• Title/Summary/Keyword: Absorption Properties

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Studies on the Manufacture of Fiber Pot and its Effect for the Good Transplanting (이식용(移植用)Pot의 제조(製造) 및 그 효과(効果)에 관(關)한 연구(硏究))

  • Kim, Ji Moon;Lee, Hwa Hyung;Kwon, Ki Won;Song, Ho Kyong
    • Journal of Korean Society of Forest Science
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    • v.46 no.1
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    • pp.1-9
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    • 1980
  • This study was carried out to examine the substitution possibility into fiber pot instead of Jiffy pot for the good transplanting. Fiber pot was made of fiber, wood waste particle, and bark powder (10% of the particle weight) and also latex was added into the furnish as a binder. The pots were sprayed with just enough urea solution to prevent nitrogen deficiency of pot media coming from the breakdown of wood fiber in the pot wan during the plant growing. The utility of fiber pot was compared with that of Jiffy pot in the service test of two tree species under a green-house condition. The results obtained can be summarized as follows ; 1. Fiber pot made of 30% wood fiber+70% particle including 10% of bark powder, and 3%-latex has shown a good results like that of Jiffy pot in the sp. gr., tear factor and burst factor. For water absorption, fiber pot made of 50% fiber+50% particle, and 3%-latex got the best result. In the consideration of the above physical and mechanical properties of the fiber pot for good root penetration through the pot wall and facile handling, fiber pot made of 30% fiber+70% particle, and 3%-latex may be seemed to be good. 2. There were no harms in sapling growth in fiber pot as well as in Jiffy pot. The root penetration ability through the fiber pot was slightly inferior to that of Jiffy pot, and yet the pot damage through transportation seemed to be slighter in fiber pot than in Jiffy pot.

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Effect of Solvent Doping and Post-Treatment on the Characteristics of PEDOT : PSS Conducting Polymer (솔벤트 도핑과 후처리 공정에 따른 전도성 고분자 PEDOT : PSS의 특성 변화)

  • Kim, Jin Hee;Seo, Yoon Kyung;Han, Joo Won;Oh, Ji Yoon;Kim, Yong Hyun
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.275-279
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    • 2015
  • Poly(3,4-ethylenedioxythiophene) : poly(styrenesulfonate) (PEDOT : PSS) has attracted a great deal of attention as a transparent conductive material for organic solar cells or organic light-emitting diodes due to its high electrical conductivity, optical transparency, and excellent mechanical flexibility. It is well known that a solvent doping for PEDOT : PSS thin-films significantly increases the conductivity of films. In this paper, the effect of various kinds of solvent doping and post-treatment on the electrical and structural properties of PEDOT : PSS thin-films is investigated. The solvent doping greatly increases the conductivity of PEDOT : PSS thin-films up to 884 S/cm. A further enhancement of the conductivity of PEDOT : PSS thin-films is achieved by the solvent post-treatment which raises the conductivity up to 1131 S/cm. The enhancement is mainly caused by the depletion of insulating PSS and forming conducting PEDOT-rich granular networks. Strong optical absorption peaks at the wavelength of 225 nm of PEDOT : PSS thin-films indicate the depletion of insulating PSS by post-treatment. We believe that the solvent post-treatment is a promising method to achieve highly conductive transparent PEDOT : PSS thin-films for applications in efficient, low-cost and flexible organic devices.

Synthesis and Photovoltaic Properties of a Low Band Gap Polymer for Organic Solar Cell (유기태양전지를 위한 작은 밴드갭 고분자의 합성과 광전특성)

  • Woo, Yong-Ho;Lee, Hyo-Sang;Park, Sungnam;Choi, E-Joon;Kim, BongSoo
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.71-77
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    • 2015
  • We synthesized a low band gap alternating copolymer containing electron-rich units (i.e. dithienosiloles and benzodithiophenes) and electron-deficient units (i.e. difluorobenzothiadiazoles) for high performance organic solar cells. The polymer was prepared by the Stille coupling reaction and characterized using $^1H$ NMR, GPC, TGA, UV-visible absorption spectroscopy, and cyclic voltammetry. Solar cells were fabricated in a structure of ITO/PEDOT:PSS/polymer: $PC_{70}BM/Al$ with five different blending ratios of polymer and $PC_{70}BM$ (1:1.5, 1:2, 1:3, 1:3.5 and 1:4 by weight ratio). The best efficiency was achieved from the 1:3 ratio of polymer and $PC_{70}BM$ in the photoactive layer, and TEM revealed that there is an optimal nanoscale phase separation between polymer and $PC_{70}BM$ in the 1:3 ratio blend film.

Verification of CDOM Algorithms Based on Ocean Color Remote Sensing Data in the East Sea (동해에서 해색센서를 이용한 CDOM추정 알고리즘 검증)

  • Kim, Yun-Jung;Kim, Hyun-Cheol;Son, Young-Baek;Park, Mi-Ok;Shin, Woo-Chur;Kang, Sung-Won;Rho, Tae-Keun
    • Korean Journal of Remote Sensing
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    • v.28 no.4
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    • pp.421-434
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    • 2012
  • Colored Dissolved Organic Matter (CDOM) is one of the important components of optical properties of seawater to determine ecosystem dynamics in a given marine area. The optical characteristics of CDOM may depend on the various ecosystem and environmental variables in the sea and those variables may vary region to region. Therefore, the retrieval algorithm for determining light absorption coefficient of CDOM ($a_{CDOM}$) using satellite remote sensing reflectance ($R_{rs}$) developed from other region may not be directly applicable to the other region, and it must be validated using an in-situ ground-truth observation. We have tested 6 known CDOM algorithms (three Semi-analytical and three Empirical CDOM algorithms) developed from other regions of the world ocean with laboratory determined in-situ values for the East Sea using field data collected during seven oceanographic cruises in the period of 2009~2011. Our field measurements extended from the coastal waters to the open oceanic type CASE-1 Waters. Our study showed that Quasi-Analytical Algorithm (QAA_v5) derived $a_{CDOM}$(412) appears to match in-situ $a_{CDOM}$(412) values statistically. Semi-analytical algorithms appeared to underestimate and empirical ones overestimated $a_{CDOM}$ in the East Sea. $a_{CDOM}$(412) value was found to be relatively high in the relatively high satellite derived-chlorophyll-a area. $a_{CDOM}$(412) value appears to be influenced by the amount of chlorophyll-a in seawater. The outcome of this work may be referenced to develop $a_{CDOM}$ algorithm for the new Korean Geostationary Ocean Color Imager (GOCI).

UVB-Shielding Effects of para-Coumaric Acid (파라-쿠마린산의 자외선B 차단 효과)

  • Song, Kyo-Sun;Boo, Yong-Chool
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.3
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    • pp.263-273
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    • 2012
  • Recent studies have uncovered attractive properties of para-coumaric acid (PCA) as a potential skin hywhitening agent. The purpose of the current study was to examine its UVB-shielding effects. Effects of PCA on the viability of HaCaT cells exposed to UVB were assessed in vitro in comparison with other aromatic amino acid metabolites that have similar UV absorption spectra. For in vivo test, PCA cream (1.5 %) and cream base were topically applied to the dorsal skin of SKH-1 hairless mice and the inflammatory responses due to UVB exposure were monitored by changes in skin color (erythema) and thickness (edema). The cream application-UVB exposure regimen was repeated every other day for a total of 12 sessions. When HaCaT cells were irradiated with UVB, there was a dose-dependent decline in cell viability. The cell viability decline due to UVB exposure (10 mJ $cm^{-2}$) was significantly prevented by 100 ${\mu}M$ PCA, cinnamic acid, urocanic acid, or indole acrylic acid by 39, 27, 39, or 31 %, respectively. Topical application of PCA cream onto the dorsal skin of hairless mice (10 ${\mu}g\;cm^{-2}$) attenuated the changes of color parameters, $L^*$, $a^*$, $b^*$ values, and thickness of the UVB (150 mJ $cm^{-2}$)-exposed skin by 59, 50, 58, and 53 %, respectively. The current study, together with the previous studies that demonstrated the antimelanogenic effects of PCA, suggested that PCA may prevent not only dyspigmentation but also inflammatory reactions in the UVB-exposed skin.

Fabrication of Schottky Device Using Lead Sulfide Colloidal Quantum Dot

  • Kim, Jun-Kwan;Song, Jung-Hoon;An, Hye-Jin;Choi, Hye-Kyoung;Jeong, So-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.189-189
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    • 2012
  • Lead sulfide (PbS) nanocrystal quantum dots (NQDs) are promising materials for various optoelectronic devices, especially solar cells, because of their tunability of the optical band-gap controlled by adjusting the diameter of NQDs. PbS is a IV-VI semiconductor enabling infrared-absorption and it can be synthesized using solution process methods. A wide choice of the diameter of PbS NQDs is also a benefit to achieve the quantum confinement regime due to its large Bohr exciton radius (20 nm). To exploit these desirable properties, many research groups have intensively studied to apply for the photovoltaic devices. There are several essential requirements to fabricate the efficient NQDs-based solar cell. First of all, highly confined PbS QDs should be synthesized resulting in a narrow peak with a small full width-half maximum value at the first exciton transition observed in UV-Vis absorbance and photoluminescence spectra. In other words, the size-uniformity of NQDs ought to secure under 5%. Second, PbS NQDs should be assembled carefully in order to enhance the electronic coupling between adjacent NQDs by controlling the inter-QDs distance. Finally, appropriate structure for the photovoltaic device is the key issue to extract the photo-generated carriers from light-absorbing layer in solar cell. In this step, workfunction and Fermi energy difference could be precisely considered for Schottky and hetero junction device, respectively. In this presentation, we introduce the strategy to obtain high performance solar cell fabricated using PbS NQDs below the size of the Bohr radius. The PbS NQDs with various diameters were synthesized using methods established by Hines with a few modifications. PbS NQDs solids were assembled using layer-by-layer spin-coating method. Subsequent ligand-exchange was carried out using 1,2-ethanedithiol (EDT) to reduce inter-NQDs distance. Finally, Schottky junction solar cells were fabricated on ITO-coated glass and 150 nm-thick Al was deposited on the top of PbS NQDs solids as a top electrode using thermal evaporation technique. To evaluate the solar cell performance, current-voltage (I-V) measurement were performed under AM 1.5G solar spectrum at 1 sun intensity. As a result, we could achieve the power conversion efficiency of 3.33% at Schottky junction solar cell. This result indicates that high performance solar cell is successfully fabricated by optimizing the all steps as mentioned above in this work.

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Synthesis, Structure and Characterization of Nd2XCd2-3XSiO4 (0.01≤X≤0.21) Solid-Solutions (Nd2XCd2-3XSiO4 (0.01≤X≤0.21) 고용체의 합성과 구조 규명)

  • Ramesh, S.;Das, B.B.
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.502-508
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    • 2011
  • Synthesis of $Nd_{2x}Cd_{2-3x}SiO_4$ ($0.01{\leq}x{\leq}0.21$) [S1-S3: x=0.01, 0.11 and 0.21] solid solutions were prepared by solgel method. Powder x-ray diffraction (XRD) results show monoclinic unit cell with space group P21/m. The average crystallite sizes are found to be 20 to 45 nm. The Scanning Electron Microcopy (SEM) images show morphology of the sample is in globular nature. The energy dispersive analysis of x-rays (EDX) and X-ray mapping results confirmed that all the constituent elements of the composites were present and that were distributed in uniformly. The optical absorption band at ~750 nm was due to $^4I_{9/2}{\rightarrow}^4F_{7/2}+^4S_{3/2}$ transition optically active $Nd^{3+}$ ions. Electron Paramagnetic Resonance (EPR) lineshapes of S1-S3 at 10, 40, 77 and 300 K show a broad unresolved isotropic lineshapes were observed due to rapid spin lattice relaxation of $Nd^{3+}$.

Synthesis of Borosilicate Zeotypes by Steam-assisted Conversion Method (수증기 쪼임법에 의한 제올라이트형 보로실리케이트 제조방법)

  • Mansour, R.;Lafjah, M.;Djafri, F.;Bengueddach, A.
    • Journal of the Korean Chemical Society
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    • v.51 no.2
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    • pp.178-185
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    • 2007
  • Intermediate pentasil borosilicate zeolite-like materials have been crystallized by a novel method named steam-assisted conversion, which involves vapor-phase transport of water. Indeed, amorphous powders obtained by drying Na2O.SiO2.B2O3.TBA2O gels of various compositions using different boron sources are transformed into crystalline borosilicate zeolite belonging to pentasil family structure by contact with vapors of water under hydrothermal conditions. Using a variant of this method, a new material which has an intermediate structure of MFI/MEL in the ratio 90:10 was crystallized. The results show that steam and sufficiently high pH in the reacting hydrous solid are necessary for the crystallization to proceed. Characterization of the products shows some specific structural aspects which may have its unique catalytic properties. X-ray diffraction patterns of these microporous crystalline borosilicates are subjected to investigation, then, it is shown that the product structure has good crystallinity and is interpreted in terms of regular stacking of pentasil layers correlated by inversion centers (MFI structure) but interrupted by faults consisting of mirror-related layers (MEL structure). The products are also characterized by nitrogen adsorption at 77 K that shows higher microporous volume (0.160 cc/g) than that of pure MFI phase (0.119 cc/g). The obtained materials revealed high surface area (~600 m2/g). The infrared spectrum reveals the presence of an absorption band at 900.75 cm-1 indicating the incorporation of boron in tetrahedral sites in the silicate matrix of the crystalline phase.

Engineering Properties of Synthetic Lightweight Aggregate Concrete Affected by Alkali-Silica Reaction (알카리-실리카 반응(反應)에 의한 인공경량골재(人工輕量骨材)콘크리트의 공학적(工學的) 성질(性質))

  • Sung, Chan Yong
    • Korean Journal of Agricultural Science
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    • v.18 no.1
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    • pp.33-40
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    • 1991
  • This study was performed to obtain the basic data applied to use of synthetic lightweight aggregate concrete affected by alkali silica reaction. The results obtained were summarized as follows; 1. The compressive strength of type A concrete was increased with increase of curing age. At the curing age 28 days, the highest compressive strength was showed at type Band C concrete, respectively. But, it was gradually decreased with increase of curing age at those concrete. 2. The flexural strength of type A concrete was increased with increase of curing age. At the curing age 14 days, the highest flexural strength was showed at type Band C concrete, respectively. But, it was gradually decreased with increase of curing age at those concrete. 3. The correlation between compressive and flexural strength of the sample was shown highly significant only at type A concrete. 4. It was shown that the water absorptions of the type Band C were 7.0-7.8 times higher than the type A concrete. It was significantly higher at the early stage of immersed time at all sample. 5. The correlation between compressive strength and water absorption of the sample was significant only at the type A concrete.

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A Preprocessing Method for Ground-Penetrating-Radar based Land-mine Detection System (지면 투과 레이더(GPR) 기반의 지뢰 탐지 시스템을 위한 표적 후보 검출 기법)

  • Kong, Hae Jung;Kim, Seong Dae;Kim, Minju;Han, Seung Hoon
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.4
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    • pp.171-181
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    • 2013
  • Recently, ground penetrating radar(GPR) has been widely used in detecting metallic and nonmetallic buried landmines and a number of related researches have been reported. A novel preprocessing method is proposed in this paper to flag potential locations of buried mine-like objects from GPR array measurements. GPR operates by measuring the reflection of an electromagnetic pulse from discontinuities in subsurface dielectric properties. As the GPR pulse propagates in the geologic medium, it suffers nonlinear attenuation as the result of absorption and dispersion, besides spherical divergence. In the proposed algorithm, a logarithmic transformed regression model which successfully represents the time-varying signal amplitude of the GPR data is estimated at first. Then, background signals may be densely distributed near the regression model and candidate signals of targets may be far away from the regression model in the time-amplitude space. Based on the observation, GPR signals are decomposed into candidate signals of targets and background signals using residuals computed from the estimated value by regression and the measurement of GPR. Candidate signals which may contain target signals and noise signals need to be refined. Finally, targets are detected through the refinement of candidate signals based on geometric signatures of mine-like objects. Our algorithm is evaluated using real GPR data obtained from indoor controlled environment and the experimental results demonstrate remarkable performance of our mine-like object detection method.