• Journal of Radiation Industry
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• v.17 no.1
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• pp.69-73
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• 2023

Commercially used organic scintillation materials (1,4 di[2-(5phenyloxazolyl)] benzene) have low solubility in solvents and a wide emission energy range, which causes a decrease in detection efficiency. In this study, an organic liquid scintillator with improved detection efficiency was developed using 7-Diethylamino-4-methylcoumarin material to compensate for the disadvantages of existing organic scintillation detectors. And to evaluate the applicability of radiation measurement, the performance of a commercial plastic detector was compared. As a result of analyzing the ⁶⁰Co detection characteristics by applying 7-Diethylamino-4-methylcoumarin as an alternative to 1,4 di[2-(5phenyloxazolyl)] benzene, the detection efficiency was improved around 2% compared with commercial scintillator when the 7-Diethylamino-4-methylcoumarin content was 0.04 wt%. Based on the results of this study, the possibility of improving detection efficiency through scintillator material modification was confirmed. In addition, since it is possible to discriminate nuclide through the spectrum correction algorithm, it will be possible to inspect and classify various decommissioning wastes generated during the decommissioning process.

• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1378-1382
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• 2013

We have investigated the complex forming behavior of cucurbit[6]urils(CB6) and cucurbit[7]urils(CB7) with 7-diethylamino-4-methylcoumarin(C460) in water. The electronic absorption maximum of C460 shows bathochromic shift with the addition of CB7 and fluorescence intensity is greatly increased, while CB6 has no noticeable effects on the spectroscopic properties of C460. It is noted that CB7 interacts more strongly with C460 than CB6 does. Fluorescence lifetime also significantly increased for the CB7 complex, which is attributed to reduced polarity surrounding C460 and/or C460 being in a restricted environment. The stoichiometry for the complex formation determined from the fluorescence titration measurement indicates that 2:1 complex in which two CB7 molecules bind to C460 is formed. Thus, two step equilibrium processes are suggested for the complex formation and the binding constants are estimated. The semi-empirical electronic structures calculations indicate that C460 is not included in the CB7 cavity but interacts noncovalently with the portal carbonyls of CB7.