• Title/Summary/Keyword: Absorption wavelength

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Dyeing Property and Antimicrobial activity of Protein Fiber Using Terminalia chebula Retzius Extract (가자열매 추출물을 이용한 단백질 섬유의 염색과 항균효과)

  • Nam, Ki Yeon;Lee, Jung Soon
    • Fashion & Textile Research Journal
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    • v.16 no.3
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    • pp.476-484
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    • 2014
  • The purpose of this study was to investigate the dyeing properties and anti-microbial ability of silk and wool fabrics dyed with Terminalia chebula Retzius(TCR) extract using two extraction solvent, hot water and methanol. Dyeing properties of fabrics were studied by investigating the characteristics of colorant, changes in dye uptake under different dyeing conditions, and by investigating color change when mordants were applied. Also, color fastness, and antimicrobial activity of dyed fabrics were estimated. Regardless of extraction solvent type, colorant showed maximum absorption wavelength at 280 nm and 578 nm, which implied that tannin was the major pigment component of TCR. Also, through FT-IR spectrum result, it was confirmed that tannin of TCR methanol extract was hydrolysable tannin. But for the hot water extract, it was only assumed that its tannin was condenced tannin. Fabric dyed with hot water solvent extract showed higher dye uptake than fabric dyed with methanol solvent extract, dye uptake increasing by higher concentration of the dye, longer dyeing time and higher dyeing temperature. And the absorption curve between TCR extract and protein fiber was shaped in the form of Langmuir adsorption isotherm. Fabric dyed without mordant was yellow in color, and when dyed with mordant, fabric showed various colors depending on mordant types except Sn. Color fastness to washing was generally fine and color fastness to light was moderate. But color fastness to rubbing and dry cleaning was outstanding. Lastly, dyed fabrics showed very good antimicrobial activity of 99.9% against Staphylococcus aureus and Kiebsiella pneumoniae.

Development of Concurrent Multi Path (CMP)-Differential Optical Absorption Spectroscopy (DOAS) for Remote Sensing of Surface Atmospheric Gases (지표면 대기중 가스상오염물질 다경로 동시 원격 모니터링을 위한 CMP-DOAS 개발: 첫 개발 사례 및 이산화질소 측정 연구)

  • Lee, Han-Lim;Hwang, Jung-Bae;Kim, Jhoon;Noh, Young-Min;Won, Yong-Kwan
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.4
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    • pp.412-419
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    • 2010
  • Concurrent Multi Path-Differential Optical Absorption Spectroscopy (CMP-DOAS) is a novel active optical system to measure simultaneously ambient trace gases (such as $NO_2$, $SO_2$, $O_3$, and HCHO) present on several light paths. The CMP-DOAS system consists of a 2D CCD camera, spectrometer, receiving telescopes, and artificial light sources. The system receives spectra, which have been transported through several paths. It also covers wavelength ranges of which trace gases of interest share at the same time. This study presents the instrumental setup of a CMP-DOAS in detail. A field campaign for a comparative measurement was carried out at an urban site in Gwangju for a month on January 2009. $NO_2$ mixing ratios measured by the CMP-DOAS system and in-situ $NO_2$ analyzers were in good agreement by 83%. It demonstrates the high capacities of the CMP-DOAS technique to cover atmospheric trace gases dispersed across wide light paths.

STUDY ON THE DEVELOPMENT OF $a_{dom}$ ESTIMATION ALGORITHM BY EMPIRICAL METHOD FOR GOCI OCEAN COLOR SENSOR

  • Moon, Jeong-Eon;Ahn, Yu-Hwan;Ryu, Joo-Hyung;Choi, Joong-Ki
    • Proceedings of the KSRS Conference
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    • 2007.10a
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    • pp.49-52
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    • 2007
  • This study uses empirical method to estimate absorption coefficient of colored dissolved organic matter $(a_{dom})$ from GOCI satellite data with the relationship between band ratio of remote sensing reflectance $(R_{rs})$ and $a_{dom}$. For development of $a_{dom}$ estimation algorithm, the used data is in-situ data about ocean optical properties in the around seawater area of the Korean Peninsula during 1998 - 2005. The relationship of $R_{rs}$(412)/$R_{rs}$(555), $R_{rs}$(443)/$R_{rs}$(555), $R_{rs}$(490)/$R_{rs}$(555), $R_{rs}$(510)/$R_{rs}$(555) and $a_{dom}$(412) showed $R^2$ values of 0.707, 0.707, 0.597 and 0.552, respectively. The spectrum of $a_{dom}({\lambda})$ is shape of exponential function $a_{dom}({\lambda})$ value decreases with increasing wavelength. For estimation of $a_{dom}$ from satellite data, we developed an algorithm from the relationship of $a_{dom}$(412) and $R_{rs}$(412)/$R_{rs}$(555). This algorithm was employed on SeaWiFS imagery to estimate $R_{rs}$(412) in the South Sea, East Sea, Yellow Sea and northern East China Sea areas. Also, SeaDAS-derived $a_{dg}$(412) from same SeaWiFS imagery, These $a_{dg}$(412) was then compared with in-situ and empirical-algorithm-derived $a_{dom}$(412), but these values were different. We think two points that such different values are caused by discrepancy related to failure of standard atmospheric correction scheme, the other are caused by error related to definition of $a_{dom}$(412) and $a_{dg}$(412).

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Detection technique of Red Tide Using GOCI Level 2 Data (GOCI Level 2 Data를 이용한 적조탐지 기법 연구)

  • Bak, Su-Ho;Kim, Heung-Min;Hwang, Do-Hyun;Yoon, Hong-Joo;Seo, Won-Chan
    • Korean Journal of Remote Sensing
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    • v.32 no.6
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    • pp.673-679
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    • 2016
  • This study propose a new method to detect Cochlodinium polykrikoides red tide occurring in South Sea of Korea using Water-leaving Radiance data and Absorption Coefficients data of Geostationary Ocean Color Imager (GOCI). C. polykrikoides were analyzed and the irradiance and light emission characteristics of the wavelength range from 412 nm to 555 nm were confirmed. The detection technique proposed in this study detects the red tide occurring in the optically complex South Sea. Based on these results, it can be used for future red tide prevention.

The Structural and Optical Properties of GaAs- SiO2 Composite Thin Films With Varying GaAs Nano-particle Size (GaAs 나노입자 크기에 따른 SiO2 혼합박막의 구조적 광학적 특성)

  • Lee, Seong-Hun;Kim, Won-Mok;Sin, Dong-Uk;Jo, Seong-Hun;Jeong, Byeong-Gi;Lee, Taek-Seong;Lee, Gyeong-Seok
    • Korean Journal of Materials Research
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    • v.12 no.4
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    • pp.296-303
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    • 2002
  • For potential application to quantum mechanical devices, nano-composite thin films, consisting of GaAs quantum dots dispersed in SiO$_2$ glass matrix, were fabricated and studied in terms of structural, chemical, and optical properties. In order to form crystalline GaAs quantum dots at room temperature, uniformly dispersed in $SiO_2$matrix, the composite films were made to consist of alternating layers of GaAs and $SiO_2$in the manner of a superlattice using RF magnetron sputter deposition. Among different film samples, nominal thickness of an individual GaAs layer was varied with a total GaAs volume fraction fixed. From images of High Resolution Transmission Electron Microscopy (HRTEM), the formation of GaAs quantum dots on SiO$_2$was shown to depend on GaAs nominal thickness. GaAs deposits were crystalline and GaAs compound-like chemically according to HRTEM and XPS analysis, respectively. From measurement of optical absorbance using a spectrophotometer, absorption edges were determined and compared among composite films of varying GaAs nominal thicknesses. A progressively larger shift of absorption edge was noticed toward a blue wavelength with decreasing GaAs nominal thickness, i.e. quantum dots size. Band gaps of the composite films were also determined from Tauc plots as well as from PL measurements, displaying a linear decrease with increasing GaAs nominal thickness.

Dyeability and Functionality of Pine Needles Extract (part I) -Characteristics of Pine Needles Extract and Dyeing Properties of Cellulose Fiber- (솔잎 추출물의 염색성과 기능성 (제1보) -솔잎 추출물의 특성과 셀룰로오스섬유에 대한 염색성-)

  • Woo, Hyo-Jung;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.2
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    • pp.218-229
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    • 2011
  • Dyeing properties of cotton and ramie fabrics with pine needles colorants were studied by investigating the analysis of pine needles colorants, the effect of dyeing conditions (such as dye concentration, dyeing temperatures and times on dye uptakes), effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use; in addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of the maximum absorption for pine needles extract was 285nm, and pine needles colorants produced a yellow color. From FT-IR and GC-MS results, it was assumed that chromophoric substance from pine needles extracts were mixed with flavonol tannin and flavanol tannin. An increased dyeing concentration resulted in a larger dye uptake and a Freundlich absorption isotherm was obtained. A larger dye uptake occurred as the dyeing time and temperature increased. Post-mordanting was more effective than pre-mordanting and the dye uptake of fabrics improved by mordanting. The colorfastness of dyed fabrics showed a low rating; however, colorfastness to washing and dry cleaning of cotton fabrics mordanted with N.Cu, and friction fastness of ramie fabric mordanted with Cu improved. The dyed fabrics showed very good antimicrobial abilities of 99.9%. In addition, the ultraviolet-cut ability and deodorant ability improved in fabrics dyed with pine needles extracts.

Dyeability and Functionality of Bamboo Extracts (Part I) -Characteristics of Bamboo Extracts and Dyeing Properties of Cotton- (대나무 추출물의 염색성과 기능성 (제1보) -대나무 추출물의 특성과 면직물에 대한 염색성-)

  • Jung, Go-Eun;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.2
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    • pp.206-217
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    • 2011
  • The dyeing properties of cotton fabrics with bamboo colorants were studied by investigating the analysis of bamboo colorants, the effect of dyeing conditions (dye concentrations, dyeing temperatures and times on dye uptakes), effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use; in addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were also estimated. In the UV-Visible spectrum, the wavelength of the maximum absorption for bamboo stems and leaves extracts was found to be 280nm and 295nm, respectively; in addition, bamboo colorants produced a yellow color. From the FT-IR and GC-MS results, it was assumed that the chromophoric substance from bamboo extracts was composed of flavones substances with tricin. An increased dyeing concentration resulted in a larger dye uptake and a Freundlich absorption isotherm was obtained. A larger dye uptake occurred as the dyeing time and temperature increased. The post-mordanting was more effective than pre-mordanting. Mordants, Fe and N.Fe, were effective for an increased dye uptake. The color of fabrics mordanted with Cu and N.Cu changed to GY. Regardless of mordanting, the colorfastness on the washing of dyed fabrics showed a low rating compared to other fastness. Mordanting adversely affected the lightfastness of dyed fabric. The dyed fabric showed very good antimicrobial abilities of 99.9%. In addition, the ultraviolet-cut ability and deodorant ability improved in cotton fabric dyed with bamboo extracts.

Preparation and characterization of g-C3N4/NaTaO3 composite and their photocatalytic activity under simulated solar light (g-C3N4/NaTaO3 복합체의 제조 및 태양광 조사 하에서의 광촉매 특성 평가)

  • Park, Ji-Su;Kim, Tae-Ho;Jo, Yong-Hyeon;Lee, Su-Wan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.264-265
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    • 2014
  • This Paper reports the photocatalytic activity of $g-C_3N_4/NaTaO_3$ hybrid composite photocatalysts synthesized by ball-mill method. The $g-C_3N_4$ and $NaTaO_3$ were individually prepared by Solid state reaction and microwave hydrothermal process, respectively. The $g-C_3N_4/NaTaO_3$ composite showed the enhanced photocatalytic activity for degradation of rhodamine B dye (Rh. B) under simulated solar light irradiation. The results revealed that the band-gap energy absorption edge of hybrid composite samples was shifted to a longer wavelength as compared to $NaTaO_3$ and the 50 wt% $g-C_3N_4/NaTaO_3$ hybrid composite exhibited the highest percentage (99.6 %) of degradation of Rh. B and the highest reaction rate constant ($0.013min^{-1}$) in 4 h which could be attributed to the enhanced absorption of the hybrid composite photocatalyst in the UV-Vis region. Hence, these results suggest that the $g-C_3N_4/NaTaO_3$ hybrid composite exhibits enhanced photocatalytic activity for the degradation of rhodamine B under simulated solar light irradiation in comparison to the commercial $NaTaO_3$.

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Study on the properties of temperature distribution at the split-disk geometry glass laser amplifier (분할디스크형 글라스레이저 증폭기의 온도분포특성에 관한 연구)

  • 김병태
    • Korean Journal of Optics and Photonics
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    • v.3 no.4
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    • pp.227-233
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    • 1992
  • The simulation code was developed for the development of the split-disk geometry glass amplifier, which could design the laser apparatus and analyze the properties of the laser system. The flashlamp emission energy at the short wavelength region must be reduced, while maintaining a current density between 2000 and 4000 A/$\textrm{cm}^{2}$, in order to reduce the thermal loading in the laser glass and to raise the coupling efficiency between the emission spectrum of the flashlamps and the absorption spectrum of the laser glass. By cutting the laser glass into three equal pieces, the temperature rise in the laser glass dropped by 70% due to the efficient removal of the heat in the laser glass. It was found that the $Nd^{3+}$ doping rate of each laser glass should be properly selected and the optimum value of the product of the absorption coefficient $\alpha$ and the thickness d of the laser glass is about 0.26 in the split-disk geometry.

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A Study on the Development of Electrophotographic Photoreceptor by Dye Sinsitized System (색소증감계를 이용한 전자사진 감광체개발에 관한 연구)

  • Jeong, Eun-Sil;Kim, Yeong-Sun;Jeong, Pyeong-Jin
    • Korean Journal of Materials Research
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    • v.3 no.5
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    • pp.505-513
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    • 1993
  • To make the electrophotographic photoreceptor that srnsirizes for panchromatic matcrial, the dying element of sunfasr yellow which has an absorption ivavclength at near 400nm, and $\alpha,\beta$-copper phthalocyaninc dying elements with 700nm absorption wavelength were adsorbed and then dispersed onto the zine oxide(Zn0). In ordcr to characterize rhe change In sensitivity the various binders and different mole ratio of ZnO to binder were employed in here. It was found rhat the optimum sensitivity was obtained with 5.5 ratio. I;rom the measurements of electrostatic and spectral sensitivity, it was found that the maximum photographic properties were obtained for mixing the sunfast yellow and $\beta$-copper phthalocyaninr. In this case the electrophotographic sensiri\ity was found to he $E{1:2}$= 1440 lux . sec. And also the spectral sensitivity shows that it had a good properties for panchromatic matcrial.

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