• 제목/요약/키워드: Absorption cross section

검색결과 131건 처리시간 0.022초

UV 영역에서 벤젠의 흡수 단면적의 측정 (Measurements of the Benzene Absorption Cross Section in the Range of Ultra Violet (UV))

  • 이정순;류성윤;김현호;우진춘;김기복
    • 한국대기환경학회지
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    • 제22권6호
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    • pp.922-928
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    • 2006
  • An absolute absorption cross section of benzene was measured with a spectrometer system including a mono-chrometer and a grating in the wavelength region of $240{\sim}280nm$ under the atmospheric pressure and room temperature in the laboratory. A certificated reference benzene gas ($98{\mu}mol/mol$ in $N_2$) was used to measure its absorption cross section. A 710 mm cell with a quartz window and a 150 W Xe arc lamp were employed. The magnitude of absorption cross section of $1.41{\times}10^{-18}cm^2$ was lower than that of the reference spectra ($2.5{\times}10^{-18}cm^2$) of high resolution spectrometer, Total measurement uncertainty was estimated to be 4.0%.

Spectroscopic Study of the Ã1A" - X~1A' System of CHBr

  • Shin, Seung-Keun;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • 제32권3호
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    • pp.905-908
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    • 2011
  • We report fluorescence excitation and emission spectra of the CHBr molecule generated via pyrolysis of $CH_3Br$ in a molecular beam experiment. The 193 nm attenuation cross sections were estimated from the reduction of the CHBr signal as a function of the excimer laser fluence. The derived 193 nm absorption cross section for CHBr [$(3.24{\pm}0.59){\times}10^{-17}\;cm^2$] is slightly higher than the absorption cross section previously determined for CHCl [$(2.6{\pm}0.8){\times}10^{-17}\;cm^2$], but the difference is within the estimated uncertainties in the measured cross section.

고충돌에너지 흡수용 알루미늄 크래쉬박스 개발 (Development of Al Crash Box for High Crashworthiness Enhancement)

  • 유정수;김석봉;이문용;허훈
    • 소성∙가공
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    • 제17권3호
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    • pp.182-188
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    • 2008
  • Crash box is one of the most important automotive parts for crash energy absorption and is equipped at the front end of the front side member. The specific characteristics of aluminum alloys offer the possibility to design cost-effective lightweight structures with high stiffness and excellent crash energy absorption potential. This study deals with crashworthiness of aluminum crash box for an auto-body with the various types of cross section. For aluminum alloys, A17003-T7 and A17003-T5, the dynamic tensile test was carried out to apply for crash analysis at the range of strain from 0.003/sec to 200/sec. The crash analysis and the crash test were carried out for three cross sections of rectangle, hexagon and octagon. The analysis results show that the octagon cross section shape with A17003-T5 has higher crashworthiness than other cross section shapes. The effect of rib shapes in the cross section is important factor in crash analysis. Finally, new configuration of crash box with high crash energy absorption was suggested.

분사펌프에 연결된 구동관로 위치변화에 따른 유동특성 (Flow Characteristics of Driven Nozzle Position Change in the Connected Injection Pump)

  • 손현철;박길문;고현선;이행남
    • 대한기계학회논문집B
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    • 제33권4호
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    • pp.215-224
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    • 2009
  • Analysis for various driven nozzle position changes. The analysis was done for different Reynolds number in entrance region of jet-pump and for several diameter ratios of driven nozzle. (1) The largest absorption energy was found at the point s=1 in condition of diameter ratio 1:3.21 and point s=0.5 in condition of diameter ratio 1:2.25. (2) The absorption energy was not related to the change of entrance velocity and the driven nozzle position having the largest absorption energy was function for cross section ratio. (3) As the position of driven nozzle moves to the downstream, the absorption energy gets weaker. Because the energy from swirl was lost at the cross section gets smaller. (4) As the position of driven nozzle moves to the downstream, the injection energy leans to the upper direction wall and as the Reynolds number increase, the lean phenomenon is more distinct. (5) The flow quantity of driven nozzle, the diameter ratio 1:3.21, was 32% higher than that of 1 : 2.25 and as the inlet velocity gets faster the efficiency decreased. And as the cross section of the driven nozzle increases.

Estimation of Neutron Absorption Ratio of Energy Dependent Function for $^{157}Gd$ in Energy Region from 0.003 to 100 eV by MCNP-4B Code

  • Lee, Sam-Yol
    • 한국방사선학회논문지
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    • 제3권3호
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    • pp.23-25
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    • 2009
  • Gd-157 material has very large neutron capture cross section in the thermal region. So it is very useful to shield material for thermal neutrons. Futhermore, in the neutron capture experiment and calculation, the neutron absorption and scattering are very important. Especially these effects are conspicuous in the resonance energy region and below the thermal energy region. In the case of very narrow resonance, the effect of scattering is to be more considerable factor. In the present study, we obtained energy dependent neutron absorption ratios of natural indium in energy region from 0.003 to 100 keV by MCNP-4B Code. The coefficients for neutron absorption was calculated for circular type and 1 mm thickness. In the lower energy region, neutron absorption is larger than higher region, because of large capture cross section (1/v). Furthermore it seems very different neutron absorption in the large resonance energy region. These results are very useful to decide the thickness of sample and shielding materials.

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태양 직달광 관측 자료로부터 포름알데히드 연직 농도 산출 시 흡수단면적이 미치는 영향 연구 (Investigation of Absorption Cross-Section Effects on the Formaldehyde Column Density Retrieval from Direct Sun Measurement)

  • 박경;박정현;이한림
    • 대한원격탐사학회지
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    • 제39권5_1호
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    • pp.551-561
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    • 2023
  • 본 연구에서는 Pandora spectrometer system의 태양 직달광 관측 자료로부터 차등흡수분광법(differential optical absorption spectroscopy, DOAS)을 이용하여 포름알데히드(formaldehyde)의 경사칼럼농도(slant column density, SCD)를 산출할 때 스펙트럼 피팅(spectrum fitting) 파장 구간 및 흡수단면적이 산출에 미치는 영향을 조사하였다. 2022년 10월 12일에서 31일까지 서울 연세대학교에서 관측한 Pandora Level 1 자료를 사용하였다. The second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2)에서 사용하는 스펙트럼 피팅 파장 구간을 포함한 8가지 범위 및 흡수단면적 구성 7종을 기반으로 포름알데히드 칼럼농도를 산출하였다. 스펙트럼 피팅 파장 구간은 8가지 범위 중 336.5-359.0 nm 구간에서 피팅 후 잔여 신호와 포름알데히드 산출 오차가 최소로 확인되었다. 흡수단면적 구성 7종 중 CINDI-2 캠페인에서 사용하는 흡수단면적에 이산화질소 흡수단면적(220 K)을 추가하여 사용한 경우에 피팅 후 잔여 신호와 포름알데히드 산출 오차가 가장 작았으며 포름알데히드 농도가 안정적으로 산출되었다. 산출 정확도가 가장 높은 경우의 평균 포름알데히드 경사칼럼농도와 그 외 조건들에서 산출된 값들은 최소 4%에서 최대 40%까지 차이를 보였다.

Calculating the Threshold Energy of the Pulsed Laser Sintering of Silver and Copper Nanoparticles

  • Lee, Changmin;Hahn, Jae W.
    • Journal of the Optical Society of Korea
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    • 제20권5호
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    • pp.601-606
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    • 2016
  • In this study, in order to analyze the low-temperature sintering process of silver and copper nanoparticles, we calculate their melting temperatures and surface melting temperatures with respect to particle size. For this calculation, we introduce the concept of mean-squared displacement of the atom proposed by Shi (1994). Using a parameter defined by the vibrational component of melting entropy, we readily obtained the surface and bulk melting temperatures of copper and silver nanoparticles. We also calculated the absorption cross-section of nanoparticles for variation in the wavelength of light. By using the calculated absorption cross-section of the nanoparticles at the melting temperature, we obtained the laser threshold energy for the sintering process with respect to particle size and wavelength of laser. We found that the absorption cross-section of silver nanoparticles has a resonant peak at a wavelength of close to 350 nm, yielding the lowest threshold energy. We calculated the intensity distribution around the nanoparticles using the finite-difference time-domain method and confirmed the resonant excitation of silver nanoparticles near the wavelength of the resonant peak.

Photophysical and Electrochmical Studies of N,N-Bis (2,5-di-tert-butylphenyl) - 3,4,9,10 perylenebis (dicarboximide) (DBPI)

  • El-Hallag, Ibrahim S.;El-Daly, Samy A.
    • Bulletin of the Korean Chemical Society
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    • 제31권4호
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    • pp.989-998
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    • 2010
  • The titled dye of DBPI gives amplified spontaneous emission (ASE) with maximum at 580 nm upon pumping by nitrogen laser (${\lambda}_{ex}\;=\;337.1\;nm$). The ground state absorption cross section (${\sigma}_A$) and emission cross section (${\sigma}_E$) as well as effective emission cross section(${\sigma}^*_E$) have been determined. The electronic absorption spectra of DBPI were measured in ethanol and tetrahydrofuran at room and low temperature. DBPI displays molecular aggregation in water. The photochemical reactivity of DBPI was also studied in carbon tetrachloride upon irradiation with 525 nm light. The electrochemical investigation of DBPI dye has been carried out using cyclic voltammetry and convolution deconvolution voltammetry combined with digital simulation technique at a platinum electrode in 0.1 mol/L tetrabutyl ammonium perchlorate (TBAP) in two different solvents acetonitrile ($CH_3CN$) and dimethylformamide (DMF). The species were reduced via consumption of two sequential electrons to form radical anion and dianion (EE mechanism). In switching the potential to positive direction, the compound was oxidized by loss of two sequential electrons, which were followed by a fast dimerization and/or aggregation process i.e $EC_{dim1}EC_{dim2}$ mechanism. The electrode reaction pathway and the chemical and electrochemical parameters of the investigated compound were determined using cyclic and convolutive voltammetry. The extracted electrochemical parameters were verified and confirmed via digital simulation method.

지상 기반 태양 UV 산란광 관측을 이용한 이산화황 경사칼럼농도 산출 시 파장 구간 및 흡수단면적에 따른 영향 조사 (Investigation of the Effects of Wavelength Range and Absorption Cross-Section on Sulfur Dioxide Slant Column Density Retrieval Using Ground-Based UV Scattered Sunlight Measurement)

  • 박경;공부주;김민지;이한림
    • 대한원격탐사학회지
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    • 제40권4호
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    • pp.377-385
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    • 2024
  • 본 연구에서는 차등흡수분광법(differential optical absorption spectroscopy)을 이용하여 지상 기반 태양 산란광 관측자료로부터 이산화황 경사칼럼농도(slant column density)를 산출할 때 다양한 피팅 파장 구간 및 흡수단면적이 미치는 영향을 확인하였다. 2023년 12월 1일부터 2024년 1월 23일까지 김해시에서 지상 기반 원격 관측 장비로 관측된 자료를 사용하여 선행 연구 기반의 피팅 파장 구간과 흡수단면적 각각 5가지 조건으로 이산화황 경사칼럼농도를 산출하였다. 5가지의 피팅 파장 구간 중 305.7-321.1 nm의 구간에서 피팅 후 잔여 신호와 이산화황 산출 오차를 고려한 산출 불확실성이 최소로 확인되었다. 흡수단면적의 경우 이산화황(293 K) 및 오존(223 K, 243 K) 흡수단면적을 사용하여 산출하는 조건의 피팅 후 잔여 신호와 산출 오차가 가장 작았다. 피팅 파장 구간 조사에 사용한 흡수단면적 기준과 4가지의 흡수단면적 조건으로 산출된 이산화황 경사층적분농도는 높은 상관성을 보였다.

RF 스텔스를 위한 밀리미터 RAM 개발 (Development of RAM in Millimeter Wave Range for RF Stealth)

  • 최창묵;임봉택;고광섭
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2009년도 춘계학술대회
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    • pp.555-558
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    • 2009
  • 본 논문은 상대방으로부터 탐지를 최소화시키는 스텔스 기술을 분석하고, 대부분의 레이더 반사 단면적 감소는 형상화로부터 기인되며, 특별한 부위에는 RAM을 이용하여 최소화 시키는 것을 확인하였다. 따라서 RF 스텔스를 위한 밀리미터파 대역의 레이더 반사 단면적을 최소화시키는 측면에서 94 GHz에서 전파흡수량 17 dB로 98 %를 흡수하는 RAM을 설계 및 제작하였다. 결과적으로 개발된 RAM을 플랫폼에 적용시 상대방으로부터 레이더 탐지거리를 62 % 축소시키는 효과를 얻을 수 있다.

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