• Title/Summary/Keyword: Absorption wavelength

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A Study on the Mechanical Properties of Joints in Laser Transmission Joining of Polymers (폴리머의 레이저 투과접합 시 접합부의 기계적 성질에 관한 연구)

  • Cha, Sang-Woo;Kim, Jin-Beom;Yoon, Suk-Hwan;Na, Suck-Joo
    • Journal of Welding and Joining
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    • v.25 no.2
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    • pp.43-48
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    • 2007
  • Laser Transmission Joining (LTJ) of plastics is a process in which light of suitable wavelength is transmitted through a transparent substrate that is in contact with an absorbing one. In this paper, LTJ is investigated by preliminary experiments from the viewpoint of mechanical engineering. To understand transmitting characteristics of each polymer substrate, transmission rate, reflection rate and absorption coefficient of polymer are measured by using a laser power-meter. Characteristics of joining in the spot welding and seam welding are investigated by measuring the fracture load. Fracture load increases in accordance to the laser power and irradiation time. However, when the laser power is over 60W and irradiation time over 4seconds, fracture load decreases. This phenomenon is probably due to heat-softening of materials. Besides, cavities are generated at a joint by evaporation of water molecules, which can be suppressed by introduction of a gap between two substrates.

Simultaneous HPLC Analysis of Arachidonic Acid Metabolites in Biological Samples with Simple Solid Phase Extraction

  • Kim, Hyung-Gun;Huh, Young-Na;Park, Kun-Suk
    • The Korean Journal of Physiology and Pharmacology
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    • v.2 no.6
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    • pp.779-786
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    • 1998
  • A reversed-phase high-performance liquid chromatogrphy (RP-HPLC) has been developed to analyze the metabolites of arachidonic acid based on the specificities of ultraviolet absorption of these various metabolites and is sensitive to the nanogram level. This procedure makes it possible to extract complex mixtures of eicosanoids efficiently with a single step and to analyze them simultaneously by RP-HPLC from biological samples using octadesylsilyl silica extraction column and $PGB_2$ as an internal standard. The cyclooxygenase products {prostaglandin $(PG)D_2,\;PGE_1,\;PGE_2,\;PGF_{1{\alpha}},\;PGF{2{\alpha}},\;6-keto-PGF_{1{\alpha}},$ and thromboxane $B_2(TXB_2)}$ and lipid peroxidation product, isoprostanes, of arachidonic acid were monitored by one isocratic HPLC system at 195 nm wavelength. The lipoxygenase products ${leukotriene(LT)B_4,\;LTC_4,\;LTD_4,$ and 5-hydroxyeicosatetraenoic acid (5-HETE), 12-HETE, 15-HETE} were measured by another isocratic HPLC system at 280 nm for LTs and 235 nm for HETEs. This method provides a simple and reliable way to extract and assess quantitatively the final arachidonic acid metabolites.

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Properties and Crystallization Characteristics of Ge-Se-Te Glasses (Ge-Se-Te계 칼코지나이드 유리의 결정 생성 현상 및 특성)

  • Lee, Yong-Woo;Heo, Jong
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.239-247
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    • 1995
  • Chalcogenide glasses with compositions of Ge10Se90-xTex(X=0~50 at.%) were prepared in order to investigate the effects of Te substitution on the transmission characteristics of Ge-Se glasses in the 8~12 ${\mu}{\textrm}{m}$ wavelength region. Absorption coefficients were observed to decrease with Te addition, indicating the improved transmission capabilities of Ge-Se-Te glasses as compared to binary Ge-Se glasses. XRD analysis of crystallized glasses suggested the formation of weaker Se-Te and/or Te-Te bonds with addition of Te substituting for Se in stronger Se-Se bonds. Incorporation of Te in excess of 20at% resulted in the formation of hexagonal Te phases when crystallized. It is speculated that the presence of Te-Te bonds with highly metallic bond character resulted in the enhanced crystallization tendencies of glasses. Fromation of Te-rich chains through gradual replacement of Se-Se with Se-Te and/or Te-Te bonds was further supported by decreases in glass transition and crystallization temperatures.

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Photoelectron Imaging Spectroscopy for (2+1) Resonance-Enhanced Multiphoton Ionization of Atomic Bromine

  • Kim, Yong-Shin;Jung, Young-Jae;Kang, Wee-Kyung;Jung, Kyung-Hoon
    • Bulletin of the Korean Chemical Society
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    • v.23 no.2
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    • pp.189-194
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    • 2002
  • Two-photon resonant third photon ionization of atomic bromine $(4p^5\;^2P_{3/2}\;and\;^2P_{1/2})$ has been studied using a photoelectron imaging spectroscopy in the wavelength region 250 - 278 nm. The technique has yielded simultaneously both relative branching ratios to the three levels of $Br^+(^3P_2,\;^3P_{0.1}\;and^1D_2)$ with $4p^4$ configuration and the angular distributions of outgoing photoelectrons. The product branching ratios reveal a strong propensity to populate particular levels in many cases. Several pathways have been documented for selective formation of $Br^+(^3P_2)$ and $Br^+(^3P_{0.1})$ ions. In general, the final ion level distributions are dominated by the preservation of the ion core configuration of a resonant excited state. Some deviations from this simple picture are discussed in terms of the configuration interaction of resonant states and the autoionization in the continuum. The photoelectron angular distributions are qualitatively similar for all transitions, with a positive $A_2$ anisotropy coefficient of 1.0-2.0 and negligible $A_4$ in most cases, which suggests that the angular distribution is mainly determined by the single-photon ionization process of a resonant excited state induced from the third photon absorption.

Crystal growth and optical properties with preheating temperature of sol-gel derived ZnO thin films

  • Kim, Young-Sung;Lee, Choong-Sun;Kim, Ik-Joo;Ko, Hyung-Duk;Tai, Weon-Pil;Song, Yong-Jin;Suh, Su-Jeung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.5
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    • pp.187-192
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    • 2004
  • We try to use isopropanol which has low boiling point to prepare ZnO thin films at low temperature. ZnO thin films were prepared by sol-gel spin-coating method using zinc acetate dehydrate-isopropanol-monoethanolamine (MEA) solution. The c-axis preferred orientation and optical properties of ZnO films with preheating temperature have been investigated. ZnO thin films were preheated at 200 to $300^{\circ}C$ with an interval of $25^{\circ}C$ and post-heated at $650^{\circ}C$. The ZnO film preheated at $275^{\circ}C$ and post-heated at $650^{\circ}C$ was highly oriented along c-axis (002) plane, and the surface with homogeneous and dense microstructures was formed having nano-sized grains. The optical transmittance was above 90 % in the visible range and exhibited absorption edges at 368 nm wavelength.

Inter-Domain Signal Transmission within the Phytochromes

  • Song, Pill-Soon
    • BMB Reports
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    • v.32 no.3
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    • pp.215-225
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    • 1999
  • Phytochromes (with gene family members phyA, B, C, D, and E) are a wavelength-dependent light sensor or switch for gene regulation that underscore a number of photo responsive developmental and morphogenic processes in plants. Recently, phytochrome-like pigment proteins have also been discovered in prokaryotes, possibly functioning as an auto-phosphorylating/phosphate-relaying two-component signaling system (Yeh et al., 1997). Phytochromes are photochromically convertible between the light sensing Pr and regulatory active Pfr forms. Red light converts Pr to Pfr, the latter having a "switch-on" conformation. The Pfr form triggers signal transduction pathways to the downstream responses including the expression of photosynthetic and other growth-regulating genes. The components involved in and the molecular mechanisms of the light signal transduction pathways are largely unknown, although G-proteins, protein kinases, and secondary messengers such as $Ca^{2+}$ ions and cGMP are implicated. The 124-127 kDa phytochromes form homodimeric structures. The N-terminal half contains the tetrapyrrolic phytochromobilin for red/far-red light absorption. The C-terminal half includes both a dimerization motif and regulatory box where the red light signal perceived by the chromophore-domain is recognized and transduced to initiate the signal transduction cascade. A working model for the inter-domain signal communication within the phytochrome molecule is proposed in this Review.

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The Physicochemical Stabilities and Antimicrobial Activities of Pigment Extracts from Zooshikella sp. 17TA (Zooshikella sp. 17TA 색소 추출물의 물리화학적 안정성과 항균활성)

  • Park, Jae-Myeong;Park, Jin-Sook
    • Journal of Marine Bioscience and Biotechnology
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    • v.11 no.2
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    • pp.89-93
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    • 2019
  • In this study, the stability of the extracted natural pigments against light, temperature, pH, metal ions, and antimicrobial activity were evaluated in marine bacteria Zooshikella sp. 17TA. The pigment of the strain used in the study was red with maximum absorption at a wavelength of 541 nm. The stability of the pigment was evaluated by measuring the absorbance while preserving for 15 days and examining the retention rate. After 15 days of irradiation, the pigment of this bacterium showed 98% retention in the dark and 91% retention in the temperature range of -20℃ ~ 30℃. When the pH was in the range 4-7, the retention was about 80%, and the retention rate was higher than 85% for all kinds of metal ions except for CuCl2, ZnCl2, and KCl. The bacterial pigments showed high stability under the given irradiated pH, temperature, and metal ion conditions and had shown activity against gram-positive strains. These results suggest that this highly conserved microbial pigment can be applied to the food industry.

Development of a Multi - channel Detector for Capillary Electrophoresis System (모세관 전기영동 장치용 Photodiode Array 다채널 검출기의 개발에 관한 연구)

  • Hong, Seung Guk;Kim, Hai-Dong
    • Analytical Science and Technology
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    • v.11 no.2
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    • pp.96-104
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    • 1998
  • A photodiode array multichannel detector system for capillary electrophoresis was developed. The photodiode array detector for capillary electrophoresis (CE-PDA) has 1024 photodetectors and can analyze sample by measuring UV/VIS absorption spectrum in 275~675 nm wavelength range. The CE-PDA instrument can get a spectrum in 30 ms during sample separation and can be programmed by a PC to control various experimental conditions required for sample analysis. The performance of the multichannel CE-PDA instrument was tested using L-ascorbic acid and alizarin yellow GG mixture. The reproducibility test of the CE-PDA system showed 5.6% RSD.

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UV Sensor using Evanescent Field Coupling of Prism and Fiber-to-Planar Waveguide Coupler (프리즘과 광섬유-평면도파로의 소산장 결합을 이용한 자외선 센서)

  • Cho, Kang-Min;Yun, Jung-Hyun;Kim, Eung-Soo;Lee, Seung-Ha;Kang, Shin-Won
    • Journal of Sensor Science and Technology
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    • v.13 no.5
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    • pp.350-355
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    • 2004
  • A novel UV sensor was manufactured and characterized using the evanescentfield coupling between fiber-planar waveguide (PWG) coupler and prism. A spiroxazine dye was chosen as planar waveguide because its photochromic isomerization induced by UV irradiation. A novel UV sensor was proposed to measure the variation of refractive index and absorption coefficient simultaneously. The wavelength responses of these sensors by UV exposure times were measured 0.48 nm/sec, 0.757 nm/sec, and ATR output power variations were measured $-0.424{\mu}W$/sec and $-0.62{\mu}W$/sec when UV exposure power were 3 mW and 5 mW, respectively.

APPLICATION OF A MULTI-WAVELENGTH NIR DIODE LASER ARRAY FOR NON-DESTRUCTIVE FOOD ANALYSIS

  • Tauscher, Bernhard;Butz, Peter;Lindauer, Ralf
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.3123-3123
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    • 2001
  • Near infrared (NIR) spectroscopy has become a widely used method in food and beverage analysis because of its speed, accuracy and the simplicity of sample preparation. One of the basic requirements of NIR instruments is a wide dynamic range if weak, or small, absorption changes or concentrations are to be measured. Thus the instrument must be sufficiently luminous, and efficient, to enable measurements to be made in a reasonably short time, as for some applications (e.g. sorting) short response times are essential. Diode lasers function the same way as lasers but linewidths are not as narrow as typical lasers. In this work an array of seven laser diodes (in the range of 750-1100 nm) with energy outputs of around hundred milliwatts each were combined with a fast diode array spectrometer (400-1100 nm, 1024 pixels, integration time from 3 ms) as detector. Measurements in transmission mode were performed in solutions of sugars in aqueous solutions and in deuteriumoxide. The feasibility of non-destructive measurements in transmission mode was investigated for different fruits and vegetables.

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