• Membrane Journal
• /
• v.32 no.4
• /
• pp.209-217
• /
• 2022

Ion exchange membrane (IEM) is an important class of membrane applied in batteries, fuel cells, chloride-alkali processes, etc to separate various mono and multivalent ions. The membrane process is based on the electrically driven force, green separation method, which is an emerging area in desalination of seawater and water treatment. Electrodialysis (ED) is a technique in which cations and anions move selectively along the IEM. Anion exchange membrane (AEM) is one of the important components of the ED process which is critical to enhancing the process efficiency. The introduction of cross-linking in the IEM improves the ion-selective separation performance due to the reduction of free volume. During the desalination of seawater by reverse osmosis (RO) process, there is a lot of dissolved salt present in the concentrate of RO. So, the ED process consisting of a monovalent cation-selective membrane reduces fouling and improves membrane flux. This review is divided into three sections such as electrodialysis (ED), anion exchange membrane (AEM), and cation exchange membrane (CEM).

• Journal of Korea Water Resources Association
• /
• v.55 no.11
• /
• pp.877-886
• /
• 2022

This study was carried out to analyze how the flow and water quality of the Sangsa Lake (juam control basin) change according to future climate change and what countermeasures are needed. Aquatic Ecosystem Model) was used in conjunction. As climate change scenarios, RCP (Representative Concentration Pathways) 4.5 and RCP 8.5 scenarios of AR5 (5th Assessment Report) according to the Intergovernmental Panel on Climate Change (IPCC) were used. For the climate change scenario, detailed data on the Sangsa Lake basin were used by the Korea Meteorological Administration, and after being evaluated as a correction and verification process for the 10-year period from 2012 to 2021, the present, 2025-2036, 2045- The summer period from June to August and the winter period from December to February were analyzed separately for each year by dividing it into 2056 and 2075-2086. RCP 8.5 was higher than RCP 4.5 as an arithmetic mean for the flow rate of the watershed of the superior lake for the entire simulation period, and TN and TP also showed a tendency to be higher at RCP 4.5. However, in RCP 8.5, the outflow of pollutants decreased during the dry season and the outflow of pollutants increased during the summer, indicating that the annual pollutant outflow was concentrated during the flood season, and it is analyzed that countermeasures are needed.

• Membrane Journal
• /
• v.32 no.6
• /
• pp.486-495
• /
• 2022

This study presents the improved recovery efficiency of rare metal ions through the modified separation membrane wettability and hydrogen ion permeation in the anion exchange membrane (AEM) under the recovery process of combined electrodialysis and solvent extraction. Specifically, the wettability of the separator was enhanced by hydrophilic modification on one separator surface through polydopamine (PDA) and lipophilic modification on the other surface through SiO₂ or graphene oxide (GO). In addition, the modified surface of AEM with polyethyleneimine (PEI), PDA, poly(vinylidene fluoride) (PVDF), etc. reduces the water uptake and modify the pore structure for proton ions generation. The suppressed transport resulted in the reduced hydrogen ion permeation. In the characterization, the surface morphology, chemical properties and composition of membrane or AEM were analyzed with Scanning Electron Microscopy (SEM) and Fourier Transform-Infrared Spectroscopy (FT-IR). Based on the analyses, improved extraction and stripping and hydrogen ion transport inhibition were demonstrated for the copper ion recovery system.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2005.09b
• /
• pp.1062-1063
• /
• 2005

• Membrane Journal
• /
• v.30 no.5
• /
• pp.350-358
• /
• 2020

A membrane capacitive deionization (MCDI) cell is constructed by applying thin layer of a cation exchange membrane (Nafion) on cathode and an anion exchange membrane (aminated polyphenylene oxide, APPO) on anode. Compared to CDI cell without CEM and AEM coating, MCDI exhibits enhanced salt removal efficiency. When Nafion and APPO are used as CEM and AEM, optimized salt removal performance as high as 82.1% is observed when 1.2 V is applied for 3 min during absorption process and -1.0 V is applied for 1 min during desorption.

• Membrane Journal
• /
• v.27 no.2
• /
• pp.109-120
• /
• 2017

The reverse electrodialysis (RED) is an energy generation system to convert chemical potential of saline water directly into electric energy via the combination of current derived from a redox couple electrolyte and ionic potential obtained when cation ($Na^+$) and anion ($Cl^-$) pass through cation exchange membrane (CEM) and anion exchange membrane (AEM) into fresh water, respectively. Ion exchange membrane, a key element of RED system, should satisfy requirements such as 1) low swelling behavior, 2) a certain level of ion exchange capacity, 3) high ion conductivity, and 4) high perm-selectivity to achieve high power density. In this paper, research trends and prospects of ionomer materials and ion exchange membranes are dealt with.

• Journal of Hydrogen and New Energy
• /
• v.32 no.5
• /
• pp.293-298
• /
• 2021

To synthesize Fe/Ni nanocatalysts loaded on carbon black, Iron(II) acetylacetonate and nickel (II) acetylacetonate and were reduced to Fe and Ni metallic nanoparticles by a spontaneous reduction reaction. The distribution of the Fe and Ni nanoparticles was observed by transmission electron microscopy, and the loading weight of Fe/Ni nanocatalysts on the carbon black was measured by thermogravimetric analyzer. The elemental ratio of Fe and Ni was estimated by energy dispersive x-ray analyzer. It was found that the loading weight of Fe/Ni nanoparticles was 6.23 wt%, and the elemental ratio of Fe and Ni was 0.53:0.40. Specific surface area was measured by BET analysis instrument and I-V characteristics were estimated.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.21 no.3
• /
• pp.377-396
• /
• 2019

Explosion after penetration of a warhead in an underground structure generally causes considerable displacement, breakage and extensive damage to the target. Therefore, in order to reduce the damage effect, it is required to design an underground structure protection against penetration. In this study, major factors for improvement of penetration protection performance of reinforced concrete underground structures using applied element method are divided into strength (concrete UCS) and density (concrete thickness, reinforcement layers, reinforcement diameters, reinforcement spacings). Based on these major factors, this study performed numerical analysis of simulation of dynamic response by penetrators under various conditions and analyzed the results. The results of this study are expected to be used as basis materials to improve penetration protection performance of reinforced concrete underground structures.

• Journal of Hydrogen and New Energy
• /
• v.33 no.3
• /
• pp.202-208
• /
• 2022

Pt-Ni nanocatalysts were loaded on carbon black by spontaneous reduction reaction of platinum (II) acetylacetonate and nickel (II) acetylacetonate, and they were characterized by transmission electron microscopy (TEM), thermogravimetric analyzer (TGA), energy dispersive x-ray analyzer (EDS), BET surface area and fuel cell test station. The distribution of the Pt and Ni nanoparticles was observed by TEM, and the loading weight of Pt-Ni nanocatalysts on the carbon black was measured by TGA. The elemental ratio of Pt and Ni was estimated by EDS. It was found that the loading weight of Pt-Ni nanoparticles was 5.54 wt%, and the elemental ratio of Pt and Ni was 0.48:0.35. Specific surface area was measured by BET analysis instrument and I-V characteristics were estimated.

• Journal of Hydrogen and New Energy
• /
• v.33 no.4
• /
• pp.330-336
• /
• 2022

In order to evaluate the possibility as a separator in alkaline water electrolysis, the high temperature characteristics were evaluated by measuring the membrane resistance and durability of 5 types of commercial anion exchange membranes in 7 M KOH solution and at 80℃. The membrane resistance of AEM membrane measured in 7 M KOH solution and at 80℃ had a lower value of about 8-24 times compared to the other membranes. The durability of AEM membrane tested with the soaking time in 7 M KOH solution and at 80℃ showed a very good stability and that of FAAM40 and FAAM75-PK showed secondly a good stability. The thermal stability with the soaking time in 7 M KOH solution and at 80℃ of FAAM40 and FAAM75-PK membrane analyzed by thermo-gravimetric analysis showed a good stability compared to the other membranes.