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Study of Polytriazine Derivatives having High Refrative Index (높은 굴절률을 가지는 Polytriazine 유도체에 대한 연구)

  • Lee, Y.H.;Kim, J.J.;Ha, T.W.;Cha, J.W.
    • Journal of Korean Ophthalmic Optics Society
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    • v.8 no.2
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    • pp.31-35
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    • 2003
  • Several poly(6-dialkylamino-1,3,5-triazine-2,4-dithioxylene) derivatives were synthesized by the polycondensation of 6-dialkylamino-1,3,5-triazine-2.4-dithiol with m- and p-dibromide xylene in a cetyltrimethyl ammonium bromide at $70^{\circ}C$ for 24h. The synthesized derivatives had refractive Indexes of 1.580~1.697 and had molar absorptivity of 97~196.6. In these derivatives, we knew that they are a polymer having high refraction indexes without double refraction because they contain triazine rings and sulfur atoms with high electron density.

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Electricity Production from Fe[III]-reducing Bacterium Geobacter sulfurreducens in Microbial Fuel Cell (미생물 연료전지에서 Fe[III] 환원 미생물 Geobacter sulfurreducens를 이용한 전기 생산)

  • Lee, Yu-Jin;Oh, You-Kwan;Kim, Mi-Sun
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.6
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    • pp.498-504
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    • 2008
  • Metal-reducing bacterium, Geobacter sulfurreducens is available for mediator-less microbial fuel cell (MFC) because it has biological nanowires(pili) which transfer electrons to outside the cell. In this study, in the anode chamber of the MFC system using G. sulfurreducens, the concentrations of NaCl, sodium phosphate and sodium bicarbonate as electrolytes were mainly optimized for the generation of electricity from acetate. 0.4%(w/v) NaClO and 0.5M $H_2SO_4$ could be utilized for the sterilization of acrylic plates and proton exchange membrane (major construction materials of the MFC reactor), respectively. When NaCl concentration in anode phosphate buffer increased from 5 to 50 mM, power density increased from 6 to $20\;mW/m^2$. However, with increasing sodium phosphate buffer concentration from 5 to 50 mM, power density significantly decreased from 18 to $1\;mW/m^2$. Twenty-four mM sodium bicarbonate did not affect electricity generation as well as pH under 50 mM phosphate buffer condition. Optimized anode chamber of MFC using G. sulfurreducens generated relatively high power density ($20\;mW/m^2$) with the maximum coulombic efficiency (41.3%).

Synthesis of Titanium Dioxides by Microemulsion Method and Their Photocatalytic Degradation of p-Nitrophenol (마이크로에멀젼법에 의한 이산화티탄의 합성 및 p-Nitrophenol의 광촉매 분해반응)

  • Jung, Won Young;Han, Yeon Hee;Lee, Gun-Dae;Park, Seong Soo;Hong, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.351-356
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    • 2008
  • Titania nanoparticles were prepared by controlled hydrolysis of titanium tetraisopropoxide (TTIP) in water-in-oil (W/O) and microemulsion stabilized with a nonionic surfactant, N P-10 (Polyoxyethylene Nonylphenol Ether: $C_9H_{19}C_6H_4(OCH_2CH_2)_{10}OH$)). The nanosized particles prepared in W/O microemulsion were characterized by FT-IR, TEM, XRD, TGA, and DTA. In addition, the photocatalytic degradation of p-nitrophenol has been studied by using a batch reactor in the presence of UV light in order to compare the photocatalytic activity of prepared nanosized titania. The nanaosized titania particles calcined at $300{\sim}600^{\circ}C$ showed an anatase structure, but it transformed to a rutile phase above $700^{\circ}C$ of calacination temperature. With an increase of $W_o$ ratio, the crystallite size increased but photocalytic activity decreased. The titania synthesized at $W_o=5$, R = 2, and calcined at $400{\sim}500^{\circ}C$ showed the highest activity on the photocatalytic degradation of p-nitrophenol.

Hydrogen Gas Production from Biogas Reforming using Plasmatron (플라즈마트론을 이용한 바이오가스 개질로부터 수소생산)

  • Kim, Seong Cheon;Chun, Young Nam
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.528-534
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    • 2006
  • The purpose of this paper is to investigate the optimal operating condition for the hydrogen production by biogas reforming using the plasmatron induced thermal plasma. The component ratio of biogas($CH_4/CO_2$) produced by anaerobic digestion reactor were 1.03, 1.28, 2.12, respectively. And the reforming experiment was performed. To improve hydrogen production and methane conversion rates, parametric screening studies were conducted, in which there are the variations of biogas flow ratio(biogas/TFR: total flow rate), vapor flow ratio($H_2O/TFR$: total flow rate) and input power. When the variations of biogas flow ratio, vapor flow ratio and input power were 0.32~0.37, 0.36~0.42, and 8 kW, respectively, the methance conversion reached its optimal operating condition, or 81.3~89.6%. Under the condition mentioned above, the wet basis concentrations of the synthetic gas were H2 27.11~40.23%, CO 14.31~18.61%. The hydrogen yield and the conversion rate of energy were 40.6~61%, 30.5~54.4%, respectively, the ratio of hydrogen to carbon monoxide($H_2/CO$) was 1.89~2.16.

Studies on Mycelial Growth and Artificial Cultivation of Pleurotus eryngii (큰느타리버섯(Pleurotus eryngii)의 균사배양 및 인공재배에 관한 연구)

  • Kang, Mi-Sun;Kang, Tae-Su;Kang, An-Seok;Shon, Hyeong-Rak;Sung, Jae-Mo
    • The Korean Journal of Mycology
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    • v.28 no.2
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    • pp.73-80
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    • 2000
  • This study was carried out to investigate the optimal mycelial growth and an artificial cultivation conditions of Pleurotus eryngii. The optimal medium for the mycelial growth and density was MYPA medium. The optimal temperature and pH for the mycelial growth were $25^{\circ}C$ and 6.0, respectively. The modified optimal medium composition were obtained to be soluble starch 3%(w/v), malt extract 0.25%(w/v), yeast extract 0.25%(w/v) and $CaCl_2{\cdot}2H_2O$ 0.05% (w/v). From the results of experiment on the nutritional requirements, the modified optimal medium was higher than MYP medium in mycelial production and growth yield (Yx/s) of Pleurotus eryngii. The optimal sawdust species of solid culture for the mycelial growth and density was Quercus spp. The optimal concentration of additives (rice bran and wheat bran) and moisture content for the mycelial growth were about 30%(v/v) and 70%(v/v), respectively. On the other hand, the optimal concentration of additives for the production of fruiting body was 20%(v/v) of rice bran.

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Production of Agarooligosaccharides using of Agarase from marine Bacterium Bacillus cereus ASK202 (해양세균 Bacillus cereus ASK202가 생산하는 Agarase를 이용한 Agarooligosaccharides의 생산)

  • 김봉조;하순득;임동중;송창문;공재열
    • KSBB Journal
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    • v.13 no.5
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    • pp.524-529
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    • 1998
  • An agarase was partially purified from the culture broth of marine bacterium Bacillus cereus ASK202. Optimal pH and temperature of this agarase were found to be 7.0 and 40$^{\circ}C$, respectively. The maximum productivity of agarooligosaccharides was obtained from 0.3 %(w/v) agar by using of 1 unit agarase. As the results of TLC and HPLC analysis, these oilgosaccharides consisted of neoagarobiose, neoagarotetraose and neoagarohexaose. Under the optimal reaction conditions, 77.5 %(w/v) neoagarobiose and 6.2 %(w/v) neoagarotetraose were produced from agar and the conversion yield of total agarooligosaccharides was 83.7 %(w/v) after for 2 h reaction at 40$^{\circ}C$.

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Effect of Duct Aspect Ratios on Pressure Drop in a Rotating Two-Pass Duct (덕트 종횡비가 회전덕트 내 압력강하에 미치는 영향)

  • Kim Kyung-Min;Lee Dong-Hyun;Cho Hyung-Hee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.6 s.249
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    • pp.505-513
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    • 2006
  • The pressure drop characteristics in a rotating two-pass duct with rib turbulators are investigated in the present study. Three ducts of different aspect ratios (W/H=0.5, 1.0 and 2.0) are employed with a fixed hydraulic diameter ($D_h$) of 26.7 mm. $90^{\circ}$-rib turbulators with $1.5mm{\times}1.5mm$ cross-section are attached on the leading and trailing surfaces. The pitch-to-rib height ratio (p/e) is 1.0. The distance between the tip of the divider and the outer wall of the duct is 1.0 W. The thickness of divider wall is 6.0 mm o. 0.225 $D_h$. The Reynolds number (Re) based on the hydraulic diameter is kept constant at 10,000 and the .elation number (Ro) is varied from 0.0 to 0.2. As duct aspect ratio increases, high friction factor ratios show in overall regions. The reason is that the rib height-to-duct height ratio (e/H) increases, but the divider wall thickness-to-duct width ($t_d/W$) decreases. The rotation of duct produces pressure drop discrepancy between the leading and trailing surfaces. However, the pressure drop discrepancy of the high duct aspect ratio (AR=2.0) is smaller than that of the low duct aspect ratio (AR=0.5) due to the decrement of duct hight (H).

Chemical Characteristics and Physiological Activities of Plums (Oishiwase and Formosa) (자두의 화학적 특성 및 생리활성)

  • Jung, Gi-Tai;Ju, In-Ok;Choi, Dong-Geun;Jeong, Jong-Sung;Ryu, Jeong;Ko, Bok-Rai;Choi, Joung-Sik
    • Korean Journal of Food Science and Technology
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    • v.37 no.5
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    • pp.816-821
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    • 2005
  • Chemical characteristics and physiological activities of plums (Oishiwase and Formosa) were evaluated. Proximate composition of plums consisted of (w/w) 1.9-6.2% protein, 2.3-7.1% fat, 3.5-4.1% ash, and 84,1-88,7% carbohydrate. Organic acids, such as oxalic, malic, succinic, and acetic acids were detected, except in Oishiwse acetic acid was not detected. Free sugars consisted of sorbitol, glucose, fructose and sucrose. Total fiber and total phenolics compounds of plum rind were higher than those of flesh. Electron-donating abilities of rind ethanol extracts were higher than those of BHA and tocopherol, and were twofold higher than those of flesh extracts. Nitrite-scavenging abilities of rind and flesh extracts were significantly higher (over 97%) at pH 1.2 and 3.0. Tyrosinase-inhibitory activities ranged 88.5 to 100%. SOD-like activities of all extracts were weak at 22.7 to 27.2%.

Design and Fabrication of Quadruple Band Antenna with DGS (DGS를 적용한 4중대역 안테나의 설계 및 제작)

  • Kim, Min-Jae;Choi, Tea-Il;Choi, Young-Kyu;Yoon, Joong-Han
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.1
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    • pp.31-38
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    • 2020
  • In this paper, we propose a quadruple band antenna for GPS/WLAN/WiMAX application. The proposed antenna has quadruple band characteristics by considering the interconnection of four strip lines and DGS on the ground place. The total substrate size is 20.0 mm (W1) ⨯27.0 mm (L1), thickness (h) 1.0 mm, and the dielectric constant is 4.4, which is made of 20.0 mm (W2)⨯ 27.0 mm (L8 + L6+ L10) antenna size on the FR-4 substrate. From the fabrication and measurement results, bandwidths of 60 MHz (1.525 to 1.585 GHz) bandwidth for GPS band, 825 MHz (3.31 to 4.135 GHz) bandwidth for WiMAX band and 480 MHz (2.395 to 2.975 GHz) and 385 MHz (5.10 to 5.485 GHz) bandwidth for WLAN band were obtained on the basis of -10 dB. Also, gain and radiation pattern characteristics are measured and shown in the frequency of triple band as required.