• 한국재료학회지
• /
• 제13권9호
• /
• pp.619-624
• /
• 2003

This paper describes a method to control Mn and Fe contents in recycled AZ91D ingots, based on the mutual solubility of Mn and Fe in AZ91 alloy melts. For this purpose, Fe solubility with the change of Mn content and temperature was investigated in the homogenized and re-precipitated liquid AZ91 alloy. The increase of the amount of Mn added to the melt resulted in the decrease of Fe content. The data obtained in this study was adopted to the pilot plant for recycling of the scrap. As a result, Mn and Fe contents measured in the recycled ingot were in good agreement with ASTM B93 standard.

• 열처리공학회지
• /
• 제25권4호
• /
• pp.190-195
• /
• 2012

This study aims to investigate and compare the microstructures and room temperature tensile properties for AZ91 and ECO-AZ91 (AZ91+0.3%CaO) alloys in as-cast, T4 and T6 states, respectively. In as-cast state, the ECO-AZ91 alloy has finer microstructure than the AZ91 alloy. The AZ91 alloy exhibits greater ductility, while YS and UTS are inferior to those of the ECO-AZ91 alloy. After T4 treatment, most of ${\beta}$ compounds disappear in the AZ91 alloy, whereas ${\beta}$ phase is still observed in the ECO-AZ91 alloy due to its enhanced thermal stability, resulting in lower values of ductility and UTS. In T6 state, YS and UTS are better in the ECO-AZ91 alloy.

• 한국주조공학회지
• /
• 제28권1호
• /
• pp.20-24
• /
• 2008

The characteristics, such as roughness, thickness, microhardness and corrosion resistance, of plasma electrolytic oxide coatings on AZ91D alloy were investigated under the processing condition of various coating times. The coatings on AZ91D alloy consisted of MgO, $MgAl_{2}O_{4}$ and $Mg_{2}SiO_{4}$ oxides. The surface roughness and thickness of coatings became larger with increasing the coating time. The microhardness in cross section of coatings was much higher than not only that in surface but that in the conventional anodic oxide coatings, which increased progressively as the coating time increased. After being immersed in 3.5%NaCl solution and methyl alcohol, the corrosion resistance of AZ91D alloy was markedly improved by plasma electrolytic oxidation coating treatment, and the AZ91D alloy coated for 50min revealed excellent corrosion resistance.

• 한국레이저가공학회지
• /
• 제18권1호
• /
• pp.1-6
• /
• 2015

High welding speed and narrow weld seam are favorable for welding of magnesium alloy. Magnesium alloy is recommended for the smart frame because it has several advantages such as low density, high thermal conductivity, EMI shielding capability and good cast ability. This study is for the assembly welding of the magnesium smart frame with high productivity, good performance and low cost. The window for battery on AZ91D frame produced by die-casting was prepared by CNC machining. Corresponding AZ31 blank of 0.2mm thickness was prepared by die-blanking cut. All system set was fixed at the stationary bed but the laser beam was manipulated by scanner up-to 1,000mm/s speed. The weld joint between AZ31 sheet and AZ91D frame was welded by fiber laser on 850~1,000W output power. The joint showed penetration enough but some humping bead. The distortion by the weld heat was almost free because of the quick dissipation of the heat by small beam size and fast welding. Consequently, the thinner magnesium foil was assembled successfully to the magnesium frame of mobile phone.

• 열처리공학회지
• /
• 제24권4호
• /
• pp.193-198
• /
• 2011

Effect of CaO addition on age hardening response has been studied by using optical microscopy, scanning electron microscopy and differential thermal analysis in AZ91 and CaO-containing ECO-AZ91 alloys. After solution treatment, the ${\beta}$($Mg_{17}Al_{12}$) phase formed during solidification mostly disappeared in the microstructure in the AZ91 alloy, whereas numerous ${\beta}$ precipitates containing Ca were still observed in the ECO-AZ91 alloy due to its enhanced thermal stability. The ECO-AZ91 alloy showed the delayed peak aging time and higher peak hardness compared with those of the AZ91 alloy. The activation energies for ${\beta}$ precipitation calculated by means of Kissinger method increased from 71.4 to 85.6 kJ/mole by the addition of CaO, which implies that CaO plays a role in reducing ${\beta}$ precipitation rate in the AZ91 alloy.

• 한국산학기술학회논문지
• /
• 제13권11호
• /
• pp.4963-4967
• /
• 2012

본 연구에서는 마그네슘 합금 AZ91D를 소재로 18인치 휠을 개발하고 동일사양의 알루미늄 휠과 해외 시판중인 마그네슘 휠과 기계적인 성질을 비교하였다. 저압주조 방식에 의해 18인치 마그네슘 휠 시제품을 제작하여 동일 사양의 알루미늄 휠 대비 26% 의 경량화를 이룩하였고, 신판 마그네슘 휠 대비 동등 수준의 연신율, 인장강도, 경도를 달성하였다. 향 후 주조와 열처리 공정 개선을 통해 항복강도 향상이 필요한 것으로 판단된다.

• 한국재료학회지
• /
• 제28권10호
• /
• pp.544-550
• /
• 2018

The passivation of AZ91D Mg alloys by plasma anodization requires deliberate choice of process parameters due to the presence of large amounts of structural defects. We study the dependence of pore formation, surface roughness and corrosion resistance on voltage by comparing the direct current (DC) mode and the pulse wave (pulse) mode in which anodization is performed. In the DC plasma anodization mode, the thickness of the electrolytic oxide film of the AZ91D alloy is uneven. In the pulse mode, the thickness is relatively uniform and the formed thin film has a three-layer structure. The pulse mode creates less roughness, uniform thickness and improved corrosion resistance. Thus, the change of power mode from DC to pulse at 150 V decreases the surface roughness (Ra) from $0.9{\mu}m$ to $0.1{\mu}m$ and increases the corrosion resistance in rating number (RN) from 5 to 9.5. Our study shows that an optimal oxide film can be obtained with a pulse voltage of 150 V, which produces an excellent coating on the AZ91D casting alloy.

• 한국주조공학회지
• /
• 제30권6호
• /
• pp.224-230
• /
• 2010

To prevent oxidation of Mg melt, $SF_6$ gas has been generally used for Mg alloys during melting and casting as a cover gas. The use of $SF_6$ gas, however, will be restricted owing to its crucial impact on global warming. Non-$SF_6$ process during melting and casting in diecasting industry has been proved with Eco-Mg alloys by a simple addition of small amount of CaO into Mg alloys. This paper shows non-$SF_6$ diecasting procedures for 0.7wt% CaO added AZ91D Eco-Mg alloys. Cold-chamber diecasting was performed under $CO_2$ atmosphere without $SF_6$ gas. An increment of mechanical properties, especially strength and ductility of Eco-Mg alloys is, in part, due to high-quality melt, refined grain size and $Al_2Ca$ second phase strengthening. Microstructures and mechanical properties of 0.7wt% CaO added AZ91D Eco-Mg alloys are evaluated in comparison with those of conventional AZ91D Mg alloy.

• 한국주조공학회지
• /
• 제27권3호
• /
• pp.131-134
• /
• 2007

[ $SF_6$ ] gas that is used as a protective cover gas for Mg and Mg alloys during melting and casting has extremely high greenhouse effect. CaO added Mg alloys could maintain their original mechanical properties and original abilities such as fluidity and hot tearing susceptibility. The ignition temperature increased with increasing CaO addition under ambient atmosphere and nitrogen atmosphere. The minimum amount of $SF_6$ gas decreased by 0.13 wt%CaO added AZ91D Mg alloy in the sealed condition.

• 한국표면공학회지
• /
• 제50권6호
• /
• pp.432-438
• /
• 2017

AZ91D casting alloy requires an advanced plasma anodizing processing because large amount of defects are liable to generate during anodization. In this study, plasma electrolytic oxidation (PEO) of AZ91D Mg alloy was conducted by the application of either constant voltage or current using a pulse mode and its effects on pore formation, surface roughness and corrosion resistance were investigated. The PEO films showed a three-layer structure. The PEO film thickness was found to increase linearly with voltage. The surface roughness, Ra, ranged between $0.2{\mu}m$ and $0.3{\mu}m$. The corrosion resistance increased from RN 3.5 to 9.5 by the PEO treatment when evaluated according to the 72 hour salt spray test. The PEO-treated surface exhibited higher pitting potential than the raw material.