• Title/Summary/Keyword: ACETYLENE

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Enhanced Adhesion of Tire Cords via Plasma Polymerizations (플라즈마 중합에 의한 타이어 코드의 접착성 향상연구)

  • Kim, R.K.;Sohn, B.Y.;Han, M.H.;Kang, H.M.;Yoon, T.H.
    • Elastomers and Composites
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    • v.34 no.2
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    • pp.128-134
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    • 1999
  • Steel tire cords were coated via RF plasma polymerization of acetylene and butadiene gas in order to enhance adhesion to rubber compounds. Adhesion of tire cords was measured by TCAT and T-test as a function of type of gas, plasma powder, treatment time, gas pressure and Ar gas etching. Some samples were subjected to aging study in distilled water at $80^{\circ}C$ for a period of 7 days. After testing, tire cords were analysed by SEM to elucidate the adhesion mechanism. The highest adhesion values were obtained at 20W, 2min and 25mtorr for acetylene plasma polymerization, and l0W, 4min, 25mtorr for butadiene plasma polymerization. However, Ar plasma etching did not affect adhesion, while the adhesion of tire cords increased rather than decreased, contrary to expectations. It was not possible to elucidate failure mode by SEM, owing to the rough surface of the tire and the thin plasma polymer coating layer.

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Carburizing Behavior of AISI 4115 Steel with a Flow Rate of Acetylene and Specimen Location in an 1 ton-class Mass Production-type Vacuum Carburizing Furnace (1 톤급 양산형 진공 침탄로에서 아세틸렌 유량과 로 내 위치에 따른 AISI 4115 강의 침탄 거동)

  • Kwon, Gi-hoon;Moon, Kyoungil;Park, Hyunjun;Lee, Young-Kook;Jung, Minsu
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.6
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    • pp.272-280
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    • 2021
  • The influence of acetylene flow rates on the carburizing behavior of an AISI 4115 steel in 1 ton-class mass production-type vacuum carburizing furnace has been studied through microstructure, carbon concentration, hardness analyses. The AISI 4115 steels were carburized with various flow rates (20, 32.7, 60 l/min) and locations in the furnace (top, center, bottom) at 950℃. The acetylene flow rate played an important role in controlling the carburizing properties of carburized samples, such as effective case depth and uniformity carburizing according to location in the furnace. At an acetylene flow rate of 20 l/min, the carburized samples had a shallow average hardened layer (0.645 mm) compared to the target hardening depth (1 mm) due to low carbon flux and spatial uniformity of carburization (17.8%) in the furnace. At a flow rate of 60 l/min, the carburized samples showed an average hardened layer (1.449 mm) deeper than the target hardening depth and had the spatial uniformity of carburization (98.8%). In particular, at a flow rate of 32.7 l/min, the carburized samples had an average hardened layer (1.13 mm) close to the target hardening depth and had the highest carburizing uniformity (99.1%). As a result, an appropriate flow rate of 32.7 l/min was derived to satisfy the target hardening depth and to have spatial uniform hardened layer in the furnace.

Quenching Effects of Acetylene, Hydrogen-Oxygen Detonation (폭굉제어기에 의한 수소. 아세틸렌 산소 혼합가스의 폭굉제어)

  • 김한석;문정기
    • Journal of the Korean Society of Safety
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    • v.6 no.2
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    • pp.31-36
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    • 1991
  • Quenching effects of acetylene and hydrogen into oxygen detonation by using detonation arrester [DA]are studied in this paper. The experiments were carried out in cylinderical shock tube. 5m long, 30mm dia., with stolchlometric ratio [SR]of each gas and 10-l20$\mu$ Cell Size of brass and Stainless Steel of DAs were installed in it To clarify arresting ability correlation with initial pressure, Pi, critical thickness, Tct, and shapes of supporting panel of DA are also investigated It is found that ­detonation velocities has most dependency on Pi, it shows notable changes around 0.5kgf/$\textrm{cm}^2$ for hydrogen, 0.15kgf/$\textrm{cm}^2$ for acetylen respectively, ­DA can be safety device able to arrest shock wave of detonation, ­over Tct flame transmission might be only the factor has to be considered, ­acetylene seems to be much more stronger detonation characteristics than hydrogen because of reaction heat.

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Characterization of Azospirillum spp. Isolated from Korean Paddy Roots (우리나라 수도근권에서 분리된 Azospirillum spp.의 특성)

  • 조무제;강규영;강성모;윤한대
    • Korean Journal of Microbiology
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    • v.25 no.2
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    • pp.129-136
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    • 1987
  • Nitrogen fixing activity associated with 40 varieties of rice was assayed at heading stage by an in situ acetylene reduction method. The in situ acetylene reduction activity and population of nitrogen fixing bacteria obtained on nitrogen-free malate medium for Azospirillum spp. enrichment showed positive correlation. Six Azospirillum spp. with high nitrogenase activity were isolated from the rice roots, from which five spp. were identified as A. lipoferum and one was A. brasilense. The physiological characteristics of the six Azospirillum isolates, that is, carbon source utilization, biotin requirement, antibiotic resistance, indole acetic acid excretion, plasmid profile and protein patterns were compared.

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Numerical Analysis for the Soot Formation Processes in Acetylene-Air Nonpremixed Turbulent Jet Flame (아세틸렌/공기 비예혼합 난류 제트화염의 Soot 생성에 대한 수치해석)

  • 김후중;김용모;윤명원
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.6
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    • pp.80-89
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    • 2002
  • The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

The Modeling of Temperature Changes of Acetylene Clusters formed in Free Jet Expansion (자유팽창으로 생성된 아세틸렌 Cluster의 온도변화에 관한 모델링)

  • Lee Kyung Hee;Kim Hong Rak;Kim Cheol Hyun
    • Journal of the Korean Institute of Gas
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    • v.7 no.1 s.18
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    • pp.41-46
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    • 2003
  • The Phase and temperature changes of large clusters formed in a free jet expansion of acetylene in 14atm and 233K has been studied. The cluster has been treated as a sphere composed of many shells. A mean diameter of 4.88 microns was obtained by modeling the experimental cooling curve of clusters based on evaporation and heat conduction theory.

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Fault Analysis of Transformer using Tunable Infrared Gas Sensors (가변 파장형 적외선 센서를 이용한 변압기 결함 진단)

  • Gun-Ho Lee;Seung-Hwan Yi
    • Journal of Sensor Science and Technology
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    • v.32 no.1
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    • pp.55-61
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    • 2023
  • The objective of this study is to determine the concentrations of mixed gases by establishing a diagnosis method of a transformer using tunable-wavelength optical infrared sensors. Absorption of infrared light by methane, acetylene, and ethylene gases injected is measured from the outputs of the infrared sensors. Regression analysis equations of the gas concentrations are acquired from their respective measured absorption. The obtained concentrations are as follows: -3-9 % errors above 600 ppm(methane), 3 % errors above 1200 ppm(acetylene), and 10 % errors above 500 ppm(ethylene). The concentration inference equations obtained using the individual gases are applicable when the absorption wavelength bands do not overlap. The results of the fault analysis of a transformer using the Duval triangle method and the tunable infrared gas sensors are as follows: temperature faults with -1-1% errors and energy faults with -7-7 % errors.

The effect of various parameters for few-layered graphene synthesis using methane and acetylene

  • Kim, Jungrok;Seo, Jihoon;Jung, Hyun Kyung;Kim, Soo H.;Lee, Hyung Woo
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.42-46
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    • 2012
  • The effect of the parameters for few-layered graphene growth by thermal CVD on nickel substrate was investigated. Graphene can be synthesized by using different strategies. Chemical vapor deposition (CVD) has known as one of the most attractive methods to produce graphene due to its good film uniformity, compatibility and large scale production. The control of parameters such as temperature, growth time and pressure in CVD process has been widely recognized as the most important process in graphene growth. Different carbon precursors, methane and acetylene, were introduced in the quartz tube with a variety of growth conditions. Raman spectroscopy was used to confirm the presence of a few- or multi-layered graphene.

Studies on Varietal Differences in Growth, Nodulation and Nitrogen Fixation in Soybeans, Glycine max (L.) Merrill I. Changes in nitrogen fixation activity and dry weight of plant organs during reproductive stage (콩의 생육, 근류형성, 질소고정에 있어서 품종간 차이 I. 등숙단계별 각 기관 건물중 및 질소고정활성의 경시적 변화)

  • Eun-Hui Hong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.32 no.3
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    • pp.323-329
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    • 1987
  • Five soybean varieties of two early maturing Karikei73 and SS 79168, and three late maturing Tohoku76, Baegunkong and Jangbaegkong were used and evaluated in the study. Of the varieties examined, Karikei73 was characterized by the delayed leaf senescence. The varieties were planted in the pots of 1/3500 a filled with volcanic ash soil at the experimental fields of the National Institute of Agrobiological Resources in Japan. Major agronomic characteristics including the activity of nitrogen fixation for root nodules during the grain filling period were measured. Measurements during the stages were followed by the stage of development descriptions for soybeans made by Fehr and Carviness (1977). The acetylene reducing activity (ARA) per dry weight of root nodule measured using acetylene reduction assays was the highest at R4-R4.5 with decreasing trends thereafter for the early matruing varieties, while it continuously increased up to R6 but decreased rapidly thereafter for the late maturing varieties. The dry weights of root nodules and all parts of the host plant at each stage checked were greater in the late maturing varieties being the same in ARA per pot.

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