• Title/Summary/Keyword: A Heavy Metal

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Adsorption of Pb(II) by Cherry (Prunus x yedoensis) Leaf-Derived Biochar (왕벚나무 잎으로 제조된 바이오차의 Pb(II) 흡착특성)

  • Lee, Myoung-Eun;Hwang, Kyu-Taek;Kim, Sun-Young;Chung, Jae-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.2
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    • pp.33-41
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    • 2018
  • Large amounts of leaves from street trees fall onto the streets annually and need to be cleaned and treated. Cherry trees are common street trees in Korea. The adsorption characteristics of Pb(II) by cherry leaf (CL) and cherry leaf-derived biochar (CB) were studied through a series of batch experiments. CB was produced through the carbonization of CL at $800^{\circ}C$ for 90 min. Carbonization increased the C content and pH value, while decreased H and O contents. Well developed pore structure was observed at the surface of CB. The pseudo-second order model better described the kinetics of Pb(II) adsorption onto CL and CB, indicating that the rate-limiting step of the heavy metal sorption is chemical sorption. Fast adsorption rates and high adsorption capacities were obtained by the carbonization from CL to CB. Langmuir models better adequately described the Pb(II) adsorption onto CL and CB. Maximum adsorption capacities of Pb(II) expressed by Langmuir constant, $Q^0$ were 37.31 mg/g and 94.34 mg/g, when CL and CB were used as adsorbents, respectively.

The Assessment of pH Variation for Neutralized Acidic Areas using Lysimeters by Seasons (라이시미터를 이용한 중화처리된 산성화경사지의 계절별 pH 용탈특성 평가)

  • Oh, Seungjin;Oh, Minah;Park, Chan-O;Jung, Munho;Lee, Jai-Young
    • Journal of the Korean Geosynthetics Society
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    • v.14 no.4
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    • pp.79-86
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    • 2015
  • Korean territories has formed about 70% of mountainous areas that have acidified serious level to average pH 4-5. There are a number of abandoned metal mines about 1,000 in Korea. However, mine tailings and waste rock included heavy metals are exposed to long-term environment without prevention facility or treatment system. Thus, ongoing management and monitoring of soil environment are required. Most of abandoned mine scattered in forest areas of slopes. Soil erosion due to continuous rainfall in the slopy areas can cause the secondary pollution by the influence eutrophication of water system and the productivity loss of the plant. Therefore, this study would like to estimate pH leaching rate by artificial rainfall using waste neutralization-agent in lysimeter. Moreover, the potentially of secondary pollution related to precipitation is figured out through the experiments, and the optimal planting methods would examinate after neutralizing treatment in soil. Experiments composed three kinds of lysimeter; lysimeter 1 had filled only acidic soil, lysimeter 2 had neutralized soil, and lysimeter 3 had planting plants after neutralized soil. In the results, lysimeter 2 showed the lowest pH leaching, and there is not specific relativity with pH leaching of the seasonal characteristics.

A Study on Physiochemical Analysis and Distributions of Coliforms in Major Streams or the Mankyung River (만경강 주요 지천수의 이화학적 검사 및 대장균군의 분포에 관한 연구)

  • 황인담;기노석;정인호;최문철;이재형
    • Journal of Environmental Health Sciences
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    • v.15 no.2
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    • pp.11-23
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    • 1989
  • This study was performed to investigate present water quality and pollution characteristics of them in the basin area of the Mankyung river near Chonju urban stream. In order to obtain the pollution characteristics of this investigation, the physio-chemical water analysis as temperature, pH, DO, BOD, Cd, Cu, Pb and Zn, and coliform group and their correlation analysis were determined from March to August 1988. The main results were summarized as follows 1. Each chemical constituent detected in three streams has the following variation range as pH(6.7-7.3), DO(1.3-8.9 mg/l), BOD(1.6-162.5mg/l) and water temperature was dominated by atmospheric temperature. 2. In three streams, concentration range of heavy metal was Cd N.D.-2.8 $\mu$g/l, Cu 1.1-10.2 $\mu$g/l, Pb 2.1-13.2 $\mu$g/l and Zn 25.6-62.2 $\mu$g/l, and was shown the order of Zn, Pb, Cu and Cd. 3. In the investigation on the bacteriological pollution-in the three streams. 1) The average number of general bacteria contaminated in the Chonju urban stream was $1.7 \times 10^{5}$ numbers/ml, which was higher than $2.6 \times 10^{2}$ numbers/ml, in the Gosan stream and 1.6 $\times$ 10 numbers/ml in the Mankyung river. 2) The average number of total coliform, fecal coliform and fecal streptococcus contaminated in the Chonju urban stream which was the highest polluted site than those of the other sampling sites were respectively $2.1 \times 10^{5}$, $2.1 \times 10^{5}$ and $9.6 \times 10^{4}$ MPN/100ml. 4. Correlation coefficient between GB and TC in the Chonju stream, Gosan stream and Mankyung river was respectively 0.99, 0.96 and 0.99, Correlation coefficient between TC and FC in Chonju stream, Gosan stream and Mankyung river was respectively 0.99, 0.97 and 0.99 and correlation coefficient between FC and TC was respectively 0.99, 0.91 and 0.99. This results mean positively dose relationship between them. 5. The occupied percentage of FC of TC in the Chonju stream, Gosan stream and Mankyung river was respectively 88.1%, 68.4% and 77.9% and the percentage of Tc of TS was respectively 43.5%, 31.6% and 41.4%. These .results was considered indicative of pollution derived from domestic wastes which had been contaminated by the feces of inhabitants and domestic animals.

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Estimation of Strength Parameter of Soil-NSS Mixture by Triaxial Compression Test (삼축압축시험을 이용한 NSS 혼합토의 강도정수 평가)

  • Oh, Sewook;Lee, Gilho;Kwon, Hyekkee;Kwon, Youngcheul
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.11
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    • pp.65-71
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    • 2013
  • Despite of the various merits of soil pavement, it has not been widely adapted because portland cement was conventionally used as soil stabilizer to improve the mechanical properties such strength parameters. Recently, natural soil stabilizer(NSS) were developed and virtually adopted to several case of soil pavement construction under control of heavy metal pollution compared to cement-used cases. However, the application of natural soil stabilizer is not settled yet, and empirical design have been widely adopted. In this study, therefore, the strength parameter of soil-NSS mixture was estimated by some triaxial compression tests, CU-test. From the tests, the relationship between curing period and strength parameter such as internal friction and effective cohesion was examined. As a result, effective cohesion of dredged clay and granite soil increased as curing time is increased. However, internal friction is almost same result in all soil type used in this study.

Toxic Effects of Arsenic and Chromium on the Fertilization and Embryo Development Rates in the Sea Urchin (Hemicentrotus pulcherrimus) (말똥성게(Hemicentrotus pulcherrimus)의 수정 및 배아 발생률에 대한 비소와 크롬의 독성영향)

  • Hwang, Un-Ki;Ryu, Hyang-Mi;Yu, Jun;Kang, Han-Seung
    • Korean Journal of Environmental Biology
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    • v.31 no.2
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    • pp.69-77
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    • 2013
  • Toxic effects of arsenic (As) and chromium (Cr) has been investigated using the sea urchin (Hemicentrotus pulcherrimus) germ cell and pluteus-larvae. The gametotoxic and embryotoxic effects of As and Cr on H. plucherrimus were each investigated at 6.25, 12.5, 25, 50, 100. Spawning was induced by 0.5 M KCl solution and the normal fertilization and embryogenesis rates were performed for 10 min and 64 hrs after fertilization, respectively. The normal fertilization and embryogenesis rates in the control condition (not including As and Cr) were greater than 94% and 93%, respectively. The fertilization rate was not significantly changed compared with control but embryogenesis rate was significantly decreased with concentration-dependent manner. As and Cr reduced normal embryogenesis rates and a significant reduction occurred at concentration greater than 6.25 ppb (P<0.01) and 25 ppb (P<0.05), respectively. The lowest-observedeffect- concentration (LOEC) of normal embryogenesis rate in As and Cr were each 6.25 and 25 ppb, respectively. From these results, normal embryogenesis rate of H. pulcherrimus have toxic effect at greater than the 6.25 ppb concentration of As and 25 ppb concentration of Cr in marine ecosystems. These results suggest that the normal embryogenesis rates of H. pulcherrimus are very useful test method for the toxicity assessment of heavy metal as As and Cr in marine ecosystems.

Sruvey of Raw Silk Reeling Water in Korea (우리나라 제사용수의 실태 조사)

  • Sung, J. C.;Lee, D.;Lee, D. S.;Kho, C. S.;Choi, K. S.;Jou, W. H.
    • Journal of Sericultural and Entomological Science
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    • v.29 no.2
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    • pp.73-81
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    • 1987
  • This investigation was carried cut to obtain the reeling water conditions in Korea. The analyzed items of water were pH, colority, turbidity, acidity, alkalinity, solids electric conductibity hardness and heavy metal ions. About 40% of the reeling water were found to be agreeable, 30% were acceptable provided with some quality control and the others were out of acceptable range mainly based on the M-alkalinity, acidity, pH and total hardness. It was found that there was a following relationship between total hardness and electric conductibity with the relative correlation coefficient r=0.9145. y=15.967+0.22774x Where x, y are electric conductivity and total hardness respectively.

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A Study on Characteristics of Leachability and Compressive Strength of Incinerator Fly Ash, Cement and Waste Stone Powder by Solidification (산업폐기물 소각장 비산재의 시멘트 및 폐석분 고형화시 압축강도 및 용출특성)

  • Jung, Ho-Young;Kim, Young-Ju;Kim, Ji-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.5
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    • pp.560-566
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    • 2008
  • In this paper, the solidification behaviour and compressive strength of fly ash, cement, and waste stone powder were studied each separately and with addition of each in different proportions. And also, we assessed stabilizing ability of waste stone powder in cement which was added in fly ash. The particle size of waste stone powder was found smaller than the fly ash and cement particle sizes. Moreover, when mixing all(fly ash, cement, and waste stone powder) showed distinctive crystal structure, and improved stiffness. In case of mixing fly ash, cement and waste stone powder in different proportions, the compressive strength was exceeded to the predicted compressive strength of 10 kgf/cm$^2$. The XRD analysis showed high contents of CaO in fly ash and SiO$_2$ in case of waste stone powder sample. Heavy metal emission experiment showed the 3mg/L of Pb after 14 days of mixing 150 kg/m$^3$ of cement with the 80$\sim$100 kg/m$^3$ of waste stone powder, which is fulfilling the National Waste Management Policy.

Comparison and Analysis on Characteristics for recycling of Multifarious Food Waste (음식물쓰레기의 자원화를 위한 배출업종별 성상 및 특성의 비교분석)

  • Joo, Hung-Soo;Ryu, Jae-Young;Phae, Chae-Gun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.4
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    • pp.117-124
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    • 2001
  • This study was executed for utilizing it as basic data in appropriate recycling way and design by examining and analyzing various characteristics of food waste which is being discharged from various restaurant and apartment house. In general, there were differences in restaurants classification and Japanese restaurant showed big differences as compared to other restaurants. Vegetable had the highest composition and its contents had big difference according to seasons. In alien substances, oyster shells were the highest and restaurants showed high rate of alien substances than apartments, therefore it was required to divide them in advance. Salinity was the highest in Japanese restaurants and most restaurants had rate of up to 1%, so it was not appropriate for recycling. However, it was considered that if there is cleaning operation in the whole process, there might not be a problem. Feed Ingredient had 28% of fiber, 25% of protein, and 11% of fats. We analyzed noxious germs and heavy metal too. However microorganisms of etiological cause were not detected and each harmful material showed less values of control concentration. In the result of analysis of each characteristic, it is required to consider collection rate from restaurants and apartments and seasonal cause into design regarding recycling. And apartments are compatible to compost than feed and food waste from Chinese, flour restaurant and collective feeding facilities are compatible for feed, as it is evaluated.

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Sanitary and Nutritional Characterization of Commercial Kwamegi from Pacific Herring Clupea pallasii (시판 청어(Clupea pallasii ) 과메기의 위생 및 영양학적 특성)

  • Heu, Min-Soo;Park, Kwon-Hyun;Shin, Joon-Ho;Lee, Ji-Sun;Yeum, Dong-Min;Lee, Dong-Ho;Kim, Hyung-Jun;Kim, Jin-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.45 no.1
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    • pp.1-10
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    • 2012
  • The objective of this study was to investigate the sanitary and nutritional requirements for the industrialization of commercial kwamegi from Pacific herring Clupea pallasii (CK-PH). The proximate composition of CK-PH was 46.4-47.2% moisture, 24.7-25.6% crude protein, 23.6-25.2% crude lipid, and 2.5-2.9% ash, which differed significantly from that of commercial kwamegi from the Pacific saury Cololabis saira. According to the volatile basic nitrogen content, heavy metal content, and viable cell and coliform group counts, products K and F (prepared by a general process) maintained their freshness, whereas product T (treated with green tea extract) did not. Products K and F contained five types of biogenic amine: agmatine sulfate (2,596 and 2,067 mg/kg, respectively), putrescine dihydrochloride (8.5 and 8.0 mg/kg, respectively), cadaverine (3.7 and 3.9 mg/kg, respectively), histamine (17.0 and 12.4 mg/kg, respectively), and spermidine (8.7 and 8.0 mg/kg, respectively). Product T contained six amine types: tyramine (12.5 mg/kg), agmatine sulfate (2,723 mg/kg), putrescine dihydrochloride (29.4 mg/kg), cadaverine (321.6 mg/kg), histamine (45.3 mg/kg), and spermidine (13.6 mg/kg). The total amino acid content of product K (22.16/100g) was 5.8% lower than that of product F. The major amino acids of products K and F were aspartic acid, glutamic acid, leucine, and lysine. No difference was found in the fatty acid composition of products K and F. The major fatty acids in products K and F were 18:1n-9, 20:5n-3, and 22:6n-3. Based on the recommended daily dietary allowances for Koreans, the significant minerals in products K and F were calcium, phosphorus, and magnesium.

Alterations of Glutathione Peroxidase Patterns by Stressor Treatment in Rice Seedling Roots (스트레스 물질에 의한 벼 glutathione peroxidase 활성패턴 변화)

  • Kim, Yoon-Kyoung;Lee, Mi-Young
    • Applied Biological Chemistry
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    • v.48 no.1
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    • pp.53-59
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    • 2005
  • The effect of various stressors such as reductant ascorbic acid, signalling molecules (salicylic acid and methyl jasmonic acid), heavy metals $(NiCl_2,\;and\;MnSO_4)$ and NaCl on the glutathione peroxidase (GPX) activities and isoenzyme expression patterns were investigated in rice seedling roots. Total GPX activity increased according to the increase of ascorbic acid concentration. Prominent enhancement of GPX1 isozyme due to ascorbic acid contributed to the increase of total GPX activity. GPX showed different reactivity toward salicylic acid and methyl jasmonic acid. GPX activity increased at 0.1 mM salicylic acid, and then decreased thereafter. However, GPX increased gradually in a methyl jasmonic acid concentration-dependent manner, and 3 fold increase of GPX activity was found at 1 mM methyl jasmonic acid. Moreover, GPX1 isozyme increased according to the increase of salicylic acid, while GPX1 isozyme decreased according to the increase of methyl jasmonic acid. When metal ions were treated, GPX activity increased considerably according to the increase of $NiCl_2$ concentration, however, GPX activity increased about 2 fold at 0.5 mM $CuSO_4$ and then decreased. Enhancement of GPX1 isozyme contributed to the increase of total GPX activities in $NiCl_2-treated$ and $MnSO_4-treated$ rice seedlings. Total GPX activity increased 1.7 fold in response to 300 mM NaCl. Especially GPX2 isozyme showed gradual increase according to the increase of NaCl concentration.