• Title/Summary/Keyword: Absorption wavelength

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Evaluation of Disinfection Characteristics for Mixed Oxidants Produced by Electro-chemical Method (전기분해 방식에 의한 혼합산화제 소독 특성 평가)

  • Lee, Kyung-Hyuk;Lim, Jae-Lim;Lee, Doo-Jin;Kim, Seong-Su;Ahn, Hyo-Won
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.625-631
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    • 2005
  • Disinfection characteristics of mixed oxidants produced by mean of electro-chemical method were evaluated. Inactivation rate of B. subtilis spore on the mixed oxidants were similar with that of chlorine. Based on the experimental results, activation energy of mixed oxidants and chlorine with B. subtilis spore at pH 8.3 were calculated as 30.8, $34.7kJ{\cdot}mol^{-1}$ respectively. UV absorption spectrum of both chlorine and mixed oxidants present similar. Molar extinction coefficients of chlorine and mixed oxidants at 292nm, which is maximum absorption wavelength of $OCl^-$ were 357, $377M^{-1}cm^{-1}$, respectively. Disinfectant decay rate and formation rate of THM in the S WTP filtrate also shows insignificant difference for both mixed oxidants and chlorine. In consequent, it was confirmed that high portion of chlorine presents in the mixed oxidants.

Characteristics and Optical Properties of the Azobenzene Functionlized Dendrimer in Organic Thin Monolayers (아조벤젠이 기능화된 덴드리머 유기단분자막의 광학적 성질과 특성)

  • 손정호;윤회찬;김정명;김병상;신훈규;장정수;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.182-185
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    • 2001
  • The functionlized dendrimer containing 48 azobenzene was synthesized. Many isolated featureless domains were explicitly observed even at the air-water interface. Also, these monolayers were representatively observed, showing the change of surface pressure with irradiation time and wavelength. In AFM images. the larger domains irregularly shaped structures on the top while the smaller ones were free from such defects. In the optical absorption spectra of the LB films by UV irradiation and heat treatment, only photoisomerization of the G4-48Az monolayers was observed, a decrease of absorbance peak without change of the spectral shape. This suggests that optical behavior and morphological change are affected by the functional group and the symmetric chain.

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A Properties of n-CdS/p-InP Heterojunction Diodes (n-CdS/P-InP 이종접합 다이오드 특성)

  • 송복식;문동찬;김선태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.11a
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    • pp.60-63
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    • 1993
  • We have prepared n-CdS/p-InP hetero- junction solar cells by thermal evaporation. The efficiency under the optium conditions without the grid line contact was 7.3%, and the solar cell having glid line contact with SiO AR coating was the open circuit voltage of 0.71V, the short circuit voltage current density of 15mA/cm$^2$, the fill factor of 0.73, and the efficiency of 11.5%. As result of photoresponse in 400-1000nm wavelength the cutoff of n-CdS/p-InP solar at 500nm results from absorption by the CdS \"window\" and the cutoff at 930 nm result from absorption by the InP.

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Modeling the optical properties of phytoplankton and their influence on chlorophyll estimation from remote sensing algorithms

  • Zhou, Wen;Cao, Wen-Xi
    • Proceedings of the KSRS Conference
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    • v.1
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    • pp.479-482
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    • 2006
  • The absorption coefficient and backscattering properties of phytoplankton were calculated from the Mie theory. Given a simple case that phytoplankton and mineral particles are the only constitutions in seawater, the reflectance $b_b({\lambda})/[a({\lambda})+b_b({\lambda})]$was analyzed. Then the chlorophyll concentrations were estimated from remote sensing OC2 algorithm. The results show that reflectance in short wavelength region is more sensitive to the Chl variation; High mineral concentrations in seawater have significant influence on the reflectance spectrum; the existence of high mineral concentration may result in the mistake in chlorophyll estimation from OC2 algorithm.

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Surface and Optical Characteristics of Cobalt Dopped-titanium Oxide Film Fabricated by Water Spray Pyrolysis Technique (습식 분무 열분해 방법으로 제조한 코발트 도핑된 티타늄 산화막의 표면 및 광학적 특성)

  • Song Ho-Jun;Park Yeong-Joon
    • Korean Journal of Materials Research
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    • v.15 no.3
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    • pp.209-215
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    • 2005
  • Titanium dioxide films $(TiO_2)$ doped cobalt transition metal were prepared on titanium metal by water spray pyrolysis technique. Micro-morphology, crystalline structure, chemical composition and binding state of sample groups were evaluated using field emission scanning microscope(FE-SEM), X-ray diffractometer(XRD), Raman spectrometer, X-ray photoelectron spectrometer(XPS). $TiO_2$ films of rutile structure were predominately formed on all sample groups and $Ti_2O_3$ oxide was coexisted on the surface of cobalt doped-sample groups. The optical absorption peaks measured by using UV-VIS-NIR spectrophotometer were observed at specific wavelength region in sample groups doped cobalt ion. This result could be analyzed by introducing crystal field theory.

The reserch evaluation of shadow influence in NOAA AVHRR data

  • Kim, Dong-Hee;Ryutaro, Tateishi;Choi, Seung-Pil
    • 한국지형공간정보학회:학술대회논문집
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    • 2005.08a
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    • pp.101-106
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    • 2005
  • Vegetation shows unique spectrum characteristics compared with other materials. If such characteristics are used, land change pattern can be determined. Thus, vegetation has an absorption belt and a reflective belt in visible and near infrared, and reflectance is very high. Then, various methods of monitoring vegetation paying attention to the absorption wavelength region and reflective region of vegetation are proposed. However, there are various problems in grasping change of vegetation by NDVI, PVI, etc. It is very difficult especially to remove various noise ingredients in the received satellite data. Until now, it is difficult to compensate for shadow effect when NDVI is used in vegetation analysis. The results is, if the shadow is about 60% the pixel will be wrongly classified as may be vegetation or not.

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Material Dependence of Laser-induced Breakdown of Colloidal Particles in Water

  • Yun, Jong-Il
    • Journal of the Optical Society of Korea
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    • v.11 no.1
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    • pp.34-39
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    • 2007
  • Laser-induced breakdown of colloidal suspensions, such as polystyrene, $ZrO_2$, and $SiO_2$ particles in diameters of 100-400 nm in water is investigated by nanosecond flash-pumped Nd:YAG laser pulses operating at a wavelength ${\lambda}$= 532 nm. The breakdown threshold intensity is examined in terms of breakdown probability as a function of laser pulse energy. The threshold intensity for $SiO_2$ particles ($1.27{\times}10^{11}\;W/cm^2$) with a size of 100 nm is higher than those for polystyrene and $ZrO_2$ particles with the same size, namely $5.7{\times}10^{10}$ and $5.5{\times}10^{10}\;W/cm^2$, respectively. Results indicate that the absorption of five photons is required to induce ionization of $SiO_2$ particles, whereas the other particles necessitate four-photon absorption. These breakdown thresholds are compared with those measured by nanosecond pulses from a diode-pumped Nd:YAG laser having a different focusing geometry.

Fluorescence Micropatterning Based on the Polymeric Photobase Generator Containing Oxime-Urethane Groups by Dansylation

  • Choi, Won San;Kim, Hak Soo;Chae, Kyu Ho
    • Rapid Communication in Photoscience
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    • v.2 no.1
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    • pp.24-27
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    • 2013
  • A polymeric photobase generator containing oxime-urethane groups is applied to a fluorescence micropatterning material. Polymer bearing oxime-urethane groups was prepared by copolymerization of methyl methacrylate with methacryloyloxyethyl benzophenoneoxime urethane (MBU). The reaction of amino groups in the irradiated copolymer film with dansyl chloride (Dns-Cl) was monitored by using UV absorption, IR absorption and fluorescence spectroscopy. The fluorescence spectrum of the Dns-Cl-treated irradiated copolymer film shows a strong fluorescence with a fluorescence maximum wavelength at 510 nm. A blue fluorescent micropattern with a line width of $2{\sim}3{\mu}m$ was obtained. Treatment of the irradiated copolymer film with Dns-Cl and rhodamine B mixture led to the formation of green, red, and orange-colored fluorescence micropatterns. Thus, various colored micropatterns on a single polymer film can be obtained by selective excitation of each dye molecules.

High-Power Conversion Efficiency of Photovoltaic Cells Fabricated with a Small-molecular and Polymer Donating Blend Layer

  • Kim, Ji-Heon;Park, Jea-Gun
    • Current Photovoltaic Research
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    • v.2 no.2
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    • pp.48-52
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    • 2014
  • A photovoltaic cell of CuPc:P3HT:PCBM was introduced to extend the light absorption in the visible wavelength between 300~500 and 550~800 nm. By fabricating the photovoltaic cells of ITO / PEDOT:PSS / CuPc:P3HT:PCBM / BCP / Al with small-molecular and polymer donating materials blended layer, we demonstrated a high PCE of 4.20% with high Jsc of $10.05mA/cm^2$. This performance of photovoltaic cell with the blended layer of small-molecular and polymer can be competitive with that of tandem cells.

Structural and Optical Properties of CdS Thin Films Deposited by R.F. Magnetron Sputtering

  • Hwang, Dong-Hyeon;An, Jeong-Hun;Son, Yeong-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.149-149
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    • 2011
  • CdS films were deposited on glass substrates by R.F. magnetron sputtering method and the films were annealed at various substrate temperatures ranging from room temperature to $300^{\circ}C$. Structural properties of the films were studied by X-ray diffraction analysis. The structural parameters as crystallite size have been evaluated. The crystallite sizes were found to increase, and the X-ray diffraction patterns were seen to sharpen by increasing substrate temperatures. X-ray diffraction patterns of these films indicated that they contain both cubic (zincblende) and hexagonal (wurtzite) structures as a mixture. Optical properties of the films were measured at room temperature by using UV/VIS spectrometer in the wavelength range of 190 to 1100nm and optical absorption coefficients were calculated using these data. The energy gap of the films was found to decrease, and the band edge sharpness of the optical absorption was seen to oscillate by annealing. The results show that heat treatments under optimal annealing condition can provide significant improvements in the properties of CdS thin films.

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