelerate the brush wear due to the friction between the brush and the commutator. Also, the accelerating stress level was determined after determining the maximum allowable level of the voltage through the preliminary test. Results: The motor failure time at each accelerating stress level was predicted by regression analysis with brush wear length as performance degradation data. The main failure mode, which is brush wear, of the motor was reproduced by this test. The shape parameter of the Weibull distribution was confirmed to be the same statistically at all accelerating stress levels by the likelihood ratio test. Conclusion: The life of the motor was investigated by performing the accelerated life test with the brush wear of the industrial cleaner motor as the main failure mode. Through the accelerating test method of the cleaner motor, various life expectancy and life expectancy of the acceleration factor are predicted.

종이 기록물의 대기 중 유해물질에 의한 가속 열화 특성 연구 (Study on Accelerated Aging Characteristics of Paper-Records by Air Pollutants)

  • 박미선;정소윤;황지현;김형진;김신도
    • 펄프종이기술
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    • 제46권4호
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    • pp.76-84
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    • 2014
  • Preventive conservation is one of most important issues in the field of conservation for paper-records. Many researchers have been studied environmental factors such as effects of humidity, temperature, biological attack and air pollutants. Air pollutants strongly associated with oxidative and hydrolytic degradation of cellulose. It is important to control air pollutants in storage environment to improve stabilities of conservation environment. Four paper samples have been analyzed for their accelerated aging characteristics by air pollutants, sulfur dioxide, nitrogen dioxide, ozone, carbon monoxide. Physical and optical properties and weight molar masses(Mw) showed that interactions between air pollutants and paper sample. Nitrogen dioxide, ozone caused severe damage to cellulose in paper by hydrolytic and oxidative decompositions during aging.

보강용 지오신세틱스의 가속 인장 크리프 시험방법 (Accelerated Tensile Creep Test Method of Geosynthetics for Soil Reinforcement)

  • 구현진;조항원
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.196-203
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    • 2008
  • Durability of geosynthetics for soil reinforcement is accounted for creep and creep rupture, installation damage and weathering, chemical and biological degradation. Among these, the long-term creep properties have been considered as the most important factors which are directly related to the failure of geosynthetic-reinforced soil(GRS). However, the creep test methods and strain limits are too various to compare the test results with each other. The most widely used test methods are conventional creep test, time-temperature superposition and stepped isothermal method as accelerated creep tests. Recently developed design guidelines recommend that creep-rupture curve be used to determine the creep reduction factor($RF_{CR}$) which is a conservative approach. In this study, the different creep test methods were compared and the creep reduction factors were estimated at different creep strain limits of 10% of total creep strain and creep rupture. In order to minimize the impact of creep strain to the GRS structures, the various creep reduction factors using different creep test methods should be investigated and then the most appropriated one should be selected for incorporating into the design.

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