The aim of this research is to obtain a basic quantitative understanding of the effect of a noncondensable gas on the absorption of water vapor by a $H_2O$ / LiBr combination with n-octanol as the surfactant. Nonflowing aqueous solutions of LiBr (40,45,50 mass%) were exposed to saturated water vapor following the addition of an n-octanol sufactant (0.01 and 0.6 mass%). A small amount of a noncondensable gas (air) was allowed into the absorber (0.03 volume%) and its effect was analyzed by measuring the amount of water vapor absorbed. This study will aid to predict the performance of heat pump and safety operating condition when the noncondensable gas is not allowed in the absorber The results indicate that, in the presence of small amounts of a noncondensable gas, vapor absorption enhancement ratios are less than half o( those obtained under the same experimental conditions when a noncondensable gas is not present (1). The presence of a noncondensable gas causes the partial vapor pressure of air to increase at the vapor / liquid interface, which results in an instability of vapor absorption rate nd. hence, in an inhibition of interfacial disturbance.
Air pollution associated with the $NO_x$ emission from the ship engines is becoming one of the major environmental concerns these days. As the regulations on ship pollutants are strengthened, the wet absorption method, for controlling complex pollutants in a confined space, has the advantage of simultaneously removing various pollutants, but the low solubility of nitrogen monoxide is drawback. In this study, for improving existing denitrification scrubber system, NO oxidation process by hydroxyl radical produced from irradiating UV light on $H_2O_2$ is suggested and the $H_2O_2$ decomposition rates and hydroxyl radical quantum yields were measured to find the optimum condition of $H_2O_2$ photolysis reaction. As a result, the optimum quantum yield and photolysis rate of $H_2O_2$ were 0.8798, $0.6mol\;h^{-1}$ at 8 W, 2 M condition, and oxidation efficiency of 1000 ppm NO gas was 40%. In batch system, NO removal efficiency has a range of 65.0 ~ 67.3% according to input gas concentration of 100 ~ 1500 ppm. This results indicate that the scrubber system using hydrogen peroxide photolysis can be applied as air pollution prevention facility of ship engines.
Korean Journal of Air-Conditioning and Refrigeration Engineering
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v.19
no.1
/
pp.94-131
/
2007
A review on the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering in 2004 and 2005 has been done. Focus has been put on current status of research in the aspect of heating, cooling, air-conditioning, ventilation, sanitation and building environment. The conclusions are as follows. (1) Most of fundamental studies on fluid flow were related with heat transportation of facilities. Drop formation and rivulet flow on solid surfaces were interesting topics related with condensation augmentation. Research on micro environment considering flow, heat, humidity was also interesting for comfortable living environment. It can be extended considering biological aspects. Development of fans and blowers of high performance and low noise were continuing topics. Well developed CFD and flow visualization(PIV, PTV and LDV methods) technologies were widely applied for developing facilities and their systems. (2) The research trends of the previous two yews are surveyed as groups of natural convection, forced convection, electronic cooling, heat transfer enhancement, frosting and defrosting, thermal properties, etc. New research topics introduced include natural convection heat transfer enhancement using nanofluid, supercritical cooling performance or oil miscibility of $CO_2$, enthalpy heat exchanger for heat recovery, heat transfer enhancement in a plate heat exchanger using fluid resonance. (3) The literature for the last two years($2004{\sim}2005$) is reviewed in the areas of heat pump, ice and water storage, cycle analysis and reused energy including geothermal, solar and unused energy). The research on cycle analysis and experiments for $CO_2$ was extensively carried out to replace the Ozone depleting and global warming refrigerants such as HFC and HCFC refrigerants. From the year of 2005, the Gas Engine Heat Pump(GHP) has been paid attention from the viewpoint of the gas cooling application. The heat pipe was focused on the performance improvement by the parametric analysis and the heat recovery applications. The storage systems were studied on the performance enhancement of the storage tank and cost analysis for heating and cooling applications. In the area of unused energy, the hybrid systems were extensively introduced and the life cycle cost analysis(LCCA) for the unused energy systems was also intensively carried out. (4) Recent studies of various refrigeration and air-conditioning systems have focused on the system performance and efficiency enhancement. Heat transfer characteristics during evaporation and condensation are investigated for several tube shapes and of alternative refrigerants including carbon dioxide. Efficiency of various compressors and expansion devices are also dealt with for better modeling and, in particular, performance improvement. Thermoelectric module and cooling systems are analyzed theoretically and experimentally. (5) According to the review of recent studies on ventilation systems, an appropriate ventilation systems including machenical and natural are required to satisfied the level of IAQ. Also, an recent studies on air-conditioning and absorption refrigeration systems, it has mainly focused on distribution and dehumidification of indoor air to improve the performance were carried out. (6) Based on a review of recent studies on indoor environment and building service systems, it is noticed that research issues have mainly focused on optimal thermal comfort, improvement of indoor air Quality and many innovative systems such as air-barrier type perimeter-less system with UFAC, radiant floor heating and cooling system and etc. New approaches are highlighted for improving indoor environmental condition as well as minimizing energy consumption, various activities of building control and operation strategy and energy performance analysis for economic evaluation.
Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
/
v.9
no.3
/
pp.121-129
/
2011
The effects of the applied current density, the $AgNO_3$ concentration, the scrubbing liquid flow rate and the NO-air mixed gas flow rate on the NO removal efficiency were investigated by using $Ag^{2+}$ mediated electrochemical oxidation (MEO). Results showed that the NO removal efficiency increased with increasing the applied current density. The effect of the $AgNO_3$ concentration on the NO removal efficiency was negligibly small in the concentration of $AgNO_3$ above 0.1 M. When the scrubbing liquid flow rate increased, the NO removal efficiency was gradually increased. On the other hands, the NO removal efficiency decreased with increasing the NO-air mixed gas flow rate. As a result of the treatment of NO-air mixed gas by using the MEO process with the optimum operating condition and the chemical absorption process using 3 M $HNO_3$ solution as a scrubbing liquid, the removal efficiency of NO and $NO_x$ was achieved as 95% and 63%, respectively.
To assess the wetland systems' capability to reduce fine dust, we used an artificial wetland module of small-sized greenhouse (70cm W × 70cm L × 60cm H) which creates a closed system. Experiment was performed twice using four species in each experiment. Non-plantation, one species, or two species condition was created in each mesocosm. We measured air quality, primarily PM2.5 and PM10 at the initial open mesocosms and 1hr later since mesocosms were closed. The dry weight of vegetation was measured at the 2nd experiment. The decreased amount of PM2.5 and PM10 was 13.7±1.3 and 13.2±1.3 ㎍·m-3hr-1 in wetland condition and 15.0±1.4 and 13.8±1.5 ㎍·m-3hr-1 in dryland condition, respectively. In 2nd experiment, the decreased amount of PM 2.5 and PM 10 in wetland condition was 13.7±1.3 and 9.2±1.5 ㎍·m-3hr-1, 15.0±1.4 and 8.8±1.4 ㎍·m-3hr-1 in dryland condition, respectively. Wetland showed higher removal effect due to its high productivity leading to more effective absorption of particulate matter. Furthermore, the aquatic characteristics of wetland system and high humidity helped purifying the air quality. This can be seen as another value of wetlands, which can be presented as one of the solutions to the problem of fine dust.
A method of measuring impulse response of acoustic system, two kinds of cross-correlation methods (the direct correlation method and the M-sequence modulation correlation method) were applied. According to the direct correlation method, by using stationary random noise source and by calculating the cross-correlation function between the sourece and the output signal, equivalent impulse response can be obtained not being influenced by the back ground noises. By applying this method, the measurement of echo-time patterns in rooms and oblique incident sound absorption characteristics of sound absorbing materials was carried out. In the case of the M-sequence modulation correlation method which was contrived by Aoshima, an intermittent random nosie modulated by M-sequence signal is used as the source signal, and the cross-correlation function between the M-sequence signal and the squared output signal is calculated. According to this method, equivalent energy impulse response (squared impulse response) of te propagation system can be obtained without being influenced by the back ground noises and the air fluctuation caused by wind. As the applcaition of this measuring method to the architectural acoustics, the meaurements of echo-time patterns, reverberation decays and sound pressure lev디 distributions in rooms and sound insulation efficiencies in buildings were carried out. From these experimental studies, it has been found that this M-sequence modulation correlation method is markedly useful especially for the field masurement of sound insulation under high back ground noise condition.
This study had a focus on investigating technical validity of Two-Lift Concrete Pavements which had never been constructed in Korea in order to olve the problem of existing concrete pavements. This study found out the application of Steel Fiber Reinforced Concrete (SFRC) which was one of ew techniques. Also, optimal steel fiber contents and pavement thickness were determined. This study also measured compressive strengths, lexural strengths, toughness indexes, tensile strengths and fatigue strengths to estimate the performance of SFRC of according to results of aboratory experiments, slumps and air contents of concrete specimens the standards satisfied and compressive strengths to open traffic. At bending ests, Toughness Index of SFRC increased but flexural strength didn’'t increase as compared with non-steel fiber concretes. And, energy absorption of SFRC was very good and SFRC showed improvement in freezing and thawing resistances. To complete this research, we will evaluate the pplication methods and performance of SFRC at field section.
Journal of Korean Society for Atmospheric Environment
/
v.34
no.4
/
pp.616-624
/
2018
In this study, a previous DNPH (2,4-dinitrophenylhydrazine) coupled with high performance liquid chromatography (HPLC) method to measure the concentration of formaldehyde in ambient and source environments has been improved. To improve the disadvantage of the previous HPLC method, an appropriate composition ratio of mobile phase (water: acetonitrile (ACN)) was determined and an isocratic analysis was conducted. Furthermore, limit of detection (LOD), limit of quantitation(LOQ), accuracy, and precision were investigated to verify the reliability of the analytical conditions determined. Finally, samples of exhaust gases from five different industrial facilities were applied to HPLC analytial method proposed to determine their formaldehyde concentrations. The appropriate composition ratio of the mobile phase under the isocratic condition was a mixture of water(40%) and ACN(60%). As the volume fraction of the organic solvent ACN increases, retention time of the formaldehyde peak was reduced. Detection time of formaldehyde peak determined using the proposed isocratic method was reduced from 7 minutes(previous HPLC method) to approximately 3 minutes. LOD, LOQ, accuracy, and precision of the formaldehyde determined using standard solutions were 0.787 ppm, 2.507 ppm, 93.1%, and 0.33%, respectively, all of which are within their recommended ranges. Average concentrations of the formaldehyde in five exhaust gases ranged from 0.054 ppm to 1.159 ppm. The lowest concentration (0.054 ppm) was found at samples from waste gas incinerator in a bisphenol-A manufacturing plant. The highest was observed at samples from the absorption process in manufacturing facilities of chemicals including formaldehyde and hexamine. The analytical time of the formaldehyde in ambient air can be shortened by using the isocratic analytical method under appropriate mobile phase conditions.
Proceedings of the Korean Society for Noise and Vibration Engineering Conference
/
2003.05a
/
pp.802-807
/
2003
International Convention Center Jeju(ICCJ) was planed and built for accommodating a variety of conventional and exhibitional activities. For a better flexibility of operation, almost all rooms in ICCJ are designed to be subdivided Into a couple of small rooms with installation of movable partition walls. Architectural and acoustical design should be deliberatively and cooperatively undertaken to cope with such a complex condition. Conference hall, the largest room in ICCJ, has a capacity of 5000 seats who:1 used as a whole. It could be divided into 3 halls, one with 2000 pre-installed seats on slanted floor, up/down removable stage and its settings above, and the other 2 flat rooms with no seats installed. A devided hall with pre-installed seats and stage is designed for a multi-use auditorium. Almost all surfaces except ceilings adjacent to the stage are sound absorptively treated, in regard to extensive use of sound reinforcement systems. Its reverberation time 1.65 sec without audience, which is roughly correspond to 1.50 sec with fully occupied audience. When there is a need for a larger room, all the partition wail Is removed and the hall could be used as a whole. Exhibition hall is located in the first floor of ICCJ. Absorption and softness are needed for the hat 1 because exhibition behavior has something noisy features. Perforated MDF panels with porous materials and air space in the back groundare adopted for the walls. There are one large, two medium, and several small convention rooms in ICJJ. The room are also acoustically designed for maximum flexibility with no defects soundwisely.
Park, Byoung-Jun;Kim, Hyun-Suk;Cho, Kyoung-Ah;Kim, Jin-Hyong;Lee, Joon-Woo;Kim, Sang-Sig
Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
/
2004.07a
/
pp.56-59
/
2004
HgTe and HgTe/CdTe core-shell structured nanocrystals(NCs) were synthesized in aqueous solution by colloidal method. HgTe and HgTe/CdTe NCs structure showed very similar XRD patterns because of the same lattice constant and crystal structure of both samples. The absorption and photoluminescence(PL) spectrum of the synthesized HgTe NCs revealed the strong exitonic peak in the IR region. The PL spectrum of HgTe/CdTe NCs have the intense peak in about 700nm shorter than that of HgTe by 400nm. The photocurrent measurement of colloidal NCs are performed using He-Ne laser for light source. The photocurrent of HgTe NCs shows the instant increased current response to light, but HgTe/CdTe NCs revealed a decreased current when lighted to the sample. In the vacuum condition, it shows reverse result that current increased under the illumination of light and it is thought that the molecules like the hydro-oxygen gas in the air give an important effect on the current mechanism.
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