• Title/Summary/Keyword: A중유

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A Study on Leaching of Vanadium and Nickel from Incineration Ash of Heavy Oil Fly Ash (중유회 소각재로부터 바나듐, 니켈 침출에 관한 기초적 연구)

  • 유연태;김병규;박경호;홍성웅
    • Resources Recycling
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    • v.4 no.3
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    • pp.32-39
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    • 1995
  • Thc purpose of this study is to develop the efficient process for recovering vanadium and nickel from the incineralionash of the oil fly ash. In this paper, the physical and chemical properties of the incineration ash was examined, and theleaching characteristics of the incineration ash were investigated by water leaching and sulEuric acid leaching tcsls. The incinerationash of oil fly ash was mainly consisted of oxldes such as V,09, V,O,, NaVO,, Ni,(VO,)Z, Fe,O,, CaSO,, SiO,.Thc waler leaching showed low extraction of metallic components, while the sulfunc acid lcaching with high temperahlreand pressure increased the extraction of vanadium and nickcl considerably. For instance, the exlraction rates of the metalllccomponents on the sulfuric acid leaching were 99% for V and 45% for Ni at 90$^{\circ}$C with pH 0.5 H,SO,, and were86% for V and 75% far Ni at ZOO"C(64 psi) with pH 1.0 H-SO,. with pH 1.0 H-SO,.

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A Selective Recovery Condition of Vanadium from Fly Ash Leach Liquor by UV-Spectrophotometry (UV 분광법을 이용한 중유회 용출액으로부터 바나듐의 선택적 회수 조건)

  • Kim, Da-Bin;Na, Su-Bin;Han, Hyea-Chul
    • Resources Recycling
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    • v.25 no.6
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    • pp.65-72
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    • 2016
  • We studied a selective recovery condition of vanadium (V) from FALL (Fly Ash Leach Liquor) produced at a fossil fuel power station using heavy oil. By applying a spectroscopy to quantify the V in a sample, we identified a concentration range V interfered by on presence of metals such as Ni, Fe Also, the optimal vanadium precipitation rate according to the amount of 5.0M $NH_3$ loaded to the sample, solution pH and stirring time. As a result of the experiment, the maximum selective recovery ratio of V was achieved to be higher than 91.5% when the stirring duration was less than 1 minute at pH 7.0, and $25^{\circ}C$.

Combustion Characteristics of Emulsified C-heavy Oil in Constant Volume Combustion with High Temperature and Pressure (고온.고압의 정적연소에서 C-중유 에멀젼 연료의 연소특성)

  • Yoo, Dong-Hoon;Nishida, Osami;Fujita, Hirotsugu;Lim, Jae-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.2
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    • pp.243-249
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    • 2010
  • The improvement of fuel economy and the reduction of diesel exhaust PM(Particulate Matter) and $NO_X$ have been successfully achieved by supplying diesel engines with emulsified diesel oil. However, combustion analysis of emulsified C-heavy oil is difficult because the combustion characteristics of emulsified C-heavy oil compared to other fuels have a special form. Therefore, these experimental researches have analyzed the combustion characteristics of emulsified C-heavy oil in a chamber with high pressure and temperature. The pressure and the rate of heat releases in a combustion chamber was decreased with increasing the water content and the ignition delay time was increased with increasing the water percent.

A Sugeestion of Rheological Performance Range for Manufacturing Mid-workability Concrete (중유동 콘크리트 제조를 위한 레올로지 성능 범위 제안)

  • Lee, Yu-Jeong;Lee, Young-Jun;Han, Dong-Yeop
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.4
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    • pp.305-318
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    • 2021
  • The aim of the research is providing the rheological performance range for manufacturing "mid-workability concrete". The mid-workability concrete means the normal strength range concrete mixture with high workability. Since there is not enough study or quantitative definitions on performance of the mid-workability concrete, in this research, the performance range for high workability of mid-workability concrete mixture using rheology. Because of the mixture characteristics of generally used normal strength concrete such as relatively high water-to-cement ratio and no SCMs, segregation of coarse aggregate should be prevent to achieve a successful high workability. From the experimental study in this research scope, 5 to 35 Pa.s of plastic viscosity was desirable to prevent segregation for nid-workability concrete, and general performance range with rheological parameters was provided.

Calculation of Breakeven Point for LNG-Heavy Oil Transfer of D Thermal Power Plant Considering $CO_2$ Emission Cost ($CO_2$ 배출비용을 감안한 D 발전소의 LNG-중유 연료교제 손익분기점 계산)

  • Jeong, Yeong-Ho;Lee, Sang-Joong;Lee, Gene-Kyu;Yang, Seong-Deog
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.10a
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    • pp.65-67
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    • 2008
  • Kyoto Protocol against global warming came into effect in Feb 2005. This paper presents a calculation $CO_2$ emission of D power plant for combusting LNG and heavy oil using the a, b, c coefficients obtained by the performance test. The authors also calculate the breakeven point of the fuel transfer from LNG to Oil considering recent $CO_2$ emission cost.

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The Demonstration Test Result of 100% Bio Heavy Oil Combustion at the 75 MWe Oil Fired Power Plant (75 MWe급 중유 발전소 보일러에 대한 바이오중유 100% 전소 실증 연소실험 결과)

  • Baek, Sehyun;Park, Hoyoung;Kim, Young Joo;Kim, Tae Hyung;Kim, Hyunhee;Ko, Sung Ho
    • Journal of the Korean Society of Combustion
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    • v.19 no.2
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    • pp.28-36
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    • 2014
  • Bio fuel oil combustion experiments were successfully demonstrated at the 75 MWe oil-fired power plant without major equipment retrofit and 100% bio-fuel oil combustion was possible without big problems. The experimental data error correction was conducted and numerical model-based analysis technique was applied for the evaluation of the results. Incase of bio fuel oil combustion, heat absorption of radiative heat transfer section was reduced while convection section has opposite trend. The furnace exit gas temperature tends to rise slightly. Environment emissions such as NOx and SOx concentrations showed a tendency to decrease during the bio fuel oil combustion period. On the other hand, boiler efficiency was slightly underestimated.

Study on the Liquefaction Characteristics of ABS Resin in a Low-Temperature Pyrolysis (ABS 수지의 저온 열분해에 의한 액화특성 연구)

  • Choi, Hong Jun;Jeong, Sang Mun;Lee, Bong-Hee
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.417-422
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    • 2011
  • The low temperature pyrolysis of ABS resin has been carried out in a batch reactor under the atmospheric pressure. The effect of the reaction temperature on the yield of pyrolytic oils has been determined in the present study. The oil products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of Ministry of Knowledge Economy. The conversion reaches 80% after 60 min at $500^{\circ}C$ in the pyrolysis of ABS resin. The amount of the final product was ranked as gas heavy oil > gasoline > gas oil > kerosen based on the yield. The yields of heavy oil and gas oil increase with an increase in the reaction time and temperature.

Analysis on the Energy Balance and Performance Variation of the Power Plant by using the Heavy Residual Oil (중질잔사유 적용시 발전플랜트의 에너지 수지 및 성능 변화 분석)

  • Park, Ho-Young;Kim, Tae-Hyung
    • Journal of Energy Engineering
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    • v.17 no.2
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    • pp.107-115
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    • 2008
  • The numerical analysis of energy and material balance, and plant performance has been carried out when applying the heavy residual oil instead of heavy oil to the existing heavy oil power station. The performance analysis model has been constructed for A heavy oil power station in Korea, and the modeling results were compared with the design data in order to ensure the validity of the model, and further compared with the plant operation data. With the heavy residual oil, the simulation gave 315 MW in power output, which is higher than that of the heavy oil combustion, but the plant efficiency turned out to be lower. The sensitivity analysis of heat rate for the changes in cooling water and ambient temperature, flue gas recirculation and power output has provided valuable information for the optimal operation of the power station.

Dispersing Properties of Heavy Crude Oil according to Dispersant Structures (중유용 분산제 구조에 따른 중유 분산 특성)

  • Son, Jeong-Mae;Kim, Nam-Kyun;Shin, Jihoon;Yang, Youngdo;Kim, Young-Wun
    • Tribology and Lubricants
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    • v.31 no.6
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    • pp.251-257
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    • 2015
  • Heavy oil production is receiving significant attention because of increased demands for thermal power generation systems of the diesel engine and boilers. However, asphaltene, which is a heavy oil components (6-8 wt%), reduces the heat efficiency of the fuels owing to its agglomerated sludge of asphaltene during the burning process. Therefore, for hassle-free operation, we should develop asphaltene dispersants to suppress the formation of the sludge. We prepare variable salt-type polymeric dispersants using poly(isobutenyl succinic anhydride) and poly(amine) through both condensation esterification and acid-base neutralization reactions, which we subsequently evaluate for dispersing performance, using Turbiscan measurement. Total acid number (TAN) and total base number (TBN) of 75Lec-25SynDis.2 composed of lecithin and the prepared polymeric salt having the ratio of 3 : 1 are 18.9 and 33.7 mg KOH/g, respectively, which are comparable to those of the commercial dispersants (15.8 and 26.5 mg KOH/g). We determine the initial turbidity observed for 15 min of the polymeric dispersant was determined with transmittance (%), which can be calculated to separability number (SN). The SN value of 75Lec-25SynDis.2 is close to zero, which is superior to that of commercial dispersants and lecithin (0.015 and 0.017).