• 전기화학회지
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• 제11권2호
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• pp.89-94
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• 2008

GNP(Glycine Nitrate Process)을 이용하여$(La_{0.75}Sr_{0.25})_{1-x}FeO_{3-\delta}$를 합성하고, perovskite의 A-site deficiency에 따른 특성을 분석하기 위해 x=0, 0.02, 0.04, 0.06, 0.08로 바꾸어 합성하였다. SEM과 XRD분석을 통하여 균질하고 결정성이 높은 분말이 합성된것을 확인하였으며, 4단자법과 AC impedance spectroscopy를 통하여 전도도는 x = 0.02가 $750^{\circ}C$ $155{\Omega}cm^2$로 가장 우수하였으며, AC impedance결과 역시 x = 0.02가 가장 낮은 분극저항과 활성화 에너지를 가지고 있었다. 이 결과 Perovskite의 A-site deficiency를 가함에 따라 산소 결핍 및 구조의 변화가 생겼으며 이로 인해 전도도와 분극 저항, 활성화 에너지에 영향을 미친 것을 알 수 있었다.

• 공업화학
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• 제33권6호
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• pp.636-645
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• 2022

이 연구에서는 은행껍질기반 활성탄으로 음이온성 염료인 메틸오렌지(MO)의 흡착 특성을 조사하였다. 이를 위해 은행껍질과 대표적인 화학활성화제인 수산화칼륨(KOH)을 이용하여 서로 다른 기공 특성을 지닌 다공성 활성탄(GS-1, GS-2, GS-4)을 제조하였다. 제조한 활성탄의 구조적 특성값과 KOH 혼합비율과의 상관관계는 질소 흡/탈착등온선으로 조사하였다. 활성탄에 대한 MO 흡착 평형 실험은 서로 다른 pH (pH 3~11) 및 온도(298~318 K) 조건에서 실시하였으며 그 결과를 Langmuir, Freundlich, Sips 및 온도 의존 Sips식으로 살펴보았다. 그리고 Langmuir 무차원 분리계수값으로 제조한 활성탄의 MO 흡착처리공정의 타당성을 조사하였다. 흡착에너지분포함수(AED)로 비교 분석한 활성탄에 대한 MO의 불균일 흡착 특성은 온도와 활성탄의 구조적 특성과 밀접한 관련이 있었다. 서로 다른 온도에서 수행한 회분식 흡착 속도 실험 결과는 외부물질전달, 입자 내 확산 및 활성사이트의 흡착을 고려한 균일표면확산모델(HSDM)로 만족스럽게 설명할 수 있었다. 또한 표면확산계수값을 Arrhenius 플롯으로 나타내어 구한 활성화에너지와 흡착에너지분포 함수값과의 상관관계를 살펴보았다. 그리고 Biot 수를 이용하여 제조한 활성탄에 대한 MO의 흡착 공정 메커니즘을 평가하였다.

• 한국연소학회지
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• 제21권3호
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• pp.1-6
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• 2016

The effect of applied electric fields on jet flow instability was investigated experimentally by varying the direct current (DC) voltage and the alternating current (AC) frequency and voltage applied to a jet nozzle. We aimed to elucidate the origin of the occurrence of twin-lifted jet flames in laminar jet flow configuration, which occur when AC electric fields are applied. The results indicate that a twin-lifted jet flames originates from cold jet instability, caused by interactions between negative ions in the jet flow via electron attachment as $O_2+e{\rightarrow}O_2{^-}$ when AC electric fields are applied. This was confirmed by experiments in which a variety of gaseous jets were ejected from a nozzle to which DC voltages and AC frequencies and voltages were applied, with ambient air between two deflection plates connected to a DC power source. Experiments in which jet flows of several gases were ejected from a nozzle and AC electric fields were applied in coflow-nitrogen provided further evidence. The flow instability occurred only for oxygen and air jets. Additionally, jet instability occurred when the applied frequency was less than 80 Hz, corresponding to the characteristic collision response time. The effect of AC electric fields on the overall structure of the jet flows is also reported. Based on these results, we propose a mechanism to reduce jet flow instability when AC electric fields are applied to the nozzle.

• 한국태양에너지학회 논문집
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• 제32권6호
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• pp.106-112
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• 2012

As a fuel cell converts the chemical energy of the fuel cell into electrical energy by electrochemical reaction, the fuel cell system is uniquely integrated technique including fuel processor, fuel cell stack, power conditioning system. The residential fuel cell-PCS(Power Conditioning System) needs to convert efficiently the DC current produced by the fuel cell into AC current using single-phase DC-AC inverter. A single-phase DC-AC inverter has naturally low frequency ripple which is twice frequency of the output current. This low frequency(120Hz) ripple reduces the efficiency of the fuel cell. This paper presents notch filter with IP voltage controller to reject specific 120Hz current ripple in single-phase inverter. The notch filter is designed that suppress just only specific frequency component and no phase delay. Finally, the proposed notch filter design method has been verified with computer simulation and experimentation.

• Progress in Superconductivity
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• 제5권1호
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• pp.61-64
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• 2003

In HTS transformer with double pancake windings, the perpendicular component of leakage magnetic flux density ($B_{r}$ ) applied to HTS tapes of double pancake windings of HTS transformer acts as a cause to decrease the critical current in HTS tape. So, in this paper, HTS transformer with reciprocal arrangement winding is designed. And in order to investigate the$ B_{r}$ applied to HTS windings, the 2-D non-linear electromagnetic analysis of HTS transformer is performed by using the OPERA 2D. The maximum $B_{r}$ applied to winding of HTS transformer is 0.112 T and the characteristics of HTS transformer were also obtained. But in this type of winding arrangement, reciprocal arrangement, the generated ac-loss to the HTS windings is very high because of the applied $B_{r}$ to HTS windings. Therefore, in order to reduce the generated ac-loss to the HTS windings, the new design of HTS transformer with concentric winding arrangement is presented in this paper and the 2-D non-linear electromagnetic analysis and the ac-loss for HTS transformer with the concentric winding arrangement is also carried out.

• 한국재료학회지
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• 제29권12호
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• pp.774-780
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• 2019

The performance of Li-ion hybrid supercapacitors (asymmetric-type) depends on many factors such as the capacity ratio, material properties, cell designs and operating conditions. Among these, in consideration of balanced electrochemical reactions, the capacity ratio of the negative (anode) to positive (cathode) electrode is one of the most important factors to design the Li-ion hybrid supercapacitors for high energy storing performance. We assemble Li-ion hybrid supercapacitors using activated carbon (AC) as anode material, lithium manganese oxide as cathode material, and organic electrolyte (1 mol L^-1 LiPF₆ in acetonitrile). At this point, the thickness of the anode electrode is controlled at 160, 200, and 240 ㎛. Also, thickness of cathode electrode is fixed at 60 ㎛. Then, the effect of negative and positive electrode ratio on the electrochemical performance of AC/LiMn₂O₄ Li-ion hybrid supercapacitors is investigated, especially in the terms of capacity and cyclability at high current density. In this study, we demonstrate the relationship of capacity ratio between anode and cathode electrode, and the excellent electrochemical performance of AC/LiMn₂O₄ Li-ion hybrid supercapacitors. The remarkable capability of these materials proves that manipulation of the capacity ratio is a promising technology for high-performance Li-ion hybrid supercapacitors.

• 설비공학논문집
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• 제24권9호
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• pp.657-662
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• 2012

The cogeneration system can operate at efficiencies greater than those achieved when heat and power are produced in separate. The optimal system can be determined by selecting the auxiliary system combined with cogeneration system. In the present study, economic investigation has been conducted with the cogeneration electric heat pump(EHP) system and the cogeneration absorption chiller(AC) system to install in a school dormitory. To analyze life cycle cost(LCC), cost items such as initial investment costs, annual energy costs and maintenance costs of each system have been considered. The initial investment cost is referred to the basis of estimated costs, and annual energy costs such as the electric power and gas consumption are based on the data in a school dormitory. LCC is evaluated with the present worth method. Considering investigated results, the initial investment cost of the cogeneration EHP system is more profitable about 24% than that of the cogeneration AC system. The energy cost of the cogeneration EHP system is more profitable about 8% than the cogeneration AC system. The LCC shows that the cogeneration EHP system is the most effective system in the school dormitory.

• KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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• 제2B권3호
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• pp.115-124
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• 2002

This paper presents an active auxiliary edge-resonant DC link snubber with a ringing surge damper and a three-phase voltage source type zero voltage soft-switching inverter with the resonat snubber treated here for the AC servo motor driver applications. The operation of the active auxiliary edge-resonant DC link snubber circuit with PWM voltage is described, together with the practical design method to select its circuit parameters. The three-phase voltage source type soft-switching inverter with a single edge-resonant DC link snubber treated here is evaluated and discussed for the small-scale permanent magnet (PM) type-AC servo motor driver from an experimental point of view. In addition to these, the AC motor stator current and its motor speed response for the proposed three-phase soft-switching inverter employing Intelligent Power Module(IPM) based on IGBTS are compared with those of the conventional three-phase hard-switching inverter using IPM. The practical effectiveness of the three-phase soft-switching inverter-fed permanent magnet type AC motor speed tracking servo driver is proven on the basis of the common mode current in a novel type three-phase soft-switching inverter-fed AC motor side and the conductive noise on the mains terminal interface voltage as compared with those of the conventional three-phase hard-switching inverter-fed permanent magnet type AC servo motor driver for the speed tracking applications.

• 대한전기학회논문지:전기기기및에너지변환시스템부문B
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• 제48권7호
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• pp.384-390
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• 1999

This paper describes a new ac-to-dc power converter using a multilevel converter. A conventional multilevel ac-to-dc converter has large output dc filter capacitors. When a short circuit happens in a load, the stored energy in the capacitors should be discharged through the load with a high short circuit current. The high current may cause considerable damage to the capacitors and the load. The output dc capacitors of the proposed converter do not discharge even under load short circuit condition. In the case of a load short circuit, the capacitors become a floating state immediately and remain in the state. Then the stored capacitor energy is supplied to the load again as soon as the short circuit has been cleared. Therefore, the rising time of the load voltage can be significantly reduced. This feature satisfies the requirement of a power supply for a load with frequent short circuits. The proposed converter has the characteristics of a simplified structure, a reduced cost, weight, and volume compared with conventional power supplies with frequent output short circuits. Experimental results are presented to verify the usefulness of the proposed converter.

• Journal of Electrochemical Science and Technology
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• 제3권2호
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• pp.72-79
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• 2012

$Li_2MnSiO_4$ was synthesized using the solid-state method under an Ar atmosphere at three different calcination temperatures (900, 950, and $1000^{\circ}C$). The optimization of the carbon coating was also carried out using various molar concentrations of adipic acid as the carbon source. The XRD pattern confirmed that the resulting $Li_2MnSiO_4$ particles exhibited an orthorhombic structure with a $Pmn2_1$ space group. Cyclic voltammetry was utilized to investigate the capacitive behavior of $Li_2MnSiO_4$ along with activated carbon (AC) in a hybrid supercapacitor with a two-electrode cell configuration. The $Li_2MnSiO_4$/AC cell exhibited a high discharge capacitance and energy density of $43.2Fg^{-1}$ and $54Whkg^{-1}$, respectively, at $1.0mAcm^{-2}$. The $Li_2MnSiO_4$/AC hybrid supercapacitor exhibited an excellent cycling stability over 1000 measured cycles with coulombic efficiency over > 99 %. Electrochemical impedance spectroscopy was conducted to corroborate the results that were obtained and described.