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Evaluation of Amino Acid and Energy Utilization in Feedstuff for Swine and Poultry Diets

  • Kong, C.;Adeola, O.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.7
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    • pp.917-925
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    • 2014
  • An accurate feed formulation is essential for optimizing feed efficiency and minimizing feed cost for swine and poultry production. Because energy and amino acid (AA) account for the major cost of swine and poultry diets, a precise determination of the availability of energy and AA in feedstuffs is essential for accurate diet formulations. Therefore, the methodology for determining the availability of energy and AA should be carefully selected. The total collection and index methods are 2 major procedures for estimating the availability of energy and AA in feedstuffs for swine and poultry diets. The total collection method is based on the laborious production of quantitative records of feed intake and output, whereas the index method can avoid the laborious work, but greatly relies on accurate chemical analysis of index compound. The direct method, in which the test feedstuff in a diet is the sole source of the component of interest, is widely used to determine the digestibility of nutritional components in feedstuffs. In some cases, however, it may be necessary to formulate a basal diet and a test diet in which a portion of the basal diet is replaced by the feed ingredient to be tested because of poor palatability and low level of the interested component in the test ingredients. For the digestibility of AA, due to the confounding effect on AA composition of protein in feces by microorganisms in the hind gut, ileal digestibility rather than fecal digestibility has been preferred as the reliable method for estimating AA digestibility. Depending on the contribution of ileal endogenous AA losses in the ileal digestibility calculation, ileal digestibility estimates can be expressed as apparent, standardized, and true ileal digestibility, and are usually determined using the ileal cannulation method for pigs and the slaughter method for poultry. Among these digestibility estimates, the standardized ileal AA digestibility that corrects apparent ileal digestibility for basal endogenous AA losses, provides appropriate information for the formulation of swine and poultry diets. The total quantity of energy in feedstuffs can be partitioned into different components including gross energy (GE), digestible energy (DE), metabolizable energy (ME), and net energy based on the consideration of sequential energy losses during digestion and metabolism from GE in feeds. For swine, the total collection method is suggested for determining DE and ME in feedstuffs whereas for poultry the classical ME assay and the precision-fed method are applicable. Further investigation for the utilization of ME may be conducted by measuring either heat production or energy retention using indirect calorimetry or comparative slaughter method, respectively. This review provides information on the methodology used to determine accurate estimates of AA and energy availability for formulating swine and poultry diets.

Effects of Temperature during Moist Heat Treatment on Ruminal Degradability and Intestinal Digestibility of Protein and Amino Acids in Hempseed Cake

  • Karlsson, Linda;Ruiz-Moreno, M.;Stern, M.D.;Martinsson, K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.11
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    • pp.1559-1567
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    • 2012
  • The objective of this study was to evaluate ruminal degradability and intestinal digestibility of crude protein (CP) and amino acids (AA) in hempseed cake (HC) that were moist heat treated at different temperatures. Samples of cold-pressed HC were autoclaved for 30 min at 110, 120 or $130^{\circ}C$, and a sample of untreated HC was used as the control. Ruminal degradability of CP was estimated, using the in situ Dacron bag technique; intestinal CP digestibility was estimated for the 16 h in situ residue using a three-step in vitro procedure. AA content was determined for the HC samples (heat treated and untreated) of the intact feed, the 16 h in situ residue and the residue after the three-step procedure. There was a linear increase in RUP (p = 0.001) and intestinal digestibility of RUP (p = 0.003) with increasing temperature during heat treatment. The $130^{\circ}C$ treatment increased RUP from 259 to 629 g/kg CP, while intestinal digestibility increased from 176 to 730 g/kg RUP, compared to the control. Hence, the intestinal available dietary CP increased more than eight times. Increasing temperatures during heat treatment resulted in linear decreases in ruminal degradability of total AA (p = 0.006) and individual AA (p<0.05) and an increase in intestinal digestibility that could be explained both by a linear and a quadratic model for total AA and most individual AA (p<0.05). The $130^{\circ}C$ treatment decreased ruminal degradability of total AA from 837 to 471 g/kg, while intestinal digestibility increased from 267 to 813 g/kg of rumen undegradable AA, compared with the control. There were differences between ruminal AA degradability and between intestinal AA digestibility within all individual HC treatments (p<0.001). It is concluded that moist heat treatment at $130^{\circ}C$ did not overprotect the CP of HC and could be used to shift the site of CP and AA digestion from the rumen to the small intestine. This may increase the value of HC as a protein supplement for ruminants.

Complementary Relationship Based Evaportranspiration Estimation Model Suitable for the Hancheon and Kangjeongcheon Watersheds in Jeju Island (제주 한천 및 강정천 유역에 적합한 보완관계법 기반 증발산량 산정 모형)

  • Kim, Nam Won;Nah, Hanna;Lee, Jeongwoo;Lee, Jeong Eun
    • Journal of Korea Water Resources Association
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    • v.47 no.12
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    • pp.1155-1163
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    • 2014
  • The complementary relationship-based evapotranspiration models, namely, AA model of Brutsaert and Stricker (1979) and the CRAE model of Morton (1983) was applied to two permanent stream watersheds Jeju island for the first time, and their major optimal parameters were suggested in this study. The representative watersheds for model calibration and validation were selected as the Hancheon watershed located in the northern part of the Jeju island and and the Kangjeongcheon watershed in southern Jeju island, respectively. The estimated actual evapotranspiration for the Hancheon watershed was compared with the result by the hydrological model, and the major parameters of the AA and CRAE models were calibrated until their results match the hydrological simulations. Through the iterative estimations, the optimal parameters were determined as ${\alpha}=1.00$, $M=30.0Wm^{-2}$ of the AA model, and $b_1=33.0Wm^{-2}$, $b_2=1.02$ of the CRAE model. The calibrated AA and CRAE models were applied to the Kangjeongcheon watershed for model validation, and it was found out that both models can accurately produce the actual evaporation on annual and semiannual bases.

The Crystal Structure of Nicotine Dihydroiodide (Nicotine Dihydroiodide의 結晶構造)

  • Koo, Chung-Hoe;Kim, Hoon-Sup
    • Journal of the Korean Chemical Society
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    • v.9 no.3
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    • pp.134-141
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    • 1965
  • Crystals of nicotine dihydroiodide, are orthorhombic with space group $p2_12_12_1$.The unit cell of dimensions a=7.61, b=11.01, e=17.27${\AA}$, contains four formula units. The structure has been determined by X-ray diffraction method and has been refined to give the R-index, ${\sum}{\mid}{\mid}F_{\circ}{\mid}-{\mid}F_c{\mid}{\mid}{\div}{\sum}{\mid}F_{\circ}{\mid}$, of 0.16 and 0.14 for $F_{okl}\;and\;F_{hol}$ respectively.The mean lengths of C-C and C-N bonds in pyridine ring are 1.40 and $1.35{\AA}$ and those in pyrolidine ring 1.56 and $1.48{\AA}$ respectively, though accurate measurement of bond length has not been attempted. The six atoms in the pyridine ring are coplanar and on the other hand $C_6,\;C_7,\;C_8$ and $N_2$ atoms in pyrrolidine ring form a plane within accuracy of the analysis, and $C_9$ atom is distant $0.22{\AA}$ out of the plane consist of $C_6,\;C_7,\;C_8$ and $N_2$ aoms. The normals to the two planes form an angle of $94^{\circ}$ with each other. Iodine atom is distant $3.55{\AA}$ from nitrogen atom in pyridine ring and the other iodine atom $3.58{\AA}$ from nitrogen atom in pyrrolidine ring, so that the nitrogen and iodine atoms are firmly linked.It seems that the only forces binding nicotine dihydroiodide molecules together in the crystal are Van der Waals forces.

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Interlayer Coupling Field in Spin Valves with CoEe/Ru/CoFe/FeMn Synthetic Antiferromagnet (Synthetic antiferromagnet CoFe/Ru/CoFe/FeMn을 이용한 스핀 밸브 구조의 interlayer coupling field)

  • Kim, K.Y.;Shin, K.H.;Kim, H.J.;Jang, S.H.;Kang, T.
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.203-209
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    • 2000
  • Top synthetic spin valves with structure Ta/NiFe/CoFe/Cu/CoFe(P 1)/Ru/CoFe(P2)/FeMn/Ta on Si (100) substrate with natural oxide were prepared by dc magnetron sputtering system. We have changed only the thickness in free layers and the thickness difference (Pl-P2) in two ferromagnetic layers separated by Ru, and investigated the effect of magnetic film thickness on interlayer coupling field in spin valve with synthetic antiferromagnet. According to the decrease of free layer thickness, interlayer coupling field was increased due to the magnetostatic coupling(orange peel coupling). In case of t$\_$P1/>t$\^$P2/, interlayer coupling field agreed well with the modified Neel model suggested in conventional spin valve structures by Kools et al. However, in case of t$\_$P1/>t$\^$P2/, it was found that the interlayer coupling field was not explained by the Modified Neel Model and was confirmed the necessity of further remodeling. The dependence of Cu thickness on the interlayer coupling field was investigated and 10 Oe of interlayer coupling field was obtained when the Cu thickness is 32 $\AA$.

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Synthesis of Amino-type Anion Exchanger from Acrylic Acid Grafted Polypropylene Nonwoven Fabric and Its Ion-Exchange Property (아크릴산 그라프트 폴리프로필렌 부직포로부터 아민형 음이온 교환체의 합성 및 이온교환특성(I))

  • Park, Hyun-Ju;Na, Choon-Ki
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.527-534
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    • 2006
  • The purpose of this study is the development of more effective filter-type polymer adsorbent for removal of anionic pollutants from wastewater. In order to synthesize the polymer adsorbent that possesses anionic exchangeable function, carboxyl(-COOH) group of PP-g-AA nonwoven fabric was converted into amine($-NH_2$) group by the chemical modification using diethylene triamine(DETA). FT-IR data indicate that amine group was introduced into PP-g-AA through amidation of grafted acrylic acid by reaction with DETA. The degree of amination increased with increase in the reaction time and temperature of the chemical modification process, and was significantly improved by the pre-swelling treatment of PP-g-AA with solvent and addition of metal chlorides as a catalyst in following order as $NH_4OH>MeOH{\geq}HCl{\geq}H_2O\;and\;AlCl_3>FeCl_3{\geq}SnCl_2{\gg}ZnCl_2{\geq}FeCl_2$, respectively. However, the addition of catalyst limited the reusability of DETA, hence was less useful from the viewpoint of cost effectiveness and waste management. The anion exchange capacity of the aminated PP-g-AA(PP-g-AA-Am) increased with increase in the degree of amination, but it reached maximum value at the degree of amination as about $50{\sim}60%$. The anion exchange capacity of PP-g-AA-Am was higher than those of commercial anion resins.

Synthesis of Poly(oxyethylene-co-adipate)-diol from Adipic Acid and Polyethylene Glycols: Effect of Catalyst Concentration (아디프산과 폴리에틸렌글리콜로부터 폴리(옥시에텔렌-아디페이트)-디올 공중합체 합성: 촉매농도의 영향)

  • Jung, Yong-Sung;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.49 no.2
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    • pp.110-116
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    • 2014
  • We investigated the effect of the concentration of stannous 2-ethylhexanoate catalyst on the esterification rate between adipic acid (AA) and each of two PEG oligomers, diethylene glycol (DEG) and polyethylene glycol (PEG600). The concentration of the catalyst was varied from 0.15 to 2.0 wt.%. To attach hydroxy group to each end of the poly(oxyethylene-co-adipate) synthesized from AA and the PEGs, the esterification was performed with excessive PEG oligomers ([PEG]/[AA]=2) at $170^{\circ}C$. The degree of polymerization of the poly(oxyethylene-co-adipate)diol products were three. The apparent rate constant ($k_{app}$) of the esterification between AA and DEG shows the first order dependency on the catalyst concentration ($k_{app}=0.88[C_{cat}]$), whereas the $k_{app}$ of the esterification between AA and PEG600 has a relation of $k_{app}=0.123[C_{cat}]^{0.55}$ with the catalyst concentration. It is expected that the rate of esterification between AA and DEG has a non-linear dependency on the catalyst concentration as the catalyst concentration approaches to 0.22M.

Study on Cryogenic Mechanical Behavior of 6000 Series Aluminum Alloys (6000계열 알루미늄 합금의 극저온 기계적 거동 연구)

  • Park, Doo-Hwan;Kim, Jeong-Hyeon;Choi, Sung-Woong;Lee, Jae-Myung
    • Journal of Ocean Engineering and Technology
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    • v.29 no.1
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    • pp.85-93
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    • 2015
  • In this study, tensile tests were performed on aluminum alloys (AA6061 and AA6082) to investigate their mechanical behaviors at cryogenic temperatures. The temperature was varied from 110 K up to 293 K, and quasi-static strain rates of 10−4 s−1 −10−2 s−1 were taken into account for the tests. The experimental results were analyzed to find the dependence on the temperature, strain rate, and fractured surfaces. As a result, it was found that the strength and elongation of the aluminum alloys were improved when the temperature was decreased. In addition, it was confirmed that the mechanical behaviors of the aluminum alloys were not dependant on the strain rate. Under a tensile load, two types of fractures were seen in the aluminum alloys: cup-cone (AA6061) and shear (AA6082).

Trap distributions in high voltage stressed silicon oxides (고전계 인가 산화막의 트랩 분포)

  • 강창수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.521-526
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    • 1999
  • It was investigated that traps were generated inside of the oxide and at the oxide interfaces by the stress bias voltage. The charge state of the traps can easily be changed by application of low voltage after the stress high voltage. It determined to the relative traps locations inside the oxides ranges from 113.4$\AA$to 814$\AA$ with capacitor areas of $10^{-3}{$\mid$textrm}{cm}^2$. The traps are charged near the cathode with negative charge and charged near the anode with positive charge. The oxide charge state of traps generated by the stress high voltage contain either a positive or a negative charge.

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Corrosion Properties of Dissimilar Friction Stir Welded 6061 Aluminum and HT590 Steel

  • Seo, Bosung;Song, Kuk Hyun;Park, Kwangsuk
    • Metals and materials international
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    • v.24 no.6
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    • pp.1232-1240
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    • 2018
  • Corrosion properties of dissimilar friction stir welded 6061 aluminum and HT590 steel were investigated to understand effects of galvanic corrosion. As cathode when coupled, HT590 was cathodically protected. However, the passivation of AA6061 made the aluminum alloy cathode temporarily, which leaded to corrosion of HT590. From the EIS analysis showing Warburg diffusion plot in Nyquist plots, it can be inferred that the stable passivation layer was formed on AA6061. However, the weld as well as HT590 did not show Warburg diffusion plot in Nyquist plots, suggesting that there was no barrier for corrosion or even if it exists, the barrier had no function for preventing and/or retarding charge transport through the passivation layer. The open circuit potential measurements showed that the potential of the weld was similar to that of HT590, which lied in the pitting region for AA6061, making the aluminum alloy part of the weld keep corrosion state. That resulted in the cracked oxide film on AA6061 of the weld, which could not play a role of corrosion barrier.