• Title/Summary/Keyword: Absorption wavelength

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Infrared Radiation Properties for SiO2 Films Made by Sol-Gel Process (졸-겔법으로 제조된 SiO2막의 적외선 복사특성에 관한 연구)

  • Kang, Byung-chul;Kim, Young-geun;Kim, Ki-ho
    • Korean Journal of Materials Research
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    • v.13 no.10
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    • pp.697-702
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    • 2003
  • FT-IR and thermograph were used to investigate the infrared radiation characteristics of $SiO_2$film made by the sol-gel method. FT-IR spectrum of the $SiO_2$film showed high infrared absorption by Si-O-Si vibration at 1220, 1080, 800 and cm$460^{-1}$ The infrared absorption and radiation wavelength ranges of the $SiO_2$film measured by the integration method coincided with the reflection method, and the infrared emissivity was 0.65, equally. Depending on the bonding of elements, the infrared emissivity was high in the wavelength range where the infrared absorption rate was high, that follows the Kirchhoff's law. The emissivity showed the highest value in the wavelength range between $8∼10\mu\textrm{m}$. $SiO_2$film was considered as an efficient materials for infrared radiator at temperature below 10$0^{\circ}C$. The heat radiation temperature was $117^{\circ}C$ for the aluminum plate, but $146^{\circ}C$ for the $SiO_2$film after 7 minutes heat absorption, consiquently, $29^{\circ}C$ higher than the former.

The Color Analysis and The Optical Absorption Properties of Yellow(x)-Blue(1-x) Color Lens (Yellow(x)-Blue(1-x) 칼라렌즈의 광흡수 특성과 color 분석)

  • Park, Sang An;Kim, Yong Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.2
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    • pp.201-205
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    • 2000
  • The colors of a tinted lens for a mixed color could be applied to a subtractive mixture's law, and the estimation of a tinted lens used the properties of optical absorptions and the color analysis. The optical absorption properties of Yellow(x)-Blue(1-x) depended on the yellow color in short wavelength below 500 nm, the absorption in the 550~650 nm wavelength regions depended on the blue color. The absorption band in the 550~650 nm wavelength regions was a peak for an ion of transition metal. The color properties of Yellow(x)-Blue(1-x) analysing by the $L^*a^*b^*$ of CIE system shifted to toward $+a^*$ decreasing x, it was formed of a pure color because of a low saturation existing in +0.6.

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Characteristics of Electronic Absorption Spectrum and Photoluminescence in Cast-Poly(3-hexylthiophene) Films (캐스팅법으로 제작한 Poly(3-hexylthiophene)의 흡수스펙트럼에 따른 형광 특성)

  • 김주승;구할본;조재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.57-60
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    • 1998
  • Poly(3-hexylthiophene)(P3HT) was synthesized by use of FeCl$_3$ as a oxidizing agent at $25^{\circ}C$. The infrared spectrum of our polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. P3HT contains the HT(head-to-tail) linkage larger than 64% based on NMR analysis. Electronic absorption and photoluminescence studies show that cast films of P3HT have three exciting state. Absorption spectrum was separated with three maximum peaks by Giese-French method and shifted to the shorter wavelength with increasing temperature. Separated absorption spectrum of P3HT is well adapted to PL peak appeared at longer wavelength. Low temperature PL spectrum is well separated at 669nm, 733nm and 812nm.

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Absorptance and Electrical Properties Evaluation of Nickel Layer Deposited onto Thin Film Pyroelectric PZT IR Detector (PZT박막 적외선 감지소자의 적외선 흡수층으로 증착된 니켈 박막의 광학 및 전기적 특성 분석)

  • Ko, Jong-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.11
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    • pp.1727-1732
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    • 2004
  • A nickel layer was deposited onto the PZT thin films, serving both as a selective radiation absorption layer and as a top electrode. The absorption properties of such nickel coated multi-layered infrared detectors were studied in the visible and infrared wavelength ranges. The optimal thickness of the nickel layer on our substrate was 10nm. The maximum absorption coefficient of the deposited 10nm thick nickel layer was 0.7 at a 632nm wavelength. However, a striking asymmetric polarization hysteresis loop was observed in these PZT thin films with nickel as the top electrode. This asymmetric polarization was attributed to the difference between the dynamic pyroelectric responses in these Ni/PZT/Pt films poled either positively or negatively before the measurement. A positively poled film showed a 40% higher voltage response than a negatively poled detector.

Two-Photon Absorption Cross Sections of Dithienothiophene-Based Molecules

  • Chung, Myung-Ae;Lee, Kwang-Sup;Jung, Sang-Don
    • ETRI Journal
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    • v.24 no.3
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    • pp.221-225
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    • 2002
  • We performed nonlinear transmission measurements and quantum-chemical calculations on dithienothiophene(DTT)-based molecules to gain insight into the effect of acceptor and donor groups on two-photon absorption(TPA) properties. The TPA intensity showed dispersion characteristics of the single-photon absorption spectrum. When the molecules included an asymmetric donor-acceptor pair, the single- and two-photon absorption maximum wavelengths were red-shifted more than when the molecules had a symmetric donor-donor structure. We interpreted this result as indicating that the $S_2$ state plays the dominating role in the absorption process of molecules with a symmetric structure. The experimental TPA ${\delta}$ values at the absorption peak wavelength showed a dependence on the structural variations. We found the self-consistent force-field theory and Hartree-Fock Hamiltonian with single configuration interaction formalism to be valid for evaluating TPA ${\delta}$. Although the quantum-chemical calculations slightly underestimated the experimental ${\delta}$ values obtained from nonlinear trans -mission measurements, they reasonably predicted the dependence of the ${\delta}$ value on the structural variations. We confirmed the role of molecular symmetry by observing that donor-donor substituted structure gave the highest experimental and theoretical TPA ${\delta}$ values and that the donor-acceptor substituted structure showed a greater red-shift in the TPA absorption maximum wavelength. Overall, the theoretical ${\delta}$ values of DTT-based molecules were in the order of $10^{-46}\;cm^4{\cdot}s{\cdot}photon^{-1}$ and are higher than that of AF-50 by nearly two orders of magnitude.

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Frequency stabilization of laser and absolute wavelength measurement of 13C2H2 for DWDM system (13C2H2 분자를 이용한 반도체 레이저 주파수 안정화 및 그 파장 측정)

  • 문한섭;서호성;이인원
    • Korean Journal of Optics and Photonics
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    • v.13 no.2
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    • pp.123-127
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    • 2002
  • We have measured the wavelengths of the absorption lines of the $^{13}$ C$_2$H$_2$molecule by using a wavelength meter calibrated against the national optical frequency standard (iodine Stabilized He-Ne Laser, KRISS-R701) in the visible wavelength region. To measure the absolute wavelengths of the absorption lines, the frequency of the laser has been stabilized in the peaks and the sides of the absorption lines of $^{13}$ C$_2$H$_2$. Also, we have proposed the development of a frequency standard source of ITU-T grid using stabilization in the sides of the absorption lines of $^{13}$ C$_2$H$_2$.

A Study on the Complex Dyeing of Natural Dye (천연염료의 복합염색에 관한 연구)

  • Shin, Young-Joon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.14 no.4
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    • pp.151-162
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    • 2012
  • Regarding experimental study on the dyeing properties of natural dye, I have dyed silk fabric with Styphnolobium japonicum, sappan wood, and indigo. The results of the experiment have been analysed by wavelength of maximum absorption, K/S and CIE Lab chromaticity co-ordinated. The results are as follows: In case of complex dyeing using Styphnolobium japonicum and sappan wood, dyeing with sappan wood, which is red related color, after dyeing with Styphnolobium japonicum, which is yellow related color, is more efficient. When dyeing was maden by complex of Styphnolobium japonicum and sappan wood, Dyeing method by the order of "Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$mordanting" made the best result of complex dyeing. In case of complex dyeing using Styphnolobium japonicum and Indigo, dyeing with Styphnolobium japonicum after the indigo made the best result. When dyeing with indigo first, and then Styphnolobium japonicum, yellow color was not well dyed, and low level of saturation caused lusterless color. Ordering of Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$indigo made the best result of complex dyeing in case of complex dying with Styphnolobium japonicum and indigo. Dyeing order, sappan wood first and then indigo last method shown 560~640 nm wavelength of maximum absorption which most color was blue related. In contrast, Indigo first and then sappan wood method shown 460~560nm wavelength of maximum absorption which color was red related. Complex dyeing with sappan wood and indigo was showing lusterless color. In case of dyeing with red and blue, dyeing with sappan wood and indigo was not appropriate.

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Estimation of Light Absorption by Brown Carbon Particles using Multi-wavelength Dual-spot Aethalometer (다파장 Dual-spot Aethalometer를 이용한 갈색탄소의 광흡수계수 평가)

  • Yu, Geun-Hye;Yu, Jae-Myeong;Park, Seung-Shik
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.2
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    • pp.207-222
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    • 2018
  • In this study, light absorption of carbonaceous species in $PM_{2.5}$ was investigated using a dual-spot 7-wavelength Aethalometer(model AE33) with 1-min time interval between January 01 and September 30, 2017 at an urban site of Gwangju. During the study period, two Asian dust (AD) events occurred in April (AD I) and May (AD II), respectively, during which light absorption in total suspended particles was observed. Black carbon (BC) was the dominant light absorbing aerosol component at all wavelengths over the study period. Light absorption coefficients by aerosol particles were found to have 2.7~3.3 times higher at 370 nm than at 880 nm. This would be attributed to light absorbing organic aerosols, which is called brown carbon (BrC), as well as BC as absorbing agents of aerosol particles. Monthly average absorption ${{\AA}}ngstr{\ddot{o}}m$ exponent ($AAE_{370-950nm}$) calculated over wavelength range of 370~950 nm ranged from 1.10 to 1.35, which was lower than the $AAE_{370-520nm}$ values ranging from 1.19~1.68 that was enhanced due to the presence of BrC. The estimated $AAE_{370-660nm}$ of BrC ranged from 2.2 to 7.5 with an average of 4.22, which was fairly consistent to the values reported by previous studies. The BrC absorption at 370 nm contributed 10.4~28.4% to the total aerosol absorption, with higher contribution in winter and spring and lower in summer. Average $PM_{10}$ and $PM_{2.5}$ concentrations were $108{\pm}36$ and $24{\pm}14{\mu}g/m^3$ during AD I, respectively, and $164{\pm}66$ and $43{\pm}26{\mu}g/m^3$ during AD II, respectively, implying the greater contribution of local pollution and/or regional pollution to $PM_{2.5}$ during the AD II. BC concentration and aerosol light absorption at 370 nm were relatively high in AD II, compared to those in AD I. Strong spectral dependence of aerosol light absorption was clearly found during the two AD events. $AAE_{370-660nm}$ of both light absorbing organic aerosols and dust particles during the AD I and II was $4.8{\pm}0.5$ and $6.2{\pm}0.7$, respectively. Higher AAE value during the AD II could be attributed to mixed enhanced urban pollution and dust aerosols. Absorption contribution by the light absorbing organic and dust aerosols estimated at 370 nm to the total light absorption was approximately 19% before and after the AD events, but it increased to 32.9~35.0% during the AD events. In conclusion, results from this study support enhancement of the aerosol light absorption due to Asian dust particles observed at the site.

A Study on the Photon Energy Spectrums of Backlight for the Analysis of the Photoelectric Characteristics of a-Si:H TFT (비정질 실리콘 박막 트랜지스터의 광특성 분석을 위한 백라이트의 광자 에너지 스펙트럼에 대한 연구)

  • Jeong, Kyung-Seo;Kwon, Sang-Jik;Cho, Eou-Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.12
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    • pp.1058-1062
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    • 2009
  • For the investigation of the mechanism of photoelectric characteristics of a hydrogenated amorphous silicon thin film transistor(a-Si:H TFT), spectral characteristics of various backlights were analyzed in terms of the photon energy at each wavelength. Photon energy spectral characteristics were obtained through the multiplication of each photon energy and spectral intensities of backlights at each wavelength and the total photon energies were obtained by the integration of the photon energy spectrums. From the comparison of the experimental photo leakage current and the calculated photon energy, it was possible to conclude that the absorption of illuminated backlight to a-Si:H layer and the generation of electrons and holes are mainly carried out at the wavelength less than 500 nm as described in previous reports.