• Title/Summary/Keyword: Absorption power

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Identification and Physical Characteristics of the Ancient Charcoals Excavated from Chudong-ri Site, Korea (서천 추동리 문화유적에서 채취된 숯의 수종식별과 물리적 특성)

  • Kim, Myung-Jin;Lee, Jong-Shin;Park, Soon-Bal
    • Journal of Conservation Science
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    • v.24
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    • pp.13-22
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    • 2008
  • The identification of species, hygroscopic property, and ability of ethylene gas absorption of 23 ancient charcoals excavated from wooden coffin burials and roof-tile kilns of Chudong-ri cultural site were investigated. All of the 12 charcoals excavated from wooden coffin burials were broad-leaved trees. Among the total 12 samples, 9 samples were Lepidobalanus and others were Celtis spp.. On the other hand, other 11 charcoals from roof-tile kilns were needle-leaved tree, Pinus spp.(hard pine). The broad-leaved tree charcoals from wooden coffin burials showed a higher moisture absorption capacity than needle-leaved tree charcoals from roof-tile kilns. The ethylene gas absorption was greater in the Lepidobalanus charcoal than that of Celtis spp. and Pinus spp. (hard pine) charcoal. The broad-leaved tree charcoal having high absorption ability of substances was due to a large microporous and specific surface area. Therefore, it was estimated that broad-leaved tree charcoals were filled in order to make favorable condition in tomb. The wood quality of pine is soft and easy to burn because of low specific gravity, as well as high calorific value by resin in wood. We could assume that the pine wood was used as fuel for roof-tile kilns because of easy control of heating and thermal power.

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Characteristics of Low Dielectric Constant SiOF Thin Films with Post Plasma Treatment Time (플라즈마 후처리 시간에 따른 저유전율 SiOF 박막의 특성)

  • 이석형;박종완
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.167-272
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    • 1998
  • The fluorine doped silicon oxide (SiOF) intermetal dielectric (IMD) films havc been of interest due to their lower dielectric constant and compatibility with existing process tools. However, instability issues related to hond and increasing dielectric constant due to water absorption when the SiOF film was exposured to atmospheric ambient. Therefore, the purpose nf this research is to study the effect of post oxygen plasma treatment on the resistance of nioisture absorption and reliability of SiOF film. Improvement of moisture ahsorption resistance of SiOF film is due to the forming of thin $SiO_2$ layer at the SiOF film surface. It is thought that the main effect of the improvement of moisture absorption resistance was densification of the top layer and reduction in the numher of Si-F honds that tend to associate with OH honds. However, the dielectric constant was inucased when plasma treatment time is above 5 min. In this study, therefore, it is thought that the proper plasma treatment time is 3 min when plasma treatment condition is 700 W of microwave power, 3 mTorr of process pressure and $300^{\circ}C$ of substrate temperature.

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Synthesis and Photovoltaic Properties of Quinoxaline-Based Semiconducting Polymers with Fluoro Atoms

  • Song, Suhee;Choi, Hyo Il;Shin, In Soo;Suh, Hongsuk;Hyun, Myung Ho;Lee, Gun Dae;Park, Seong Soo;Park, Sung Heum;Jin, Youngeup
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2245-2250
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    • 2014
  • A new accepter unit, 6,7-difluoro-2,3-dihexylquinoxaline, was prepared and utilized for the synthesis of the conjugated polymers containing electron donor-acceptor pair for OPVs. New series of copolymers with dioctyloxybenzodithiophene as the electron rich unit and 6,7-difluoro-2,3-dihexylquinoxaline as the electron deficient unit are synthesized. The solid films of poly[2,6-(4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b']dithiophene)-alt-5,8-(6,7-difluoro-2,3-dihexylquinoxaline)] (PBQxF) and poly[2,6-(4,8-bis(2-ethylhexyloxy) benzo[1,2-b:4,5-b']dithiophene)-alt-5,8-(6,7-difluoro-2,3-dihexyl-5,8-di(thiophen-2-yl) quinoxaline)] (PBDTQxF) show absorption bands with maximum peaks at about 599 and 551 nm and the absorption onsets at 692 and 713 nm, corresponding to band gaps of 1.79 and 1.74 eV, respectively. The devices comprising PBQxF with $PC_{71}BM$ (1:2) showed open-circuit voltage ($V_{OC}$) of 0.64 V, short-circuit current density ($J_{SC}$) of $1.58mA/cm^2$, and fill factor (FF) of 0.39, giving power conversion efficiency (PCE) of 0.39%. To obtain absorption in the longer wavelength region, thiophene units without any alkyl group are incorporated as one of the monomers in PBDTQxF, which may result in low solubility of the polymers to lead lower efficiency.

Monitoring of Climate Change of Northeast Asia and Background Atmosphere in Korea

  • Oh, Sung-Nam;Chung, Hyo-Sang;Choi, Jae-Cheon;Bang, So-Young;Hyun, Myung-Suk
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.232-235
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    • 2003
  • In general, the parameters of climate change include aerosol chemical compounds, aerosol optical depth, greenhouse gases(carbon dioxide, CFCs, methane, nitrous oxide, tropospheric ozone), ozone distribution, precipitation acidity and chemical compounds, persistent organic pollutants and heavy metals, radioactivity, solar radiation including ultra-violet and standard meteorological parameters. Over the last ten years, the monitoring activities of Korea regarding to the climate change have been progressed within the WMO GAW and ACE-Asia IOP programs centered at the observation sites of Anmyeon and Jeju Gosan islands respectively. The Greenhouse gases were pointed out that standard air quality monitoring techniques are required to enhance data comparability and that data presentation formats need to be harmonized and easily understood. Especially, the impact of atmospheric aerosols on climate depends on their optical properties, which, in turn, are a function of aerosol size distribution and the spectral reflective indices. Aerosol optical depth and single scattering albedo in the visible are used as the two basic parameters in the atmospheric temperature variation studies. The former parameter is an indicator of the attenuation power of aerosols, while the latter represents the relative strength of scattering and absorption by aerosols. For aerosols with weak absorption, surface temperature decreases as the optical depth increases because of the domination of backscattering. For aerosols with strong absorption, however, warming could occur as the optical depth increases. The objective of the study is to characterize the means, variability, and trends of Greenhouse gases and aerosol properties on a regional basis using data from its baseline observatories in Korea peninsula. A further goal is to understand the factors that control radiative forcing of the greenhouse and aerosol.

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Effect of Deposition Parameter on Ionic Conductivity of RF Magnetron Sputtered Li$_2$O-B$_2$O$_3$-SiO$_2$ Solid Electroiyte Films (RF 마그네트론 스퍼터링법으로 증착된 Li$_2$O-B$_2$O$_3$-SiO$_2$ 계 비정질 박막 고체전해질의 증착변수에 따른 이온전도 특성에 관한 연구)

  • 노남석;권혁상
    • Journal of the Korean institute of surface engineering
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    • v.27 no.2
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    • pp.65-73
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    • 1994
  • Effects of deposition parameter on the ionic conductivity and structural change of the Lithium borosili-cate solid electrolyte films, prepared by rf sputtering using 7$LI_2O-3B_2O_3-1SiO_2$ single phase target and also a mosaic target enriched with $LI_2O$, were analyzed by measuring AC impedance and IR absorption spectra for the films. Thed solid electrolyte film deposited from the single phase target exhibited very low ionic conductivi-ty of $10^{-10}{\Omega}^{-1}cm{-1}$ at room temperature, a result of low $Li^+$ ion content(7.52 at%) in the film. The $Li^+$ con-ductivity for the films deposited from the mosaic target, however, significantly increased to $10^{-7}{\Omega}^{-1}cm{-1}$ due to both an increased $Li^+$content (14.75 at %) and a structural change of the films. The increased ionic conduc-tivity of the film appears to be associated with an easiness of ionic mobility by structural change of glassy film from a some close packed network structure to a open one. These structural changes of film were found to be closely related to the increase in the peak intensity at~$960cm^{-1}$ of IR absorption spectra for the glassy films. With increasing either argon pressure from 3 to 21 mtorr or rf power from 2 to 3 W/$cm^2$, the $Li^+$ conduc-tivity for the films significantly increased to an order of $10^{-6}{\Omega}^{-1}cm{-1}$ due to an increase in openness of film structure, as confirmed by both an increase in the IR absorption peak intensity at ~$960cm^{-1}$ and a resultant reduction of activation energy for mobility of $Li^+$ ion.

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Enhancement of Power Conversion Efficiency from Controlled Nanostructure in Polymer Bulk-Hetero Junction Solar Cells

  • Wang, Dong-Hwan;Park, O-Ok;Park, Jong-Hyeok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.76-76
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    • 2011
  • Polymer-fullerene based bulk heterojunction (BHJ) solar cells can be fabricated in large area using low-cost roll-to-roll manufacturing methods. However, because of the low mobility of the BHJ materials, there is competition between the sweep-out of the photogenerated carriers by the built-in potential and recombination within the thin BHJ film [12-15]. Useful film thicknesses are limited by recombination. Thus, there is a need to increase the absorption by the BHJ film without increasing film thickness. Metal nanoparticles exhibit localized surface plasmon resonances (LSPR) which couple strongly to the incident light. In addition, relatively large metallic nanoparticles can reflect and scatter the light and thereby increase the optical path length within the BHJ film. Thus, the addition of metal nanoparticles into BHJ films offers the possibility of enhanced absorption and correspondingly enhanced photo-generation of mobile carriers. In this work, we have demonstrated several positive effects of shape controlled Au and Ag nanoparticles in organic P3HT/PC70BM, PCDTBT/PC70BM, Si-PCPDTBT/PC70BM BHJ-based PV devices. The use of an optimized concentration of Au and Ag nanomaterials in the BHJ film increases Jsc, FF, and the IPCE. These improvements result from a combination of enhanced light absorption caused by the light scattering of the nanomaterials in an active layer. Some of the metals induce the plasmon light concentration at specific wavelength. Moreover, improved charge transport results in low series resistance.

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Wave Energy Absorption Efficiency of Pneumatic Chamber of OWC Wave Energy Converter (진동수주형 파력발전장치 공기실의 파력에너지 흡수효율)

  • Hong, Key-Yong;Shin, Seung-Ho;Hong, Do-Chun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.3
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    • pp.173-180
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    • 2007
  • Oscillating wave amplitude in a bottom-mounted OWC chamber designed for wave energy converter is investigated by applying characteristic wave conditions in Korean coastal water. The effects of shape parameters of OWC chamber in a view of wave energy absorbing capability are analyzed. Both experimental and numerical approaches are adopted and their results are compared to optimize the shape parameters which can result in a maximum power production under given wave distribution. The experiment was carried out in a wave flume under 2-D assumption of OWC chamber. The numerical scheme employed a hybrid Green integral equation which adopts the Rankine Green function inside chamber to take account of fluctuating air pressure, while it uses the Kelvin Green function in outer domain. Air duct diameter, chamber width, and submerged depths of front skirt and back wall of chamber changes the magnitude and peak frequency of wave absorption significantly.

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Realization of High Impedance Surface Characteristics Using a Periodically Transformed Artificial Magnetic Conductor Structure and Reduction Technique of Specific Absorption Rate

  • Lee, Seungwoo;Rhee, Seung-Yeop;Kim, Pan-Yeol;Kim, Nam
    • Journal of electromagnetic engineering and science
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    • v.13 no.2
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    • pp.113-119
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    • 2013
  • We developed a transformed, symmetrical, mushroom-like surface without via holes in cells focused on a 2.4-GHz WLAN band. Each slot in the novel type structure plays a key role in modeling at the desired frequencies. The designed artificial magnetic conductor (AMC) has several advantages, including a small size, a wider bandwidth, a short reflecting distance to the antenna, and easy fabrication because there are no via holes. Overall dimensions of the AMC cell are 21 mm $(Width){\times}21mm$ $(Height){\times}2.6mm$ (Thickness), and the bandwidth is about three times wider (11.7%) compared to that of a conventional AMC (4.0%). For evaluating the performance of the proposed structure, a reflector, which periodically consists of the designed AMC cells, was developed. The antenna with the investigated AMC reflector not only works within a quarter of the wavelength because of the extremely high wave impedance generated by the AMC cells on the surface of the structure but also reduces the specific absorption rate (SAR). Electromagnetic field (EMF) exposure to a human phantom was analyzed by applying the designed reflector to the 2.4-GHz dipole antenna in a tablet PC. The calculated peak SAR averaged over 1 g was 0.125 W/kg when the input power was 1 W and the antenna was located at 20 cm from the human phantom. However, the SAR value was only 0.002 W/kg (i.e., 98.4% blocked) when the designed reflector was inserted in front of the antenna.

Model for Transport of Accidently Released Radionuclides onto Rice-Fields and its Comparison with Experimental Data (사고시 논으로 유출된 핵종 이동 모델 및 실험결과와의 비교)

  • Keum, Dong-Kwon;Lee, Han-Soo;Choi, Heui-Joo;Kang, Hee-Suk;Lim, Kwang-Muk;Choi, Young-Ho;Lee, Chang-Woo
    • Journal of Radiation Protection and Research
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    • v.29 no.2
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    • pp.117-127
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    • 2004
  • A dynamic compartment model was developed to evaluate the transport of accidently released radionuclides onto rice-fields. In the model, the surface water compartment and shoot-base absorption were introduced to account for the effect of irrigation, which is essential to a rice cultivation. The soil mixing by plough and irrigation before transplanting rice was also considered, and the rate of root-uptake and shoot-base absorption were modeled in terms of the function of biomass. In order to test the validation of the model, it was applied to the analysis of some simulated $^{137}Cs$ deposition experiments that were performed while cultivating rice in a greenhouse using soils sampled from rice-fields around Kori, Yonggwang and Ulchin nuclear power plants. The model prediction was generally agreed within about one order of magnitude with experimental data.

Materials Technology for Car Sound and Vibration Barriers (자동차용 소리, 진동 차단성 소재기술)

  • Kim, Ki-Seok;Choi, Kyeong-Eun;Ryu, Jeong-Seok;Kweon, Young-Min;Kang, Chang-Gi;Youn, Woo-Won;Park, Soo-Jin
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.10-21
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    • 2011
  • Recently, with developments in the automotive industry, sound and vibration damping have a considerable attraction with a diversified customer needs and advanced automobile. In general, among various materials, textile materials, such as felt and glass fibers, polyurethane foam, and PET fiber materials were used to reduce sound and vibration of the automobile. These materials were located in various main parts of the automobile to block sound and vibration, resulting in a comfortable ride. In addition, to improve fuel economy, weight reduction and cost saving for the automobile were also being considered together as well as the reduction of sound and vibration of the automobile. Therefore, in this paper, we focused on the need of interior sound and vibration absorption materials in the automobile and absorption materials-related technologies.