• Bulletin of the Korean Chemical Society
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• 제21권6호
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• pp.588-594
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• 2000

Structural changes of an iron phthalocyanine (FePC) monolayer induced by adsorption and externally applied potential on high area carbon surface have been investigated in situ by iron K-edge X-ray absorption fine structure (XAFS) in 0.5 M $H_2S0_4.$ Fine structures shown in the X-ray absorption near edge structure (XANES) for microcrystalline FePC decreased upon adsorption and further diminished under electrochemical conditions. Fe(II)PC(-2) showed a 1s ${\rightarrow}$ 4p transition as poorly resolved shoulder to the main absorption edge rather than a distinct peak and a weak 1s ${\rightarrow}$ 3d transition. The absorption edge position measured at half maximum was shifted from 7121.8 eV for Fe(lI)PC(-2) to 7124.8 eV for $[Fe(III)PC(-2)]^+$ as well as the 1s ${\rightarrow}$ 3d pre-edge peak being slightly enhanced. However, essentially no absorption edge shift was observed by the 1-electron reduction of Fe(Il)PC(-2), indicating that the species formed is $[Fe(II)PC(-3)]^-$. Structural parameters were obtained by analyzing extended X-ray absorption fine structure (EXAFS) oscillations with theoretical phases and amplitudes calculated from FEFF 6.01 using multiple-scattering theory. When applied to the powder FePC, the average iron-to-phthalocyanine nitrogen distance, d(Fe-$N_p$) and the coordination number were found to be 1.933 $\AA$ and 3.2, respectively, and these values are the same, within experimental error, as those reported ( $1.927\AA$ and 4). Virtually no structural changes were found upon adsorption except for the increased Debye-Wailer factor of $0.005\AA^2$ from $0.003\AA^2.$ Oxidation of Fe(II)PC(-2) to $[Fe(III)PC(-2)]^+$ yielded an increased d(Fe-Np) (1 $.98\AA)$ and Debye-Wailer factor $(0.005\AA^2).$ The formation of $[Fe(II)PC(-3)]^-$, however, produced a shorter d(Fe-$N_p$) of $1.91\AA$ the same as that of crystalline FePC within experimental error, and about the same DebyeWaller $factor(0.006\AA^2)$.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2007년도 춘계학술대회논문집
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• pp.51-55
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• 2007

In this paper Statistical Energy Analysis has been considered to predict high frequency air borne interior noise. Dash panel Insulation is major part to reduce engine excitation noise. Transmission loss and absorption coefficient are considered to predict dash insulation performance. Transmission lose is derived from coupling loss factor and absorption coefficient is derived from internal damping loss factor. Material Biot properties were used to calculate each loss factors. Insulation geometry thickness distribution was hard to measure, so FeGate software was used to calculate thickness map from CAD drawing. Each predicted transmission losses between conventional insulation and light weight insulation were compared with SEA. Transmission loss measurement was performed to validate each prediction result, and it showed good correlation between prediction and measurement. Finally interior noise prediction was performed and result showed light weight insulation system can reduce 40% weight to keep similar performance with conventional insulation system, even though light weigh insulation system has lower sound transmission loss and higher absorption coefficient than conventional system.

• 반도체디스플레이기술학회지
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• 제9권4호
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• pp.67-70
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• 2010

X-ray absorption rate and multiplication factor of X-ray detector were calculated with Garfield code. High Z (= atomic number) was important factor to increase the absorption rate but low Z is also important to increase the multiplication. Five different gas composition were examined under the condition of 1400 V bias and 400 um gap. Xe 100% gas showed the highest absorption rate and He 96% + isobutene 4% showed the highest multiplication.

• 한국세라믹학회지
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• 제25권1호
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• pp.1-6
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• 1988

The IR edge absorption of the important pure components of ZrF4-based glasses, including two previously uncharacterized components(ZrF4 and AlF3), has been measured. Values of the glass IR edge absorption coefficients have been calculated from these results, assuming additivity, and are compared with experimental glass absorption coefficients. The calculated ${\alpha}$ values are about a factor of two lower than the experimental values for ZrF4-based glasses, and the ZrF4 makes the largest contribution to the calculated ${\alpha}$ value.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2001년도 춘계학술대회논문집
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• pp.65-71
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• 2001

Absorbers such as porous materials and panels have limited absorption characteristics to some frequency bands. There is a need for absorbers with high absorption coefficients in a wide frequency ranges to make good response of room acoustics. This is almost impossible for a single absorption material. Composite absorption structure with cover, porous material. and air gap is known to have those wide frequency characteristics. In this basis. various composite absorption structures are measured and investigated as wide range absorption structures. Measurements are performed according to an international standard, ISO 354. Various surface types such as wooden slits, wood/steel perforated panels are selected as surface covers, and also various porous materials such as polyurethanes, polyesters, and glasswools are used inside the covers. Result shows that the area of void parts of surface materials is critical to high frequency absorptions, and thickness of air gaps are critical factor of the peak absorptions of low frequency bands.

• 한국지진공학회논문집
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• 제27권1호
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• pp.69-75
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• 2023

In Korea, most nuclear power plants were designed based on the design response spectrum of Regulatory Guide 1.60 of the NRC. However, in the case of earthquakes occurring in the country, the characteristics of seismic motions in Korea and the design response spectrum differed. The seismic motion in Korea had a higher spectral acceleration in the high-frequency range compared to the design response spectrum. The seismic capacity may be reduced when evaluating the seismic performance of the equipment with high-frequency earthquakes compared with what is evaluated by the design response spectrum for the equipment with a high natural frequency. Therefore, EPRI proposed the inelastic energy absorption factor for the equipment anchorage. In this study, the seismic performance of welding anchorage was evaluated by considering domestic seismic characteristics and EPRI's inelastic energy absorption factor. In order to reflect the characteristics of domestic earthquakes, the uniform hazard response spectrum (UHRS) of Uljin was used. Moreover, the seismic performance of the equipment was evaluated with a design response spectrum of R.G.1.60 and a uniform hazard response spectrum (UHRS) as seismic inputs. As a result, it was confirmed that the seismic performance of the weld anchorage could be increased when the inelastic energy absorption factor is used. Also, a comparative analysis was performed on the seismic capacity of the anchorage of equipment by the welding and the extended bolt.

• E2M - 전기 전자와 첨단 소재
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• 제7권6호
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• pp.520-526
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• 1994

A rectifying heterojunction consisting of polyparaphenylene(PPP) and polypyrrole(PPY) films was prepared by the electrochemical method. The photoresponse in the heterojunction of PPY and PPP is similar to the absorption spectrum of undoped PPP. This fact suggests that photoresponse depends strongly upon polyparaphenylene of semiconductor. The fill-factor was calculated from the photo current-voltage curve to be 0.19, which is relatively small compared to polyacetylene-polythiophene heterojunctions.

• 한국음향학회지
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• 제40권6호
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• pp.649-659
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• 2021

벽면 흡음 처리는 잔향의 제어에는 효과적이나, 잔향이 큰 공간의 경우에는 넓은 면적에 대한 적용이 필요하며, 각 벽면의 흡음은 음성 명료도에 다르게 영향을 미친다. 본 연구에서는 실내 음성 명료도의 관점에서 빔포밍 수음장치에 대한 잔향 제어를 위해 흡음 처리가 가장 효과적인 벽을 선택하는 모사 방법을 제안한다. 고정된 위치의 빔포밍 수음어레이에 대해, 화자 혹은 스피커에서 방출된 음향이 각 벽면과 충돌하는 변수를 이용해 벽면 중요도 계수를 정의하고, 이를 이용해 흡음 처리에 따른 수음부의 음성개선 효과를 예측하는 방법을 제시했다. 검증을 위해 체적이 107 m³, 잔향 시간이 1.1 s인 직육면체형 실내공간에 대해 모사 실험을 진행했다. 중요도 계수가 가장 높은 벽면에 헬름홀츠 흡음기를 적용할 때 수정된 음성 명료도는 500 Hz, 1 kHz에서 각각 5.1 dB와 4.8 dB, 또 음성전달 지수는 0.06만큼의 향상이 예측되었는데, 이는 상용코드의 계산 결과와 차이인지 역치(Just-Noticeable Difference, JND) 이내의 차이로 일치했다. 분석결과, 벽면 중요도가 가장 높은 곳에 흡음 처리한 결과는 면적이 가장 넓은 천장에 같은 흡음률을 적용할 때보다 음성 명료도 지수가 JND 이상으로 더 개선되는 것을 알 수 있었다.

• 한국방사선학회논문지
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• 제3권3호
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• pp.23-25
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• 2009

Gd-157 material has very large neutron capture cross section in the thermal region. So it is very useful to shield material for thermal neutrons. Futhermore, in the neutron capture experiment and calculation, the neutron absorption and scattering are very important. Especially these effects are conspicuous in the resonance energy region and below the thermal energy region. In the case of very narrow resonance, the effect of scattering is to be more considerable factor. In the present study, we obtained energy dependent neutron absorption ratios of natural indium in energy region from 0.003 to 100 keV by MCNP-4B Code. The coefficients for neutron absorption was calculated for circular type and 1 mm thickness. In the lower energy region, neutron absorption is larger than higher region, because of large capture cross section (1/v). Furthermore it seems very different neutron absorption in the large resonance energy region. These results are very useful to decide the thickness of sample and shielding materials.

• 청정기술
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• 제9권1호
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• pp.43-48
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• 2003

As a result of study on factor affecting absorption efficiency using the structured packing, Mellapak N. 250Y for the chemical absorption of $CO_2$ that cause global warming due to development of industry, it is shown that Mellapak N. 250Y has lower pressure drop and superior efficiency of mass transfer than 25mm Pall ring. Also, in the absorption process, it produces high efficiency in the increase of load and concentration of absorption liquid and produces low efficiency in the increase of temperature. In the effect of overall mass transfer coefficient for 15% MEA on the temperature variation of absorbent, when absorbent temperature for 15% MEA varied as 25, 50, $80^{\circ}C$, overall mass transfer coefficients were shown as 0.83, 1.00, $0.90kmol/m^3-h-kPa$.