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3차원 Zinc-Phosphate 배위 고분자: $Zn_3(PO_4)_2(H_2O)$의 수열합성 및 구조 (A Three-Dimensional Zinc-Phosphate Coordination Polymer: Hydrothermal Synthesis and Structure of $Zn_3(PO_4)_2(H_2O)$)

  • Dongwon Min;Ji-Young Back;Hyun Sue Hoe;Soon Won Lee
    • 한국결정학회지
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    • 제12권3호
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    • pp.145-149
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    • 2001
  • Pyrazine 존재 하에서, Zn(NO₃)₂·존재 하에서 . Zn(NO,)7·6H₂O와 K₂HPO₄가 수열반응하여 Zn₃(PO₄)₂(H₂O) (1)실험식을 갖는 3차원 zinc-phosphate 배위 고분자가 합성되었다. 화합물 1의 구조가 IR 분광법 및 X-ray 회절법으로 규명되었다. 화합물 1의 결정학적 자자료: 단사정계 공간군 P2₁/c, a=8.750(1)Å, b=4.901(1)Å, c=16.759(3)Å, β=94.98(2)°, Z=4, R(wR₂)=0.0332(0.0927).

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Effect of Kaolin on Arsenic Accumulation in Rice Plants (Oryza Sativa L.) Grown in Arsenic Contaminated Soils

  • Koonsom, Titima;Inthorn, Duangrat;Sreesai, Siranee;Thiravetyan, Paitip
    • Environmental Engineering Research
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    • 제19권3호
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    • pp.241-245
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    • 2014
  • The As accumulation in part of roots, shoots, husks and grains of rice plants was significantly decreased with the increasing dosage of kaolin addition from 0.5% to 10% w/w. Kaolin addition could reduce As accumulation in rice plants, which mainly could be attributed to the formation of stable crystalline Al oxides bound As that decreased the available As in soil with decreased As accumulation in rice plants. The pH values of the soils did not change significantly when amended with kaolin. The pH values of the soils was neural that proper to adsorb of arsenic with $Al_2O_3$. Arsenic tends to adsorb with $Al_2O_3$ at acid neutral pH and with desorbing at alkaline pH. The dry weight of rice plant was significantly increased with the increasing dosage of kaolin addition from 2.5% to 10% w/w. The highest dry weight of rice plants was 6.67 g/pot achieved at kaolin addition of 10% w/w with about 13% increasing over the control, which was probably attributed to the highest As concentration formation with kaolin at this dosage. The results of this study indicated that kaolin has the potential to reduce As accumulation in rice plants and enhance the dry weight of rice plants.

석임을 첨가한 탁주의 품질 특성 (Quality Characteristics of Takju added with Seokim)

  • 조재철;이상정;강병남
    • 한국조리학회지
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    • 제19권1호
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    • pp.244-251
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    • 2013
  • 본 연구는 찹쌀에 석임을 각각 0, 2, 4, 그리고 6%를 첨가하여, 전통방식으로 탁주를 제조한 후 발효기간 동안 이화학적 특성의 변화를 측정하였다. 탁주 발효과정 중 pH는 담금 직후부터 1일까지 급격히 감소하는 경향을 나타냈으며, 총산은 급격히 증가하였다. pH가 감소할수록 총산은 증가하는 경향을 나타났다. 당도는 발효 직후부터 급격히 증가하였고, 2일부터 7일까지 감소하는 경향을 보였다. 환원당은 발효 2일까지 증가하여 석임 0%가 0.22 g/mL로 다른 시료구보다 높았으며, 발효 2일부터 7일까지 감소하는 경향을 보였다. 알코올은 대조구와 모든 시험구가 최종일까지 알코올 함량이 증가된 것으로 나타났다. 석임 첨가량에 따른 알코올 함량은 석임첨가량이 많을수록 높게 나타내었으며, 석임 0, 2, 4 그리고 6% 첨가 탁주는 발효 7일째 10.3, 10.9, 12.1 그리고 12.2%의 최대 알코올 함량을 나타났다. 석임 4% 이상 첨가구에서는 12.2%로 차이가 미비했다. 탁주 제조 시 석임 첨가량이 4%이면 알코올 생성을 높여주고 발효과정 중 좋은 환경을 만들어주며 탁주의 보존성 증대 및 주질 향상을 높여 준다고 본다.

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멸치스낵제품의 품질비교 및 저장안정성 (Comparisons in Food Quality of Anchovy Snacks and Its Changes during Storage)

  • 이응호;김진수;안창범;주동식;이승원;임치원;박희열
    • 한국수산과학회지
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    • 제22권2호
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    • pp.49-58
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    • 1989
  • 멸치를 보다 효율적으로 식량화하기 위한 일련의 연구로서 4가지 조건으로서 가공한 멸치스낵의 품질비교 및 저장안정성에 대하여 실험하였다. 마쇄한 멸치에 부원료를 첨가하고, 어취개선을 위하여 향신료를 첨가한 후 저장중 문제가 되는 지질산패를 방지하기 위하여 sodium erythorbate를 첨가한 다음, 소금튀김하여 제조한 제품이 가장 좋았다. 이런 조건하에서 제조된 스낵제품은 제조직후 수분함양이 $6.5\%$, 조단백질 $8.7\%$, 조지방 $28.1\%$, 탄수화물이 $51.6\%$, pH가 7.6이었으며, 저장중수분함양, 수분활성, pH, 휘발성염기질소 및 구성 아미노산의 변화는 거의 없었다. sodium erythorbate를 첨가함으로서 저장중 제품지질의 산패를 다소 억제시킬 수 있었다. 원료어의 주요구성지방산은 16:0, 22:6, 20:5 및 18:1 이었고, 제품의 경우는 18:1, 16:0 및 18:2였는데 이러한 차이는 튀김유인 팜유에 기인한다고 볼 수 있다. 저장중제품의 색조는 L값은 감소하였고 a값, b값 및 ${\Delta}E$ 값은 증가하였다. 무기질, 아미노산조성 및 관능검사결과로 미루어 보아 멸치스낵제품은 쓴맛과 튀김공정후에 다소의 지질을 제거한다면 시판스낵제품과 비교하여 품질면에서 손색이 없으면서 영양성분의 균형이 잡힌 우수한 스낵식품이라는 결론을 얻었다.

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폴리비닐알코올 $H_6P_2W_{18}O_{62}$ hybrid membranes의 광색 및 열적 특성 (Photochromic and thermal properties of poly (Vinyl alcohol)/ $H_6P_2W_{18}O_{62}$ hybrid membranes)

  • Jian Gong;Kim, Hak-Yong;Lee, Duck-Rae;Bin Ding;Xiangdan Li
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2002년도 봄 학술발표회 논문집
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    • pp.459-461
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    • 2002
  • A new class of materials based on organic and inorganic species combined at a molecule level has obtained more attention recently[1]. HPA(heteropolyacid) shows unmatched applied perspective in terms of synthesis chemistry, analysis chemistry, biology, medicine and materials science[2]. As a potential photochemical material, the hybrid system of HPA and polymer has been investigated. However, the design and synthesis of heteropolyacid-based hybrids, which are at the forefront of the materials chemistry research, is still in its infancy. (omitted)

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Surface pH Of The Northeastern Pacific Ocean

  • Park, Kilho
    • 한국해양학회지
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    • 제1권1_2호
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    • pp.1-6
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    • 1966
  • A latitudinal, differential pH distribution is observed in the Northeastern Pacific Ocean with a pH range of 8.15 at high latitude (42 N) to 8.29 at low latitude (23 N). These pH values are generally greater than the calculated equilibrium pH with respect to atmospheric carbon dioxide. If we assume that the calculated equilibrium pH values ae valid, then the surface waters are undersaturated with respect to the atmospheric carbon dioxide during April to June 1966. A high surface pH value of about 8.26 was observed immediately south of the SubarcticBoundary zone near 170 W. This value differs from the equilibration pH by as much as 0.1 unit.

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미성숙 쥐에 이식한 뇌하수체의 경시별제거가 배란유도와 Estrogen 및 Progesterone수준에 미치는 영향 (Effects of Removal Times of Transplanted Pituitary Gland on Induction of Ovulation and Levels of Estrogen and Progesterone in Immature Rats)

  • 이장헌;김영훈;이완
    • 한국수정란이식학회지
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    • 제2권1호
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    • pp.36-46
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    • 1987
  • The present work was designed to understand the mechanism of superovuiation and the cause of early embryo loss and Implantation failure in the superovulating immature female rats which were elaborated by a pituitary gland transplantation. A pituitary gland obtained from the orchidectomized rats was transplanted under the right kidney capsule of 28 day old female rats (PGT group) on the starting day of experiment which was designated as Day 2. The grafted pituitary glands were removed at 6h (RPGT 6h group), 12h (RPGT 12hgroup) and 24h (RPGT 24h group) after the transplantation. Control rats were treated with 41U PMSG on Day 2 (PMSG group). The estrous cycle and the levels of plasma progesterone and estradiol-17$\beta$ were observed on Day 0, Day 5, respectively. The implantation sites, the weights of ovary and uterus, and the number of corpora lutea were examined in all group on Day 8. The resuft obtained were summarized as follows: 1. The percentages of the number of the rats in proestrus and estrus were 93.0%, 82.6%, 0%, 90.7% and 89.5% in PMSG, PGT, RPGT6h, RPGT12h and RPGT24h group, respectively. The synchronization of estrus cycle was dchieved in all groups. 2. The mating rates of each group were 80.2, 75.0, 0, 56.4, 57.8% in PMSG, PGT, RPGT6h, RPGT12h, RPGT24h group, respectively. 3. The numbers of copora lutea on Day 8 were 47.1 i 4.9, 18.1 $\pm$0.5, 14.1 i 0.3 and 8.9 $\pm$ 0.3 in PGT, RPGT24h, RPGTl2h and PMSG group, respectively. There were signIficantly difference between all groups (P<0.05). 4. The numbers of implantation sites (18.1 +- 4.0) in PGT group on Day 8 were higher than those of PMSG (8.5 $\pm$ 2.5), RPGT 12h (9.8 i 0.2) and RPGT 24h group (10.8 i 0.2) (P<0.05). 5. The ovarlan weights in PGT (95.2 $\pm$ 14.3mgIlOOg BW), RPGT 12h (51.7 $\pm$ 0.6mgIlOOg BW), and RPGT24h (57.9 $\pm$ 0.9mg/l00g 8W) groups were significantly higher than those of PMSG group (30.4 $\pm$7.4mg/l00g BW) (P<0.05). 6. The uterine weights in PMSG (672.4 $\pm$ 4.7mg/l00g 8W), and PGT (660.7 $\pm$7.8mg/l00g BW) groupswere greater than those of RPGT 12h (403.0 $\pm$ 1.lmg/lOOg BW) and RPGT 24h (490.1 $\pm$ 0.9mg/l00g BW) group (P<0.05). 7. The plasma progesterone levels in PGT groups (15 lng/ml) on Day 5 were higher than those of PMSG (83ng/ml), RPGT 12h (S7ng/ml), RPGT24h (8lng/ml) group (P<0.05). 8. The plasma estradiol-17$\beta$ levels in PMSG group (lBSpg/ml) on Day S were higher than those of RPGT 24h (l3pg/ml) group (P<0.05). But estradiol-17$\beta$ levels in PGT and RPGT 12h group were too low to discuss.

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과산화수소를 이용한 몰리브덴(Mo) 용해 반응과 이에대한 청정기술 개발에 관한 연구 (A clean technology development and the molybdenum dissolution reaction with hydrogen peroxide)

  • 김재우;강수정;김남기
    • 환경위생공학
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    • 제18권2호
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    • pp.1-8
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    • 2003
  • The advantages of hydrogen peroxide dissolution method were no discharge of noxious matter when dissolution of molybdenum wire which used as the center supporter, reactions occur in room temperature. The results were as follows : 1. In the FL/10-A type: Dissolution-reaction Time was 50Min., C.R.(Coil resistance) was $9.27{\Omega}(St.{\;}:{\;}9.2{\pm}0.22{\Omega})$, P.W.(Piece weight) was $10.59mg(St.{\;}:{\;}10.5{\pm}0.26mg)$. In the FL/15-D type: Dissolution-reaction Time was 55Min., C.R. was $6.39{\Omega}(St.{\;}:{\;}6.38{\pm}0.02{\Omega})$, P.W. was $16.7mg(St.{\;}:{\;}16.5{\pm}0.3mg)$. In the FL/20-H type: Dissolution-reaction Time was 45Min., C.R. was $4.7{\Omega}(St.{\;}:{\;}4.6{\pm}0.3{\Omega})$, P.W. was $20.8mg(St.{\;}:{\;}20{\pm}1.5mg)$. In the FL/20-C type: Dissolution-reaction Time was 60Min., C.R. was $4.5{\Omega}(St.{\;}:{\;}4.6{\pm}0.3{\Omega})$, P.W. was $19.8mg(St.{\;}:{\;}19{\pm}1.0mg)$. 2. In the GLS-230/40-B type: Dissolutiona-reaction Time was 45Min., C.R. was $105.1{\Omega}(St.{\;}:{\;}104{\pm}2.6{\Omega})$, P.W was $6.37mg(St.{\;}:{\;}6.3{\pm}0.16mg)$. In the GLS-230/60-F type: Dissolution- reaction Time was 45Min., C.R. was $65.92{\Omega}(St.{\;}:{\;}65{\pm}1.62{\Omega})$, P.W. was $11.91mg(St.{\;}:{\;}11.8{\pm}0.29mg)$.

칼슘 용해도에 미치는 식포의 영향 (Effect of Vinegar on the Solubility of Calcium)

  • 장세영;백창호;정규호;박난영;정용진
    • 한국식품저장유통학회지
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    • 제12권2호
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    • pp.112-116
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    • 2005
  • 본 연구에서는 시판되는 3종의 칼슘 용해에 미치는 식초의 영향을 조사하였다. 식초의 초기총산에 따른 영향을 조사한 결과 초기총산과 칼슘첨가량이 높을수록 용해 후 pH와 잔사량은 낮게, 총산과 칼슘함량은 높게 나타났다. 식초 함량에 따른 영향을 조사한 결과 식초함량이 높을수록 pH는 낮게 총산은 높게 나타났으며, 칼슘함량은 해조칼슘과 탄산칼슘에서 높게 나타났다. 식초를 이용하여 해조칼슘과 탄산칼슘의 포화농도를 조사한 결과 해조칼슘은 $7.0\%$ (w/v), 탄산칼슘은 $6.0\%$(w/v) 농도이며 이때 칼슘함량은 $2,234\;mg\%$$2,490\;mg\%$로 나타났다.