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Effect of Metallic Tungsten Concentration on Resistance Switching Behavior of Sputtered W-doped NbOx Films

  • Lee, Gyu-Min;Kim, Jong-Gi;Na, Hui-Do;Son, Hyeon-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.288-288
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    • 2012
  • In this study, we investigated that the resistance switching characteristics of W-doped NbOx films with increasing W doping concentration. The W-doped NbOx based ReRAM devices with a TiN/W-doped NbOx/Pt/Ti/SiO2 were fabricated on Si substrates. The 50 nm thick W-doped NbOx films were deposited by reactive dc magnetron co-sputtering at $400^{\circ}C$ and oxygen partial pressure of 35%. Micro-structure of W-doped NbOx films and atomic concentration were investigated by XRD, TEM and XPS, respectively. The W-doped NbOx films showed set/reset resistance switching behavior at various W doping concentrations. The process voltage of set/reset is decreased and whereas the initial current level is increased with increasing W doping concentration in NbOx films. The change of resistance switching behavior depending on doping concentration was discussed in terms of concentration of metallic tungsten of oxygen of W-doped NbOx.

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Effect of the Ni Content and W Grain Size on the High Temperature Com-pressive Properties of W-Ni Activated Sintered Parts (Ni 함량과 W 결정립 크기에 따른 W-Ni 활성소결체의 고온압축 특성)

  • 박영삼;오승탁;양주환;김영도;문인형
    • Journal of Powder Materials
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    • v.11 no.2
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    • pp.149-157
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    • 2004
  • High temperature deformation behavior of activated sintered W powder compacts was investigated. The compression tests were carried out in the temperature range between 900 and 110$0^{\circ}C$ at the strain rate of $10^{-3}s^{-1}$. The sintered specimens of Ni-doped submicron W powder compacts showed decrease in W grain size with increasing the Ni content. As the result, the flow stress was significantly increased with increasing the Ni content. We obtained Ni-activated sintered W compacts with the relative density of 94 $\pm$ l%and the average grain size of less than 5${\mu}{\textrm}{m}$. A moderate true strain up to 0.60 was obtained without fracture even at 110$0^{\circ}C$ with the strain rate of $10^{-3}s^{-1}$ for the activated W compact despite adding the 1.0 wt%Ni to submicron W powder.

THE LOWER BOUNDS FOR THE HYPERBOLIC METRIC ON BLOCH REGIONS

  • An, Jong Su
    • Journal of the Chungcheong Mathematical Society
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    • v.20 no.3
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    • pp.203-210
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    • 2007
  • Let X be a hyperbolic region in the complex plane C such that the hyperbolic metrix ${\lambda}_X(w){\mid}dw{\mid}$ exists. Let $R(X)=sup\{{\delta}_X(w):w{\in}X\}$ where ${\delta}_X(w)$ is the euclidean distance from w to ${\partial}X$. Here ${\partial}X$ is the boundary of X. A hyperbolic region X is called a Bloch region if R(X) < ${\infty}$. In this paper, we obtain lower bounds for the hyperbolic metric on Bloch regions in terms of the distance to the boundary.

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Effect of Substituted Residue 139 and 258 on Structural Changes of Mutant Tryptophan Synthase Pro96→Leu α-Subunit (트립토판 중합효소 α 소단위 잔기 치환체 Pro96→Leu의 구조 변화에 영향을 미치는 139 및 258 잔기의 치환 효과)

  • Lee, Joo-Youn;Jeong, Jae-Kap;Shin, Hae-Ja;Lim, Woon-Ki
    • Journal of Life Science
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    • v.12 no.4
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    • pp.464-468
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    • 2002
  • Enzymatic activities and fluorescence spectroscopic properties of the double mutant proteins P96L/F139W, P96L/F258W and a triple mutant protein P96L/F139W/F258W of tryptophan synthase $\alpha$ subunit from Escherichia coli was examined to study tertiary and local structure changes around the tryptophan residues. The enzymatic activities of P96l./F139W and P96L/F258W were similar, but P96L/F139W/F258W had lower activity, as compared to wild type. The fluorescence intensities of double mutant, P96L/F139W and P96L/F258W, were decreased but that of a triple mutant, P96L/F139W/F258W, was increased when compared to wild type. The sum of the maximum fluorescence intensity (fluorescence intensity at the λ$_{max}$) for the double mutant proteins was not equal to the intensity seen in the triple mutant protein. The enzymatic activity and fluorescence data indicate that the replacement of Pro$^{96}$ longrightarrowLeu might affect on the stability of helix 8 and the loop located between strand 4 and helix4. The result suggests that the tertiary structure of triple mutant (P96L/F139W/F258W), being different from wild type, might have more compact residual structure at the vicinity of 139 and 258.8.

ℂ-VALUED FREE PROBABILITY ON A GRAPH VON NEUMANN ALGEBRA

  • Cho, Il-Woo
    • Journal of the Korean Mathematical Society
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    • v.47 no.3
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    • pp.601-631
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    • 2010
  • In [6] and [7], we introduced graph von Neumann algebras which are the (groupoid) crossed product algebras of von Neumann algebras and graph groupoids via groupoid actions. We showed that such crossed product algebras have the graph-depending amalgamated reduced free probabilistic properties. In this paper, we will consider a scalar-valued $W^*$-probability on a given graph von Neumann algebra. We show that a diagonal graph $W^*$-probability space (as a scalar-valued $W^*$-probability space) and a graph W¤-probability space (as an amalgamated $W^*$-probability space) are compatible. By this compatibility, we can find the relation between amalgamated free distributions and scalar-valued free distributions on a graph von Neumann algebra. Under this compatibility, we observe the scalar-valued freeness on a graph von Neumann algebra.

A Study on Estimation of End Bearing Capacity of a PHC-W Pile in Building Underground Additional Wall Using the PHC-W Earth Retaining Wall (PHC-W 흙막이 벽체를 이용한 건축물 지하증설벽체에서 PHC-W말뚝의 선단지지력 산정에 관한 연구)

  • Kim, Chea Min;Yun, Daehee;Lee, Chang Uk;Johannes, Jeanette Odelia;Kim, Sung Su;Choi, Yongkyu
    • Journal of the Korean Geotechnical Society
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    • v.35 no.3
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    • pp.5-16
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    • 2019
  • With the recent concentration of urban populations, the constructions of large structures are increasing, along with the development of foundations for large structures. PHC Piles have been used in many structures ever since Japanese introduced the technology at the end of the 20th century. Recently, many studies on the use of the PHC Pile have been carried out as earth retaining using the merits of PHC piles. In this study, static axial compression tests were conducted on the PHC-W piles constructed as column-type in building underground additional wall using the PHC-W earth retaining wall. The end bearing capacity of pile was calculated using the axial load transfer measurement that was obtained from the static axial compression test result. Since end bearing capacity of the PHC-W pile embedded in weathered rock showed a different behaviour from the conventional PHC pile, the calculation method of end bearing capacity for column-type PHC-W piles would be proposed. The unit ultimate end bearing equation proposed for single and group PHC-W pile embedded in weathered rock is $q_b=13.3N_b$ and $q_b=6.8N_b$.

A Novel Trp-rich Model Antimicrobial Peptoid with Increased Protease Stability

  • Bang, Jeong-Kyu;Nan, Yong-Hai;Lee, Eun-Kyu;Shin, Song-Yub
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2509-2513
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    • 2010
  • In order to increase protease stability of a novel Trp-rich model antimicrobial peptide, $K_6L_2W_3$ (KLWKKWKKWLK-$NH_2$)and investigate the effect of L-amino acid to peptoid residue conversion on biological functions, we synthesized its antimicrobial peptoid, $k_6l_2w_3$. Peptoid $k_6l_2w_3$ had similar bacterial selectivity compared to peptide $k_66L_2W_3$. The bactericidal rate of $k_6l_2w_3$ was somewhat slower than that of $K_6L_2W_3$. Peptoid $k_6l_2w_3$ exhibited very little dye leakage from bacterial outer-membrane mimicking PE/PG liposomes, as observed in $K_6L_2W_3$, indicating that the major target site of $K_6L_2W_3$ and $k_6l_2w_3$ may be not the cell membrane but the cytoplasm of bacteria. Trypsin treatment of $K_6L_2W_3$ completely abolished antimicrobial activities against Escherichia coli and Staphylococcus aureus. In contrast, the antimicrobial activity of $k_6l_2w_3$ was completely preserved after trypsin treatment. Taken together, our results suggested that antimicrobial peptoid $k_6l_2w_3$ can potentially serves as a promising therapeutic agent for the treatment of microbial infection.

Reduction in the contents of acetaldehyde, methanol and fusel alcohols in the Muscat Bailey A wine fermented by Korean indigenous sugar-tolerant yeasts Saccharomyces cerevisiae S13 and D8 (토착형 아황산 및 당 내성 효모 Saccharomyces cerevisiae S13과 D8에 의한 Muscat Bailey A 포도주의 아세트알데히드, 메탄올 및 고급알코올의 감소 효과)

  • Kim, Mi-Sun;Park, Heui-Dong
    • Food Science and Preservation
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    • v.21 no.6
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    • pp.851-858
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    • 2014
  • Muscat Bailey A (MBA) wine was fermented using the indigenous Korean Saccahromyces cerevisiae strains S13 and D8, and the fermentation characteristics were compared with those of S. cerevisiae W-3, an industrial wine yeast. The strains S13 and D8 showed delayed alcohol fermentation compared with the W-3 strain, but the final alcohol contents of the S13 and D8 wines after fermentation were similar to those of the W-3 wine. The S13 wine showed significantly lower malic-acid content than the W-3 wine, but the D8 wine showed a similar level. Both the wines fermented using the S13 and D8 strains showed significantly lower acetaldehyde, methanol, and fusel oil contents, including n-propanol, iso-butyl alcohol, and iso-amyl alcohol, compared to the W-3 wine. Especially, the methanol content was 98.6 mg/L in the S13 wine and 112.0 mg/L in the D8 wine, which were much lower than 192.8 mg/L in the W-3 wine. The S13 wine obtained the highest score in terms of color among the three wines in the sensory evaluation, with lower Hunter's L, a, and b values compared to the W-3 wine.