• Title/Summary/Keyword: Absorption wavelength

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Two-Dimensional Behavior and J-Aggregate Formation of Merocyanine Dye Monolayers in Mutual Mixing (상호혼합에 의한 메로시아닌 색소 단분자막의 2차원 거동 및 J-회합체 형성)

  • Sin, Hun-Gyu;Kwon, Young-Soo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.3
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    • pp.105-110
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    • 2002
  • J-aggregates in the mutual mixing LB films of [6Me-DS]$_{1-x}$ [DO]$_{x}$,[DS]$_{1-x}$ [DO]$_{x}$ and [DSe]$_{1-x}$ [DO]$_{x}$ have been studied by optical absorption, fluorescence and surface pressure-area isotherms. In [6Me-DS]$_{1-x}$ [DO]$_{x}$ films, sharp J-band absorption and fluorescence of [6Me-DS] are linearly shifted to the longer wavelength for the replacement of [6Me-DS] by [DO]. According to the x, a smooth shift of the limited area has been cleared. In the [DS]-[DO] system, the J-band is enhanced at 1:1 composition and strong fluorescence is also observed. Also, the presence of phase separation was suggested in the [DSe]-[DO] system, because the absorption spectra were decomposed into [DSe] and [DO] spectra. On the other hand, in the pressure-area isothermal study, reduction in the molecular occupying area of monolayers has been clarified. This could be ascribed to the enhancement of molecular ordering in J-aggregates. These facts are also believed to reflect the most closely packed arrangement of chromophores in the merocyanine dye monolayers. Thus, it was confirmed that the interaction between mixed dye molecules and the CdC1$_2$+KHCO$_3$subphases affected the J-aggregates of the LB films. Also. it is thought that the J-aggregates are formed non-dimensionally in LB films, such as solution synthesized [DX:DO] assemblies on mixing.s on mixing.

Determination of Lead in Urine by Atomic Absorption Spectrophotometry (원자흡광법을 이용한 요중 연 배설량의 정량)

  • Paik, Nam-Won;Yoon, Bock-Sang;Chung, Kyou-Chull
    • Journal of Preventive Medicine and Public Health
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    • v.7 no.2
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    • pp.377-381
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    • 1974
  • Determination of lead in urine is important in industrial hygiene and toxicology. Dithizone method has been principally used for the determination of lead in urine, which gives accurate results in skilful hands but is usually complex and time-consuming. Atomic absorption spectrophotometry is a new simple method and several procedures have been described. However, the influences of pH and the presence of chelating agents during treatment of lead poisoning are not clear. The purpose of this study was to find out the effect of pH and chelating agents on the determination of lead using Shimadzu atomic absorption/flame spectrophotometer, model AA-610. The results obtained were as follows: 1. The atomic absorption spectrophotometry(AAS) could be applied without prior acid digestion to specimens in the absence of chelating agents. The absorbance at $2,170\;{\AA}$, though more sensitive, was more noisy electronically. Therefore, we selected the wavelength of $2,833\;{\AA}$ plus scale expansion. 2. The optimal pH was in the range from 2 to 3. 3. The sensitivity was $0.075{\mu}g/ml/%$ and detection limit was about $0.2{\mu}g/ml$. 4. In the presence of EDTA, lead could not be completely determined without prior acid digestion. 5. On specimens from patients receiving penicillamine therapy, a comparison was made between the values obtained with dithizone method and AAS method with prior acid digestion. The results of comparison showed a very good agreement.

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A study on optical properties of InP for implementation of fiber-optic temperature sensor (광섬유 온도센서를 위한 InP의 광학적 특성 연구)

  • Kim, Young-Soo;Shin, Keon-Hak;Chon, Byong-Sil
    • Journal of Sensor Science and Technology
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    • v.3 no.3
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    • pp.36-44
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    • 1994
  • A fiber-optic temperature sensor utilizing InP as a sensing medium was implemented and tested to determine the dependance of the optical characteristics of InP on physical parameters for the use as design parameters in this type of sensors. The optical absorption coefficient of InP has been determined through the experimental measurement of the fundamental optical absorption characteristics at various temperature points. The transmission characteristics of light source at three temperature points($249^{\circ}K$, $298^{\circ}K$, $369^{\circ}K$) are computed from the optical absorption coefficient for a fixed length of InP. A series of measurement concluded that optical absorption edge moves to longer wavelength region at a speed of 0.42 nm / $^{\circ}K$ as the specimen gets hotter, and that increasing the thickness of the InP sensing layer shifts power density curve to lower temperature region.

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Efficiency of a Direct Absorption Solar Collector using Ag Nanofluids Synthesized by Chemical Reduction Method (화학적 환원법으로 제조된 은나노유체를 사용한 직접흡수식 태양열 집열기의 효율)

  • Lee, Seung-Hyun;Park, Yong-Jun;Choi, Tae Jong;Jang, Seok Pil
    • Journal of the Korean Solar Energy Society
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    • v.34 no.5
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    • pp.65-72
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    • 2014
  • In this paper, the water-based Ag nanofluids are synthesized by the chemical reduction method and their extinction coefficients are measured by an in-house developed measurement device. The Ag nanofluids are manufactured by the chemical reduction method with the mixing of silver nitrate ($AgNO_3$) and sodium borohydride ($NaBH_4$) in an aqueous solution of polyvinyl pyrrolidone (PVP). The extinction coefficients of Ag nanofluids are measured by means of the in-house developed apparatus at a wavelength of 632.8nm according to the particle volume fractions. The results show that the extinction coefficient of water-based Ag nanofluids increases with the increase of nanoparticle concentrations. Finally, the temperature field and efficiency of direct absorption solar collector (DASC) are analytically estimated based on the measured extinction coefficient of water-based Ag nanofluids. The results indicate that the direct absorption solar collectors using nanofluids have the feasibility to improve the efficiency of conventional flat-plate solar collectors without using an absorber plate.

Influence of Reducing Agents and Additives on the Synthesis of ZnSe Nanoparticles (ZnSe 나노분말 합성에 미치는 환원제와 첨가제의 영향)

  • Back, Geum Ji;Lee, Da Gyeong;Lee, Min Seo;Song, Ha Yeon;Hong, Hyun Seon
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.233-240
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    • 2020
  • Nano-sized ZnSe particles are successfully synthesized in an aqueous solution at room temperature using sodium borohydride (NaBH4) and thioglycolic acid (TGA) as the reducing agent and stabilizer, respectively. The effects of the mass ratio of the reducing agent to Se, stabilizer concentration, and stirring time on the synthesis of the ZnSe nanoparticles are evaluated. The light absorption/emission properties of the synthesized nanoparticles are characterized using ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy, and particle size analyzer (PSA) techniques. At least one mass ratio (NaBH4/Se) of the reducing agent should be added to produce ZnSe nanoparticles finer than 10 nm and to absorb UV-vis light shorter than the ZnSe bulk absorption wavelength of 460 nm. As the ratio of the reducing agent increases, the absorption wavelengths in the UV-vis curves are blue-shifted. Stirring in the atmosphere acts as a deterrent to the reduction reaction and formation of nanoparticles, but if not stirred in the atmosphere, the result is on par with synthesis in a nitrogen atmosphere. The stabilizer, TGA, has an impact on the Zn precursor synthesis. The fabricated nanoparticles exhibit excellent photo-absorption/discharge characteristics, suggesting that ZnSe nanoparticles can be alloyed without the need for organic solutions or high-temperature environments.

The Study of DEP Degradation Properties by Combination US and UV Lamp of Different Wavelength (초음파 (US)와 다양한 파장범위의 자외선 (UV) 조사에 따른 DEP 분해특성에 관한 연구)

  • Na, Seung-Min;Cai, Jinhua;Shin, Dong-Hoon;Cui, Mingcan;Khim, Jee-Hyeong
    • Journal of Environmental Science International
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    • v.21 no.7
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    • pp.845-853
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    • 2012
  • Diethyl phthalate (DEP) is widely spread in the natural environment as an endocrine disruption chemicals (EDs). Therefore, in this study, ultrasound (US) and ultraviolet (UVC), including various applied power density (10-40 W/L), UV wavelengths (365 nm, 254 nm and 185 nm) and frequencies (283 kHz, 935 kHz) were applied to a DEP contaminated solution. The pseudo-first order degradation rate constants were in the order of $10^{-1}$ to $10^{-4}\;min^{-1}$ depending on the processes. Photolytic and sonophotolytic DEP degradation rate also were high at shortest UV wavelength (VUV) due to the higher energy of photons, higher molar absorption coefficient of DEP and increased hydroxyl radical generation from homolysis of water. Sonolytic DEP degradation rate increased with increase of applied input power and the dominant reaction mechanism of DEP in sonolysis was estimated as hydroxyl radical reaction by the addition of t-BuOH, which is a common hydroxyl radical scavenger. Moreover, synergistic effect of were also observed for sonophotolytic degradation with various UV irradiation.

Applications of Extracellular Polysaccharide p-m10356

  • Park, Hee-Jung;Kim, Hyong-Ju;Lee, Chang-Moon;Kim, Jin;Lee, Hong-Kum;Yim, Joung-Han;Lee, Ki-Young
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.566-569
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    • 2005
  • The extracellular polysaccharide...(EPS) has been used in a wide variety of industrial applications because of gel formation, emulsion stability, control of the surface tension, water absorption and film formation etc. In this study, inhibitory activity on tyrosinase and inhibitory activity on angiotensin converting enzyme...(ACE) are determined. UV adsorption wavelength, beads formation of EPS were investigated. In the result, in 1%(w/v) EPS concentration, EPS had inhibitory activity of 71.8% on tyrosinase and inhibitory activity of 61.5% on angiotensin converting enzyme in 1.5% EPS concentration. Adsorption wavelength of EPS was UV-B,C . Beads based on EPS were prepared by w/o emulsion method and the shape of EPS beads observed by SEM was spherical and uniform.

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CLINICAL APPLICATION OF ARGON LASER IN PEDIATRIC DENTISTRY (아르곤 레이저의 소아치과에서의 임상적 적용)

  • Lee, Mi-Na;Lee, Sang-Hoon;Kim, Chong-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.1
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    • pp.139-147
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    • 1997
  • Argon laser used in this case report, is special in having two wavelength of 488, 514nm blue-green visible light spectrum. Blue light is used for composite resin polymerization and caries detection. Green light is used for soft tissue surgery and coagulation. Maximum absorption of this laser light occurs in red pigmentation such as hemoglobin. The argon laser may be well-suited for selective destruction of blood clots and hemangioma with minimal damage to adjacent tissues. Argon laser light penetrates tissue to the 1 mm depth, so its thermal intensity is lower than $CO_2$ laser light. Also, due to its short wavelength it can be focused in a small spot and even single gene can be excised by this laser and microscopy. After applicating argon laser to 4 patient for surgical procedure and to 1 patient for curing the composite resin, following results were obtained. 1. Improved visibility were gained due to hemostasis and no specific technique were needed according to easy recontouring of the tissue. 2. Ability to use by contact mode, tactile sense was superior but tissue dragability and accumulation of tissue on the tip needed sweeping motion. 3. Additive local anesthetic procedure was needed. 4. No suture and less curing time reduced chair time, this made argon laser available in pediatric dentistry.

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AN EXTENSION OF A RELIABLE WAVELENGTH COVERAGE OF THE AKARI NG GRISM MODE

  • Baba, Shunsuke;Nakagawa, Takao;Isobe, Naoki;Shirahata, Mai;Ohyama, Youichi;Yano, Kenichi;Kochi, Chihiro
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.45-47
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    • 2017
  • The Infrared Camera onboard the AKARI satellite carried out spectroscopic observations with a grism mode named NG, whose wavelength coverage was $2.5-5.0{\mu}m$. We reinvestigate the current flux calibration for the NG grism mode, with which calculated flux density implausibly decreases at $4.9{\mu}m$ especially for red objects due to the second-order light contamination. We perform a new spectral response calibration using blue and red standard objects simultaneously. New response curves which contain both the first-and second-order light are able to separate each contribution consistently and useful for studies of red objects such as CO ro-vibrational absorption in active galactic nuclei.

The fabrication of 6H- SiC UV photodiode and the analysis of the photoresponse (6H-SiC UV 광다이오드의 제작 및 수광특성 해석)

  • 박국상;이기암
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.126-136
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    • 1997
  • 6H-SiC UV photodiodes with $p^+$/n/n mesa structure were fabricated. The photocurrents of the photodiodes were measured in the wavelength range of 200~600 nm. The photocurrents were sensitive to ultraviolet radiation of 200~500 nm, and come to the maximum value at 260 nm. The quantum efficiency was calculated by using the diffusion model of minority carriers, and compared with the distribution of the photocurrent measured as a function of wavelength each other. The photocurrents of the 6H-SiC photodiode were explained by the diffusion model of the minority carriers which contained the optical absorption of the depletion region as well as the other layers.

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